The influence of the amount of hydrogen (H) in hydrogenated silicon nitride films (SixNy:Hz) on the etching properties and etching mechanism are unclear for hydrofluorocarbon plasma etching. Therefore, the authors have investigated the effect of H in SixNy:Hz films on the surface reactions during CH2F2/Ar/O2 plasma etching by experimental and numerical simulation techniques. The experimental etch yield (EY) and polymer layer thickness (TC−F) values for SixNy:Hz films with different H concentrations of 2.6% (low-SiN), 16.8% (mod-SiN), and 21.9% (high-SiN) show different trends with the CH2F2/(CH2F2 + O2) flow rate ratio. To understand the mechanism of the different etching properties, the authors estimated the chemical reaction probabilities of the H outflux between F, O, N, C, and Si dangling bonds using first principles calculations and the results of Fourier transform infrared spectroscopy. Based on the estimated reaction probabilities, the authors modeled the surface reactions of SixNy:Hz films under the assumption that the H outflux mainly scavenges incident F radicals (the main etchant species). The authors also consider that the reaction between H and N from outfluxes decreases the desorption reactions of C2N2 and HCN, resulting in a larger TC−F value. Comparing the simulation results of the trends in the whole flow rate ratio range and the absolute values of EY and TC−F with experimental data, the surface model can successfully explain the mechanism. Furthermore, the authors demonstrated time-dependent etched profile and damage distribution for fin-type field-effect transistor SixNy:Hz side-wall etching using the three-dimensional voxel-slab model with the above surface reactions to obtain knowledge about the effect of H on the etched profile and damage distribution. The results show that the etched profile and damage distribution on the Si fin structure are very different for low-SiN and high-SiN because of the different EY and TC−F values induced by different H outfluxes. These results indicate that it is important to carefully control both the etching process and amount of H in the SixNy:Hz film to achieve high-performance advanced complementary metal oxide semiconductor devices.