One of the principal topics of this paper concerns the realization of self-adjoint operators L Θ,Ω in L 2(Ω; d n x) m , m, n ∈ ℕ, associated with divergence form elliptic partial differential expressions L with (nonlocal) Robin-type boundary conditions in bounded Lipschitz domains Ω ⊂ ℝ n . In particular, we develop the theory in the vector-valued case and hence focus on matrix-valued differential expressions L which act as $$Lu = - \left( {\sum\limits_{j,k = 1}^n {\partial _j } \left( {\sum\limits_{\beta = 1}^m {a_{j,k}^{\alpha ,\beta } \partial _k u_\beta } } \right)} \right)_{1 \leqslant \alpha \leqslant m} , u = \left( {u_1 , \ldots ,u_m } \right).$$ The (nonlocal) Robin-type boundary conditions are then of the form $$v \cdot ADu + \Theta [u|_{\partial \Omega } ] = 0{\text{ on }}\partial \Omega ,$$ where Θ represents an appropriate operator acting on Sobolev spaces associated with the boundary ∂Ω of Ω, ν denotes the outward pointing normal unit vector on ∂Ω, and $$Du: = \left( {\partial _j u_\alpha } \right)_{_{1 \leqslant j \leqslant n}^{1 \leqslant \alpha \leqslant m} } .$$ Assuming Θ ≥ 0 in the scalar case m = 1, we prove Gaussian heat kernel bounds for L Θ,Ω, by employing positivity preserving arguments for the associated semigroups and reducing the problem to the corresponding Gaussian heat kernel bounds for the case of Neumann boundary conditions on ∂Ω. We also discuss additional zero-order potential coefficients V and hence operators corresponding to the form sum L Θ,Ω + V.