Elastic Properties Research Articles

Investigation of the variation of mechanical and durability properties of elements manufactured with rubber substituted SCMs with element height

Controlling the homogeneous distribution of granulated rubber materials added to self-compacting concrete/mortars along the height is of great importance in terms of preserving and defining the holistic behavior of structural elements. In this study, the effect of EPDMGR (ethylene propylene diene monomer granulated rubber) ratio (0 %, 5 %, 10 %, 15 %, 20 % and 25 %), test age, L/D (slenderness ratio) and element test zone (bottom, middle and top) on the mechanical properties (flexural and compressive), durability properties (porosity and sorptivity) of the elements produced with SCM were evaluated. The results obtained were statistically evaluated by GLM-ANOVA. It was observed that flexural tensile strength was strengthened up to 5 % substitution rate due to the hydrophobic properties and elasticity properties of EPDMGR used, while porosity values increased with height in the upper regions compared to the lower regions due to the placement properties of SCM. Differences in compressive strength appeared in the upper and lower sections after 5 % EPDMGR substitution. This indicates that for the mixture properties used, the properties examined in terms of mechanical and durability test results may have different properties with limited variability in terms of L/D ratio depending on the EPDMGR ratio used and the region where the element was taken.

Investigation of structural, electronic, mechanical, and thermoelectric properties of the defect chalcopyrite semiconductor ZnIn[formula omitted]Se[formula omitted] from density functional theory

In this study, the detailed structural, electronic, mechanical, and thermoelectric properties of ZnIn2Se4 defect chalcopyrite semiconductor are carried out using density functional theory & semi-classical Boltzmann transport theory. From the band structure analysis, the compound is confirmed to be a direct band gap semiconductor with a band gap of 1.20 eV. The presence of flat valence bands near the Fermi level indicates a higher effective mass of holes. From the elastic and mechanical properties, it has been found that the compound is mechanically stable and revealed to be ductile. The phonon dispersion study of the compounds shows that the compound is dynamically stable with no imaginary phonon modes. The electronic transport properties were studied within a temperature range of 300K to 900K as a function of chemical potential (μ), temperature(T), and carrier concentrations (n). The μ dependent electronic transport properties show enhanced values in the p-type doping region because of the cationic site vacancy. The dependency of electronic transport properties on n and T agrees well with Mott’s relation. The highest ZT is found to be 0.96 at 900K for a low carrier concentration of 1019cm−3. The phonon thermal conductivity of the compound is found to be 2.52 W/mK near room temperature and 0.84 W/mK at 900K using the Slack method. All these results support ZnIn2Se4, a defect chalcopyrite semiconductor, as a favorable candidate for thermoelectric applications.

Tensile and Low‐Cycle Fatigue Behavior of Laser Powder Bed Fused Inconel 718 at Room and High Temperature

This study investigates the room‐ and high‐temperature (650 °C) tensile and low‐cycle‐fatigue behavior of Inconel 718 produced by laser powder bed fusion (PBF‐LB/M) with a four‐step heat treatment and compares the results to the conventional wrought material. The microstructure after heat treatment is characterized on different length scales. Compared to the wrought variant, the elastic and yield properties are comparable at both test temperatures while tensile strength, ductility, and strain hardening capacity are lower. The fatigue life of the PBF‐LB/M variant at room temperature is slightly lower than that of the wrought material, while at 650 °C, it is vice versa. The cyclic stress response for both material variants is characterized by cyclic softening, which is more pronounced at the higher test temperature. High strain amplitudes (≥0.7%) at room temperature and especially a high testing temperature result in the formation of multiple secondary cracks at the transitions of regions comprising predominantly elongated grain morphology and columns of stacked grains with ripple patterns in the PBF‐LB/M material. This observation and pronounced crack branching and deflection indicate that the cracks are controlled by sharp micromechanical gradients and local crystallite clusters.

Two-dimensional imaging of elastic properties of rock core samples from measurements of angle-dependent ultrasonic reflection coefficients

Laboratory and field measurements often fail to identify small-scale variations in rock elastic properties. Due to limited spatial resolution, conventional laboratory methods cannot properly describe rock formations exhibiting a high degree of heterogeneity, thereby masking differences between stiff and compliant layers. Continuous sample measurements can mitigate this problem but are not widely used by the industry. We build upon our previous work and apply laboratory angle-dependent ultrasonic reflection coefficient (ADURC) measurements to achieve detailed two-dimensional descriptions of the elastic properties of complex rock samples. This method successfully yields high-resolution information on P- and S-wave velocities, as well as bulk density, across the surface of rock samples. Elastic properties are estimated using a nonlinear inversion algorithm that matches laboratory measurements with numerical simulations. ADURC data acquired at various sample locations enable detailed rock descriptions, where the effective measurement area is determined by the size of the receiver, measurement frequency, and incidence angle. Consequently, the sampling area is smaller compared with triaxial loading and acoustic transmission tests, for which the resolution is controlled by sample size. Measurements conducted on samples exhibiting different levels of spatial complexity validate the capability of the ADURC method to identify small-scale heterogeneities. For the reported experiments, variations in angle-dependent reflectivity give rise to corresponding variations in the estimated P- and S-wave velocities and density, which can exceed 60%. These small-scale variations across heterogeneous rock samples often are overlooked by conventional laboratory methods.

First-principles investigation of elastic anisotropy and thermal transport property of transition metal monosilicides CrSi, TiSi, and ZrSi under pressure

In this paper, the influence of pressure on the elastic anisotropy and thermodynamics of CrSi, TiSi, and ZrSi monosilicides are investigated by the first-principles method. Those three alloys have elastic anisotropy, and the degree of anisotropy meets the relationships TiSi > ZrSi > CrSi. In addition, all the elastic anisotropy is enhanced with the increasing pressures. The melting point and Vicker’s hardness are investigated, and the results show that CrSi, TiSi, and ZrSi alloys may be promising high-temperature and hard materials. Furthermore, the lattice thermal conductivity is calculated by Slack’s equation only using the elastic properties. The pressure-dependent Debye temperature, Grüneisen parameter, and lattice thermal conductivity are systematically analyzed. Debye temperature enhances with increasing pressure while the Grüneisen parameter reduces with pressure. Consequently, the lattice thermal conductivity can be enhanced by the pressure, which benefits heat transportation. The calculation reveals that the pressure can effectively control the elastic anisotropy, Deby temperature, Grüneisen parameter, and the lattice thermal conductivity, which is useful for its practical application in industry.

In-situ characteristic elastic properties of bond-lines in laminated engineered wood products using microscopic digital image correlation

Adhesively laminated engineered wood products (EWPs), such as glue-laminated timber (GLT) and cross-laminated timber (CLT), have gained global popularity due to the increasing development of tall wood buildings. The mechanical performance of a bond-lines is crucial for the structural behavior of EWPs. In this study, a novel method was developed for evaluating in-situ elastic properties of a bond-line in adhesively laminated solid wood products. This method deployed the microscopic digital image correlation (DIC) technique to capture the strain distribution along the bond-line under axial (0°) and off-axis (45°) tensile loading. Three types of adhesives, namely polyurethane (PUR), emulsion polymer isocyanate (EPI), and phenol–resorcinol–formaldehyde (PRF), were used to make specimens. The modulus of elasticity (E) and modulus of shear (G) of a bond-line were accordingly calculated based on the strain along a bond-line and load applied on a specimen. For verification purpose, finite element (FEA) models on CLT and GLT beams were, considering the elastic properties of bond-lines and disregarding the elastic properties, developed to evaluate the effects of the elastic properties of a bond-line on the stress distribution. It was found that the proposed method could be used to accurately determine the in-situ characteristic elastic properties of bond-lines in EWPs. The elastic properties of a bond-line exhibited a large variability, but did not appear to have a significant impact on the overall stress distribution in a specimen. The E and G of bond-lines might be neglected in the structural analysis of large-sized laminated wood products such as GLT and CLT.

Large deformation response of a novel triply periodic minimal surface skeletal-based lattice metamaterial with high stiffness and energy absorption

Triply periodic minimal surface (TPMS) lattice metamaterials present superior mechanical performance over traditional strut-based lattice metamaterials due to their unique structural characteristics. However, the high stiffness–stable plastic response trade-off dilemma is still the major challenge for skeletal-based metamaterials. Herein, a novel TPMS skeletal lattice metamaterial is proposed. Finite element simulations are conducted to reveal its elastic properties and plastic response under compression. Afterwards, validation experiments are performed on the lattice specimens fabricated by the most common Fused Deposition Modeling (FDM) process. The nominal stress–strain curves and collapse mode of the lattice materials are obtained accordingly. Both the numerical simulations and experiments demonstrate that the proposed TPMS lattice metamaterial exhibits high specific modulus, strength and energy absorption, together with a smooth and elongated stress plateau, thereby overcoming the strength-efficiency trade-off. Different from the rigid nodal region in traditional strut-based lattices, the strut connection parts in the novel TPMS lattices experience shear and twisting, which avoids the catastrophic failure of the struts and enhances the loading efficiency of the structure under compression. Meanwhile, the numerical results indicate that the stable plastic response of the designed architecture is insensitive to the plastic flow behavior of the bulk material, which is also supported by the experimental results. It is also demonstrated that the novel TPMS lattice metamaterial presents several times higher stiffness as well as energy absorption simultaneously than the current strut-based lattice materials, which can be potentially applied as load-bearing components and impact energy absorbers.

The elasticity and piezoelectricity of AlN containing charged vacancies

Wurtzite aluminum nitride (w-AlN) piezoelectric film plays a key role in modern MEMS actuators and sensors. Density functional theory can be used to predict the elastic and piezoelectric properties of AlN containing various charged vacancies, thereby obtaining methods for improving the piezoelectric properties. The theoretical investigations suggested that the Young’s modulus of defectants are smaller than that of intrinsic AlN, indicating that charged vacancies can effectively improve the elastic properties of AlN. A high piezoelectric coefficient d 33 values were obtained in V Al 3 − , V N 1 + and V N 3 + that may be a cause of the non-symmetrical charges assignation. This work suggests that the elasticity and piezoelectricity of AlN films can be effectively enhancing using the introduction of charged vacancies.

Effect of Different Concentrations of Co Doping on the Properties of η′‐Cu6Sn5 and Ni3Sn4: First‐Principles Study

In the field of electronic packaging, Ni3Sn4‐based and η′‐Cu6Sn5‐based compounds are common Sn‐based intermetallic compounds into which doping of other appropriate elements has been widely studied. Herein, the structural stability, mechanical properties, and electronic structures of (Ni,Co)3Sn4 and η′‐(Cu,Co)6Sn5 are systematically investigated using first‐principles calculations. By comparing the heat of formation of the doped and undoped intermetallic compounds, it is found that the doped Ni3Sn4 structure has a higher heat of formation and a less stable structure, while the doped η′‐Cu6Sn5 structure has a lower heat of formation and a more stable structure. The doped Ni3Sn4 exhibits an increasing bulk modulus (B) and Young's modulus (E), and the doped η′‐Cu6Sn5 exhibits a gradually increasing bulk modulus (B). These findings suggest that doping improves the rigidity and elastic deformation properties of the two intermetallic compounds. And yet the anisotropy of both intermetallic compounds is decreasing as doping concentration increases. According to the calculations of the electronic structures, the doped (Ni,Co)3Sn4 structure and the doped η′‐(Cu,Co)6Sn5 structure exhibit stronger metallicity. In addition, stronger Co–Sn ionic bonds are formed in the doped Ni3Sn4 and η′‐Cu6Sn5 structures. This suggests that the doped Ni3Sn4 and η′‐Cu6Sn5 structures are harder.

Structural, elastic, mechanical, electronic, and optical properties of cubic K2Pb2O3 from first-principle study.

Based on first principles, the structure, elasticity, mechanics, electronics, and optical properties of cubic K2Pb2O3 were studied. The structural parameters calculated by this method are close to the previous theoretical results. The elastic constant, bulk modulus, shear modulus, Young's modulus, Poisson's ratio, and mechanical stability are studied, and it is shown that cubic K2Pb2O3 is mechanically stable, isotropic, and brittleness. The electrical conductivity and chemical bonding of cubic K2Pb2O3 were analyzed based on the calculated band structure, density of states (DOS), and bond populations. The dispersion of optical functions, including the dielectric function, refractive index, extinction coefficient, reflectivity, absorption coefficient, and loss function, is displayed and analyzed. All computations have been carried out based on density functional theory (DFT) as implemented in the CASTEP code. The norm conservation pseudopotential method is used to exchange correlation functionals within the generalized gradient approximation (GGA).

Asymptotic, second-order homogenization of linear elastic beam networks

We propose a general approach to the higher-order homogenization of discrete elastic networks made up of linear elastic beams or springs in dimension 2 or 3. The network may be nearly (rather than exactly) periodic: its elastic and geometric properties are allowed to vary slowly in space, in addition to being periodic at the scale of the unit cell. The reference configuration may be prestressed. A homogenized strain energy depending on both the macroscopic strain ɛ and its gradient ∇ɛ is obtained by means of a two-scale expansion. The homogenized energy is asymptotically exact two orders beyond that obtained by classical homogenization. The homogenization method is implemented in a symbolic calculation language and applied to various types of networks, such as a 2D honeycomb, a 2D Kagome lattice, a 3D truss and a 1D pantograph. It is validated by comparing the predictions of the microscopic displacement to that obtained by full, discrete simulations. This second-order method remains highly accurate even when the strain gradient effects are significant, such as near the lips of a crack tip or in regions where a gradient of pre-strain is imposed.

Analysis of the State of Moisture Control to Ensure and Regulate the Quality of Grain and Grain Products

The article discusses the methods for determining the maturity of grain and describes its behavior during harvesting, to optimize the selection of the grain moisture state, discusses the requirements for the choice of measurement method and the design of moisture control measuring devices, as well as its high accuracy and the possibility of measuring from field conditions, collection, storage, transportation, and industrial processing and release of finished products of granular materials. The purpose of the study is to improve the efficiency of control and management of complex technological processes and moisture control devices for granular bulk materials of plant origin through the development of systems for automatic and automated control of the electrophysical characteristics of grain products and to increase the reliability of quantitative and qualitative assessments of production and technological measurement information. To achieve this goal, it is necessary to conduct analytical and experimental studies of the possibility of creating an express method for controlling the moisture content of grain and products of their industrial processing and the development of a moisture meter for automated control of raw material parameters during acceptance and storage at grain processing enterprises. The article discusses the scientific and methodological foundations for measuring the electrophysical characteristics of grain products of agricultural production and the implementation on this basis of the functional subsystem of information support by the Automated Process Control System for Controlling the Mass Ratio of Moisture of Plant Origin Materials. A critical analysis of the current state of the theory and practice of automatic control of electrophysical characteristics of grain products and the identification of the trend of their further development and improvement are carried out. A mathematical model of the interaction of a high-frequency field with a granular material has been constructed, where the influence of the elastic properties of the grain on the electrical characteristics of the electromagnetic wave, which distinguishes its behavior in the field of a high-frequency wave from many other dielectrics, has been substantiated, and the influence of a large number of various disturbing factors has been studied, often the measurement results cannot be applied in the control of the technological process due to the uneliminated error, which is the cause of inaccurate information. Primary measuring transducers of electrophysical parameters of grain products are proposed, and their mathematical models are considered. A functional scheme of the measuring device based on the dielcometric method of moisture control of grain and granular materials has been developed, and metrological characteristics have been given.

Differences in the elastic work of breathing of the pulmonary parenchyma in patients with bronchial asthma and COPD

To determine and compare the work of breathing to overcome elastic resistance (Ael) in patients with bronchial asthma (BA) and chronic obstructive pulmonary disease (COPD) with similar changes in the elastic properties of the parenchyma in the same settings of ventilation disorders (grade 1). Differences in the manifestations of similar changes in the elastic properties of the lungs in patients with BA and COPD were evaluated. To identify differences, a comparative study was conducted on Аel overcome in BA patients with positive bronchodilator (with salbutamol) and bronchoconstrictor (with methacholine) tests, with reduced and preserved bronchial conductance (groups 1 and 2, respectively), and in COPD patients with negative bronchodilator and bronchoconstrictor tests (group 3). All study patients showed a grade 1 lung ventilation disorder (a decrease in the one-second forced expiratory volume by 15-35%). The results were compared with each other and with the control group (group 4, healthy non-smokers). All study patients were comparable by age and sex. The respiration mechanics was studied using simultaneous registration of spirogram and transpulmonary pressure, and the parameters of bronchial conductance and ventilation were determined using body plethysmopressography using the Jager software and hardware system. In COPD patients, Ael was significantly increased (p>0.05), whereas in both BA groups, it was unchanged. Increased elastic work of breathing in patients with COPD may be associated with the involvement of certain types of contractile elements, which are preserved in patients with BA at the initial stages of the disease.

Characterisation of hygroelastic properties of compression and opposite wood found in branches of Norway spruce

The differential swelling seen between softwood opposite wood (OW) and its neighbouring compression wood (CW) developed in branches prompts several engineering issues such as dimensional instability and cracking. For a more efficient use of resources, the inevitable CW and OW should not be discarded or used as fuel, but incorporated into engineered wood products. Swelling is a hygroelastic phenomenon, where both the swelling and elastic properties of CW and OW are needed in order to make proper structural predictions. In this paper, swelling coefficients and moisture dependent elastic moduli for both CW and OW in the three principal material directions are provided along with measurements of moisture content, density, and microfibril angle. The small deformations necessitate the use of precise X-ray micro-computed tomography for measurements. The results indicate that CW and OW from Norway spruce branches differ in swelling, especially in longitudinal direction at low moisture content. It is noted that CW is a wood type with less pronounced anisotropic behaviour than both OW and normal wood from the stem, with the elastic moduli less sensitive to moisture changes in both longitudinal and transverse directions.

Structural, elastic, mechanical, and electronic properties of chalcogenide perovskite SnZrS3 under pressure

In this paper, we have presented the structural, elastic, mechanical, and electronic properties of the transition metal chalcogenide perovskite SnZrS3 under different pressures by using first-principles method. Our calculated lattice parameters at ambient pressure are in good agreement with the experimental and previous theoretical results. The elastic constants were evaluated numerically for orthorhombic SnZrS3 using the strain-stress approach. Orthorhombic SnZrS3 shows a strong anisotropic behavior of the elastic and structural properties. According to the calculations of the electronic properties, we find the states near the valence band top are derived from S 3p, Zr 4d, Sn 5p, and Sn 5s orbitals, and the lowest conduction band is composed of Zr 4d, S 3p, and Sn 5p orbitals. As the pressure increases, the conduction and valence band shift to lower and higher energies, respectively. These results indicated that lattice constants and band gap decrease with the increase of pressure.

Superporous Hydrogel: A Novel Approach for Safe Gastroretentive Drug Delivery System

Superporous hydrogel are developed initially as novel drug delivery system to retain dosage form in upper gastrointestinal tract, and absorbs drug in gastric medium. The generation-based classification of superporous hydrogel is covered in this review. The hydrophilic polymer networks formed by the molecular entanglements which absorb water up to thousands of times to their dry weight. These systems swells quickly and resist in an extremely acidic condition in stomach. This hydrogel is instantly swell through capillary force which is driven by absorption of water through an open porous structure. This system provides better solubility and bioavailability by targeting the specific site of absorption. The conventional superporous hydrogels have the poor mechanical strength which is overcome by developing the second superporous hydrogel generation composites and the third-generation superporous hydrogel hybrids. This article has mainly focused on the classification, techniques, drug loading, research papers, characterizations and applications of superporous hydrogel.
 Keywords: Gastric retention, Cross-linking, Superporous hydrogel, Swelling rate, Elastic property, Hydrophilic polymer networks.

Modeling Nonlinear Dynamics of Functionalization Layers: Enhancing Gas Sensor Sensitivity for Piezoelectrically Driven Microcantilever.

This article presents a parametrized response model that enhances the limit of detection (LOD) of piezoelectrically driven microcantilever (PD-MC) based gas sensors by accounting for the adsorption-induced variations in elastic properties of the functionalization layer (binder) and the nonlinear motional dynamics of the PD-MC. The developed model is demonstrated for quantifying cadaverine, a volatile biogenic diamine whose concentration is used to assess the freshness of meat. At low concentrations of cadaverine, an increase in the resonance frequency is observed, contrary to the expected reduction due to mass added by adsorption. The study explores the variations in the elastic modulus vis-à-vis the adsorbed mass of cadaverine and derives the resonance frequency to the adsorbed mass response function. We advance a blended technique involving the analysis of atomic force microscopy (AFM) force-distance (f-d) curves and fitting of the quartz crystal microbalance (QCM) impedance response spectrum to deduce the adsorption-induced changes in the viscoelastic properties of the functionalization layer. The findings obtained are subsequently employed in modeling the response function for a structurally nonhomogenous PD-MC, highlighting the significance of the functionalization layer to the global elastic properties. The structural composition of the PD-MC beam adopted herein features a trapezoidal base hosting the actuating piezoelectric stratum and a rectangular free end with a functionalization layer. The Euler-Bernoulli beam theory coupled with Hamilton's principle is used to develop the equation of motion, which is subsequently discretized into a set of nonlinear ordinary differential equations via Galerkin expansion, and the solutions to the first fundamental mode of vibration are determined using the method of multiple scales. The obtained solutions provide a basis for deducing the nonlinear response function model to the adsorbed mass. The derived model is validated by recorded resonance frequency changes resulting from exposure to known concentrations of cadaverine. We demonstrate that the increase in resonance frequency for low concentrations of cadaverine is due to the dominance of the variation of the elastic modulus of the functionalization layer originating from the initial binder-analyte interactions over damping due to added mass. It is concluded that the developed nonlinear response function model can reliably be used to quantify the cadaverine concentration at low concentrations with an elevated Limit of Detection.

Estimating elastic properties of sediments by pseudo-wells generation utilizing simulated annealing optimization method

The hydrate concentration model considerably affects elastic properties, including bulk and shear modulus. Defining seismic properties of sediments, such as compressional and shear wave velocity and density, provides valuable information to identify rock facies and fluid types. This information commonly results from pre-stack seismic inversion, while post-stack seismic information provides acoustic impedance as a layer-based property. Traditionally, seismic inversion requires well logs to produce an initial guess of inversion routines and provide a low-frequency part of the amplitude spectrum. Eventually, seismic inversion methods could not be performed in the areas without well-log data, such as deep sea areas. In such cases, pseudo-well logs derived from pre-stack seismic data are a solution. Pseudo-well generation is a title used to estimate the elastic parameters of sediments in areas, such as deep marine environments, where drilled wells are absent or sparse. Metaheuristic optimization algorithms are suitable tools for minimizing the cost function as they best match real and synthetic seismic data. In this study, the SEAM earth model has been used as a reference to investigate the quality of pseudo-well generation utilizing a simulated annealing (SA) algorithm as an optimization method of property model change, which minimizes the cost function of seismic inversion. As a result, considering an initial model type of the SEAM model, simultaneous seismic inversion introduced the best compressional and shear wave velocities and density logs, which provide the best real and synthetic seismic data match when synthetic data is calculated from the simplified Zoeppritz equation.

Elastic properties and microstructure evolution of Zn2SnO4-spinel-containing composite ceramics based on tin oxide and zinc oxide

Ceramics based on tin oxide (SnO2) and zinc oxide (ZnO) were sintered at temperatures up to 1400 °C. Except for the end members, all these ceramics are two- or three-phase composites containing spinel phase (Zn2SnO4). Similar to pure SnO2 ceramics, also the spinel-rich composite (50:50 mixture) does not exhibit densification after sintering at 1400 °C. Spinel Zn2SnO4 is formed in all composites, with a major increase of spinel content at around 1000 °C. Young’s modulus values, determined via impulse excitation, are between the exponential relation for convex pores and a benchmark relation for concave pores (or a percolation relation). The evolution of Young’s modulus during sintering reveals significant differences between SnO2 (weak increase above 1000 °C), ZnO (significant increase above 800 °C) and the composites (intermediate). Spinel formation is revealed during heating by a distinct peak (elastic anomaly) at around 1000 °C.

Spectral analysis and dynamic properties of polyurethanes dyed with rhodamine 6G and rhodamine B as matrices of a solid-state laser element

A comparison was carried out of the nature of intermolecular interactions, elastic properties and gas permeability of the crosslinked polyurethanes doped with xanthene dyes and original polyurethane using IR spectroscopy, dynamic mechanical analysis (DMA) and electron paramagnetic resonance (EPR). The introduced dye can be considered as useful microimpurity which, however, can affect the efficiency of the laser. In IR spectra of polyurethanes the complex band of stretching vibrations of C=O groups is sensitive to the nature of intermolecular interaction of urethane groups. From the analysis of that band it is shown that in the presence of dyes, self-association of urethane groups within the hard segment predominates and the interaction of urethane groups with the oligoether component decreases, which can contribute to increasing the mobility of the flexible component. A decrease in the dynamic storage modulus (E’) and a decrease in the glass transition temperature (Tc) of polyurethanes in the presence of dyes is shown by the DMA method. The results of both DMA and IR spectroscopy indicate a greater increase in the mobility of the elastic component with the introduction of the rhodamine B dye, covalently bound to the polyurethane chain. According to nitroxyl paramagnetic probe data the introduction of both rhodamine B and rhodamine 6G dyes into polyurethanes increases their permeability to vapors of low-molecular weight compounds, but rhodamine 6G has a more prominent effect on this characteristic. This is consistent with DMA data indicating a greater increase in the Mc value in the presence of rhodamine 6G in polyurethane. The obtained results make it possible to determine the optimal composition of the active laser medium and are important in assessing the radiation resistance of the polymer matrix. Its increase is facilitated by a decrease in the storage modulus and an increase in the gas permeability of the polymer, leading to a decrease in pressure in the area of local heating.