Emission Threshold Research Articles

A Brief theoretical approach on Green Hydrogen Production

Many different technical techniques can be used to manufacture hydrogen from both renewable and nonrenewable feed supplies while reducing greenhouse gas emissions. Hydrogen is employed in upcoming low-carbon energy systems since it emits relatively little carbon. The bulk of the present green hydrogen activities are geared toward the possibility of a green hydrogen market. Green hydrogen and origin guarantees have been defined using various approaches. These vary according on the following: the carbon financial statements' characteristics; the emission threshold at which hydrogen is classified as green; the plan's feedstock and production techniques; and whether or not sustainable hydrogen must be produced through the use of renewable energy. To overcome obstacles and improve green hydrogen production's viability as a sustainable energy source, research is always moving forward. To hasten green hydrogen's integration into clean energy transitions and slow down global warming, research efforts are concentrated on increasing its efficiency, cutting prices, and broadening its applications. A study that focused on the near-zero carbon production method of green hydrogen by electrolysis using renewable energy sources underscored the advancements and prospects of this field of study. This article describes the current techniques for creating hydrogen from sustainable and renewable energy sources. Keywords: Green Hydrogen, Biomass, Efficiency, Renewable, Hydrogen production.

Secondary roughness effect of surface microstructures on secondary electron emission and multipactor threshold for PTFE-filled and PI-filled single ridge waveguides

Secondary electron yield (SEY) is a dominant factor in determining the multipactor threshold. In this study, we analyzed the secondary roughness effect of surface microstructures for plastic dielectric on SEY reduction and multipactor mitigation. A single ridge waveguide (SRW) operating in Ku-band, filled with polytetrafluoroethylene (PTFE) or polyimide (PI), was designed with a dielectric–metal multipactor gap. By employing a femtosecond laser, periodic microstructures were fabricated on PTFE and PI surfaces to suppress SEY. The SEY peak values of PTFE and PI decreased from 2.05 to 1.40 and 1.37 to 1.07 by the porous surface. The surface morphologies and cross-sectional images of the porous PTFE and PI demonstrated the existence of secondary roughness structures. Via simulation, we obtained multipactor thresholds of 8496 W, 12 374 W, and 9397 W for the SRWs filled with untreated PTFE surface, ideal porous surface (without secondary roughness), and real porous surface (with secondary roughness). Similar works were implemented for the PI-filled SRWs, resulting in simulated multipactor thresholds of 7640 W, 11 327 W, and 9433 W. The results indicate that the multipactor effect may not be effectively suppressed under the influence of secondary roughness structures such as plastic velvet and foam. Besides, simulation works indicated that the radio frequency electric field could extract secondary electrons from the microstructures, weakening the mitigation effect of microstructures on multipactor. The impact of surface charging on electron motion was also analyzed by considering energy distribution. It was suggested that the surface microstructures of plastic dielectrics lead to a decrease in the surface charge density and the electrostatic field strength, weakening the self-extinguishing effect and lowering the multipactor threshold. This study provides an in-depth analysis of the effect of secondary roughness on SEY and multipactor for organic dielectrics, which makes significant sense for the further investigation of dielectric multipactor.

Exhaust Emission Control in Sport Motorcycles: A Comparison of Catalytic Converters with Alternative Metal Materials

In this modern era, motor vehicles have brought significant changes in human life. Faster and more efficient mobility has increased connectivity between regions, supported economic growth, and improved quality of life. However, increased mobility also means an increase in vehicle exhaust emissions, which contribute to climate change and air pollution. One effective technology for controlling exhaust emissions is the use of catalytic converters. Metal catalytic converters, such as copper, brass, and chrome-plated copper, have been researched as more affordable and effective catalyst alternatives. This research aims to analyze the optimal design of exhaust systems with catalytic converters among three types of alternative materials (copper, brass, and chrome-plated copper) as well as standard exhaust systems without catalysts (STD NC) and standard platinum group metal exhaust systems (STD PGM) in maximizing the reduction of motor vehicle exhaust emissions. An experimental research design was used by utilizing a 2015 Yamaha Vixion Lightning as the research object. Catalytic converters were prepared with specific specifications to ensure consistency and accuracy in measurements. CO (carbon monoxide), HC (hydrocarbons), CO2 (carbon dioxide), and O2 (oxygen) emissions were analyzed using an Exhaust Gas Analyzer. The research results indicate that the CuCr sample exhibits excellent performance in reducing CO and HC emissions. The CuCr sample has an average CO emission of 4.09% Vol with a standard deviation of 1.46, demonstrating good consistency in CO emissions. Meanwhile, the average HC emissions from the CuCr sample are 320 ppmVol with a standard deviation of 106, indicating good consistency in HC emissions. All samples meet the emission standards set by the government, except for the STD NC sample, which exceeds the CO emission threshold.

A new process-based and scale-aware desert dust emission scheme for global climate models – Part II: Evaluation in the Community Earth System Model version 2 (CESM2)

Abstract. Desert dust is an important atmospheric aerosol that affects the Earth's climate, biogeochemistry, and air quality. However, current Earth system models (ESMs) struggle to accurately capture the impact of dust on the Earth's climate and ecosystems, in part because these models lack several essential aeolian processes that couple dust with climate and land surface processes. In this study, we address this issue by implementing several new parameterizations of aeolian processes detailed in our companion paper in the Community Earth System Model version 2 (CESM2). These processes include (1) incorporating a simplified soil particle size representation to calculate the dust emission threshold friction velocity, (2) accounting for the drag partition effect of rocks and vegetation in reducing wind stress on erodible soils, (3) accounting for the intermittency of dust emissions due to unresolved turbulent wind fluctuations, and (4) correcting the spatial variability of simulated dust emissions from native to higher spatial resolutions on spatiotemporal dust variability. Our results show that the modified dust emission scheme significantly reduces the model bias against observations compared with the default scheme and improves the correlation against observations of multiple key dust variables such as dust aerosol optical depth (DAOD), surface particulate matter (PM) concentration, and deposition flux. Our scheme's dust also correlates strongly with various meteorological and land surface variables, implying higher sensitivity of dust to future climate change than other schemes' dust. These findings highlight the importance of including additional aeolian processes for improving the performance of ESM aerosol simulations and potentially enhancing model assessments of how dust impacts climate and ecosystem changes.

Collectively enhanced Ramsey readout by cavity sub- to superradiant transition

When an inverted ensemble of atoms is tightly packed on the scale of its emission wavelength or when the atoms are collectively strongly coupled to a single cavity mode, their dipoles will align and decay rapidly via a superradiant burst. However, a spread-out dipole phase distribution theory predicts a required minimum threshold of atomic excitation for superradiance to occur. Here we experimentally confirm this predicted threshold for superradiant emission on a narrow optical transition when exciting the atoms transversely and show how to take advantage of the resulting sub- to superradiant transition. A π/2-pulse places the atoms in a subradiant state, protected from collective cavity decay, which we exploit during the free evolution period in a corresponding Ramsey pulse sequence. The final excited state population is read out via superradiant emission from the inverted atomic ensemble after a second π/2-pulse, and with minimal heating this allows for multiple Ramsey sequences within one experimental cycle. Our scheme is an innovative approach to atomic state readout characterized by its speed, simplicity, and highly directional emission of signal photons. It demonstrates the potential of sensors using collective effects in cavity-coupled quantum emitters.

Extremely Low Threshold Quasi‐CW Amplified Spontaneous Emission Achieving and Its Mechanism Study

AbstractThe development of lasing materials with weak pile‐up effect from triplet excitons, low lasing threshold, and long operational lifetime is much significant for truly continuous wave operation and electrically pumping organic lasers. However, most of organic gain media has been verified to have extreme quenching effect from triplet excitons due to its wide‐band distribution of triplet absorption spectrum. Here, it is found that the phenanthroimidazole derivatives as gain media have congenital advantages on handling triplet's issues. A very low amplified spontaneous emission (ASE) threshold of 0.56 µJ cm−2 and a long operational lifetime of 5.77 × 105 pump pulses in air atmosphere are well obtained. When increasing the pump repetition frequency from 20 Hz to 20 kHz, the operational lifetimes of the thin films have small reduction. Under a high pump repetition frequency of 200 kHz, which is quasi‐continuous wave operational regime, the PI2PhDPO thin film exhibits very low ASE threshold of 0.78 µJ cm−2 due to the tiny overlap between triplet absorption and ASE spectra.

Advanced Molecular Design for Efficient Multicolor Electrochemiluminescence and Amplified Spontaneous Emission Based on Tetra‐BF2 Complexes

AbstractAdvanced organoboron dyes, incorporating tetra‐boron difluoride (tetra‐BF2) moieties, are developed, demonstrating efficient electrochemiluminescence (ECL) emissions in the green to orange regions through direct ion annihilation. By introducing diverse alkyl modifications in the molecules, luminescence color tuning is achieved via alterations in conjugation and bending angle. A photoluminescence quantum yield of 100% in dilute solutions is successfully achieved. Notably, the introduction of alkyl groups to the methine side stabilizes the radical ionic state, resulting in a high ECL efficiency of 74% through an efficient radical‐ion annihilation pathway. The key factor is that the energy of the annihilation reaction exceeds the S1 energy required for luminescence. Spin density calculations further elucidate the substituent effects on the radical ions of complexes. Moreover, the lasing properties of these materials in the solution‐processed blend films are investigated, revealing a low amplified spontaneous emission (ASE) threshold (Eth) of 6.40 ± 0.24 µJ cm−2, which is notably lower among organic laser materials. This is attributed to their large Stokes shifts and high quantum yield. The excellent ECL and ASE performances establish these materials as a valuable addition to the existing library of organoboron dyes, offering fresh insights into the development of organic solid‐state lasers.

Carbon-13 Radiofrequency Amplification by Stimulated Emission of Radiation of the Hyperpolarized Ketone and Hemiketal Forms of Allyl [1-13C]Pyruvate.

13C hyperpolarized pyruvate is an emerging MRI contrast agent for sensing molecular events in cancer and other diseases with aberrant metabolic pathways. This metabolic contrast agent can be produced via several hyperpolarization techniques. Despite remarkable success in research settings, widespread clinical adoption faces substantial roadblocks because the current sensing technology utilized to sense this contrast agent requires the excitation of 13C nuclear spins that also need to be synchronized with MRI field gradient pulses. Here, we demonstrate sensing of hyperpolarized allyl [1-13C]pyruvate via the stimulated emission of radiation that mitigates the requirements currently blocking broader adoption. Specifically, 13C Radiofrequency Amplification by Stimulated Emission of Radiation (13C RASER) was obtained after pairwise addition of parahydrogen to a pyruvate precursor, detected in a commercial inductive detector with a quality factor (Q) of 32 for sample concentrations as low as 0.125 M with 13C polarization of 4%. Moreover, parahydrogen-induced polarization allowed for the preparation of a mixture of ketone and hemiketal forms of hyperpolarized allyl [1-13C]pyruvate, which are separated by 10 ppm in 13C NMR spectra. This is a good model system to study the simultaneous 13C RASER signals of multiple 13C species. This system models the metabolic production of hyperpolarized [1-13C]lactate from hyperpolarized [1-13C]pyruvate, which has a similar chemical shift difference. Our results show that 13C RASER signals can be obtained from both species simultaneously when the emission threshold is exceeded for both species. On the other hand, when the emission threshold is exceeded only for one of the hyperpolarized species, 13C stimulated emission is confined to this species only, therefore enabling the background-free detection of individual hyperpolarized 13C signals. The reported results pave the way to novel sensing approaches of 13C hyperpolarized pyruvate, potentially unlocking hyperpolarized 13C MRI on virtually any MRI system─an attractive vision for the future molecular imaging and diagnostics.

Photoluminescence from Two-Phase Nanocomposites Embedded in Polymers.

A set of polymer-embedded, two-colored nanocomposites were prepared where the co-existing emission peaks (~578 nm and ~650 nm) had different ratios at their emission thresholds. The nanocomposite samples were simultaneously excited by a 405 nm laser, and the growth of photoluminescence intensities was studied as a function of excitation intensity. The two peaks showed different growth evolution mechanisms. The factors impacting this difference could be (1) energy transfer between the two sized nanoparticles; (2) relaxation mechanism of smaller nanoparticles; and (3) material properties of the polymer.

Device parameter to evaluate exciton energy transfer in organic whispering-gallery-mode microresonators and its dependence on the amplified spontaneous emission threshold.

Exciton energy transfer in organic whispering-gallery-mode (WGM) resonators and its effect on the amplified spontaneous emission (ASE) threshold have been investigated using the stilbene-based energy donor 4,4'-bis[(N-carbazole)styryl]biphenyl (BSB-Cz) and the coumarin-based energy acceptor 2,3,6,7-tetrahydro-1,1,7,7,-tetramethyl-1H,5H,11H-10-(2-benzothiazolyl)quinolizino[9,9a,1gh]coumarin (C545T). Using the stacked-layer structure of BSB-Cz/C545T/BSB-Cz, we fabricated bowl-shaped microresonators on silica microspheres with a total thickness of 250 nm fixing the thickness of the C545T layer to 1 nm. The ASE threshold depended on the thicknesses of the top and bottom BSB-Cz layers, which affect the magnitude of the energy transfer. To assess the relationship between the ASE threshold and energy transfer, we developed a device parameter to evaluate the magnitude of the energy transfer by formulating the rate equations. We found that ASE easily occurs under the condition that the C545T molecules become unable to accept energy from the BSB-Cz excitons owing to the high exciton density of C545T, and that the ASE threshold decreases with decreasing device parameter. The device parameter is useful for optimizing microresonator structures in multi-component organic WGM resonators that utilize energy transfer.

The Toxic Effects of Strong Chlorin Disinfectant on Mangroves and Emission Thresholds

The Toxic Effects of Strong Chlorin Disinfectant on Mangroves and Emission Thresholds

Behavior of the continuum coupling correlation energy in the vicinity of the particle emission threshold - Gamow shell model study

The Gamow shell model provides the open quantum system formulation of nuclear shell model. In the coupled-channel representation, Gamow shell model provides the unified theory of nuclear structure and reactions which is well suited for the study of resonances and clustering. In this work, we apply this approach to study the continuum-coupling correlation energy for selected near-threshold states of 7Li, 7Be, using a translationally invariant Hamiltonian with an effective finite-range two-body interaction.

Description of the Proton-Decaying 0_{2}^{+} Resonance of the α Particle.

The recent precise experimental determination of the monopole transition form factor from the ground state of ^{4}He to its 0_{2}^{+} resonance via electron scattering has reinvigorated discussions about the nature of this first excited state of the α particle. The 0_{2}^{+} state has been traditionally interpreted in the literature as the isoscalar monopole resonance (breathing mode) or, alternatively, as a particle-hole shell-model excitation. To better understand the nature of this state, which lies only ∼410 keV above the proton emission threshold, we employ the coupled-channel representation of the no-core Gamow shell model. By considering the [^{3}H+p], [^{3}He+n], and [^{2}H+^{2}H] reaction channels, we explain the excitation energy and monopole form factor of the 0_{2}^{+} state. We argue that the continuum coupling strongly impacts the nature of this state, which carries characteristics of the proton decay threshold.

Analysis of the optical gain due to free-to-bound electronic transitions in indium-rich InGaN layers

Interband recombination in bulk indium-rich InGaN is studied via both spontaneous and stimulated emissions. Based on the low-temperature luminescence and absorption data, the magnitude of the edge tails in conduction and valence bands is determined, and the non-thermal energy distribution of excess holes localized in the fluctuating band potential is revealed. We show that the combination of carrier localization effects and Auger-determined interband rates fully accounts for the experimentally observed stimulated emission thresholds and gain values (∼20–30 kW/cm2 and >100 cm−1, respectively) at low temperatures (T < 100 K). It is suggested that exploiting structural disorder to keep injected holes below the mobility edge, thus suppressing defect-related recombination, is a prerequisite for high-temperature infrared lasing from degenerate InGaN with relatively temperature-stable threshold intensities of some 100 kW/cm2.

Online characterization of solid biofuels via pocket sized and low-cost near-infrared devices during small-scale boiler operation: Model development, evaluation and application tests

Optimal boiler settings are required to ensure high efficiencies during biomass combustion and to enable compliance with emission thresholds despite lower and fluctuating fuel qualities. Thus, an affordable and simple near-infrared retrofit solution for online fuel characterization was developed and tested to allow for automatic adjustments of the boiler control with respect to actual characteristics of the used fuel assortments. To this end, a low-cost online near-infrared spectroscopy device (SCiO™, Consumer Physics), with investment costs less than 1000 € was employed. Partial least squares regression models based on 13 different spectral preprocessing methods for the prediction of moisture, ash, nitrogen and potassium content, as well as the net calorific value were developed and validated in the lab. The resulting model predictions of biomass properties agree in terms of root mean square error and R2 with the reference values obtained from laboratory analysis. Furthermore, a near-infrared retrofit solution was successfully coupled to the fuel feeding system of a commercially available small-scale biomass boiler for automatic and continuous operation. The automatically predicted values obtained by the near-infrared retrofit solution during continuous boiler operation are stable while the predicted values for moisture and net calorific value are in the range of the reference values obtained from the laboratory analysis but with a small offset. Non-reliable results were obtained for ash and nitrogen content.

Regulation on carbon emissions for buildings with special conditions: analysis, calculation model and stakeholder perspectives

Climate change enhances the focus on reducing global greenhouse gases from the construction industry since it is responsible for 37% of the emissions. Several nations are implementing regulating laws by requiring life cycle assessments and by setting a threshold of CO2e emissions. In the case of Denmark, the valid limit value of 12 kg CO2e/m2/year is based primarily on a sample of conventional buildings consisting of residential and office buildings. Initially, 90% of all new buildings are expected to comply with this value, while the remaining 10% must apply strategies for carbon reduction. Some building typologies that need to serve specific functions might not be able to reduce emissions due to special conditions, which will result in additional carbon emissions, and thus, exceed the limit value. This study identifies special conditions, such as hygiene requirements, that can lead to exceeding the limit value and recommends adaptation to handle the allowable additional carbon emissions in building regulations. The findings of the study are useful for policymakers that must decide how to handle special conditions of buildings in regulations.

Room temperature amplified spontaneous emissions in a sub-centimeter sized CsPbBr3 bulk single crystal.

All inorganic perovskite CsPbBr3 shows great potential in laser device because of its excellent luminescence characteristics, while the room temperature amplified spontaneous emission (ASE) in a large size CsPbBr3 bulk single crystal is still quite difficult. Herein, we have obtained the room temperature ASE in a sub-centimeter size CsPbBr3 bulk single crystal pumped with the single-photon excitation. Based on the reproducible light path within the CsPbBr3 bulk single crystal, the photonic feedback between the bottom and top facets naturally enhances the population inversion, which exhibits an amplified spontaneous emission threshold of ∼320 µJ/cm2. The blue shift of the ASE peak along with the increased pumping intensity is also observed and ascribed to the reduction of the refractive index and the energy band filling effect. These findings demonstrate the sub-centimeter size CsPbBr3 bulk single crystal to be an excellent candidate as an optical gain media for crystal lasers.

Quantifying non-threshold Auger-recombination processes in mid-wavelength infrared range HgCdTe quantum wells

We study photoluminescence temperature quenching in HgTe/CdHgTe quantum wells (QWs) emitting at 3–4 μm wavelengths and recover temperature-dependent interband recombination rates. Recombination coefficients are determined for the process that we identify as a non-threshold ehh Auger process involving valence band continuum states in barriers. With the effective Auger coefficient CA reaching ∼10−13 cm4/s under resonant conditions, such a process is shown to determine stimulated emission thresholds in a wide temperature interval, while the contribution of conventional, activated Auger processes is presumably rather limited. Thus, threshold energy considerations should be used with caution for the optimization of HgCdTe QW lasers operating around 3 μm, and relatively low-barrier QWs may provide better performance than the high-barrier ones despite lower energy thresholds for thermally activated eeh-Auger recombination. It holds as long as the conduction band offset is detuned from the bandgap energy to avoid additional non-threshold eeh-processes and sufficient hole localization at elevated temperatures is maintained.

Cavity Lasing Characteristics of Thioflavin T and Thioflavin X in Different Solvents and Their Interaction with DNA for the Controlled Reduction of a Light Amplification Threshold in Solid-State Biofilms.

The lasing characteristics of Thioflavin T (ThT) and Thioflavin X (ThX) dyes were investigated in solvents with increasing viscosity: water, ethanol, butanol, ethylene glycol, and glycerol and three forms of DNA (double-helix natural, fragmented, and aggregated). The results identified that lasing thresholds and photostability depend on three critical factors: the solvation shell surrounding dye molecules, the organization of their dipole moments, which is driven by the DNA structure, and the molecules diffusion coefficient in the excitation focal spot. The research highlights that dye doped to DNA accumulated in binding sites fosters long-range dye orientation, facilitating a marked reduction of lasing thresholds in the liquid phase as well as amplified spontaneous emission (ASE) thresholds in the solid state. Leveraging insights from lasing characteristics obtained in liquid, ASE in the solid state was optimized in a controlled way by changing the parameters influencing the DNA structure, i.e., magnesium salt addition, heating, and sonication. The modifications led to a large decrease in the ASE thresholds in the dye-doped DNA films. It was shown that the examination of lasing in cavities can be useful for preparing optical materials with improved architectures and functionalities for solid-state lasers.

Developing system arrays for new experimental approach in nuclear astrophysics

The advent of facilities providing high-intensity and high-resolution gamma ray beams and/or ultra-short and high-repetition laser pulses can potentially open a new path of astrophysical research. Indeed, a pencil size gamma beams with tunable energies from few keV up to tens MeV will offer distinctive chances to conduct precise measurements of small cross sections (on the scale of μb or even smaller) pertaining to nuclear reactions in the field of astrophysics. Consequently, it provides essential data for modeling astrophysical S-factors crucial to stellar evolution. On the other hand, the possibility to mimic the stellar conditions by laser-matter interaction generating a controlled laboratory plasma with thermodynamical status not too different from stellar conditions will open the way for the study of nuclear reactions of utmost importance for nuclear astrophysics.For photonuclear reactions with astrophysical significance, as photodissociations occur at photon energies slightly above particle emission thresholds due to typical stellar temperatures, the resulting fragments possess low energies spanning from a few hundred keV to a few MeV. Consequently, detectors with low thresholds become imperative in such cases. Also, in the case of laser-induced reactions, in order to detect the fusion products and to measure the laser-accelerated ion distribution a proper system of detection is needed. Depending on the available exit channels of the nuclear reaction of interest, both charged particles and neutrons are foreseen.Here, we present the Asfin’s efforts on developing new detectors arrays suitable for the experimental requirements in these challenging measurements. Indeed, an experimental campaign is ongoing in order to test the feasibility of excitation functions and angular distributions determinations using versatile silicon strip arrays (namely LHASA and/or ELISSA). Moreover, extensive studies and simulations will be presented regarding the developing of a dedicated detection system comprising a cryogenically cooled supersonic nozzle, an appropriate interaction chamber, an array of neutron and charged particle detectors and two compact ion spectrometers for performing systematic study of laser-induced nuclear fusion reactions.