Fouling Rate Research Articles

Functionalized hexagonal boron nitride sheets and charge triggered interpenetrating polymer network based membranes work in tandem towards water remediation

Charge triggered membranes demonstrate excellent resistance to fouling and high rejection rates towards charged dyes.

Experimental and mechanism studies on high CaCO3 fouling inhibition of PTFE coating with enhanced stability and anti-corrosion

Surface coatings are an effective technique for mitigating fouling in heat exchangers. In this study, a stable polytetrafluoroethylene (PTFE) coating was prepared with improved corrosion resistance and CaCO3 fouling inhibition rate. The prepared PTFE coating remains strongly stable even undergoing tape stripping, sandpaper abrasion, water impacting and immersion. The corrosion-suppression efficiency of the coating is 95.09 % compared to the stainless steel surface. Fouling tests reveal that the coating possesses an inhibition rate of 86.25 %, and it retains a high level of fouling inhibition rate even after 100 cycles of tape stripping and 400 mm of sandpaper abrasion. Additionally, molecular dynamics simulation was performed to gain insight into the anti-fouling mechanism of the PTFE coating. The results demonstrate the presence of two dense adsorption layers of water molecules in close proximity to the metal surface, which is found to be a crucial role in facilitating the adsorption of CaCO3 ions due to their strong attraction (Einteraction = -15.47 eV) towards the ions. In contrast, the weaker interaction (Einteraction = -1.52 eV) between PTFE and water molecules results in the absence of dense water adsorption layers on the PTFE coating. Consequently, the PTFE coating effectively reduces the rate of ion adsorption on the metal surfaces in the initial stage of CaCO3 fouling formation.

Modification of PAN electrospun nanofiber membranes with g-C3N4 nanotubes/carbon dots to enhance MBR performance

This study is dedicated to the enhancement of electrospun polyacrylonitrile (PAN) nanofiber membranes for their application in membrane bioreactor (MBR) processes. The improvement is achieved through the incorporation of graphitic carbon nitride nanotubes/carbon dots (g-C3N4 NT/CDs) and subsequent heat post-treatments at varying temperatures. Notably, the hot-pressing methodology effectively mitigates surface roughness and significantly reduces issues related to peeling during nanofiber experimentation. Our results demonstrate that the introduction of 0.5 wt% of g-C3N4 NT/CDs leads to a substantial enhancement in water flux. In particular, nanocomposite membranes subjected to hot-pressing at 90 °C for 10 min exhibited an impressive flux recovery ratio (FRR) of 70%. Furthermore, the heat-treated nanocomposite membranes exhibited remarkable antifouling properties and significantly reduced fouling rates when compared to their heat-treated bare counterparts. This study underscores the noteworthy potential of g-C3N4 NT/CDs-modified PAN nanofiber membranes to substantially elevate MBR performance, firmly positioning them as highly promising candidates for critical applications in the domains of water and wastewater treatment. However, it is imperative to underscore that the existing written material necessitates a comprehensive overhaul to align with the provided structural framework.

Constructing quaternized graphene oxide filtration layer on PVDF membrane by a facile strategy via dopamine crosslinking and its performance

The increasing utilization of polyvinylidene fluoride (PVDF) ultrafiltration membranes in water treatment has necessitated the development of membranes with superior separation, antifouling performance and high pure water permeability. As a hydrophilic and antibacterial modifier, quaternized graphene oxide (QGO) has been successfully applied to improve the antifouling and antibacterial properties of the membranes simultaneously. Herein, we proposed a simple and effective strategy to fabricate a nanocomposite ultrafiltration membrane by coating the PVDF membrane surface with QGO and using polydopamine (PDA) as a “bio-glue”. The filtration followed by cross-linking method was utilized to construct a “brick-mud” structure on the membrane surface. The prepared QGO/PDA-PVDF membrane exhibited favorable separation and antifouling properties (79.5% of BSA rejection rate, 15.7% of irreversible fouling rate when filtering 0.5 g/L BSA solution, 97.2% of E. coli and 96.3% of S. aureus antibacterial rate), while maintaining a high pure water permeability of 1105.4 L.m−2.h−1.bar−1. QGO nanosheets were stably coated on the membrane surface, and the QGO/PDA-PVDF membrane prepared by this novel strategy also demonstrated application potential in the field of seawater desalination pretreatment. Besides, the possible mechanisms during modifications were also discussed. This research could serve as a reference for improving the comprehensive performance of PVDF ultrafiltration membrane through surface coating.

Oligohexamethylene Guanidine Derivative as a Means to Prevent Biological Fouling of a Polymer-Based Composite Optical Oxygen Sensor.

The use of biocidal agents is a common practice for protection against biofouling in biomass-rich environments. In this paper, oligohexamethyleneguanidine (OHMG) polymer, known for its biocidal properties, was further modified with para-aminosalicylic acid (PAS) to enhance its properties against microorganisms coated with a lipid membrane. The structure of the product was confirmed by 1H NMR, 13C NMR, and FTIR spectroscopy. The values of the minimum inhibitory concentration (MIC) against Mycobacterium smegmatis ATCC 607 and Pseudomonas chlororaphis 449 were found to be 1.40 and 1.05 μg/mL, respectively. The synthesized substance was used as an additive to the polymer matrix of the composite optical oxygen sensor material. A series of samples with different contents of OHMG-PAS was prepared using a co-dissolution method implying the fabrication of a coating from a solution containing both polymers. It turned out that the mutual influence of the components significantly affects the distribution of the indicator in the matrix, surface morphology, and contact angle. The optimal polymer content turned out to be wt.3%, at which point the water contact angle reaches almost 122°, and the fouling rate decreases by almost five times, which is confirmed by both the respiratory MTT assay and confocal microscopy with staining. This opens up prospects for creating stable and biofouling-resistant sensor elements for use in air tanks or seawater.

Impacts of electric field-magnetic powder coupled membrane bioreactor on phenol wastewater treatment: Performance, synergistic mechanism, antibiotic resistance genes, and eco-environmental benefit evaluation

A novel electric field-magnetic powder coupled membrane bioreactor (EM-MBR) was constructed, which was superior on improvement of phenol treatment performance and sludge characteristics, and mitigation of membrane fouling. EM-MBR enhanced the phenol degradation via the improvement activity of phenol degrading enzymes. The EPS contents and SVI of EM-MBR were significantly reduced by 49.3 % and 58.7 % than that of the conventional MBR, respectively. Moreover, EM-MBR successfully reduced fouling rate by 57.0 %, delaying the membrane resistance. The EPS contents were positively correlated with the SVI and fouling rate, implying that the sludge settleability was strengthened by improving the properties of EPS with the assistance of electromagnetic, thus mitigating the membrane fouling. Microbial co-occurrence network demonstrated that EM-MBR enriched phenol-degrading and EPS-degrading genera correlated to Fe redox cycle. Furthermore, the activation of the antioxidant system in the EM-MBR resulted in the suppression of reactive oxygen species (ROS) generation, consequently impeding the dissemination of antibiotic resistance genes (ARGs). Co-occurrence patterns of MGEs and ARGs revealed that intercellular binding facilitated by ist and Integrase may account for the horizontal transfer of ARGs. The reduction of unit capital costs (15.63 %), running costs (53.00 %), and total average carbon emissions (15.18 %) indicated that EM-MBR was environmentally beneficial.

Self-cleaning foulant attachment on near-infrared responsive photocatalytic membrane for continuous dynamic removing antibiotics in sewage effluent environment

Bifunctional photocatalytic nanofiltration (PNF) membrane has become a reliable frontier technique for removing refractory organic micropollutants. However, the active mitigated fouling mechanism from the microscopic perspective during its long-term operation of purifying real micro-polluted water is rarely studied. Herein, with an integrated use of QSense Explorer and confocal laser scanning microscope techniques, self-cleaning foulant attachment on an activated and customized near-infrared responsive polymeric PNF (termed as nPNF) membrane with good service performance for continuous dynamic removing antibiotics in sewage effluent environment was firstly elucidated. Time-dependent changes in dissipation oscillation frequency, sensed mass and the visualized foulant spatial distribution all indicated that there were only sporadic foulant attachment, an extremely low fouling layer thickness and irreversible fouling rate on/of the activated nPNF membrane top surface, thereby endowing it with excellent self-cleaning characteristic. This is probably because the reactive oxygen species (mainly •O2− and •OH) concurrently destroys the integrity of fouling layer and its internal adhesion structure, transforming part of the irreversible fouling on nPNF membrane surface into reversible one that is easy to wash off. These new horizons provided useful insight on the fate of selected antibiotics in the to-be-removed stage and self-cleaning foulant attachment of PNF membrane.

Investigation of filtration performance and phosphorus removal in an electric field controlled dynamic membrane bioreactor

Dynamic membrane bioreactor (DMBR) offers several advantages over traditional membrane bioreactor, including cheaper costs, less resistance, and easier cleaning. Membrane fouling and poor phosphate removal performance restrict the application of DMBR. To address it, this study creatively combined electric field with DMBR and investigated the mechanisms. The results showed that applying an electric field significantly decreased membrane fouling rate in electric dynamic membrane bioreactor with Ti anode (E-DMBR-Ti). The median membrane fouling rate of E-DMBR-Ti was 2.28 kPa/h, which was 48.99 % lower than that of control group (4.47 kPa/h) during stable operation period. However, hydrogen bubbles formed on the cathode blocked membrane during membrane formation period. The enrichment of electroactive and denitrifying microorganisms (e.g., Lactococcus, Hydrogenophaga) in E-DMBR-Ti, which consumed electrons that would flow to the hydrogen evolution reaction, alleviated the negative impact. To address the issue of poor phosphorus removal efficiency of DMBR, based on the previous research, we replaced the titanium mesh of the anode with aluminum plates, and innovatively using the electrocoagulation technology which named E-DMBR-Al. At 2.4 A/m2 current density, E-DMBR-Al showed the highest phosphorus removal efficiency, with a median of 94.69 %, which was 37.69 % higher than that of DMBR. Furthermore, the enrichment of electroactive microorganisms (e.g., Lactococcus) and polyphosphate-accumulating organisms (e.g., unclassified_f__Comamonadaceae) on membrane contributed to the excellent phosphorus removal performance of E-DMBR-Al.

Pilot study on ceramic flat membrane bioreactor in treatment of coal chemical wastewater

Some toxic and refractory pollutants in coal chemical wastewater can penetrate the biochemical treatment systems and cause high concentrations of suspended solids in the effluent, which may obstruct the subsequent advanced treatment. In this project, a submerged ceramic plate membrane system was integrated to the last oxic corridor of an existing multistage anoxic/oxic tank. In the ceramic flat membrane bioreactor, the influent chemical oxygen demand (COD) was 102.24–178.88 mg/L, with a removal ratio of approximately 30%. The NH3–N concentration in the effluent was relatively stable with an average value of 1.76 mg/L. The turbidity of the effluent was in the range of 0.235–0.852 NTU and was stable below 1 NTU. A flux of 30 L m−2·h−1 could meet the requirements of the pilot test. A gas-water ratio of 50:1 was found optimal. When the concentration of mixed liquor suspended solids (MLSS) was >3769 mg/L, the extracellular polymeric substance in the mixed solution was utilized by microorganisms as a substrate. High MLSS decreased membrane fouling rate. NaClO backwashing can effectively remove pollutants without adversely affecting the treatment efficiency of membrane bioreactors.

Comparative Study of Membrane Fouling with Aeration Shear Stress in Filtration of Different Substances.

The formation process of membrane fouling is complex and diverse, which is an important problem that needs to be overcome in membrane applications. In this paper, three foulant systems consisting of humic acid, humic acid plus Ca2+ and humic acid plus Ca2+ plus yeast were selected to compare membrane fouling processes with different aeration intensities. The aim was to establish the quantitative relationship between membrane fouling rate and shear stress, respectively, in a large-scale flat sheet MBR (FSMBR). The shear stress values at different aeration intensities were obtained using computational fluid dynamics (CFD). The membrane fouling rate during the filtration of different substances was measured by performing experiments. The comparison results showed that the membrane fouling rate varied greatly during the filtration of different substances. With the help of particle size distribution, the effect of different shear forces on floc size was further explored. Using the dual control of fouling rate and floc size, the recommended aeration intensity was 6~8 L/(m2·min).

Long-term operation optimization of circulating cooling water systems under fouling conditions

Fouling caused by excess metal ions in hard water can negatively impact the performance of the circulating water system (CCWS) by depositing ions on the heat exchanger's surface. Currently, the operation optimization of CCWS often prioritizes short-term flow velocity optimization for minimizing power consumption, without considering fouling. However, low flow velocity promotes fouling. Therefore, it’s crucial to balance fouling and energy/water conservation for optimal CCWS long-term operation. This study proposes a mixed-integer nonlinear programming (MINLP) model to achieve this goal. The model considers fouling in the pipeline, dynamic concentration cycle, and variable frequency drive to optimize the synergy between heat transfer, pressure drop, and fouling. By optimizing the concentration cycle of the CCWS, water conservation and fouling control can be achieved. The model can obtain the optimal operating parameters for different operation intervals, including the number of pumps, frequency, and valve local resistance coefficient. Sensitivity experiments on cycle and environmental temperature reveal that as the cycle increases, the marginal benefits of energy/water conservation decrease. In periods with minimal impact on fouling rate, energy/water conservation can be achieved by increasing the cycle while maintaining a low fouling rate. Overall, the proposed model has significant energy/water saving effects and can comprehensively optimize the CCWS through its incorporation of fouling and cycle optimization.

Rethinking gold mining wastewater treatment with an integrated process of membrane distillation and membrane contactors for minimal waste discard and resource recovery

The generation of wastewater in the mining industry is followed by concerns about the environmental impacts derived from its incorrect disposal. This study intended to simultaneously treat and recover water for reuse, sulfuric acid, and copper from gold mining wastewater, from an innovative integrated system of membrane distillation (MD) and non-dispersive solvent extraction (NDSX). The performance of this system was compared when different polymeric membranes (namely polypropylene (PP), polyvinylidene fluoride (PVDF), and polytetrafluoroethylene (PTFE)) were tested. The PP membrane yielded better results in terms of distillate flux (0.67 ± 0.32 L/m2h), owing to its reduced thickness compared with the other membranes. However, the PTFE membrane demonstrated superior outcomes in terms of rejection efficiency, achieving values >99.2 %. The occurrence of fouling due to the organic phase was observed, requiring periodical cleaning protocols and the development of oleophobic membranes to reduce the fouling rate in MD. In the extraction and re-extraction processes the PTFE membrane outperformed in terms of extraction efficiency (recovery of 94.0 % for acid and 97.3 % for copper). The results were explained by its greater porosity and lower roughness, variables that directly impacted the mass transfer of sulfuric acid and copper across the membrane. The study, therefore, demonstrates potentiality in the recovery of high-quality water, sulfuric acid, and copper, clearing the path of technologies with the potential to lower the wastewater discarded from industrial facilities.

Physical, mechanical, chemical, and environmental characterization of stockpiled BOF slag as railway ballast material

Crushed stone from natural sources is commonly used as ballast in railways. The material is a good ballast, but its extraction is destructive. Therefore, this study characterizes basic oxygen furnace (BOF) slag as an alternative material for railway ballast in Kazakhstan with respect to physical, mechanical, chemical and environmental properties. The characterized BOF slags are of two types (top and bottom) with 10 years minimum age. Grain size distribution, specific gravity, absorption capacity, flakiness, lightweight particles, and 3D image analysis for forms and angularity were used for physical characterization. These BOF slags were found to have high specific gravity and a predominantly spherical shape, with larger particles displaying lower sphericity and greater angularity than smaller ones. The mechanical characterization of the BOF slag were carried out using various methods, including LA abrasion, Micro-Deval, aggregate crushing value, aggregate impact value, volumetric expansion, and fouling. BOF slag aggregates demonstrated exceptional strength with good resistance to fragmentation, crushing, surface abrasion, and sudden loading. The expansion rate is considerably lower than the standard limit, and the fouling rate is better than limestone and similar to granite. X-ray fluorescence (XRF), X-ray diffraction (XRD), and scanning electron microscopy (SEM) were all used for chemical characterization. Both BOF slags contain CaO and Fe2O3 with a high peak of SiO2 and portlandite, which suggests that most of the free lime has undergone hydration due to the natural aging of the BOF slag. Regarding the environmental characterization, the tests employed were organic impurity, freeze and thaw, and sodium-based soundness. No organic impurity was observed in the BOF slag, and the BOF slag demonstrated good resistance to weathering and degradation. The characteristics of the investigated BOF slag obtained from laboratory testing were analyzed to confirm its performance for implementation in railway ballast in compliance with the specific requirements, primarily the GOST standard, which is commonly employed in Russia and former Soviet republics, including Kazakhstan. As a result, both BOF slags demonstrated total compliance with the specifications, and the possibility of using stockpiled BOF slag for railway ballast material in Kazakhstan was established.

Reactor performance of static magnetic field membrane bioreactor for treating actual high-salt textile dyeing wastewater and possible mechanism on magnetically enhanced membrane fouling control

Performance of the static magnetic field membrane bioreactor (SMFMBR) for treating actual high-salt textile dyeing wastewater was evaluated. Membrane fouling behavior and possible mechanisms were investigated using multiple methods including chemical composition analysis, microbial community analysis, and four-dimensional label-free quantification metaproteomic analysis. The results showed that three SMFMBRs equipped with the SMFs of 97.2 mT (1#), 202.3 mT (2#) and 303.4 mT (3#) possessed higher removal efficiency of color, chemical oxygen demand (COD) and acute toxicity, as well as higher activity of key enzymes than the conventional MBR (0#). Treatment efficiency of 3# SMFMBR was the highest among all the four groups. Potentially effective bacterial and fungal species were selectively enriched in the suspended sludge of three SMFMBRs according to the results of both high-throughput sequencing and quantitative real-time polymerase chain reaction (QRT-PCR). Membrane fouling rate of 3# SMFMBR was the lowest among all the groups, followed by that of 2#, 0# and 1# reactors. SMF of higher intensity (in 2# and 3# SMFMBRs) mitigated membrane fouling by inhibiting the production of microbial products (mainly consisting of proteins) and the growth of potential fouling-causing microbes on the membrane surface. By contrast, SMF of lower intensity (in 1# SMFMBR) aggravated membrane fouling by improving the yield of fouling-causing microbial products and the growth of biofilm on the membrane surface. Furthermore, the down-regulated porin and the up-regulated Ca2+-binding protein in biocake EPS were also responsible for the mitigation of membrane fouling in 3# SMFMBR.

Membrane fouling, methane production and microbial community under fluidization of biocarrier with conductive surface in anaerobic fluidized bed membrane bioreactor for greywater treatment

A comparative study of organic removal efficiency, fouling control, and methane production from synthetic greywater was performed operating three anaerobic fluidized bed membrane bioreactors (AFMBRs). Granular activated carbon (GAC) particles, polyaniline-coated polyethylene terephthalate (PET) beads, and uncoated PET beads were added as scouring agent to control fouling through each AFMBR. The use of PET spherical beads coated with polyaniline as a fluidized medium improved both fouling reduction and methane production kinetics. Although the GAC particles showed the highest organic removal efficiency in AFMBR due to adsorption capability, their progressive fragmentation reduced the methanogenic population and accelerated fouling rate. Microbial activity was adversely affected when the bulk biomass was exposed to the surfactant in the synthetic greywater. Microbiome analysis showed that the methanogenic archaeal population in the GAC bulk biomass reduced significantly from 10 to 0.5%, which corroborates the decrease in methane production rate. The methanogens on the PET beads shifted gradually from acetoclastic Methanosaeta to hydrogenotrophic Methanospirillum presumably because of the detachment of the biofilm that suppressed the slow-growing Methanosaeta. In addition, the key exoelectrogenic microbes were related to Desulfovibrio and Geobacter, which may be associated with direct interspecies electron transfer with the methanogens.

Perchlorate reduction in a thiosulfate-based denitrifying membrane bioreactor

Reductive removals of perchlorate and nitrate, which can be present simultaneously in groundwater, were investigated in a novel thiosulfate-based denitrifying lab-scale membrane bioreactor (MBR) equipped with a polyethersulfone membrane module. Complete denitrification at a hydraulic retention time (HRT) as low as 3 h and a rate of 800 mg NO3--N/(L.d) was accomplished. Simultaneous with nitrate, complete perchlorate reduction was also detected at the feed concentration of 3000 µg/L and at 12 h HRT. Although further rise in perchlorate loading caused its incomplete reduction, the reduction rate reached up to 38 mg/(L.d). Hence, the developed process is promising for simultaneous perchlorate and nitrate reduction from contaminated groundwater. Sustainable filtration performance was observed up to a flux of 12.5 L/(m2.h) (LMH) at which the fouling rate was 85.32 ± 19.65 mbar/d. However, when the flux was raised further to 25 L/(m2.h), the TMP drastically increased to a rate of 393 ± 40 mbar/d.

Adsorption and cake layer fouling in relation to Fenton cleaning of ceramic nanofiltration membranes

Catalytic ceramic nanofiltration (NF) is a promising technology for direct wastewater reclamation, given its high separation selectivity and reactive surfaces for oxidative removal of fouling. A better understanding of the relation between fouling types and oxidative cleaning efficacy under high organic loading conditions is of practical importance for realizing stable filtration/cleaning performance in long-term water reclamation operations. In this work, Fenton cleaning, using a hydrogen peroxide solution and an iron oxychloride catalyst pre-coat layer on top of commercially available ceramic NF membranes, was studied with respect to high organic loaded fouling, simulated by a concentrated sodium alginate solution in the presence of calcium. Adsorption (in the absence of a permeate flow) and constant-pressure filtration (with a permeate flow) experiments were performed to distinguish between permeance decreases as a result of either adsorptive or cake layer fouling. The results show that the flux evolution could be divided into an initial sharp flux decline, due to rapid adsorption of the foulants, and a subsequent gradual flux decrease, resulting from progressive cake build-up on the membrane. The two-stage flux decrease was enhanced during the constant-pressure filtration experiments, because they start at a high flux with a high fouling rate, while the flux gradually decreases as fouling proceeds. During multiple adsorption/cake filtration/Fenton cleaning cycles, the cake layer fouling was sufficiently removed by Fenton cleaning in contrast to the adsorptive fouling. However, the total permeate production during ceramic NF was not influenced by the remaining adsorptive fouling (after cleaning), since the adsorptive fouling always only occurs at the beginning of each cycle. The findings provide new insights into the criteria for evaluating and optimizing the efficacy of oxidative (Fenton) cleaning during ceramic NF in water treatment.

Interaction of Heat Transfer Enhancement and Fouling in Operating Heat Exchangers

Interactions of heat transfer enhancement and fouling can occur due the change in nature of the surface, operating condition, or the fluid itself. Interactions arising relating to higher clean heat transfer coefficients, and higher wall shear stresses of the enhanced surfaces are discussed in this paper. On the lab-scale, enhancement was often achieved by static elements, such as wire wrapping on a heated rod in an annular flow. Lab-scale tests of necessity suffered from effects of relatively short duration of runs, and re-circulation of a batch of liquid with the danger of changing the fluid composition during experiment. Nevertheless, initial fouling rate results consistent with expected trends could be achieved for hydrocarbon fouling, and particulate fouling. There is a continued need to better represent and compare performance of plain and enhanced surfaces over prolonged operating periods in industrial heat exchangers, using commercial enhancement technologies. Example case studies are discussed which demand different methods of comparing performances. A daily averaged cost analysis is identified as a possible systematic approach on the evaluation of the economic benefit of the use of enhancement devices. This is illustrated for a case study example where tube insert is used as an enhancement option.

Overview of Butadiene Chemical Reaction Fouling in Steam Crackers and Its Control by Carbon Steel Surface Modification

The main objective of the Steam Cracker is to produce monomers prone to polymerization. The drawback is that polymerization can occur in the Steam Cracker itself. The main monomers fouling precursor is Butadiene. All along the separation process, Butadiene concentration and process temperature change. This implies step changes in polymer structure and fouling level. Several techniques are used to control this fouling, including oxygen ingress control, the use of additives such as antioxidants and free radical scavengers. By a catalytic effect, the metal surfaces can also be a polymerization initiator. The objective of passivation is to modify the Carbon Steel surface into stable magnetite and maghemite. Using electrochemistry to characterize different Carbon Steel samples, we were able to improve our passivation procedure. And when applying metal passivation, we were able to increase run length of Depropanizer reboilers limiting the fouling rate and its impact on operation.

Impact of salinity on anaerobic ceramic membrane bioreactor for textile wastewater treatment: Process performance, membrane fouling and machine learning models

Anaerobic membrane bioreactor (AnMBR) shows great potential for textile wastewater treatment, but high salinity in the influent may undermine its performance. This study evaluated the impact of salinity on the treatment performance of an upflow anaerobic sludge blanket (UASB) configured AnMBR using a flat sheet ceramic membrane. The salinity was stepwise increased (0, 5, 10 and 20 g/L) in four phases of the AnMBR operation. Results indicated that increased salinity jeopardized the COD removal efficiency of AnMBR from 92% to 73%, but had a marginal effect on dye removal efficacy (90–96%). Low salinity (5 g/L) boosted the biogas production whilst high salinity (>10 g/L) had a negative impact. Additionally, the increase of salinity resulted in the soluble microbial production (SMP) concentration soar and membrane fouling rate increase, peaking at a salinity of 10 g/L (Phase III) and recovering back to a lower level at a salinity of 20 g/L (Phase IV). This indicated a transition occurrence at a salinity of 10 g/L (Phase III). The microbial diversity analyses further suggested a transition from salinity-sensitive microbes (Aminiphilus, Caldatribacterium, Mesotoga, Methanobrevibacter, Methanobacterium, Methanosaeta) to salinity-tolerant microbes (Longilinea, Ignavibacterium, Rhodovarius, Bosea and Flexilinea). This transition can be associated with the increase SMP concentration and more severe membrane fouling in Phase III, which were mitigated after a new equilibrium was reached when the microbial consortium acclimatized to the high salinity. Finally, a machine learning model of the Adaboost algorithm was established to predict COD removal under different salinities. Importantly, this study revealed that AnMBR process performance and membrane operation can be maintained for high salinity textile wastewater treatment with a halophilic microbial community growth under high-salinity selection pressure.