Improving the efficiency and performance of the solar cells by enhancing the quality and conductivity of the contacts was studied using electron migration (EM). By using intense light that covers the entire cell area at high current densities, the process of EM creates a huge number of charge carriers and helps for enhancing overall cell performances. This study examined the effects of various parameters, including temperature, voltage, time, incident light, and current, on the enhanced performances of n-type tunnel oxide passivated contact (n-TOPCon) solar cells. According to experimental data, 60 V and 10 s at room temperature are the ideal circumstances for optimising both voltage and time. As compared to before the EM experiment in the n-TOPCon solar cells, the illuminated current–voltage (I-V) characteristics of the optimised condition are Jsc of 39.24 mA/cm2, Voc of 707.45 mV, FF of 69.954 %, and PCE of 19.42 %. After the EM condition, this study shows improvements in PCE (19.04 %) and FF (48.02 %). This work provides insight into optimizing the maximum performance in developing solar technologies.