In this study, (1-x)BaTiO3-xBi(Zn2/3Sb1/3)O3 ((1-x)BT-xBZS) ceramics were designed and tested. With the introduction of BZS, it was found that the grain size of the ceramics was increased, which increased the breakdown field strength (Eb) of the ceramics and further improved the energy storage density. The 0.84BT-0.16BZS ceramic achieved both high recoverable energy density (Wrec = 2.32 J/cm3) and energy efficiency (η = 89.7 %) at 620 kV/cm. In addition, excellent temperature stability (20-160 °C) and frequency stability (1–200 Hz) of recoverable energy density have been obtained under 300 kV/cm. A high power density of 28.93 MW/cm3 and transient discharge time (t0.9 = 1.07 μs) were achieved for 0.84BT-0.16BZS ceramic under 200 kV/cm.
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