A modified cellular automaton model (MCA) was developed in order to simulate the evolution of dendritic microstructures in solidification of alloys. Different from the classical cellular automata in which only the temperature field was calculated, this model also included the solute redistribution both in liquid and solid during solidification. The finite volume method, which was coupled with the cellular automaton model, was used to calculate the temperature and solute fields in the domain. The relationship between the growth velocity of a dendrite tip and the local undercooling was calculated according to the KGT (Kurz–Giovanola– Trivedi) model. The effects of constitutional undercooling and curvature undercooling on the equilibrium interface temperature were also considered in the present model. The MCA model was applied to predict thedendritic microstructures, such as the free dendritic growth from an undercooled melt and competitive dendritic growth in practical casting solidification. The simulated results were compared with those obtained experimentally.