Faceted Grains Research Articles

Transitioning of deformation mode in bicrystalline Al-Mg alloy with Σ3 [1 1 1] 60° {11 8 5} faceted grain boundary

In this letter, the authors have elucidated the effect of alloying biocompatible and lighter magnesium (Mg) solute atoms in a bicrystalline aluminium (Al) solvent incorporated with a faceted coherent-incoherent grain boundary (GB) to analyze the tensile deformation mechanisms. Cryogenic temperature and high strain rate conditions were imposed through molecular dynamics simulations to report the detrimental effect of Mg addition on the tensile strength of Al-Mg alloys. Evidence of transitioning in deformation modes for pure Al and Al-Mg alloys was seen. On elaborating, for pure Al, GBs acted as the dislocation nucleation site; whereas for Al-Mg alloy, it was both the GBs and grains. It was observed that stacking faults (SFs) originated from GBs and propagated toward grains in Al. In contrast, in Al-Mg alloys, SFs were generated simultaneously from both GBs and grains. This simultaneous nucleation of dislocations and SFs from both GBs and grains renders bicrystalline alloys lower the elastic limit than pure metal. Conversely, beyond this elastic limit, the alloys exhibit higher flow stress than the pure metal due to the Mg-dislocation interactions. These findings offer valuable insights for tailoring the mechanical properties of Al-Mg alloys to meet aerospace, automotive and marine engineering-related application requirements.

Impact of the Li-loss mechanisms inherent to the physical vapor deposition of LiCoO2 cathode on its electrochemical performance

GPa-resistant conformal LiCoO2 cathodes grown by physical vapor deposition (PVD), with negative chemical expansion coefficients, are promising systems for mechanically stabilizing cathode/solid electrolyte interfaces in solid-state lithium-ion batteries. However, exploiting its potential preliminarily requires that we are able to control the reversibility of Li stoichiometry under PVD conditions, which represents a major challenge since metal Li is lightweight, volatile and has high diffusivity. By combining different chemical and structural analysis techniques, we identify the mechanisms of Li loss by PVD and demonstrate that unlike the electrochemical delithiation of LiCoO2, the crystallization of LiCoO2 admits only a small amount of Li vacancies, so that in a Li-deficient regime, segregated phases of fully stoichiometric LiCoO2 and Li-free Co oxides are formed. From the laterally- and depth-resolved concentrations of the coexisting phases, we can conclude that PVD-grown LiCoO2 is partially stabilized into morphological features with reduced specific surface areas (i.e., large isotropic faceted grains and thick films), resulting in an improvement of its specific electrochemical properties and performance.

Solidification behavior of SiCf/Ti17 induced by fixed-point laser surface remelting

Taking advantage of laser additive manufacturing, continuous SiC fiber reinforced titanium matrix composites (SiCf/TMCs) with low density and excellent mechanical properties can be used to hybrid-fabricate large components with complex shape for aerospace applications. However, due to the anisotropy in both microstructure and heat transfer ability, the high-density and rapid heat input from laser during hybrid manufacturing process will cause the non-uniform damage of fibers and various solidification microstructure in the molten pool. In order to understand the solidification behavior of molten pool in SiCf/Ti17 composites, the fixed-point laser surface remelting was used to bring in rapid and symmetrical heat input. With the decrease of temperature from center to edge of the molten pool, both fiber damage degree and the contents of Si and C elements in melt decreased. The solidification microstructure contains TiCx, Ti5Si3 and β-Ti, and their morphology varies according to the melt composition. SiC fibers act as heterogeneous nucleation sites for first solidified phases and promote their preference growth along the radial direction of fibers resulting from the excellent heat transfer ability. The faceted Ti5Si3 grains solidified through peritectic reaction L+TiCx→Ti5Si3 exhibit strong <0001> texture.

Synergistic effects of temperature and strain rate on tensile properties of simulated Ni-6Cu alloy with Σ3 non-Arrhenius grain boundary

ABSTRACT Comprehending the mechanical response of materials on an atomic level is pivotal in the optimisation of advanced materials with superior mechanical properties. This research article utilises the atomistic-scale based molecular dynamics simulations to report the uniaxial tensile behaviour of bicrystalline Ni-6Cu (Nickel – 94% and Copper – 6%) alloy incorporated with pre-existing faceted Σ3 [111] 60° {11 8 5} grain boundaries. The primary aim of this investigation is to comprehend the performance of bicrystalline Ni-6Cu alloy under varying thermodynamic conditions and to assess the influence of pre-existing faceted grain boundaries on its tensile behaviour. This work encompasses a range of strain rates (108 to 1010 1/s) and temperatures (spanning from 100 to 900 K) for the uniaxial tensile deformation simulations. The outcomes unveil that the Young’s modulus of Ni-6Cu alloy (with pre-existing faceted grain boundaries embedded in its domain) was inversely proportional to temperature and constant with respect to strain rate. For the same configuration, yield stress was inversely and directly proportional to temperature and strain rate, respectively. Interestingly, incipient plasticity in the tensile stress–strain response was observed at lower temperature and lower strain rate. From the microstructural point of view, at lower temperatures, the incoherent twin boundary served as a source for the nucleation of stacking faults; however, as the temperature increased, both the incoherent twin boundary and the tips of coherent twin boundary function as the source for stacking faults formation. Our simulations also verified the GB’s anti-thermal (or non-Arrhenius) migration behaviour even under tensile load.

Crack nucleation and dislocation activities in titanium alloys with the strong transverse texture: Insights for enhancing dwell fatigue resistance

Cold dwell sensitivity of near α titanium alloys has posed a significant challenge to the engineering safety within the aerospace industry. However, there exists inconsistency regarding the critical facet formation mechanism between basal and prismatic nucleation. A key revelation in this paper is that the controversy surrounding the facet nucleation plane primarily arises from variations in texture: when the loading direction is parallel to the c-axis or at a 45 ° angle, it leads to basal plane cracking, whereas loading direction perpendicular to the c-axis results in prismatic plane cracking. What's more, a large anisotropy is observed in the dwell fatigue performance in descending order: rolling direction (RD) > transverse direction (TD) >45° direction. To be specific, the dwell fatigue life of RD specimens was 2 times and 4.07 times longer than that of TD and 45 ° specimens, which exhibits excellent dwell fatigue resistance. Furthermore, the high prismatic dislocation density near the facet of RD specimen was confirmed through the Transmission Electron Microscope (TEM) and Transmission Kikuchi Diffraction (TKD) map, which is evidenced that prismatic slips lead to higher strain hardening during cyclic loading. The basal plane of facet grain is generally parallel to the facet line, indicating that the elliptical facet developed by the transgranular fracture through basal plane. Twinning activation in hard grain to accommodate deformation in Ti60 alloy is firstly observed under dwell fatigue tests, which is a product of high stress level in the hard grain. This paper unveils the significant impact of texture on dwell fatigue resistance, offering novel insights into enhancing dwell fatigue performance through texture control.

Nitrogen-incorporated boron-doped diamond films for enhanced electrochemical supercapacitor performance

The electrochemical (EC) supercapacitor, known for its rapid charging, reliability, and versatile applications, demands optimized electrode characteristics and an understanding of their electrochemical behaviour. Although boron-doped diamond (BDD) holds promise as a supercapacitor electrode, a crucial gap exists in comprehending its material behaviour under specific growth conditions. Here, nitrogen-incorporated BDD (N-BDD) films with different microstructures are investigated. The morphology of N-BDD films is varied by tuning the substrate temperature (Ts) from 400 °C to 850 °C during the growth process. The diamond films grown at lower Ts = 400 °C consist of faceted grains, and the grain sizes shrink as Ts is increased (550 °C and 700 °C). Interestingly, the films grown at 850 °C (N-BDD850°C) show nanowire-like morphology with enhanced electrical conductivity. The spectroscopy and microscopy results reveal the concurrence of sp3-diamond and sp2-graphitic phases in the nanowire morphology. The EC supercapacitor studies disclose that formation of nanowire-like morphology for N-BDD850°C increases the active surface area and electron transport properties; hence, higher current response and enhanced specific capacitance (0.09 F cm−2 at a current density of 1.53 mA cm−2) are observed. Lifecycle stability of 82% is observed after 5000 cycles indicating the efficient performance of N-BDD850°C films.

Communication—Texture and Bandgap Tuning of Phase Pure Cu2O Thin Films Grown by a Simple Potentiostatic Electrodeposition Technique

Highly textured phase pure Cu2O thin films have been grown by a simple electrodeposition technique with varying deposition voltages (−0.3 to −1.0 V). The surface morphology characterized by Scanning Electron Microscopy (SEM) revealed that the deposited thin films coherently carpet the underlying substrate and are composed of sharp faceted well-defined grains of 0.5–1.0 μm sizes. XRD analyses showed that all films are composed of polycrystalline cubic Cu2O phase only and have average crystalline domain size in the range of 30–73 nm. The preferred crystalline orientation of phase pure Cu2O films was found to be changing from (200) to (111) with increasing cathodic voltages and showed the highest (111) and (200) crystalline texture coefficient while growing at −1.0 and −0.8 V respectively. The optical bandgap of the as-grown samples was calculated in the range of 1.95–2.20 eV using UV–vis Transmission data. The performance of Cu2O/FTO photocathodes was tested by estimating LED “ON/OFF” modulated surface photovoltage into a photoelectrochemical cell at a zero bias.

Low traces of acetone detection with WO3-based chemical sensors

This work presents the ability of WO3-based sensors to detect low traces of acetone, specifically within the range of 0.25–5 ppm, specific to the in-field atmosphere. The WO3 powder was synthesised through the hydrothermal method. Morpho-structural investigations showed a monoclinic structure and a good crystallization of the WO3 powder, containing well-grown and faceted grains along low-index crystallographic planes. The paste obtained by mixing the powder with propanediol was screen-printed as a thick layer onto commercial alumina substrates, obtaining the chemical sensors. A dynamic computer-controlled Gas Mixing System was utilized to ensure controlled airflow with variable relative humidity and acetone concentrations. The sensor response was explained based on physico-chemical equations, taking into consideration pre-adsorbed species of oxygen and water, both of which are relevant constituents of atmospheric conditions. The results highlight the applicative potential of WO3, having a good signal-to-noise ratio in relative humidity conditions up to 90% and a pronounced sensitive selectivity to acetone.

Deformation and boundary motion analysis of a faceted twin grain boundary

In this article, molecular dynamics simulations are used to understand how a nickel bicrystal with faceted incoherent Σ3 grain boundaries responds to uniaxial tensile loading. The deformation response is studied over a wide range of temperatures (100 – 900 K) and strain rates (107 – 1010 s−1). The dislocation extraction algorithm and common neighbor analysis are employed to identify the deformation mechanisms. Our results reveal that the yield stress decreases with temperature and increases with strain rate; whereas the elastic modulus decreases with temperature and is independent of strain rate. Furthermore, incipient plasticity is detected ahead of the yield point at lower temperatures and lower strain rates. Interestingly, the incoherent twin grain boundaries are quite mobile under the uniaxial tensile loading at lower temperatures and lower strain rates. But this mobility decreased at higher temperatures and higher strain rates, thereby, confirming this faceted grain boundary's non-Arrhenius (anti-thermal) migration behavior even under mechanical loading. From a deformation perspective, the incoherent twin facet of the grain boundary served as the major source for stacking fault formation at lower temperatures and higher strain rates. However, with the increase in temperature, the stacking faults became shorter and originated from both the incoherent twin facet and the tips of coherent twin facet. These results are in qualitative agreement with the experimental results documented in the literature.

Unravelling the atomistic-scale insights into tensile response of equiatomic cupronickel alloy with pre-existing faceted grain boundary interface

The aim of this research work is to investigate the effect of strain rates and temperatures on the mechanical properties of an equiatomic copper-nickel (Cu–Ni) alloy with a pre-existing faceted Σ3 [111] 60° {11 8 5} grain boundary. Molecular dynamics simulations conducted in this scrutiny focuses on understanding the tensile behaviour of bicrystalline equiatomic Cu–Ni alloys (denoted by Cu50Ni50) under various thermodynamic conditions. The uniaxial tensile deformation simulation was carried out at various strain rates (108, 109 and 1010 1/s) in conjunction with different conditions of cryogenic temperature (100 K), room temperature (300 K) and high temperature (500 K). The authors found that the yield stress and Young's modulus of the bicrystalline Cu50Ni50 alloy were highest at the cryogenic temperature, and decreased as the temperature increased. To add on, the yield stress of the bicrystalline Cu50Ni50 alloy increased with an increase in the strain rate value. From the microstructural and dislocation analysis point of view, it was observed that the formation of dislocations was lowest at the cryogenic temperature. Interestingly, at the yield point, the coherent twin boundary tip act as the nucleation site for the dislocations for cryogenic temperature condition. These findings shed light on the relationship between the temperatures, strain rates, and the mechanical properties of Cu–Ni alloys, which will aid in reporting the optimized conditions for their desired engineering applications. It is also proposed that tailoring of the tensile properties is achievable by exposing Cu–Ni alloys to various environmental conditions (cryogenic, ambient, and elevated temperatures with different applied strain rates).

MT-CVD Ti(C,N,O) coatings controlled by CO: Microstructure evolution and its effect on the hardness

Incorporation of oxygen into Ti(C,N) coating by CO doping during moderate temperature chemical vapor deposition (MT-CVD) process is a promising strategy for enhancing the performance of cutting tools. In this work, Ti(C,N,O) coatings were prepared by MT-CVD in a hot-wall industrial-scale CVD reactor with increased CO volume fraction from 0 % to 8.0 % in the feed gas mixture. Microstructure evolution is revealed by high-resolution scanning electron microscopy, electron backscatter diffraction detector, and high-resolution transmission electron microscopy. Its effect on the hardness is investigated. The results show that as the CO fraction increases, the microstructure changes from columnar and large faceted grains to equilateral and nanoscale grains. An increasing density of plane defects including twins, especially Σ3 twin boundaries and stacking faults are identified in Ti(C,N,O) coatings with increasing CO fraction. The hardness of Ti(C,N,O) coatings increase from 26 GPa at 0 % CO to 34 GPa at 8.0 % CO, due to the grain refinement, solution strengthening, increased stacking faults, twins and {111} texture. A considerably lower rate of hardness increase is observed at CO fractions above 4.0 %, which is hypothesized to be related to grain boundary sliding, residual chlorine and excessive density stacking faults.

Investigation of the Abnormally Large Grains of a Super304H Heat-Resistant Steel Tube over Long-Term, High-Temperature Service

Abstract Abnormally large grains (ALGs) were detected in the outer walls of Super304H superheater steel tubes of an ultra-supercritical unit in long-term service. In this study, the microstructure and mechanical properties of steel tube samples were investigated to reveal the formation mechanism of the ALGs. The results showed that the room-temperature and high-temperature strength and plasticity of the coarse-grain zone were much lower than those of the fine-grain zone. Inhomogeneous residual strain distribution in the outer wall led to high distortion energy differences in the as-supplied steel tube. The low-distortion austenite grains annex the neighboring high-distortion grains via the strain-induced grain boundary migration mechanism. Moreover, the two-dimensional step mechanism of the faceted grain boundaries also causes the ALGs to form.

Preparation of Molybdenum Coatings by Molten Salt Electrodeposition in Na3AlF6-NaF-Al2O3-MoO3 System

In this paper, electrodeposition of a molybdenum coating was conducted in Na3AlF6-NaF-Al2O3-MoO3 molten salts at 930 °C to investigate the availability of preparation of thick molybdenum coatings. The effects of current density and electrodeposition time on the morphology of the produced molybdenum coating were studied. With the increase of current density (10~70 mA·cm−2), the coating thickness was increased from 10 μm to 30 μm, with all the current efficiency above 97%. Under a current density of 30 mA/cm2, with the rise of electrodeposition time (10~60 min), three stages of the deposit growth were observed, including the formation of a large number of fine crystals, transformation into fibrous morphology and well-developed faceted grains. The formation of a large number of fine crystals at the initial stage of the electrodeposition could facilitate electroplating molybdenum coatings with good quality at higher current density and longer duration. Thus electrodeposition at a current density of 100 mA·cm−2 for 3 h has been performed, resulting in the preparation of relatively flat, dense, and coherent molybdenum coatings with a thickness of 140 μm on a nickel substrate, with a current efficiency above 85%. It is anticipated that the electrodeposition of molybdenum coatings in the present molten system is suitable for electroplating thick molybdenum coatings.

The effect of SbCl3 treatment on CdTe produced by close space sublimation method

In this study, influence of SbCl3 treatment on CdTe films deposited by the close space sublimation method was investigated. SbCl3 treatment was compared with conventional CdCl2 treated and untreated samples. It was determined that CdTe grew as Cd-rich and there was a slight decrease in Cd-amount after SbCl3 and CdCl2 treatments. In addition, a significant amount of Sb was detected in the SbCl3 treated sample. The samples crystallized in the cubic structure of CdTe. However, graded structures such as phase-I and phase-II with different structural parameters were formed. In the SbCl3 sample, it was revealed that the presence of Sb- caused a slight increase in the lattice parameter, compared to the other samples. Morphological analyses of the samples showed facet and large-small grain structures. CdCl2 treatment caused a slight decrease in grain size, while SbCl3 treatment resulted in a coarser and rougher grain structure. CdCl2 treatment increased transmittance, whereas SbCl3 treatment caused a decrease in transmittance (hence, an increase in absorbance). It was observed that the bandgaps were ∼1.49 eV in all samples, and annealing, as well as CdCl2 and SbCl3 heat treatments did not cause a sharp change in the bandgaps. Photoluminescence spectra revealed the presence of band-edge and shallow-level defect transitions (except CdCl2 treated) in the samples. All results suggest that SbCl3 heat treatment has a significant effect on CdTe and may be an alternative to CdCl2.

A study of high cycle fatigue life and its correlation with microstructural parameters in IN713C nickel-based superalloy

IN713C nickel-based superalloy is widely used in the form of turbine blades in the automobile industry. High cycle fatigue (HCF) or very-HCF is one of the major failure modes for the alloy. The significant grain structure/size variations produced during the casting process are supposed to affect its fatigue life. In the present study, IN713C cast bars with different grain structures and grain size were HCF tested under similar stress level (∼300 MPa) at 650 °C. The fatigue life, varying from ∼87,000 to 10 × 106 cycles, mainly determined by the size of porosity and faceting grain. Size of porosity determines the time of initiation of faceting and crack, i.e., the crack initiation stage, which occupies the major part of fatigue life. Smaller pore size leads to delay of faceting and higher fatigue life. Whilst size of facet has profound effects in the crack propagation stage. Smaller facet (grain) size leads to lower crack propagation rate and longer loading cycles, and finally contributes to higher fatigue life. This research revealed the beneficial effect of smaller grain size on fatigue property from the perspective of reducing initial crack propagation rate, which has rarely been reported before.

Synthesis of ΝbN faceted grains from oxides and boron nitride with sodium

Agglomerates of ε-NbN hexagonal prismatic faceted grains with a size between 5 and 50 μm were formed by heating Nb2O5 or NbFeO4 powder and Na lump in a BN crucible at 900–1100 °C under an Ar atmosphere. Wavelength-dispersive X-ray analysis demonstrated that the ε-NbN faceted grains have a nearly stoichiometric composition. In addition to the ε-NbN grains, powders of niobium nitrides containing δ-NbN and Nb2N, and water-soluble Na3BO3 were included in the sample prepared from Nb2O5 at 1100 °C, while powders of Fe and Na3BO3, and a trace of δ-NbN were included in the sample from NbFeO4. These reactions were attributed to metathesis reactions in which the oxygen in the oxides and the nitrogen in the solid nitrogen source, BN, were replaced by the formation of Na3BO3. An extra amount of nitrogen supplied from the starting material enhances the formation of ε-NbN and suppressed the formation of δ-NbN and Nb2N.

Phase-field modeling of solid-state sintering with interfacial anisotropy

Sintered structures observed in experiments can consist of faceted crystal grains. To predict the formation of such structures, a new phase-field (PF) model of solid-state sintering that can analyze morphological changes and microstructural evolutions considering the strong interface anisotropies of sintered particles was developed in this study. The developed PF model treats the crystal grain orientation-dependent surface and misorientation-dependent grain boundary anisotropies. Furthermore, this model employs quaternions to calculate the particle rotation, eliminating complicated calculations involved in analyzing the crystal orientation in three-dimensional (3D) simulations. The morphological change in a sintered particle and the grain boundary formulation at triple junctions simulated using the developed model were validated by comparing them with theoretical solutions. The neck growth and densification rates were investigated by performing 3D simulations using two particles with interface anisotropies. The simulation results revealed that neck growth and densification are affected by surface energy and mobility anisotropies. A 3D PF simulation using 200 particles demonstrated that the developed PF model can potentially reproduce sintered structures with faceted particles observed in experiments. The PF model provides a promising simulation for predicting the microstructural evolution of actual materials during solid-state sintering.

Crack initiation mechanism in a high-strength Ti-5Al-7.5V alloy subjected to high cycle fatigue loading

Fatigue crack initiation mechanism at high cycle regime in a bimodal Ti-5Al-7.5V alloy are investigated by fracture observations, focused-ion-beam cross-section and electron back-scattered diffraction characterizations. The aged Ti-5Al-7.5V exhibits superior tensile and fatigue properties, alongside a wide range of fatigue life when tested at the stress levels of ∼ 700–800 MPa. Fatigue failure was dominated by surface and subsurface crack initiation at facets matching basal planes. These faceted primary α (αp) grains generally have a medium or high Schmid factor (SF) for basal < a > slip. Moreover, a basal faceting process also occurred in the “hard” grains, in which the c-axis of the HCP-α grains was approximately parallel to the loading axis so that the < a > type slips were thought to be suppressed. The observed internal microcracks were formed along the grain boundaries located in clusters of αp grains, especially along (0001) twist boundaries. Furthermore, transmission electron microscope observations evidenced the absence of intense slip bands within faceted grain and fatigued αp grains, which indicates that the facet growth should not along the pre-existing slip bands resulting from high cycle fatigue loadings. The pre-existing structural defects including dislocation networks and subgrain boundaries within αp grains are relatively stable configurations under fatigue loadings. The observed fine (∼500 nm in diameter) silicides were widely dispersed, whether the silicide can act as the crack nucleation site still needs further more detailed studies and this remains an open question.

Melt/solid interaction and melt super-saturation effect on the microstructure asset of ultra-refractory composites prepared by reactive melting infiltration

The reactions occurring between a Zr2Cu melting phase and possible compounds intended for use in ultra-refractory ceramic matrix composite, i.e. SiC, TiB2 and ZrB2 are first explored through sessile drop tests, confirming a promising infiltration capability of the melt. Then, a multiphasic ultra-high temperature ceramic matrix composite was prepared by reactive melt infiltration (RMI), using a TiB2-coated carbon fiber preform infiltrated with Zr2Cu at 1500 °C which resulted in the precipitation of ZrB2 and ZrC sub-micrometric faceted grains and a general damage of both fiber and fiber coating, which were penetrated by the melt. Then, to decrease the RMI process temperature down to 1200 °C and limit the fiber damage degree, a second composite was prepared by introducing an additional ZrB2-B infiltration step. Although processing at 300 °C lower, notable alteration of the fiber occurred upon reaction with the Zr2Cu melt and developed a ZrC layer around them, but still allowing pull-out. In addition, the local B-rich environment promoted the development of a dual-phase microstructure within the matrix composed of new sub-micrometric grains and of larger ZrB2 grains, partially dissolved in the melt and re-precipitated acquiring a nano-sized lamellar eutectic structure. The combination of factors on multiple scale length, from the micro- of the fiber to the nano-of the lamella, seems to provide synergistic reinforcing phenomena and thus could be a valuable approach to develop materials for extreme environments.

Microstructure and integrity of multilayer ceramic coating with alumina top coat on silicon carbide by laser chemical vapor deposition

Thin double-layer coatings comprising an alumina top coat and mullite bond coat were deposited on SiC substrates by laser chemical vapor deposition (CVD). The effect of the presence of mullite bond coat and the phases of alumina top coat on the structural integrity against the thermal residual stress loaded by the high-temperature CVD process was examined by microstructural characterization and simulative consideration. A laminated layered structure having a dense γ-alumina top surface with a cone-like morphology are grown at a deposition temperature of 1323 K, whereas an α-alumina top layer comprising densely packed faceted grains was grown at 1473 K. The interfaces between the SiC and mullite layers were coherent owing to the formation of a thin transition layer. The γ-alumina layer formed an adhesive interface bordering the mullite layer, whereas small residual defects were formed in the α-alumina layer bordering the mullite layer. Spacings of surface cracking induced by the high-temperature deposition process in the double-layer coatings were approximately half of those in the coatings without mullite layers. As simulative results by finite element method suggested, the double-layer coatings were experimentally verified to be more tolerant to the formation of surface cracks and interfacial delamination, compared to single-layer coatings without the mullite bond layers.