Macrofibers have often been used to increase the tensile strength, durability, crack resistance, spalling, impact resistance, and toughness of concrete. However, the impact behavior of fiber-reinforced concrete (FRC) structures is quite different from their static behavior, and the effectiveness of macrofibers in improving impact resistance should be carefully evaluated. In this study, the impact behavior of FRC with polypropylene (PP) macrofibers was studied through a series of drop-weight impact tests. First, the material characteristics of the FRC with PP fibers under static conditions were evaluated. Test specimens were constructed and drop-weight impact tests were performed. The main parameters were the presence or absence of PP fibers and the drop height, which is related to the magnitude of the impact energy. From the results, it can be found that the crack width of the FRC specimen was smaller than the normal concrete specimen for a similar residual deflection after the impact test due to the bridging effect of the macrofibers. However, the effect of PP fibers on the impact resistance was not significant, even though there was a considerable increase in tensile and flexural performance under static conditions, since the hardening effect after the sharp reduction in strength shown in the static test of FRC is not effective in the impact test.