The rapid convergence of precise point positioning real-time kinematics (PPP-RTK) with centimeter-level accuracy is of utmost importance for many applications. One way of accelerating this convergence is to explore the use of ionospheric models and multiple global navigation satellite system (GNSS) observations, e.g., Global Positioning System (GPS) and Galileo Satellite Navigation System (Galileo) observations. Because the temporal and spatial variations of the ionosphere are significant, convergence analysis of PPP-RTK should be investigated in networks with different scales, especially networks with large differences in their scales. This study describes the convergence performance of PPP-RTK using GPS/Galileo observations derived from networks with different scales under medium ionospheric conditions. Slant ionospheric corrections were first estimated from the reference network and then imported as virtual observations to enhance the convergence performance of PPP-RTK at the user interface. The results show that for the 165-km reference site spacing, the portions of single-differenced (SD) ionospheric residuals within 0.3 total electron content units (TECU) were 85.2% and 81.7% for the GPS and Galileo observations, respectively. Considering the 90th percentile of horizontal position errors, the PPP-RTK convergence time within the network with 165-km spacing was shortened from 2.5 min for GPS-only observations to 2.0 min for integrated GPS + Galileo observations. For the network of about 50 km, the proportions of the SD ionospheric residuals of the GPS and Galileo constellation within 0.3 TECU were 95.9% and 82.8%, respectively. The PPP-RTK convergence time of the 90th percentile horizontal positioning errors based on GPS-only observations was 2.0 min but 1.5 min based on integrated GPS + Galileo observations. Using GPS and Galileo observations, the convergence time could be reduced by 25% for the network with 50-km spacing. Our results suggest that the convergence time of PPP-RTK depends on the scale of the reference network and becomes shorter as the scale of the network decreases. Compared with the GPS-only PPP-RTK, the GPS/Galileo PPP-RTK could shorten the convergence time further.Graphical