Electrode Materials For Lithium-ion Batteries Research Articles

Poly(o-phenylenediamine)-Decorated V4C3Tx MXene/Poly(o-phenylenediamine) Blends as Electrode Materials to Boost Storage Capacity for Supercapacitors and Lithium-Ion Batteries

Two-dimensional transition-metal carbides/nitrides (MXenes), as pseudocapacitor materials, have attracted extensive attention in the field of energy storage in recent years. However, the MXene surface is prone to oxidation and their layered structure is easy to stack, which limit their practical application. Here, we propose a facile and cost-effective strategy to fabricate a blend of poly(o-phenylenediamine) (PoPD)-decorated vanadium carbide MXene (N–V4C3Tx) and PoPD as electrode materials to boost the storage capacity for supercapacitors and lithium-ion batteries. N–V4C3Tx nanosheets and PoPD nanoparticles were prepared by in situ oxidant-free polymerization and redox methods, respectively. The electrochemical performance of the blend shows that the introduction of PoPD nanoparticles can effectively improve the specific capacitance of N–V4C3Tx. The N–V4C3Tx/PoPD electrode exhibits excellent specific capacitance of up to 676.5 F g–1 at 1 A g–1 for supercapacitor application. Compared with the V4C3Tx-based device (276.3 F g–1), the capacitance reaches up to 2.48 times enhancement. In addition, the N–V4C3Tx/PoPD electrode also presents satisfactory cyclic stability, and the retention rate can remain unchanged after 10,000 cycles. As the electrode material for lithium-ion batteries, it also shows a high capacity of 561.2 mA h g–1 at 0.1 A g–1, excellent rate performance, and cyclic stability. Our work broadens the application of MXenes and conductive polymers as electrode materials in the field of energy storage and offers a simple and effective strategy to improve the capacity and stability of the pristine MXene.

Low-temperature graphitization of lignin via Co-assisted electrolysis in molten salt

The ever-growing energy demand and environmental issues have stimulated the development of sustainable energy technologies. Herein, an efficient and environmentally friendly electrochemical transformation technology was proposed to prepare highly graphitized carbon materials from an abundant natural resource - lignin (LG). The preparation process mainly includes pyrolytic carbonization of raw LG material and electrochemical conversion of amorphous carbon precursor. Interestingly, with the assistance of Co catalyst, the graphitization degree of the products was significantly improved, in which the mechanism was the removal of heteroatoms in LG and the rearrangement of carbon atoms into graphite lattice. Furthermore, tunable microstructures (nanoflakes) under catalytic effects could also be observed by controlling the electrolytic parameters. Compared with the products CN1 (without catalyst) and CN5 (with 10% catalyst), the specific surface area are 158.957 and 202.246 m2 g−1, respectively. When used as the electrode material for lithium-ion batteries, CN5 delivered a competitive specific capacity of ∼350 mAh g−1 (0.5 C) compared with commercial graphite. The strategy proposed in this work provides an effective way to extract value-added graphite materials from lignin and can be extended to the graphitization conversion of any other amorphous carbon precursor materials.

Theoretical prediction of two-dimensional Cr3C2 monolayer and its derivatives as potential electrode of Li-ion batteries

The investigations on Cr3C2 and Cr3C2T2 (T = F, Cl, O, OH) monolayers as promising electrode materials for lithium-ion battery (LIBs) are systematically carried out by Hubbard-corrected density functional theory (DFT + U). It indicates that Cr3C2 monolayer and its derivatives are dynamically and thermally stable. At the same time, the pristine Cr3C2 monolayer exhibits metallic character and the conductivity can be maintained through chemical modification. The lithium diffusion barrier on Cr3C2 monolayer is only 0.024 eV, which can guarantee a fast rate during the charge/discharge process. The storage capacity of Cr3C2 monolayer adsorbing one layer of Li atoms is about 298 mAh/g. It is found that the Cr3C2T2 (T = Cl, O, OH) monolayer can keep at least one layer of Li atoms adsorbed without any structural deformation, and the theoretical capacities are 214, 253 and 250 mAh/g, respectively. The Li storage capacities can be increased exponentially with the more layers of Li atoms adsorbing on the two-dimensional (2D) materials. Thus, Cr3C2 and Cr3C2T2 monolayers are potential electrode materials for LIBs.

Active electrode materials for lithium-ion battery

Nanoproducts spherical spinel lithium manganese oxide (LiMnO) with about 20 nm in diameter was synthesized by explosive method. The growth of lithium manganate via detonation reaction was investigated with respect to the presence of an energetic precursor, such as the metallic nitrate and the degree of confinement of the explosive charge. The detonation products were characterized by scanning electron microscopy. Powder X-ray diffraction and transmission electron microscopy were used to characterize the products. Lithium manganate with spherical morphology and more uniform secondary particles, with smaller primary particles of diameters from 10 to 30 nm and a variety of morphologies were found. Lithium manganate with a fine spherical morphology different from that of the normal spinel is formed after detonation wave treatment due to the very high quenching rate. It might also provide a cheap large-scale synthesis method. Explosive detonation is strongly nonequilibrium processes, generating a short duration of high pressure and high temperature. Free metal atoms are first released with the decomposition of explosives, and then theses metal and oxygen atoms are rearranged, coagulated and finally crystallized into lithium manganate during the expansion of detonation process.

Evaluation of cracking damage in electrode materials of a LMO/Al-Lix lithium-ion battery through analysis of acoustic emission signals

Damage due to the internal degradation of electrode materials in lithium-ion batteries (LIBs) during charge-discharge cycles can cause capacity fading and safety issues. Therefore, it is essential to assess damage to LIBs using nondestructive methods. In this study, the relationship between the damage mechanism and acoustic emission (AE) activity of a commercial lithium manganese oxide (LMO)/Al-Lix alloy battery is systematically investigated. Microstructural observations of the electrodes revealed that the damage mechanisms of the LMO cathode and Al-Lix anode during accelerated charge-discharge were identical to those of microcracking. Energy, amplitude, duration, rise time, and peak frequency were considered as possible AE parameters for real-time damage detection. The generation of AE hits was prominent during the later stages of the charging and discharging processes. The AE signals produced by damage to the Al-Lix alloy anode during charging had a lower amplitude (0–60 dB) and energy (0–10 aJ). In comparison, those produced by damage to the LMO cathode during charging had a relatively high amplitude (100 dB) and energy (120 aJ). Additionally, the energy levels and amplitudes of the AE signals obtained during discharging decreased with an increasing number of cycles, indicating that they can be used as indicators for evaluating the damage progression of the primary, secondary, and tertiary cracks in LMOs. The AE technique offers the possibility of monitoring and evaluating the damage to the anode and cathode of a commercial full cell separately, as well as predicting the remaining capacity of the battery by monitoring the AE hits.

Current and deformation induced by voltage in the single LiNi0.8Co0.1Mn0.1O2 particle from atomic force microscopy technique and phase field simulation

One of the key factors affecting lithium-ion battery electrode materials’ efficiency is the process of lithiation and delithiation. Studies of the electrochemical behavior of Ni-rich active electrode materials at the nanoscale have largely been focused on macroscopic measurements, but few have investigated the intrinsic microscopic mechanism underlying their failure. In this paper, lithium-ion diffusion current and surface deformation of single LiNi0.8Co0.1Mn0.1O2 (NCM811) nanoparticles under external electric fields were measured by atomic force microscopy (AFM) techniques. Then, the current and deformation of NCM811 single particle under the applied voltage were simulated by phase field method to analyze electrochemical behaviors of the particle from experiments based on the electrochemical-mechanical coupled model. The simulation results revealed that the change of lithium-ion concentration and stress in particles are the factors leading to the evolution of current and deformation under applied voltage observed by AFM.

Regulating surface condition of cotton-derived carbon towards enhanced lithium ion storage behavior

With the advancement of battery technology, graphite as a negative electrode material for commercial lithium-ion batteries (LiBs) is reaching the limit of its capacity, and mesoporous carbon with a larger capacity is regarded as its best alternative. In this paper, waste cotton is used as the carbon source, and KOH and urea are used as pore formers and pore size regulators to prepare uniform mesoporous materials (N-PCC800) with a pore size distribution of 2–5 nm. Compared with the traditional KOH pore-making method, the addition of urea can adjust the pore size upward, thereby increasing the effective number of pores for Li+ insertion. While optimizing the structure, urea can also be used as an additional nitrogen source for the material to enrich the content of heteroatoms and defects, thereby increasing the amount of Li+ adsorbed by porous carbon. As an anode material, N-PCC800 exhibits a stable discharge capacity (1086 mAh g−1 at 100 mA g−1) far exceeding that of graphite. At a current density of 1000 mA g−1, there is still a capacity of 596 mAh g−1 remaining after 1000 cycles, indicating its advantages in rate performance and cycle performance. The optimized pore size and higher nitrogen content endow the carbon material with higher Li+ storage performance, and further kinetic analysis indicates that the increased capacity comes from the increased Li+ insertion. This work proposes a new pore size optimization scheme to obtain high-capacity mesoporous carbon, which provides an effective scheme for the reuse of waste cotton and cotton products and helps achieve the goal of carbon neutrality.

Improved photocatalytic performance of Li+/Eu3+-co-doped V2O5 ultralong nanowires

Layered-structure V2O5 has attracted extensive research attention as an ideal electrode material for lithium batteries and gas sensors, among others. In this study, we investigated the effects of Li+ and Eu3+ single- and co-doping on the electronic structure, optical properties, and pollutant-photodegradation efficiency of V2O5. All the samples were fabricated by a simple one-step hydrothermal method using NH4VO3 and phthalic acid as precursors. Pure and Eu3+-doped V2O5 developed into short, thick nanorods, while, Li+/Eu3+-co-doped V2O5 crystallized into ultralong nanowires. Furthermore, Li+ and Eu3+ doping significantly increased the ability of V2O5 to photodegrade Rhodamine B in solution. In order to elucidate the mechanism of this photochemical enhancement, the multivalence of V, charge dispersion characteristics, luminescence, and carrier lifetime were measured. The improved photocatalysis of Li+/Eu3+-co-doped V2O5 was found to be related to its increased specific surface area, multivalent V4+/5+ ions, prolonged charge lifetime, and accelerated charge dispersion. Experimental results showed that Eu3+ and Li + ions are present in the interlayers of V4O5 as pillars. Thus, co-doping represents a viable strategy to improve the photochemical properties of layered V2O5.

Rational fabrication of low carbon foot-print electrode materials for lithium-ion batteries from electric arc furnace dust via integrated hydrometallurgical process

Transforming industrial waste into high-value-added products represents a new avenue in the field of material science. This paper puts forward a comprehensive example for future works which target fabricating low-carbon footprint electrodes for rechargeable batteries. Within this scope, first time in the open literature, an integrated hydrometallurgical process has been designed to fabricate metal oxide powders of different properties from electric arc furnace (EAF) dust. Leaching, cementation, distillation, chemical precipitation, and calcination are used to produce powders rich in zinc oxide (Sample 1), ferrite (Sample 2), and nanocomposite (Sample 3) from the electric arc furnace flue dust.While sample 1 (zinc oxide with 97.8% purity) may be used in optics and other engineering applications, sample 2 (rich in zinc ferrite) and sample 3 (made of nanocomposites) that are recovered from the EAF dust may be utilized as electrode active material in lithium-ion batteries: Sample 2 and Sample 3 retain 43% and 50% of their capacities after 125th cycle, respectively. To further improve the cycle performance of Sample 2, the powder rich in ferrite is mixed with nickel salt, then heat treated. The latter performs 65% capacity retention after 125th cycle. The fact that every fabricated electrode achieves 125 cycles with success demonstrates the viability of the proposed technique; thus, various procedures may be developed to further elaborate the use of various industrial wastes in electrode fabrication.

Extraction of precious metals from used lithium-ion batteries by a natural deep eutectic solvent with synergistic effects

As the demand for lithium-ion batteries rises, the growing quantity of waste produced from lithium-ion battery electrode materials becomes an issue of concern. We propose a novel approach for effectively extracting precious metals from cathode materials that address the problem of secondary pollution and high energy consumption that arise from the conventional wet recovery process. The method employs a natural deep eutectic solvent (NDES) composed of betaine hydrochloride (BeCl) and citric acid (CA). The leaching rates of manganese (Mn), nickel (Ni), lithium (Li), and cobalt (Co) in cathode materials may reach 99.2 %, 99.1 %, 99.8 %, and 98.8 %, respectively, due to the synergy of strong coordination ability (Cl-) and reduction (CA) in NDES. This work avoids the use of hazardous chemicals while achieving total leaching in a short period (30 min) at a low temperature (80 °C), achieving an efficient and energy-saving aim. It reveals that NDES has a high potential for recovering precious metals from cathode materials and offers a viable, environmentally friendly method of recycling used lithium-ion batteries (LIBs).

Synthesis and Characterizations of TiO2/Carbon Nanofibers Anode Materials for Lithium-Ion Battery Applications

The integration of titanium dioxide (TiO2) nanoparticles with carbon fibers leads to the formation of a stable structure and a synergistic effect, resulting in improved conductivity and electrochemical performance of lithium-ion batteries. Various techniques such as the hydrothermal method, ultrasonic mixing method, and electrospinning technology are used to achieve uniform distribution of TiO2 nanoparticles within the high-conductivity carbon fiber matrix, thereby preventing agglomeration and electrolyte corrosion. The resulting material serves as a high-performance negative electrode material for lithium-ion batteries. Compared with the TiO2/CNFs composite (U-TiO2/CNFs) prepared by directly mixing TiO2 nanoparticles into the spinning solution through ultrasonic treatment, the TiO2/CNFs composite (H–TiO2/CNFs) prepared by hydrolyzing tetrabutyl titanate (TBT) has more uniform distribution of TiO2 nanoparticles, so it shows more excellent electrochemical performance. The initial discharge specific capacity at 0.1 C is 231 mAh· g−1, and after 300 cycles at 0.2 C, there is still 204 mAh· g−1 reversible capacity, the coulombic efficiency can reach 99%.

Defect-rich conversion-based manganese oxide nanofibers: An ultra-high rate capable anode for next-generation binder-free rechargeable batteries

Recently, nanostructured materials with oxygen defects and their utilization as electrode materials for lithium-ion batteries (LIBs) are gaining considerable popularity. However, it is still unclear how surface morphology, nanostructuring, and oxygen defects contribute to Li-storage characteristics. In view of this, the present research work is focused on the fabrication of one-dimensional, porous, and oxygen-deficient nanofibers of MgMn2O4 (MMO) through electrospinning technique, followed by their subsequent heat-treatment on various temperatures such as 450 °C, 600 °C, and 750 °C. A quantitative analysis of oxygen defects indicates that MMO-600 contains a high number of oxygen vacancies. Further, the binder-free electrodes of all the samples are fabricated via electrophoretic deposition technology and their Li-storage performance is investigated. As a binder-free LIB anode, MMO-600 exhibits excellent reversible specific capacity, rate capability, and cyclic stability (817 mAh g−1 after 500 cycles at 2 C) with ∼ 99% coulombic efficiency. Further, MMO-600 displays the capacity of 228 mAh g−1 at 10 C is found to be better than the MMO-450 and MMO-750. Additionally, the feasibility of MMO-600 is also investigated in full cell configuration with a binder-free LiNi1/3Mn1/3Co1/3O2 cathode, which exhibited an energy density of 166 ( ± 3) Wh kg−1.

Conjugated microporous polyimide cathodes for sodium/lithium-ion batteries with ultra-long cycling performance

Conjugated microporous polyimides (CMPs) have been emerging as the promising electrode materials for sodium-ion batteries (SIBs) and lithium-ion batteries (LIBs) owing to their low cost, tunable structures, environmental benefit, and high porosity. However, the low intrinsic conductivity, poor structural stability and sluggish diffusion kinetics have hindered their further applications. Herein, a novel conjugated microporous polyimide trapped by multi-walled carbon nanotubes (TAPBA-NTCDA@MWCNTs) as cathodes for SIBs/LIBs have been prepared by in situ polycondensation. The addition of MWCNTs profits greatly in conductivity and structural stability of electrode materials. Consequently, when explored as cathode materials for SIBs, TAPBA-NTCDA@MWCNTs exhibits the good reversible specific capacity, predominant rate capability and ultra-long cycling stability. Moreover, the reaction mechanism and outstanding reversibility are investigated by the detailed ex-situ XPS/FT-IR/SEM analysis. Finally, the cathode also delivers an excellent lithium storage performance. In view of the outstanding cycle stability and such simple synthetic route, this work perhaps provides an effective strategy to fabricate high-performance conjugated microporous polyimide-based cathodes for energy storage and conversion devices.

Two-dimensional CrP2 with high specific capacity and fast charge rate for lithium-ion battery

The electrode material is regarded as one of the key factors that determine the performance of lithium-ion batteries (LIBs). However, it is still a challenge to search for an anode material with large capacity, low diffusion barrier, and good stability. In the present work, two new CrP2 monolayers (Pmmn-CrP2 and Pmma-CrP2) are predicted by means of first principles swarm structure search. Our study shows that both the two CrP2 monolayers have high dynamical and thermal stability, as well as excellent electron conductivity. Additionally, Pmmn-CrP2 exhibits a remarkably high storage capacity of 705 mA⋅h⋅g−1 for Li, meanwhile the diffusion energy barrier of Li on the surface of this monolayer is 0.21 eV, ensuring it as a high-performance anode material for LIBs. We hope that our study will inspire researchers to search for new-type two-dimensional (2D) transition metal phosphides for the electrode materials of LIBs.

Improved lithium ion storage performance of Ti3C2Tx MXene@S composite with carboxymethyl cellulose binder

MXenes are regarded as promising electrode materials for lithium-ion batteries owing to their high electrical conductivity and two-dimensional structure but suffer from low intrinsic specific capacities. In this study, we fabricate sulphur-doped multilayer Ti3C2Tx MXenes via calcination and annealing using sublimed sulphur as the sulphur source. After sulphur doping, the interlayer spacing of Ti3C2Tx increases, which is favourable for Li-ion insertion. The Ti3C2Tx MXene@S composite exhibits excellent electrochemical performance. A high reversible specific capacity of 393.8 mAh g−1 at a current density of 100 mA g−1 after 100 cycles is obtained. Additionally, a negative fading phenomenon is observed when the specific capacity increases to 858.9 mAh g−1 after 2550 cycles at 1 A g−1 and to 322.2 mA h g−1 after 3600 cycles at 5 A g−1 from the initial 267.3 mAh g−1. We systematically investigate the effects of two different binders (polyvinylidene difluoride and carboxymethyl cellulose, hereinafter abbreviated as PVDF and CMC, respectively) on the electrochemical performance of the Ti3C2Tx MXene@S composite and discovered that the electrode using the CMC binder exhibits better lithium-ion storage performance than that using the PVDF binder, which is attributed to the lower charge transfer resistance, higher ion diffusivity, and enhanced adhesion force.

Energy storage enhancement of LixMn1.8Ti0.2O4@N-doped graphene oxide in organic and ionic liquid electrolytes

Spinel-type Li1-xMn2O4 material is a promising positive electrode material for lithium-ion batteries. This material presents 3D diffusion channels through the structure, allowing for the rapid diffusion of lithium ions during charge/discharge processes. Given its relevant properties, such as a theoretical specific capacity of 149 mA h g−1 and high working potential, we propose LixMn1.8Ti0.2O4@N-doped graphene oxide (x ≤ 1) as a superior positive electrode material for lithium-ion battery applications. In organic media, the spinel showed excellent Li storage performance due to the incorporation of a conductive carbonaceous matrix (using 1,10 phenanthroline as a graphene precursor). We obtained a specific capacity of 139 mA h g–1, which represented 81% charge retention after 70 cycles. Furthermore, taking advantage of the high working potential of this material, we studied the Li storage capacity using ionic liquids as electrolyte solvents. High rate cycling at high temperatures is essential for their practical applications in extreme environments. In this work, we performed rate capability experiments at different temperatures, obtaining the best response at 40 °C with a specific capacity of 117 mA h g–1 at an applied current density of 1 C.

Edge-Protected Ni-Enriched LiNixCoyMnzO2 Cathode Materials by Interface Modification with a Si- and F-Functionalized Surface Modifier

Many advances made in recent years have highlighted Ni-enriched nickel, cobalt, manganese (NCM) material as a prospective positive electrode material for lithium-ion batteries. However, prolonged cycling is limited by several critical issues, including surface instability, gas generation, and transitional metal dissolution upon cycling. Here, we propose a simple interfacial modification approach that uses 1H,1H,2H,2H-perfluorooctyltriethoxysilane (POS) as a coating precursor to improve surface stability. A one-step thermal heat treatment creates bifunctional cathode electrolyte interphase (CEI) layers from F- and Si-functionalized POS, especially at the edge sites of the Ni-enriched NCM cathode, where serious undesired reactions occur during cycling. The POS-modified Ni-enriched NCM cathode exhibits improved cycling retention compared to the unmodified Ni-enriched NCM cathode because parasitic reactions are well suppressed upon cycling. Systematic analyses show an apparent inhibition of electrolyte decomposition in the POS-modified Ni-enriched NCM cathode due to the effective protection of the active edge sites by the artificial POS-derived CEI layers. The dissolution of metal components is also greatly decreased because the Si-functional groups that develop on the POS-derived CEI layers selectively scavenge F– species formed by electrolyte decomposition.

Effect of Post-synthesis Processing on the Electrochemical Performance of Y2W3O12

Lithium-ion batteries (LIBs) are enabling the uptake of electric vehicles and providing grid-scale storage solutions for renewable energy generation. However, it is vital to develop new and advanced electrode materials for lithium-ion batteries to meet various applied considerations such as cost, safety, toxicity, and performance. Here, solid-state synthesized Y2W3O12 is demonstrated as a high-rate active anode material in lithium-ion batteries, producing an initial discharge capacity of 637 mAh/g although with a very poor initial Coulombic efficiency of 35%. To improve the performance, simple post-synthetic milling and carbon coating are investigated. Carbon coating of the material leads to significant performance enhancement in both the unmilled and milled samples. For instance, the unmilled carbon coated electrodes maintained a high capacity of ∼140 mAh/g at 1600 mA/g after 2000 cycles with no capacity fading from cycle 200 to 2000. Such a remarkable rate performance and an excellent long-term cycling stability showcase the great potential of this unconventional electrode material in fast-charge and high-power applications. This facile post-synthesis process can be easily applied to other electrode material candidates to enhance their electrochemical performance.

Influence of Samarium on Structural, Morphological, and Electrical Properties of Lithium Manganese Oxide

Research and developments on preparing electrode material for lithium-ion batteries are burgeoning nowadays widely. In this study, we used the high energy ball-milling method to prepare pure and samarium-doped lithium manganese oxide (Li4Mn5O12) and investigated its structural, morphological, and electrical properties. The XRD spectrum for the produced materials confirmed the phase purity and crystallinity of the material. The fourier transform infrared spectrum was used to determine the different sorts of vibrations between molecules. The particle size with the presence of polyhedral-shaped morphology was certified by using SEM and TEM analysis. EDS mapping was used to assess the elemental composition and purity of the samples. Complex impedance spectroscopy analysis was used to investigate the temperature dependency of the materials’ electrical properties, and high conductivity (1.15 × 10−7 S cm−1) was reported for samarium-doped lithium manganese oxide at 100°C, and its dielectric relaxation behavior was examined.

Study on Electrochemical Properties of Carbon Submicron Fibers Loaded with Cobalt-Ferro Alloy and Compounds

In this work, carbon submicron fiber composites loaded with a cobalt-ferric alloy and cobalt-ferric binary metal compounds were prepared by electrospinning and high temperature annealing using cobalt-ferric acetone and ferric acetone as precursors and polyacrylonitrile as a carbon source. The phase transformation mechanism of the carbon submicron fiber-supported Co-Fe bimetallic compound during high temperature annealing was investigated. The electrochemical properties of the carbon submicron fiber-supported Co-Fe alloy and Co-Fe oxide self-supported electrode materials were investigated. The results show that at 138 °C, the heterogeneous submicron fibers of cobalt acetylacetonate and acetylacetone iron began to decompose and at 200 °C, CoFe2O4 was generated in the fiber. As the annealing temperature increases further, some metal compounds in the carbon fiber are reduced to CoFe2O4 alloy, and two phases of CoFe2O4 and CoFe-Fe-alloy exist in the fiber. After 200 cycles, the specific capacity of CF-P500 is 500 mAh g−1. The specific capacity of the composite carbon submicron fiber electrode material can be significantly improved by the introduction of CoFe2O4. When the binary metal oxides are used as electrode materials for lithium-ion batteries, alloy dealloying and conversion reactions can occur at the same time in the reverse process of lithium intercalation, the two reactions form a synergistic effect, and the cobalt-iron alloy in the material increases the electrical conductivity. Therefore, the carbon submicron fiber loaded with CoFe2O4/CoFe has an excellent electrochemical performance.