Precise light manipulation is of paramount importance in improving the performance of semi-transparent organic photovoltaics (STOPVs) for their orientation toward building-integrated photovoltaic window. Nevertheless, one critically important issue for the integration of optical modulation with STOPV devices, lies in the damage from the harsh direct deposition steps to the intrinsic properties and long-term durability of STOPVs. Here a transfer-printing (TP) approach, in which photonic crystals (PC) films are deposited onto a self-adhesive and flexible matrix for their integration with STOPV devices, was first reported, enabling the resultant TPPC-STOPV devices with superior optical-related multifunction. In contrast to these devices based on direct-evaporated PC film, the non-encapsulated TPPC-STOPVs present an ultraviolet blocking (UVB) as high as 96%, an infrared rejection (IRR) of 92%, an enhanced power conversion efficiency (PCE) by 5% as well as superior long-term durability as 96% of its initial PCE. Their gifted superior UVB and IRR properties are individually on a par with those of the stat-of-the-art commercial optical films for smart solar window. This transfer-printing approach makes it possible to separate the high-energy fabrication of high-quality contacts from target optoelectronic devices, providing a wide range of possibilities for the integration of high-quality contacts with optoelectronic devices, including organic, silicon and perovskite optoelectronic devices, as well as their large-area flexible integration.
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