The first human deaths due to air pollution were recorded in the mid-20th century. There were 6,000 cases of illness recorded in Donora, Pennsylvania, in 1948 and 20,000 in London in 1952; 15 and 4,000 cases of death, respectively, were allegedly ascribed to air pollution. Since then, many countries have adopted standards of air quality in order to protect environmental and human health, although the quality of the air in some industrialized countries remains worrying. Emerging countries in the Far East and South America are also cause for concern because of the growth in the population, industrialization and transport (1). The WHO World Health Report 2002 estimated that air pollutants, particularly PM10, are associated with a mortality rate of 5% for cancer of the respiratory system, 2% for cardiovascular diseases and about 1% for respiratory tract infections. These estimates consider the mortality but not the morbidity rate, which would increase proportionally the number of cases of these pathologies, despite the difficulty in evaluation (2). ENVIRONMENTAL POLLUTANTS According to the Italian Presidential Decree no. 203 dated May 24th 1998, air pollution is defined as “any modification to the normal composition or to the physical state of the air, due to the presence of one or more substances in such quantities and characteristics as to alter its healthiness and the normal environmental conditions; this contamination can be directly or indirectly dangerous for human health and could jeopardize recreational and normal activities performed in the environment. Moreover, this could seriously affect biological resources, the ecosystem, and public and private tangible assets”. The thus-defined pollutants, which can be in gaseous, liquid or solid form, are commonly classified as either primary or secondary. Primary pollutants are released into the atmosphere directly by nature or as a consequence of human activity. Many of these pollutants, which have an elevated reactivity, either intrinsic or sunlight-induced, can combine easily or react with natural substances in the atmosphere, causing secondary pollutants. The main pollutants derive from: the combustion process in car engines, domestic heating and industrial equipment; wear and tear and the dispersion of materials, e.g. the road surface and car tires; certain manufacturing processes.