This study aimed to seek for effective educational methods by sharing experiential cases of peaceful unification education for college students and also considering the characteristics of college students. This study shared the peaceful unification education performed as a part of extracurricular activity of C university in K province during the second semester of 2021. C university performed varied education including five times of special lecture on peaceful unification, experiential peaceful unification education, and unification field trip during a semester. Among them, the experiential peaceful unification education aimed to add meanings to it by combining lecture and experiential activities, which aimed to share opinions of participated college students. As college students are the key generation that should design and prepare for the unification process of South and North Korea and the unified future, they need to be encouraged to participate in it. The peaceful unification education of college would need to connect the educational content, major, and college students who are the subjects of unification education, and also to reflect the characteristics of the generation.