Experimental Scheme Research Articles

Research on Radial Double Velocity Measurement Method of Laser Tracker

For the dynamic problem that the low-speed sliding table is unable to meet the radial measuring speed of the laser tracker, this paper takes the sliding table of the indoor large-length standard device as the moving object to double the measuring distance by adding a pyramid prism, thereby doubling the radial speed of the laser tracker. In this paper, the measurement data are analyzed through equal interval measurement experiments, equal sampling frequency experiments and repeatability measurement experiments using a pyramid prism to obtain the following conclusions, respectively: Firstly, the stability of the actual interval of the laser tracker is optimal when the rated speed of the sliding table is 50 mm/s. When the pyramid prism is not used, the minimum standard deviation obtained by the laser tracker at a sampling interval of 5 mm is 0.0158 mm. Secondly, during the equal sampling frequency measurement, the stability of the laser interferometer is better than that of the laser tracker when the pyramid prism is not used. With two instruments at a sampling frequency of 10 Hz, the standard deviations of the local velocity of the laser interferometer are 0.1466 mm/s, 0.0693 mm/s and 0.1106 mm/s, respectively. The standard deviations of the laser tracker are 0.1582 mm/s, 0.1033 mm/s and 0.2008 mm/s, respectively. The same conclusion is obtained at a sampling frequency of 20 Hz. The stability of the laser tracker is better than that of the laser interferometer when the pyramid prism is used. Thirdly, the stability and reliability of the local velocity of the laser tracker are better than that of the laser interferometer. For example, at 10 Hz, the standard deviations of the local velocity of the laser tracker are 0.2745 mm/s and 0.2097 mm/s, respectively, and the repeatability of the local velocity is 0.9140 mm/s. The standard deviations of the local velocity of the interferometer are 0.6141 mm/s and 0.6368 mm/s, respectively, and the repeatability of the local velocity is 1.4886 mm/s. And the local velocity of the two measuring instruments is more reliable and stable at a low frequency (10 Hz). This experimental scheme provides a way to measure the high speed of a laser tracker using a sliding table at low speed.

The physical and chemical properties of the technosols in the pot experiment with waste and groundwater irrigation


 
 
 Mediterranean areas are characterized by a strong spatial variability that makes the soil hydrogeological logical response highly complicated. Some seasons provoke dramatic changes in soil properties determining the runoff rates, such as soil water content or soil water repellency. In recent years, important progress has been made in adapting water needs to local conditions through the use of various parameters to assess soil water status. Estimation of the water status of the soil has been widely used in soil science as a tool for quantitative analysis. The main objective of this case study was to analyze technosol and irrigation water physical and chemical properties in the pot experiment with lysimeters. A pot experiment with Avocado rootstocks was equipped with lysimeters in the facilites of the «La Mayora Experimental Field site» of the Higher Council for Scientific Research (Spain). The scheme of the pot experiment included three sources of irrigation: a) groundwater; b) regenerated municipal wastewater (100%); c) a mix of ground and regenerated municipal wastewater (50 / 50%). Chemical analysis data indicate that the reclaimed wastewater does not meet irrigation requirements in terms of pH, EC and due to the significant content of sodium and chlorine. Even groundwater satisfies irrigation water qualitative requirements partially. The suitability of irrigation water on pH level can be characterized mainly as unsuitable and doubtful. Diluting regenerated wastewater with groundwater following the 50% principle led to a decrease in the potential risks for salinization of groundwater connected with leaching of the leachate. The dynamics of the change in the volume of leachate are related to precipitation, the frequency of irrigation, and different manifestations of the physical, mineralogical, and chemical properties of technosols.
 
 

Buckling Defect Optimization of Constrained Ring Rolling of Thin-Walled Conical Rings with Inner High Ribs Combining Response Surface Method with FEM

A buckling defect will appear on the outer surface of the deformed ring during the constrained ring rolling (CRR) of an aluminum alloy thin-wall conical ring with inner high ribs (AATWCRIHR) if the geometrical dimension of the ribs does not match the wall thickness. To avoid the buckling defect, a quantitative method for characterizing the degree of the buckling defect is proposed using the area of the buckling profile. Then, an orthogonal experimental scheme was designed, taking the width of the middle rib, thickness of wall, and height of the middle rib as the design variables and defining the area of the buckling profile as the optimization objective. Subsequently, a quadratic polynomial response surface model was established by combining the optimization algorithm with the finite element method (FEM), and the geometrical dimension of the middle ribs of the deformed AATWCRIHR is optimized. Moreover, the optimal parameter combination to minimize the area of the buckling profile is obtained and verified using FE simulation. The results show that the AATWCRIHR after optimization does not generate the buckling defect during constrained ring rolling, and it is proven that the quantitative buckling defect representation method and the optimization design method based on the response surface model and the finite element simulation results are feasible for the constrained ring-rolling process of the AATWCRIHR.

Conformer-Selective Photoelectron Circular Dichroism.

Conformational flexibility and chirality both play a key role in molecular recognition. It is therefore very useful to develop spectroscopic methods that simultaneously probe both properties. It has been theoretically predicted that photoelectron circular dichroism (PECD) should be very sensitive to conformational isomerism. However, experimental proof has been less forthcoming and only exists for a very few favorable cases. Here, we present a new PECD scheme based on resonance-enhanced two-photon ionization (RE2PI) using UV/Vis nanosecond laser excitations. The spectral resolution obtained thereby guarantees conformer-selectivity by inducing resonant conformer-specific ππ* S1←S0 transitions. We apply this experimental scheme to the study of chiral 1-indanol, which exists in two conformers linked by a ring inversion and defined by the position of the hydroxyl group, namely axial and equatorial. We show that the PECD of the equatorial and axial forms considerably differ in sign, magnitude and shape. We also discuss the influence of the total ionization energy, vibronic excitation of intermediate and final states, and relative polarization of the excitation and ionization lasers. Conformer-specificity adds a new dimension to the applications of PECD in analytical chemistry addressing now the general case of floppy systems.

Conformer‐Selective Photoelectron Circular Dichroism

AbstractConformational flexibility and chirality both play a key role in molecular recognition. It is therefore very useful to develop spectroscopic methods that simultaneously probe both properties. It has been theoretically predicted that photoelectron circular dichroism (PECD) should be very sensitive to conformational isomerism. However, experimental proof has been less forthcoming and only exists for a very few favorable cases. Here, we present a new PECD scheme based on resonance‐enhanced two‐photon ionization (RE2PI) using UV/Vis nanosecond laser excitations. The spectral resolution obtained thereby guarantees conformer‐selectivity by inducing resonant conformer‐specific ππ* S1←S0 transitions. We apply this experimental scheme to the study of chiral 1‐indanol, which exists in two conformers linked by a ring inversion and defined by the position of the hydroxyl group, namely axial and equatorial. We show that the PECD of the equatorial and axial forms considerably differ in sign, magnitude and shape. We also discuss the influence of the total ionization energy, vibronic excitation of intermediate and final states, and relative polarization of the excitation and ionization lasers. Conformer‐specificity adds a new dimension to the applications of PECD in analytical chemistry addressing now the general case of floppy systems.

Identification of vector autoregressive models with nonlinear contemporaneous structure

We propose a statistical identification procedure for recursive structural vector autoregressive (VAR) models that present a nonlinear dependence (at least) at the contemporaneous level. By applying and adapting results from the literature on causal discovery with continuous additive noise models, we show that, under certain conditions, a large class of structural VAR models is identifiable. We spell out these specific conditions and propose a scheme for the estimation of structural impulse response functions in a nonlinear setting. We assess the performance of this scheme in a simulation experiment. Finally, we apply it in a study on the effects of the macroeconomic shocks that propagate through the economy, allowing for asymmetry between responses from positive and negative impulses.

Visual performance as a factor of increase performance in ball shooting

The article examines the question of the effectiveness of the factor of visual performance on indicators of technical training of shooters of different levels. In particular, the indicator of the average length of the aiming trajectory during the performance of the competitive exercise AP-3 on the electronic simulator "Scatt" was studied. The purpose of the article: to justify the need to use indicators of visual performance when analyzing the technical characteristics of a shot, obtained on the basis of the use of the optoelectronic simulator "Scatt". The methodological basis of the study was a systematic approach, which allows considering the aiming phase as a complex functional system of constant sensory control over the shooter's precise movements. The research used the method of computer simulation of the execution of a shot based on the use of an electronic simulator. To study visual performance, the correction test method was used. To assess visual productivity, which characterizes working capacity, the Weston formula was used, which calculated the quality and speed of visual work, as well as its integral index. The scheme of the ascertainment experiment consisted in the parallel collection of data on indicators of technical readiness and visual performance when performing the competitive exercise AP-3 (AP-60 according to the international classification) on the " Scatt " simulator. Correction sheets were filled out before and after the mentioned competitive exercise. The scientific novelty consists in substantiating the significance of the factor of visual performance as a stable sensory ophthalmoergonomic basis of the predictor of the average length of the aiming trajectory.

Effect of particle size distribution on the transmission efficiency of atomized water to the tracheal tube

Ultrasonic atomization is a widely used technology. As the atomization device, lead zirconate titanate (PZT) and lithium niobate (LN) are comparatively investigated through experimental and numerical schemes. However, knowledge on a profitable scheme by which to efficiently deliver the atomized particles into the tracheal tube remains unclear. In this study, the physical difference of the transmission efficiency of water particles atomized by PZT and LN devices was measured. The water particles atomized by PZT and LN were injected into a human airway model including a nasal cavity and bronchial tube. The distribution of the amount of transmitted particles deposited at each of the monitoring positions was then estimated using the results of image analysis of color intensity. As a result, the atomized particles of the PZT device, which produced larger particles than the LN device, were more strongly affected by inertia and tended to be deposited at the area closer to the entrance of the nasal cavity. In contrast, the particles produced by the LN device tended to be transmitted deeper into the trachea. The experimental results indicated that the particle size distribution of PZT and LN, which have quite different maximum sizes of particles, largely influences the spatial distribution characteristics of particle deposition along the airway from the nasal cavity to the trachea.

Confidence Intervals for Parameters of Unobserved Events

Consider a finite sample from an unknown distribution over a countable alphabet. Unobserved events are alphabet symbols which do not appear in the sample. Estimating the probabilities of unobserved events is a basic problem in statistics and related fields, which was extensively studied in the context of point estimation. In this work we introduce a novel interval estimation scheme for unobserved events. Our proposed framework applies selective inference, as we construct confidence intervals (CIs) for the desired set of parameters. Interestingly, we show that obtained CIs are dimension-free, as they do not grow with the alphabet size. Further, we show that these CIs are (almost) tight, in the sense that they cannot be further improved without violating the prescribed coverage rate. We demonstrate the performance of our proposed scheme in synthetic and real-world experiments, showing a significant improvement over the alternatives. Finally, we apply our proposed scheme to large alphabet modeling. We introduce a novel simultaneous CI scheme for large alphabet distributions which outperforms currently known methods while maintaining the prescribed coverage rate. Supplementary materials for this article are available online including a standardized description of the materials available for reproducing the work.

Experimental Proposal on Non-Hermitian Skin Effect by Two-dimensional Quantum Walk with a Single Trapped Ion

Non-Hermitian Hamiltonians are widely used in describing open systems with gain and loss, among which a key phenomenon is the non-Hermitian skin effect. Here we report an experimental scheme to realize a two-dimensional (2D) discrete-time quantum walk with non-Hermitian skin effect in a single trapped ion. It is shown that the coin and 2D walker states can be labeled in the spin of the ion and the coherent-state lattice of the ion motion, respectively. We numerically observe a directional bulk flow, whose orientations are controlled by dissipative parameters, showing the emergence of the non-Hermitian skin effect. We then discuss an experimental implementation of our scheme in a laser-controlled trapped Ca+ ion. Our experimental proposal may be applicable to research of dissipative quantum walk systems and may be able to generalize to other platforms, such as superconducting circuits and atoms in cavity.

Improving the dyeability of ramie fibre by sequential alkaline and alcohol pretreatments

The high crystallinity of ramie fibre poses challenges in achieving optimal dyeing performance, such as reduced dye exhaustion. To enhance the dyeing capabilities of ramie fibre, several alterations were experimented with, such as caustic mercerization using a NaOH solution. However, because of the high NaOH concentration, removing the NaOH residue from inside the fibre becomes challenging. Herein, the present research aims to enhance the dyeing efficiency of ramie fibre by using sequential alkaline and alcohol pretreatment methods to reduce NaOH usage, accordingly relieving the wash process stress. The preliminary screening findings have revealed that iso-butanol is the most suitable alcohol solvent for modifying ramie fibres after treating it with NaOH solution since it leads to higher dye exhaustion (E%, 95.7%), dye fixation rate (F%, 88.2%), total dye fixation efficiency (T%, 84.4%), and K/S values (41.4). After that, the orthogonal array experimental scheme (L16) was applied to optimize dyeing performance. The NaOH usage was decreased to 160 g/L, the treating time was reduced to 3 min, and the dyeing performance of ramie fibre treated under the optimum conditions was better than that of a caustically mercerized one. It was determined that the NaOH concentration factor had the most contribution, accounting for 75.34% of the observed effects. The NaOH solution temperature factor followed closely behind, contributing 22.69%. Additionally, using analytical methods such as XRD, FTIR, TG, and SEM confirmed that the sequential treatment with the optimum conditions altered the structural behaviour of the original ramie fibre, which performances were similar to the mercerized ramie fibre. The barium value of sequentially iso butanol solvent treated fibre showed a greater level (213) compared to caustic mercerized fibre (179), indicating a significant advantage of mercerization performance was achieved. This advantage may be linked to improved colourfastness and handling qualities. Furthermore, the breaking force of both ramie fabrics was increased after the alkaline treatment and the sequential alkaline and iso-butanol treatment.

Selecting mode by the complex Berry phase in non-Hermitian waveguide lattices

Bloch oscillations (BOs) in a parity-time (PT)-symmetric Su–Schrieffer–Heeger (SSH) waveguide array are theoretically investigated. We show that the BOs are amplified or damped even for the systems to exhibit entirely real energy bands. The amplified and damped BOs stem from the complex Berry phase and closely relate to the topological properties of the lattice. For the topological nontrivial lattice, the amplification and attenuation of BOs are much more prominent than the trivial case and the output Bloch mode can be selected. Furthermore, we propose an experimental scheme and perform a numerical simulation based on a bent waveguide array. Our work uncovers the impact of the topological properties on the dynamics of the bulk Bloch modes and unveils a horizon in the study of non-Hermitian physics. The mode selection induced by the complex Berry phase may also find application in integrated photonic devices such as the mode filter.

Numerical Simulation of Storm Surge Inundation in Estuarine Area Considering Multiple Influencing Factors

With global climate change, the risk of extreme storms and storm surges in estuarine areas is increasing; thus, storm surge inundation research and prediction have become important issues to ensure sustainable development in estuarine areas. The Jitimen estuary in Guangdong Province, China, was chosen as our study area. In this study, a numerical model for simulating storm surge inundation in small regions based on unstructured triangular grids was established, and the model accuracy was validated. The typhoon characteristics in the study area were statistically analyzed based on historical data. Three experimental schemes, involving factors influencing storm surge inundation, such as typhoon landfall location, intensity, and direction, were used to evaluate the differences in the numerical results. The results showed that when the typhoon landfall direction remained unchanged and the highest tide levels at the Sanzao tide gauge station were similar, the differences between the numerical results for the typhoon landfall location and typhoon intensity schemes were less than 5%, and the inundation characteristics were similar. However, when the typhoon location and intensity were unchanged and the highest tide levels at the Sanzao tide gauge station were similar, the numerical results for the typhoon landfall direction scheme significantly differed; this result was caused by the difference in the duration of the high tide level (exceeding 3 m); these results indicated that the topographic characteristics and the typhoon landing direction had a greater impact on storm surge inundation. The results from this study can aid in the prediction of storm surge inundation information for the Jitimen estuary area when the typhoon landing direction and the maximum tide level are known.

A simple weighting method for inverting earthquake source parameters using geodetic multisource data under Bayesian algorithm

SUMMARY More accurate inversion of source fault geometry and slip parameters under the constraint of the Bayesian algorithm has become a research hotspot in the field of geodetic inversion in recent years. In nonlinear inversion, the determination of the weight ratio of the joint inversion of multisource data is more complicated. In this context, this paper proposes a simple and easily generalized weighting method for inversion of source fault parameters by joint geodetic multisource data under the Bayesian framework. This method determines the relative weight ratio of multisource data by root mean square error (RMSE) value and can be extended to other nonlinear search algorithms. To verify the validity of the method in this paper, this paper first sets up four sets of simulated seismic experiment schemes. The inversion results show that the joint inversion weighting method proposed in this paper has a significant decrease in the large residual value compared with the equal weight joint inversion and the single data source joint inversion method. The east–west deformation RMSE is 0.1458 mm, the north–south deformation RMSE is 0.2119 mm and the vertical deformation RMSE is 0.2756 mm. The RMSEs of the three directions are lower than those of other schemes, indicating that the proposed method is suitable for the joint inversion of source parameters under Bayesian algorithm. To further verify the applicability of the proposed method in complex earthquakes, the source parameters of the Maduo earthquake were inverted using the method of this paper. The focal depth of the inversion results in this paper is closer to the focal depth released by the GCMT agency. In terms of strike angle and dip angle, the joint inversion in this paper is also more inclined to the GCMT results. The joint inversion results generally conform to the characteristics of left-lateral strike-slip, which shows the adaptability of this method in complex earthquakes.

Entangled Two-Photon Absorption in Transmission-Based Experiments: Deleterious Effects from Linear Optical Losses.

Recently different experimental schemes have been proposed to study the elusive phenomenon of entangled two-photon absorption (ETPA) in nonlinear materials. The attempts to detect ETPA using transmission-based schemes have led to results whose validity is currently under debate because the ETPA signal can be corrupted or emulated by artifacts associated with linear optical losses. The present work addresses the issue of linear losses and the corresponding artifacts in transmission-based ETPA experiments through a new approach that exploits the properties of a Hong-Ou-Mandel (HOM) interferogram. Here, we analyze solutions of rhodamine B (RhB), commonly used as a model of a nonlinear medium in ETPA studies. Then, by using the HOM interferometer as a sensing device, we first demonstrate the equivalence of the standard transmission vs pump power ETPA experiments, presented in many reports, with our novel approach of transmission vs two-photon temporal delay. Second, a detailed study of the effects of optical losses, unrelated to ETPA, over the HOM interferogram is carried out by: (1) characterizing RhB in solutions prepared with different solvents and (2) considering scattering losses introduced by silica nanoparticles used as a controlled linear loss mechanism. Our results clearly expose the deleterious effects of linear optical losses over the ETPA signal when standard transmission experiments are employed and show how, by using the HOM interferogram as a sensing device, it is possible to detect the presence of such losses. Finally, once we showed that the HOM interferogram discriminates properly linear losses, our study also reveals that under the specific experimental conditions considered here, which are the same as those employed in many reported works, the ETPA was not unequivocally detected.

Analysis and research on polarized radiation characteristics of ship targets at sea

The traditional ship infrared detection method cannot solve the edge details when the ship target interacts flexibly with the sea surface background. Polarization detection technology has gradually become an important research direction for high-precision detection of marine targets because of its advantages of acquiring the intrinsic characteristics of targets. This paper selects the typical part panels and scaled models of ships as experimental research object, focusing on the analysis of the polarized radiation characteristics of marine ship targets. Starting from the principle of polarization detection, we extended the application of the bidirectional polarization reflection distribution function that can obtain the polarization spectral characteristics of the target. According to the principle of time-sharing polarization detection, we designed a simulation experiment scheme for the polarization characteristics of the typical parts of the ship and the overall model related to the sea surface background. Finally, we implemented the measurement experiment of multi-angle polarization characteristics in the field and performed data analysis. The results show that: (1) The polarization reflectivity and polarization degree of the typical parts of the ship tend to be consistent with the changes of the observation geometric conditions, both increase with the increase of the observation zenith angle, and the forward scattering area is larger than the back scattering area. (2) The observation direction has a great influence on the overall detection results of the ship. When using the 30°zenith angle of the forward scattering area of the main plane for observation, the contrast between the ship and the water body is obvious, and it is easy to detect the ship.

Shape reconstruction of axisymmetric Taylor bubbles using conductivity probes through a scheme of combined experiment and theory.

A simple measurement scheme is proposed to reconstruct the geometry of an axisymmetric void propagating through a conducting liquid using a pair of parallel wire conductivity probes. An experimental study allows for obtaining the time variation of the resistance of the film surrounding the void. Analytical modeling and numerical simulation has been adopted to correlate the resistance between the wire electrodes and the film thickness. Finally, the shape of the void can be estimated by combining the predicted resistance-film thickness relationship and the measured time variation of resistance. For validation, this scheme has been used to reconstruct the shape of a rising Taylor bubble. There is a fair match between the reconstructed shape of the bubble and its photographic image. The probable errors in the measurement scheme have been discussed and assessed mathematically.

Numerical study of the suppression of magnetic reconnection onset with injected plasma

In this study, we perform two simulations with different plasma injection times. These simulations use the experimental setup of double-coil target-driven magnetic reconnection. The injected plasma is introduced as an external factor influencing the suppression of magnetic reconnection. Under the influence of the injected plasma, the magnetic field cannot pile up in the current sheet because the magnetic force and thermal pressure on both sides have decreased. As a result, under the combined influence of these factors, the current sheet cannot become sufficiently thin and reconnection is suppressed. Consequently, the terms for electron inertia and the non-diagonal components of the electron pressure tensor, which contribute to the reconnection electric field, are all smaller due to a reduction of the magnetic flux in the current sheet. The study provides a plausible experimental scheme for studying the onset of magnetic reconnection in the laboratory. It may also potentially provide new ideas for investigating the onset of magnetic reconnection in different environments, such as turbulent magnetic reconnection in Earth's magnetosheath.

Метод оценки факторов, влияющих на вибрацию судового дизеля, вызванную работой цилиндропоршневой группы

The efficiency of the use of the marine fleet is associated with a reduction in the cost of transportation, the need for which is steadily increasing. A significant share of the total transportation costs is occupied by the costs associated with the operation of ships, therefore, reducing these costs is a reserve for reducing the cost of maritime transportation. The problem of increasing the efficiency of the operation of marine vessels is closely related not only to reducing the cost of it, but also to reducing the time for maintenance and repair of ships. The existing system of scheduled preventive maintenance and repair provides for the maintenance and restoration of the normal technical condition of the vessel and its elements with a pre-planned frequency. The transfer of ships to work with extended repair periods is possible only when solving a whole range of engineering and technical measures and scientific research aimed at improving the quality of repairs, the level of technical operation, improving logistics, etc. An essential role in this is played by the use of modern methods and means to determine the technical condition of shipboard devices and mechanisms, primarily engines of shipboard power plants (SEUs), without disassembling them. High vibration loads of SEU parts lead to fatigue stresses, accelerate wear of the contacting surfaces, reducing the reliability and service life of marine diesel engines, therefore monitoring of their vibration activity is important, especially during operation. The safe operation of ships of the transport fleet largely depends on the reliability of marine diesel engines. Technical means of monitoring their operability in the process of work are currently insufficiently effective and need to be improved. It is relevant not only to develop new, more advanced and mobile hardware and software, but also to search for new scientific and methodological approaches to using the information contained in the spectrum of vibration parameters. Marine diesel internal combustion engines are complex systems that involve many variable parameters. The study of such engines requires the use of methods that can be used to systematically investigate the influence of various factors on their operation, in particular, random experimental schemes are used, since they provide systematic control over variable parameters and maximize the accuracy of estimates. The results of the application of the method of ranking the factors influencing the vibration of a marine diesel engine are presented in order to establish the most significant of them. A mathematical model is presented that allows calculating current values and predicting changes in the most significant indicators, among which the most important is the size of the gap between the piston and the cylinder sleeve.

Experimental research on compressive strength deterioration of coal seam floor sandstone under the action of acidic mine drainage

In sulphur-coal symbiotic coal seams, after the mining of sulphide iron ore, when the coal resources are mined, the mine water accumulated in the roadway mining area will have a certain impact on the stability of the surrounding rock of the coal seam roadway. Taking the floor sandstone of sulfur coal symbiotic coal seam as the research object, the roof fissure water with pH values of 7.48, 4.81 and 2.62 was used as the experimental solution. 10 experimental schemes were designed to measure the compressive strength of the samples under the action of AMD, and the hydrochemical analysis of AMD was conducted. The pore structures of the samples before and after the action of AMD were analyzed. Based on the hydrochemistry and pore structure, the deterioration mechanism of compressive strength of the coal seam floor sandstone under the action of AMD was explained. The results indicated that the compressive strength of the samples decreased with the increasing action time of AMD. The compressive strength decreased with the increment of the porosity. The concentration of H+ ion in AMD was relatively small. Na2O in albite dissolved and reacted with water, leading to an increase in the concentration of Na+ ion. Soluble substances such as MgCl2 and CaSO4 in the pore structure dissolved, leading to an increase in the concentration of Ca2+ and Mg2+ ions. The dissolution of soluble substances and the physical–chemical reactions between solutions and minerals were the essential causes of the continuous deterioration of the compressive strength of the coal seam floor sandstone. The results of this study can provide a theoretical basis for the deterioration of the mechanical properties of the peripheral rock in the roadway of the sulphur coal seam, and can also provide a certain engineering reference for the sulphur coal seam roadway.