Low traces of acetone detection with WO3-based chemical sensors

Abstract

This work presents the ability of WO3-based sensors to detect low traces of acetone, specifically within the range of 0.25–5 ppm, specific to the in-field atmosphere. The WO3 powder was synthesised through the hydrothermal method. Morpho-structural investigations showed a monoclinic structure and a good crystallization of the WO3 powder, containing well-grown and faceted grains along low-index crystallographic planes. The paste obtained by mixing the powder with propanediol was screen-printed as a thick layer onto commercial alumina substrates, obtaining the chemical sensors. A dynamic computer-controlled Gas Mixing System was utilized to ensure controlled airflow with variable relative humidity and acetone concentrations. The sensor response was explained based on physico-chemical equations, taking into consideration pre-adsorbed species of oxygen and water, both of which are relevant constituents of atmospheric conditions. The results highlight the applicative potential of WO3, having a good signal-to-noise ratio in relative humidity conditions up to 90% and a pronounced sensitive selectivity to acetone.