Fast Data Acquisition Research Articles

Fast and Efficient Acquisition of Kinetic Data in Microreactors Using In-Line Raman Analysis

This study demonstrates that a microreactor setup with fast in-line reaction monitoring by Raman spectroscopy can be a highly efficient laboratory tool for kinetic studies and process development. Using a coaxial probe and commercial spectrometer to perform real-time measurements in the microchannel prevents the need for reaction quenching, sampling, and time-consuming off-line analysis methods such as GC or HPLC. A specially designed, temperature-controlled aluminum plate microreactor was developed and tested in the exothermic synthesis of 3-piperidino propionic acid ethyl ester by Michael addition. In-line measurements through a fused quartz screen in the reactor channel, which had an increasing cross-sectional area, allowed time-series kinetic data to be collected over nearly the full range of reaction conversions. An optimum flow rate range in which nearly ideal plug flow behavior can be assumed was identified. Furthermore, a time gradient was applied to the reactant flow rates, and the product concen...

Automatic boundary extraction of inland water bodies using LiDAR data

Inland waters have vital importance in terrestrial ecosystems as they contribute to the total diversity in surrounding areas as well as enhancing horizontal and vertical ecological connectivity of various habitats. Therefore, temporal monitoring of changes on water bodies is crucial. Morphological changes of inland waters can be conveniently determined using Remote Sensing (RS) techniques. For instance, optical satellite images are widely used for change detection studies; however, it might be difficult to get a proper optical image of an area of interest all the time as the area might be covered by clouds or haze. Moreover, aerial images collected by an optical sensor mounted on aircraft can also be employed for monitoring inland water change. On the other hand, optical images are two dimensional which makes very difficult to detect changes in three dimensions such as for inland water bodies. Hence, alternative technologies such as Light Detection and Ranging (LiDAR) which has direct and fast 3D data acquisition can be used instead of images for change detection. Since LiDAR sensors are mounted on an aircraft, the data collection time can be scheduled according to weather conditions for avoiding from rain and haze. Therefore, in this study, LiDAR technology was chosen as the source of the data and two algorithms are proposed for extracting boundary of inland water bodies. It is known that inland water bodies are generally planar, as a first step of the proposed methodology, point cloud of the water surface was extracted using RANdom SAmple Consensus (RANSAC) algorithm from LiDAR data. For the second step, two algorithms were proposed for delineating of inland water surface boundary. The first algorithm is the Angles of Points (AOP) which is mainly based on line and angle properties of point cloud. The second algorithm is the LiDAR to Image (LTI) and it basically involves conversion of point clouds to binary images for extraction of boundary of water bodies. The two algorithms for boundary extraction of water bodies were tested with three different inland water bodies. Finally, the results produced by the algorithms were compared to each other and with manually extracted boundaries for different time periods. The experimental results showed that the proposed algorithms are capable of extracting the boundaries of water bodies; however, the LTI algorithm performed better than the AOP when applied on water surfaces with complex geometry.

Gas chromatography–vacuum ultraviolet spectroscopy for analysis of fatty acid methyl esters

A new vacuum ultraviolet (VUV) detector for gas chromatography was recently developed and applied to fatty acid methyl ester (FAME) analysis. VUV detection features full spectral acquisition in a wavelength range of 115–240nm, where virtually all chemical species absorb. VUV absorption spectra of 37 FAMEs, including saturated, monounsaturated, and polyunsaturated types were recorded. Unsaturated FAMEs show significantly different gas phase absorption profiles than saturated ones, and these classes can be easily distinguished with the VUV detector. Another advantage includes differentiating cis/trans-isomeric FAMEs (e.g. oleic acid methyl ester and linoleic acid methyl ester isomers) and the ability to use VUV data analysis software for deconvolution of co-eluting signals. As a universal detector, VUV also provides high specificity, sensitivity, and a fast data acquisition rate, making it a powerful tool for fatty acid screening when combined with gas chromatography. The fatty acid profile of several food oil samples (olive, canola, vegetable, corn, sunflower and peanut oils) were analyzed in this study to demonstrate applicability to real world samples.

From Asteroids to Space Debris

AbstractSince 2011, Oukaimeden Observatory (OUCA) has become one of the active NEO search facilities in the word. Its discovery statistics shows that the MOSS (Morocco Oukaimeden Sky Survey) project received credits for more than 2,145 new designations, including 3 NEOs and 4 comets. Its excellent astro-climactic characteristics are partly behind the success. The average number of observable nights is around 280 nights per year, while median seeing is 0.8-0.9 arcsec. We completed construction of a new telescope at the site in March 2015. It is Optical Wide-field Patrol (OWL) facility designed and built by Korea Space Science Institute (KASI). The primary objective of this facility is to monitor national space assets of Korea; either wide-field imaging- or fast data acquisition- capabilities enable the 0.5m telescope to conduct observation programs to catalog and follow-up various transient events in the night sky. We present the seeing condition, the OWL system and preliminary results obtained at OWL@Oukaimeden during the past several months.

Measurements of reflectance and fluorescence spectra for nondestructive characterizing ripeness of grapevine berries

In vivo reflectance and fluorescence spectra from berry skins of a white (Riesling) and red (Cabernet Sauvignon) grapevine variety were measured during a ripening season with a new CMOS radiometer instrument. Classical reference measurements were also carried out for a sugar content of the berry juice [°Brix] and pigment contents (chlorophyll a and b, carotenoids, anthocyanins) from methanol extracts of the berry skin. We showed that the colours and the spectra analysed from them could be taken as an unambiguous indicator of grapevine ripening. Reflectance spectra, which were affected by the content of pigments (chlorophylls and anthocyanins), effects of surface (wax layers), and tissue structure (cell size) of the berries well correlated (R 2 = 0.89) with the °Brix measurements of the berries. The fast data acquisition of both reflectance and fluorescence spectra in one sample with our radiometer instrument made it superior over the time-consuming, traditional, and mostly destructive chemical analysis used in vine-growing management.

Status of the cold test facility for the JT-60SA tokamak toroidal field coils

JT-60SA is a fusion experiment which is jointly constructed by Japan and Europe and which shall contribute to the early realization of fusion energy, by providing support to the operation of ITER, and by addressing key physics issues for ITER and DEMO. In order to achieve these goals, the existing JT-60U experiment will be upgraded to JT-60SA by using superconducting coils. The 18 TF coils of the JT-60SA device will be provided by European industry and tested in a Cold Test Facility (CTF) at CEA Saclay. The coils will be tested at the nominal current of 25.7kA and will be cooled with supercritical helium between 5K and 7.5K to check the temperature margin against a quench. The main objective of these tests is to check the TF coils performance and hence mitigate the fabrication risks. The most important components of the facility are: a 11.5m×6.5m large cryostat in which the TF coils will be thermally insulated by vacuum; a 500W helium refrigerator and a valve box to cool the coils down to 5K and circulate 24g/s of supercritical helium through the winding pack and through the casing; a power supply and HTS current leads to energize the coil; the control and instrumentation equipment (sensors, PLC's, supervision system, fast data acquisition system, etc.) and the Magnet Safety System (MSS) that protects the coils in case of quench. The paper will give an overview of the design of this large facility and the status of its realization.

Fast terahertz imaging using a quantum cascade amplifier

A terahertz (THz) imaging scheme based on the effect of self-mixing in a 2.9 THz quantum cascade (QC) amplifier has been demonstrated. By coupling an antireflective-coated silicon lens to the facet of a QC laser, with no external optical feedback, the laser mirror losses are enhanced to fully suppress lasing action, creating a THz QC amplifier. The addition of reflection from an external target to the amplifier creates enough optical feedback to initiate lasing action and the resulting emission enhances photon-assisted transport, which in turn reduces the voltage across the device. At the peak gain point, the maximum photon density coupled back leads to a prominent self-mixing effect in the QC amplifier, leading to a high sensitivity, with a signal to noise ratio up to 55 dB, along with a fast data acquisition speed of 20 000 points per second.

Control and data acquisition of the ITER full-scale ion source for the neutral beam test facility

The neutral beam test facility, which is under construction in Padova, Italy, is developing the ITER full-scale ion source for the ITER heating neutral beam injectors, referred to as the SPIDER experiment, and the full-size prototype injector, referred to as MITICA. The SPIDER control and data acquisition system (CODAS) has been developed and its construction will start in 2014.Slow control and data acquisition will be based on the ITER CODAC core system software suite that has been designed to facilitate the integration of ITER plant systems with CODAC. Fast control and data acquisition will use solutions specific to the test facility, as the corresponding concepts are not ready-to-use in the ITER design.The ITER hardware catalog for fast control has been taken into consideration. The software development will be based on the integration of MDSplus and MARTe, two framework software packages that are well known in the fusion community, targeting data organization and fast real-time control, respectively.The paper revises the system requirements and the system design and shows the results already achieved in terms of system integration. In addition, the paper will report the experience in the usage of different cooperating software frameworks and in the integration of industrial procured plant systems.

Trust Region Methods for the Estimation of a Complex Exponential Decay Model in MRI With a Single-Shot or Multi-Shot Trajectory.

Joint estimation of spin density R2* decay and OFF-resonance frequency maps is very useful in many magnetic resonance imaging applications. The standard multi-echo approach can achieve high accuracy but requires a long acquisition time for sampling multiple k-space frames. There are many approaches to accelerate the acquisition. Among them, single-shot or multi-shot trajectory-based sampling has recently drawn attention due to its fast data acquisition. However, this sampling strategy destroys the Fourier relationship between k-space and images, leading to a great challenge for the reconstruction. In this paper, we present two trust region methods based on two different linearization strategies for the nonlinear signal model. A trust region is defined as a local area in the variable space where a local linear approximation is trustable. In each iteration, the method minimizes a local approximation within a trust region so that the step size can be kept in a suitable scale. A continuation scheme is applied to reduce the regularization gradually over the parameter maps and facilitates convergence from poor initializations. The two trust region methods are compared with the two other previously proposed methods--the nonlinear conjugate gradients and the gradual refinement algorithm. Experiments based on various synthetic data and real phantom data show that the two trust region methods have a clear advantage in both speed and stability.

Excited-State Vibrational Coherence in Perylene Bisimide Probed by Femtosecond Broadband Pump-Probe Spectroscopy.

Broadband laser pulses with ultrashort duration are capable of triggering impulsive excitation of the superposition of vibrational eigenstates, giving rise to quantum beating signals originating from coherent wave packet motions along the potential energy surface. In this work, coherent vibrational wave packet dynamics of an N,N'-bis(2,6-dimethylphenyl)perylene bisimide (DMP-PBI) were investigated by femtosecond broadband pump-probe spectroscopy which features fast and balanced data acquisition with a wide spectral coverage of >200 nm. Clear modulations were observed in the envelope of the stimulated emission decay profiles of DMP-PBI with the oscillation frequencies of 140 and 275 cm(-1). Fast Fourier transform analysis of each oscillatory mode revealed characteristic phase jumps near the maxima of the steady-state fluorescence, indicating that the observed vibrational coherence originates from an excited-state wave packet motion. Quantum calculations of the normal modes at the low-frequency region suggest that low-frequency C-C (C═C) stretching motions accompanied by deformation of the dimethylphenyl substituents are responsible for the manifestation of such coherent wave packet dynamics.

Collective Flux Jumps Observed During Operation of the EDIPO Magnets

The tilted head race track coils of the EDIPO test facility are wound with cable-in-conduit conductors made by high current density Nb3Sn strands, Jc = 2400 A/mm2 at 12 T – 4.2 K. Since the commissioning of the coils, frequent voltage spikes were observed at the quench detection taps during the low current range of operation, completely disappearing above 2 T. The large amplitude of some spikes triggered the quench detection system: the parameters for protection (voltage thresholds and validation time) had to be modified for the voltage pairs monitoring the windings. The occurrence of partial flux jumps in the high current density strands is known from former characterization. The fast data acquisition of the quench detection system, with 800 Hz sampling frequency, allows investigation of the dynamics and propagation of the voltage spikes in the various layers of the winding. From the collected data of several runs of operation, statistics of amplitude, initial location, propagation and reproducibility were drawn, looking also for correlation with the operation history, e.g. first cooldown, ramp up vs. ramp down, ramp rate, etc. The energy released by the flux jumps is conservatively estimated by the time integration of the voltage spikes and discussed in terms of energy margin and heat removal rate in the layers. In conclusion, the limitation of the use of high current density Nb3Sn strands in high current conductors is discussed.

Simultaneous acquisition of three NMR spectra in a single experiment for rapid resonance assignments in metabolomics

NMR-based approach to metabolomics typically involves the collection of two-dimensional (2D) heteronuclear correlation spectra for identification and assignment of metabolites. In case of spectral overlap, a 3D spectrum becomes necessary, which is hampered by slow data acquisition for achieving sufficient resolution. We describe here a method to simultaneously acquire three spectra (one 3D and two 2D) in a single data set, which is based on a combination of different fast data acquisition techniques such as G-matrix Fourier transform (GFT) NMR spectroscopy, parallel data acquisition and non-uniform sampling. The following spectra are acquired simultaneously: (1) 13C multiplicity edited GFT (3,2)D HSQC-TOCSY, (2) 2D [ 1H- 1H] TOCSY and (3) 2D [ 13C- 1H] HETCOR. The spectra are obtained at high resolution and provide high-dimensional spectral information for resolving ambiguities. While the GFT spectrum has been shown previously to provide good resolution, the editing of spin systems based on their CH multiplicities further resolves the ambiguities for resonance assignments. The experiment is demonstrated on a mixture of 21 metabolites commonly observed in metabolomics. The spectra were acquired at natural abundance of 13C. This is the first application of a combination of three fast NMR methods for small molecules and opens up new avenues for high-throughput approaches for NMR-based metabolomics. We describe here a first application of a combination of different fast NMR methods to simultaneously acquire three spectra in a single data set. The method combines G-matrix Fourier transform (GFT) NMR spectroscopy, parallel data acquisition and non-uniform sampling. This opens up new avenues for high-throughput approaches in metabolomics.

Rapid volumetric T1 mapping of the abdomen using three-dimensional through-time spiral GRAPPA.

To develop an ultrafast T1 mapping method for high-resolution, volumetric T1 measurements in the abdomen. The Look-Locker method was combined with a stack-of-spirals acquisition accelerated using three-dimensional (3D) through-time spiral GRAPPA reconstruction for fast data acquisition. A segmented k-space acquisition scheme was proposed and the time delay between segments for the recovery of longitudinal magnetization was optimized using Bloch equation simulations. The accuracy of this method was validated in a phantom experiment and in vivo T1 measurements were performed with 35 asymptomatic subjects on both 1.5 Tesla (T) and 3T MRI systems. Phantom experiments yielded close agreement between the proposed method and gold standard measurements for a large range of T1 values (200 to 1600 ms). The in vivo results further demonstrate that high-resolution T1 maps (2 × 2 × 4 mm(3)) for 32 slices can be achieved in a single clinically feasible breath-hold of approximately 20 s. The T1 values for multiple organs and tissues in the abdomen are in agreement with the published literature. A high-resolution 3D abdominal T1 mapping technique was developed, which allows fast and accurate T1 mapping of multiple abdominal organs and tissues in a single breath-hold.

3D RECONSTRUCTION OF CULTURAL TOURISM ATTRACTIONS FROM INDOOR TO OUTDOOR BASED ON PORTABLE FOUR-CAMERA STEREO VISION SYSTEM

Abstract. Building the fine 3D model from outdoor to indoor is becoming a necessity for protecting the cultural tourism resources. However, the existing 3D modelling technologies mainly focus on outdoor areas. Actually, a 3D model should contain detailed descriptions of both its appearance and its internal structure, including architectural components. In this paper, a portable four-camera stereo photographic measurement system is developed, which can provide a professional solution for fast 3D data acquisition, processing, integration, reconstruction and visualization. Given a specific scene or object, it can directly collect physical geometric information such as positions, sizes and shapes of an object or a scene, as well as physical property information such as the materials and textures. On the basis of the information, 3D model can be automatically constructed. The system has been applied to the indooroutdoor seamless modelling of distinctive architecture existing in two typical cultural tourism zones, that is, Tibetan and Qiang ethnic minority villages in Sichuan Jiuzhaigou Scenic Area and Tujia ethnic minority villages in Hubei Shennongjia Nature Reserve, providing a new method and platform for protection of minority cultural characteristics, 3D reconstruction and cultural tourism.

Fast stopped-flow enzymatic sensing of fenitrothion in grapes and orange juice

This article describes a fast analytical method for the determination of the organophosphorus pesticide fenitrothion in spiked orange juice and grape samples. Fast data acquisition (2s) facilitates excellent selectivity because no interference from kinetically slower side reactions in the matrix occurs on such a short time scale. The mechanical mixing of the reagents and short residence time in the reactor after onset of reaction allow a precise study of the mechanistic details of the reaction. The stopped-flow device used to make measurements was coupled to a fluorescence detector to obtain excellent sensitivity. The precision, in terms of repeatability (expressed as relative standard deviation, n=7), was 0.27% at a 5μgmL−1 level. The detection limit was 1.34μgmL−1. Calibration data over the range 5.0–35μgmL−1 afforded the correlation coefficient R=0.998. The proposed method was applied to directly determine fenitrothion in orange juice samples as well as in fresh grapes crushed and filtered after solid-phase extraction. Mean recovery values were 99.3±0.28% and 97.2±2.37%, respectively. The enzymatic mechanism was discussed on the basis of the obtained stopped-flow data.

Method of Processing Ultrasonic In-line Monitoring Signals in Polymer Mixing Extrusion to Determine Mixing State

Abstract The polymer mixing status along a screw channel has significant impacts the quality of the polymer extrusion process. The development of the techniques for monitoring the polymer mixing status is highly desirable for controlling polymer extrusion results. Therefore, we developed a system equipped with ultrasonic probes for fast data acquisition capability and carried out extrusion experiments on different polymers. Results show that the amplitude of the resulting ultrasonic signals is affected by the mixing status of the polymers; these results can be used to monitor the polymer mixing process along the extruder channel. In this study, we use both rank and low pass filtering to correct amplitude differences in acquired raw signals that arise due to the influence of temperature. We employ the correlation coefficient method to ensure that our comparison of the amplitudes of the acquired signals is reflected from the same screw position. Subsequently, we define signal fluctuation coefficients to investigate the polymer's mixing state. The results show that this method is highly effective for monitoring the inline mixing processes of polymers.

Temperature- and field-dependent characterization of a conductor on round core cable

The conductor on round core (CORC) cable is one of the major high temperature superconductor cable concepts combining scalability, flexibility, mechanical strength, ease of fabrication and high current density; making it a possible candidate as conductor for large, high field magnets. To simulate the boundary conditions of such magnets as well as the temperature dependence of CORC cables a 1.16 m long sample consisting of 15, 4 mm wide SuperPower REBCO tapes was characterized using the ‘FBI’ (force—field—current) superconductor test facility of the Institute for Technical Physics of the Karlsruhe Institute of Technology. In a five step investigation, the CORC cable’s performance was determined at different transverse mechanical loads, magnetic background fields and temperatures as well as its response to swift current changes. In the first step, the sample’s 77 K, self-field current was measured in a liquid nitrogen bath. In the second step, the temperature dependence was measured at self-field condition and compared with extrapolated single tape data. In the third step, the magnetic background field was repeatedly cycled while measuring the current carrying capabilities to determine the impact of transverse Lorentz forces on the CORC cable sample’s performance. In the fourth step, the sample’s current carrying capabilities were measured at different background fields (2–12 T) and surface temperatures (4.2–51.5 K). Through finite element method simulations, the surface temperatures are converted into average sample temperatures and the gained field- and temperature dependence is compared with extrapolated single tape data. In the fifth step, the response of the CORC cable sample to rapid current changes (8.3 kA s−1) was observed with a fast data acquisition system. During these tests, the sample performance remains constant, no degradation is observed. The sample’s measured current carrying capabilities correlate to those of single tapes assuming field- and temperature dependence as published by the manufacturer.

Improved estimation of soil clay content by the fusion of remote hyperspectral and proximal geophysical sensing

Planning sustainable soil exploitation and land resource evaluation require up-to-date and accurate maps of soil properties. In that respect, geophysical techniques present particular interests given their non-invasiveness and their fast data acquisition capacity, which permit to characterize large areas with fine spatial and/or temporal resolutions. We investigated the relevancy of combining data from airborne hyperspectral (Hs), electromagnetic induction (EMI) and far-field ground-penetrating radar (GPR) for mapping soil properties, in particular soil clay content, at the field scale. Data from the three techniques were acquired at a test site in Mugello (Italy) characterized by relatively strong spatial variations of soil texture. Soil samples were collected for determining ground truth clay content. For the frequencies used in this study (200–650MHz), the GPR surface reflection is mainly determined by soil dielectric permittivity, itself primarily influenced by soil moisture. In contrast, EMI is mostly sensitive to soil electrical conductivity, which integrates several soil properties including in particular soil moisture and clay content. Taking advantage of the complementary information provided by the two instruments, the GPR and EMI data were combined and correlated to local ground-truth clay content data to provide high-resolution clay content maps over the entire field area. Besides, a relationship was also observed between Hs data and clay content measurements, which permitted to produce a Hs-derived clay content map. EMI–GPR and Hs maps showed close spatial patterns and a relatively high correlation was observed between both clay content estimates, as well as between clay content estimates and ground-truth clay content measurements. Moreover, data fusion allowed constraining the EMI–GPR and Hs information and reduced the uncertainty of mapped clay content estimates. These results demonstrated great promise for integrated, digital soil mapping applications.

Ultrasonic Mammography with Circular Transducer Array

Abstract Ultrasonic projection imaging is similar to X-ray radiography. Nowadays, ultrasonic projection methods have been developed in the set-up of multi-element flat arrays with miniature transducers, where one of the array acts as a transmitter and the other one is a receiver. In the paper, a new method of the projection imaging using a 1024-element circular ultrasonic transducer array is presented. It allows the choice of a projection scanning plane for any angle around a studied object submerged in water. Fast acquisition of measurement data is achieved as a result of parallel switching of opposite transmitting and receiving transducers in the circular array and vertical movement of the array. The algorithm equalizing the length of measurement rays and the distances between them was elaborated for the reconstruction of projection images. Projection research results of breast phantom obtained by means of the elaborated measurement set-up and compared with mammography simulations (acquired through overlapping of X-ray tomographic images) show that ultrasonic projection method presented in this paper (so-called ultrasonic mammogra-phy) can be applied to the woman's breast and be used as a diagnosis for an early detection of cancerous lesions. It can, most of all, be used as an alternative or complementary method to standard mammography, which is harmful because of ionizing radiation and invasive due to the mechanical compression of tissue.

Gas chromatography–vacuum ultraviolet spectroscopy for multiclass pesticide identification

A new vacuum ultraviolet detector for gas chromatography was recently developed and applied to multiclass pesticide identification. VUV detection features full spectral acquisition in a wavelength range of 115–240nm, where virtually all chemical species absorb. VUV absorption spectra of 37 pesticides across different classes were recorded. These pesticides display rich gas phase absorption features across various classes. Even for isomeric compounds, such as hexachlorocyclohexane (HCH) isomers, the VUV absorption spectra are unique and can be easily differentiated. Also demonstrated is the ability to use VUV data analysis software for deconvolution of co-eluting signals. As a universal detector, VUV provides both qualitative and quantitative information. It offers high specificity, sensitivity (pg on-column detection limits), and a fast data acquisition rate, making it a powerful tool for multiclass pesticide screening when combined with gas chromatography.