Biobased solid particles for stabilizing high internal phase emulsions (HIPEs) are widely used in food and cosmetics industries. This study report a kind of zein-cyclodextrin complex particles which could HIPEs with various oil phases (log P values: 1.14–9.26), showcasing their wide applicability across different oil types. This versatility due to the slight differences (6–8°) in the three-phase contact angles for different oils. Furthermore, the complex particles showed a marked improvement in emulsification performance, as evidenced by their significantly higher diffusion rates (7–15 times faster) and reorientation speeds (2–5 times faster) at the oil-water interface. Moreover, the emulsions prepared were stable across a broad pH range (3–9), successfully addressing the common stability challenges associated with protein-based emulsifiers near their isoelectric points. Therefore, these complex particles have great potential in cosmetics, waste oil treatment and food field, such as multifunctional 3D bioprinting ink.