Anion exchange membranes (AEM) are very important for water desalination and sustainable energy conversion devices. For the synthesis of AEM, carcinogenic chemicals were used, which are banned in India. So based on the requirement quaternized poly (phenylene oxide) (QPPO) based composite membranes has been synthesized in combination with functionalized boron nitride (f-BN). Membrane properties are tuned by varying f-BN content in QPPO. Composite membranes are characterized by means of their water content, ion exchange capacity and ionic conductivity. Additionally, thermal and mechanical properties are also evaluated. BPO-5 membrane displays 1.92 meq/g ion exchange capacity and 6.29 × 10–3 S/cm ionic conductivity. The power consumption and current efficiency during salt removal for BPO-5 membrane is found to be 1.96 kWh/kg and 96.26%, respectively. Among all membranes, BPO-5 exhibits excellent thermal and mechanical stability. BPO-5 membrane show lower power consumption, with high current efficiency during salt removal and better electrochemical selectivity.
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