The study of spectral properties of natural geometric elliptic partial differential operators acting on smooth sections of vector bundles over Riemannian manifolds is a central theme in global analysis, differential geometry and mathematical physics. Instead of studying the spectrum of a differential operator [Formula: see text] directly one usually studies its spectral functions, that is, spectral traces of some functions of the operator, such as the spectral zeta function [Formula: see text] and the heat trace [Formula: see text]. The kernel [Formula: see text] of the heat semigroup [Formula: see text], called the heat kernel, plays a major role in quantum field theory and quantum gravity, index theorems, non-commutative geometry, integrable systems and financial mathematics. We review some recent progress in the study of spectral asymptotics. We study more general spectral functions, such as [Formula: see text], that we call quantum heat traces. Also, we define new invariants of differential operators that depend not only on the eigenvalues but also on the eigenfunctions, and, therefore, contain much more information about the geometry of the manifold. Furthermore, we study some new invariants, such as [Formula: see text], that contain relative spectral information of two differential operators. Finally, we show how the convolution of the semigroups of two different operators can be computed by using purely algebraic methods.
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