Aggregate packing significantly affects the characteristics of fresh and hardened concrete; aggregates having higher packing density (PD) improve these characteristics. There is a lack of research on how the PD affects the properties of geopolymer concrete (GPC). Hence, the present study includes the effect of the PD on the mechanical and durability properties of the standard and high-strength GPC. The study parameters are the binder content, the concentration of NaOH, and the fly ash to ground granulated blast furnace slag (GGBS) ratio. Six aggregate groups (like 12.5–10 mm, 10–4.75 mm, 4.75–2.36 mm, 2.36-1.18 mm, 1.18–0.6, and 0.6–0.15 mm) were investigated for the particle packing experiment, and the blended coarse:fine aggregate ratio of 55:45 which produced the highest packing density of 0.702, were used in the GPC mixes. A total of 120 cubes of size 100 mm, 30 cylinders of size 100 × 200 mm, and 30 prisms of size 100 × 100 × 500 mm were cast for 10 different mixes in the study. Sorptivity and water absorption are the tests performed for the durability studies. The result shows that GPC mixes with Particle packing theory significantly improved the compressive strength, and durability, and showed better workability. The workability of the GPC reduces by increasing the GGBS and concentration of the NaOH solution. As the GGBS proportion and the concentration of the NaOH solution increases, the concrete compressive, split, and flexural strength increases. As the binder content increases, the strength increases at first, then reduces. Increasing the GGBS content, binder content, and molarity of the NaOH accomplishes a reduction of the sorptivity coefficient and water absorption of the GPC.