Electromagnetic Interference Shielding Effectiveness Research Articles

Lightweight graphene foam composites with enhanced electrical conductivity and microwave absorption for electromagnetic interference shielding

Next-generation flexible electronics call for high-performance electromagnetic interference (EMI) shielding materials with lightweight and multifunctionality. Here, the chemical vapor deposition (CVD) graphene foam (GF) composites, containing flexible polymer matrix and magnetic Fe3O4 nanoparticles, are reported. The systematic manipulation of GF growth condition and the content of Fe3O4 reveals the effect of graphene thickness and integration of Fe3O4 on improving the electromagnetic shielding performance of composites. Owing to abundant internal interfaces, high conductivity from the three-dimensional interconnected graphene, and magnetic loss from Fe3O4, the ternary composites exhibit substantial improvement in microwave absorption, resulting in a superior EMI shielding effectiveness (SE) and absolute EMI SE up to 71 dB and 3641 dB·cm2/g, respectively, at a low density of 0.65 g/cm3 and minimal thickness of 0.3 mm. Moreover, the flexible composites display great EMI shielding stability after repeatedly bending, validating the composites as promising materials for practical applications in aerospace and flexible electronics.

Depositing gradient thickness silver film on CNF/rGO/polyimide surface to form a sandwich structure for efficient electromagnetic interference shielding

Deployable satellites in space are exposed to high-frequency electromagnetic interference (EMI) for long periods of time, resulting in shortened lifetimes, so there is an urgent need for supportive electromagnetic shielding materials. To address this limitation, our team has developed innovative ultrathin carbon nanofiber/reduced graphene oxide/polyimide (CNF/rGO/PI) composites. It has excellent strength, shape memory properties, thermal stability and wide temperature range tolerance. Among them, polyimide with 4 % CNFs and 4 % rGO (CGPI44) has the best performance. Gradient-thick Ag films are deposited on both sides of the CGPI44 substrate by magnetron sputtering to form sandwich structure composites. With a sputtered Ag thickness of only about 5 μm and a total thickness of 0.146 mm, the material exhibited an extremely high electrical conductivity and excellent EMI shielding effectiveness (SE) of up to 112 dB in the 8.2–12.4 GHz band. Finite element analysis is performed to calculate the electric field strength and energy distribution. By providing a feasible scheme for highly effective shielding of high-frequency EMI, this approach will promote research on magnetron-sputtered polymer composites in the field of electromagnetic shielding.

A Sandwich Structural Filter Paper-AgNWs/MXene Composite for Superior Electromagnetic Interference Shielding.

A thin, lightweight and flexible electromagnetic interference (EMI) shielding paper composite is an urgent need for modern military confrontations. Herein, a sandwich-structured EMI shielding paper composite with an easy pavement consisting of a filter paper layer, middle AgNWs/MXene layer, and polyvinyl butyral (PVB) layer was constructed by vacuum-assisted filtration, spraying and air-drying. The middle AgNWs/MXene compound endowed the filter paper with excellent electrical conductivity (166 S cm-1) and the fabricated filter paper-AgNWs/MXene-PVB composite exhibits superior EMI shielding (30 dB) with a 141 μm thickness. Remarkably, the specific EMI shielding effectiveness (SSE/t) of the filter paper-AgNWs/MXene-PVB composite reached 13,000 dB cm2 g-1 within the X-band frequency range. This value represents one of the highest reported for cellulose-based EMI shielding materials. Therefore, our sandwich-structured filter paper composite with superior EMI shielding performance can be used in the medical and military fields.

3D interconnected graphene nanoplatelets and nickel ferrite based silicone rubber foams for effective electromagnetic interference shielding and thermal insulation performance

In the present study, porous composite foams made of silicon rubber (SR), graphene nanoplatelets (GnP), and nickel ferrite (NiFe2O4) nanoparticles were developed using the salt template approach. SR act as a 3D porous network, the conductive channel provided by graphene nanoplatelets and the magnetic and dielectric loss provided by the NiFe2O4 and the composite foam as a whole showed absorption-dominated EMI shielding due to synergism between GnP and NiFe2O4. Without NiFe2O4, the total EMI SE is 23 dB, while different NiFe2O4 weight percentages (0%, 3%, 6%, & 9%) increase the SET up to 36.7 dB. The thermal conductivity of this prepared sample is found to be 0.0313 Wm−1K−1 for 9 wt% filler content of NiFe2O4. It shows a moderately low value as compared to existing polymer composites. The resulting SR/GnP@NiFe2O4 composite foams, which are lightweight, strong, and multifunctional, have straightforward synthesis procedures and have a myriad of possible uses for EMI shielding systems and thermal insulations in the disciplines of aerospace, military engineering, electrical engineering and electronics.

Regulated orientation and exfoliation of flaky fillers by close packing structures in polymer composites for excellent thermal conduction and EMI shielding

Efficient heat dissipation and electromagnetic interference (EMI) shielding are essential demands on packaging intensively integrated circuits in advanced electronics. Multicompetent polymer composites with thermal conduction and EMI shielding capacity have attracted tremendous interest in the material science community. Herein, we report the preparation of thermally conductive polymer composites with superior EMI shielding effectiveness (SE) by building a 3D interconnected conductive network under close-packing circumstances. The build of the 3D network relies on the coordinated stacking of flaky and spherical fillers, where the asymmetric graphite flakes (FG) are confined in the interstitial regions of the close-packing structures of hollow glass microspheres (HGμS). The “rigid” close-packing structure of HGμS inhibits the in-plane orientation of FG along the flow direction during melt processing and facilitates the exfoliation of FG under external forces producing a conductive network with enhanced interconnectedness. The model system comprised of thermoplastic polyurethane (TPU), FG and HGμS has attained in-plane and through-plane thermal conductivity of 20.54 W m−1 K−1 and 6.55 W m−1 K−1 with 30 vol% FG (while maintaining a low mass density of 1.15 g cm−3, identical to neat TPU). Meanwhile, a high EMI SE of 69 dB has been achieved at a thickness of 1 mm.

Application of Multilayered Blend Films as Soft, Stretchable, Self‐Adhesive, and Self‐Healing Absorption‐Dominant EMI Shielding and Microwave Absorber

AbstractSolution‐processable organic conductor–supramolecular elastomer blends are emerging materials for intrinsically stretchable and autonomously self‐healing organic electronics. Herein, the feasibility of a heterogenous multiphase polymer blend is demonstrated for soft, ultraflexible, self‐adhesive, and self‐healing multilayered film structures for electromagnetic interference (EMI) shielding and microwave absorber (MWA) purposes. The developed soft multilayered films achieve a 5–40 fold improvement in the thickness of the MWA compared to the current state‐of‐the‐art. The thickness normalized reflection loss (RL) is up to 65.26 dB mm−1 with 8.5 GHz bandwidth at 18–26.5 GHz. The maximum thickness normalized EMI shielding effectiveness peaks at up to 175 dB mm−1. The EMI shielding and MWA properties are maintainable up to 150% tensile strain with only a small decrease in the overall attenuation and RL. Furthermore, the developed films are capable of fully autonomously self‐healing and achieve a tough adhesion in temperatures of −30–145 °C, and underwater with maximum single‐lap shear adhesion strength of ≈481.5 kPa to soft thermoplastic polyurethane films. Thus, the developed multilayered films can be utilized for absorption‐dominant EMI shielding or MWA purposes as stretchable coatings. The developed materials also show considerable potential for emerging damage and puncture‐resistant organic soft electronics with autonomous material‐level self‐healing.

Multilayered silver nanowires and graphene fluoride-based aramid nanofibers for excellent thermoconductive electromagnetic interference shielding materials with low-reflection

Multilayered films composed of alternating layers of graphene fluoride (GF) and silver nanowires (AgNWs) in an aramid nanofiber (ANF) matrix were fabricated. The films were prepared by sequential vacuum filtration of GF@ANF and AgNWs@ANF suspensions to obtain multilayered composite architectures. The multilayered GF@ANF/AgNWs@ANF films exhibited exceptional mechanical flexibility and strength, with tensile strength up to 130 MPa and 5000 bending cycles with negligible performance deterioration. The films displayed remarkably high electromagnetic interference (EMI) shielding effectiveness up to 54 dB in X-band frequencies, attributed to the multiple internal reflections in the multilayered structure. EMI shielding was dominated by absorption rather than reflection, enabling attenuation of incident microwaves without secondary pollution. The multilayered films also exhibited ultrahigh in-plane thermal conductivity of up to 45 W/mK, owing to the thermally conductive GF and AgNWs networks. The EMI shielding effectiveness and thermal conductivity were retained after temperature and bending cycling. The composite films also demonstrated excellent flame retardancy. This study provides an effective route toward concurrent enhancement of multi-functional properties through architectural engineering at the nanoscale. The combination of robust EMI shielding, mechanical flexibility, thermal management, and fire safety highlights the potential of rationally designed multilayered composites for practical applications in 5 G wearable electronics devices, communications systems, and radar technologies.

The multifunctional flexible conductive viscose fabric prepared by thiol modification followed by copper plating

Based on the current rapid development of electronic products, the development of light-weight, processable, environmentally friendly, long-life, durable, less corrosive, and tunable conductive composite materials with multiple applications may be the development direction of next-generation electronic devices. In this work, for the first time, we employed 3-Mercaptopropyltrimethoxysilane (3-MT) to modify viscose nonwovens and enhance the copper plating process. The prepared samples were characterized by Fourier transform infrared, Wide-angle X-ray diffraction (WAXD), scanning electron microscope + energy dispersive X-ray spectroscopy (SEM + EDS), thermogravimetric analysis (TGA), electrical resistivity, anti-corrosion, Joule heating, and electromagnetic interference (EMI) shielding. Results showed that 3-MT was covalently bound to the viscose surface through hydrolysis and condensation reactions and introduced SH groups. WAXD confirmed that the thiol modification did not change the internal crystal structure of viscose and copper ions. TGA and surface morphology analysis confirmed that the modified viscose promoted the deposition of metal particles in the copper plating process due to the affinity of thiol to metal so that copper particles almost completely wrapped the viscose fibers. In addition, 3MT@Cu@Viscose exhibits extremely low surface and volume resistivity (346.6 and 333.2 mΩ·m), improved corrosion resistance (corrosion rate reduced by 58% compared to the unmodified sample), fast Joule heating response (within 10 s) in low voltage (1 V) and excellent EMI shielding effectiveness (EMI SE > 50 dB). It showed great potential in future multi-functional electronic products such as electric heating sensors, smart clothing, and EMI shielding barrier.

Stretchable and translucent liquid-metal composite mesh for multifunctional electromagnetic shielding/sensing and Joule heating

Flexible liquid metal (LM)-based composite materials with strain-undiminished electromagnetic interference (EMI) shielding effectiveness (SE) and multifunctional integration are attracting great attention due to the urgent need for flexible electronic and wearable devices. Herein, stretchable and translucent polydimethylsiloxane/LM composite mesh (PLM) is developed by introducing highly deformable LM filler into elastomer and constructing conductive mesh structures by cast molding and mechanical sintering, which shows strain-enhanced EMI SE without a significant decrease in light transmittance due to the contribution of stretch-induced enhanced conductivity, mesh densification, and orientation. The linear response of relative SE change with tensile strain allows the PLM to exhibit ideal EM sensing characteristics, superior to most reported stretchable EMI shields. The oriented mesh structure endows the stretched PLM with anisotropic EMI SE under rotation, revealing a feasible means to realize tunable SE in a tensile state. More importantly, the high conductivity and deformability of the LM network further provide the PLM with excellent and relatively stable Joule-heating performance when served as a stretchable Joule heater. This work offers a new strategy for developing multifunctional stretchable LM-based composites that can achieve strain-enhanced EMI SE and ideal EM sensing capability without significantly sacrificing the light transmittance and Joule-heating performances under stretching.

Creation of Wood-Based Hierarchical Superstructures via In Situ Growth of ZIF-8 for Enhancing Mechanical Strength and Electromagnetic Shielding Performance.

Given the escalating prevalence of electromagnetic pollution, there is an urgent need for the development of high-performance electromagnetic interference (EMI) shielding materials. Herein, wood-based electromagnetic shielding materials have gained significant popularity due to their exceptional performance as building materials. In this study, a novel wood-based composite with electromagnetic shielding properties is developed. Through the in situ growth of zeolitic imidazolate framework-8 (ZIF-8) crystals on wood fibers, coupled with uniform integration of carbon nanotubes (CNTs), a multifunctional composite named ZIF-8/Poplar-CNT composite is synthesized via a one-step thermoforming process. The incorporation of CNTs endows the composites with excellent EMI shielding effectiveness (EMI SE). Among these elements, despite ZIF-8 crystals not possessing intrinsic electromagnetic shielding functionality, their distinctive dodecahedral structure proves adept at scattering and reflecting electromagnetic waves within the composites, further improving the electromagnetic shielding effect. Hence, the ZIF-8/Poplar-CNT composite (56.95dB) has ≈10dB higher EMI SE compared to that of the composites without ZIF-8 crystals. Meanwhile, ZIF-8 crystals endow the materials with excellent tensile strength (54.84MPa, enhanced by 4 times). Moreover, the introduction of Zn2+ provides superior antibacterial properties. The potential applications of ZIF-8/Poplar-CNT composites extend to diverse areas such as building decoration, electronic products, and medical equipment.

Electromagnetic shielding Janus membrane for direct current‐type pressure and sliding sensing

AbstractFacing increasing electromagnetic radiation pollution, soft sensors with electromagnetic interference (EMI) shielding is highly desirable. Here, flexible electromagnetic shielding [polyacrylonitrile/Fe3O4/polyaniline]//[multiwalled carbon nanotube/polyvinyl pyrrolidone] (denoted [PAN/Fe3O4/PANI]//[MWCNT/PVP]) Janus membrane is reported for pressure and sliding sensing. The [PAN/Fe3O4/PANI] layer of Janus membrane as the force and sliding sensing unit can generate direct current‐type (DC‐type) voltage signals by conducting polymer/metal Schottky junction, whereas [MWCNT/PVP] layer serves as main electromagnetic shielding unit. Under the vertical force and horizontal sliding of aluminum (Al) foil, it can output DC‐type voltage signals based on the Schottky contact. The performance of [PAN/Fe3O4/PANI]//[MWCNT/PVP] Janus membrane for pressure and sliding sensing is appropriately explored and assessed. Moreover, the Janus membrane exhibits excellent shielding effects with average EMI shielding effectiveness (SE) of 37.54 dB in 8.2–12.4 GHz (X‐Band) frequency ranges. Thus, based on the asymmetrical double‐layer structure, soft DC‐type sensor with EMI shielding is achieved, showing utilization potential in wearable electronics and intelligent robots.

Durable and sustainable CoFe2O4@MXene-silver nanowires/cellulose nanofibers composite films with controllable electric–magnetic gradient towards high-efficiency electromagnetic interference shielding and Joule heating capacity

Exploring electromagnetic waves (EMW) absorption-dominated high-performance electromagnetic interference (EMI) shielding materials with robust mechanical properties and remarkable Joule heating capability is highly desired but remains a daunting challenge for the development of modern electronic equipment. Herein, durable and multifunctional cellulose nanofiber-based composite films with elaborate electric–magnetic dual gradient structure were successfully fabricated through highly controllable vacuum-assisted filtration technology. The electric–magnetic dual gradient network consists of CoFe2O4@MXene hybrids with electric–magnetic cooperative loss concentrated on the top region as impedance matching layer and silver nanowires (AgNWs) with high conductivity placed on the bottom as high-efficiency shielding layer. Benefiting from the construction of dual gradient network with rational arrangement of the impedance matching layer and conductive shielding layer, the synergy of electric–magnetic loss, polarization loss induced by the numerous heterointerfaces and “absorption-reflection-reabsorption” shielding mechanism, the resultant composite films simultaneously reveal ultraefficient EMI shielding effectiveness (SE) and low EMW reflectivity. The prepared composite films (0.1 mm in thickness) achieve an extraordinary EMI SE of 84.3 dB and a satisfactory reflection coefficient of 0.42, realizing EMW absorption-dominated shielding feature. Moreover, the mechanical properties and Joule heating capacity of the prepared composite films are outstanding, which mainly benefits from the construction of hierarchically layered structure. This work paves a novel route for designing and fabricating absorption-dominated high-performance EMI shielding composite films with durable mechanical performance and outstanding Joule heating capability, which are potentially suitable for new-generation advanced electronics.

Flexible and Robust Core-Shell PANI/PVDF@PANI Nanofiber Membrane for High-Performance Electromagnetic Interference Shielding.

Developing high-performance electromagnetic interference (EMI) shielding materials that are lightweight and flexible and have excellent mechanical properties is an ideal choice for modern integrated electronic devices and microwave protection. Herein, we report the preparation of core-shell polyaniline (PANI)-based nanofiber membranes for EMI shielding through seed polymerization. Electrospinning a PANI solution leads to homogeneously dispersed PANI on the nanofiber surface, with abundant attachment sites for aniline through electrostatic adsorption and hydrogen bonding interaction, allowing PANI to grow on the nanofiber surfaces. This stable core-shell heterostructure provides more interfaces for reflecting and absorbing microwaves. The PANI/PVDF@PANI membranes achieved a shielding efficiency (SE) of 44.7 dB at a thickness of only 1.2 mm, exhibiting an exceptionally high specific EMI shielding effectiveness (SE/t) of 372.5 dB cm-1. Furthermore, the composite membrane exhibits outstanding mechanical stability, durability, air permeability, and moisture permeability, also making it suitable for applications such as EM shielding clothing.

Investigation on surface metallization of epoxy resin and its electromagnetic interference shielding performance

In this study, aluminum and aluminum/nickel metal layers with varying thicknesses were deposited on the surface of epoxy resin using electron beam evaporation technology. The research aimed to explore and compare the impact of the thickness and material of the metal layer on electromagnetic interference shielding efficiency. The study revealed that the metal layer on the pre-treated surface of the epoxy resin displays a more complete morphology with uniform coverage and a distinctive stratification in the aluminum/nickel (Al/Ni) metal layer. The application of aluminum and aluminum/nickel metal layers onto the surface of epoxy resin demonstrates effective electromagnetic interference shielding. The investigation reveals that electromagnetic interference shielding efficiency escalates with the thickness of the metal layer within the test frequency range of 4 GHz to 15 GHz. Notably, it attains 70 dB when the aluminum/nickel metal layer achieves a thickness of 1 μm. These findings signify that the aluminum/nickel metal layer displays outstanding electromagnetic interference shielding performance, making it suitable for widespread application in the domain of electromagnetic interference shielding for polymer composites.

Flexible, hierarchical MXene@SWNTs transparent conductive film with multi-source thermal response for electromagnetic interference shielding

Flexible transparent electromagnetic interference (EMI) shielding films in visual windows are crucial for the innovation of optoelectronic devices, but the challenge of balancing light transmittance and EMI shielding effectiveness (SE) still exists. Herein, this work described a flexible transparent MXene@SWNTs/PC film with a hierarchical conductive layer that was fabricated via an alternating rotation spraying method. The multi-scale hierarchical structure configured with 1D SWNTs and 2D MXene endow the obtained film with good comprehensive properties, i. e, low sheet resistance of 32.8 Ω/sq at 56.1% light transmittance, thus causing a satisfactory EMI SE of 20.8 dB. Moreover, the transparent shielding films exhibit remarkable flexibility, which can maintain steady EMI SE after 1000 continuous bending cycles. More importantly, the low sheet resistance and high light absorption capacity of hybrid conductive layer facilitate the transparent shielding film with low-voltage-driven electric heating effect and outstanding photothermal conversion ability, respectively, ensuring the normal operation under extreme cold condition. The combination of good light transmittance, satisfactory EMI shielding performance, and multi-source thermal response enables MXene@SWNTs/PC film to have great potential as a transparent shielding film in emerging optoelectronic devices.

Multifunctional syndiotacticity-rich poly (vinyl alcohol)/MXene sediment for multilayered composite films with effective electromagnetic interference shielding and thermal conductivity

Utilizing remarkable polymer matrix and efficient filler to propose an ingenious strategy for designing composite films synergistically with high electromagnetic interference shielding effectiveness (EMI SE) and thermal conductivity. Herein, a novel type of flexible composite film based on syndiotacticity-rich poly (vinyl alcohol) (sPVA)/modified MXene sediment (mMS) is fabricated through an alternating casting approach. The sPVA/mMS multilayered film containing effective noncovalent combining between sPVA layer and mMS layer not only presents a high strength of ∼66.3 MPa but also possesses a superior electrical conductivity of 683 S/m. Notably, the mMS layer with dense conductive and thermal networks endows the 95-μm-thick composite film with the synergy of favorable EMI SE (∼15.8 dB) in the X band and impressive in-plane thermal conductivity (3.31 W/mK, enhanced by ∼2365%). Moreover, this multilayered architecture realizes multiple internal reflection-absorption of microwaves and efficient heat dissipation, while confers the film with advantageable flame retardancy and significant water resistance. Therefore, sPVA-based composite films from MS provide a promising solution for the development of multifunctional polymeric materials tailored for upcoming electronic devices in challenging environments.

Electromagnetic shielding effectiveness of silver‐coated hollow glass microsphere‐graded short carbon fiber epoxy composite

AbstractThe present study is investigating the use of short carbon fiber (SCF) and silver‐coated hollow glass microsphere (Ag@HGM) reinforced epoxy light‐weight composites for electromagnetic interference (EMI) shielding applications in the X‐band frequency range (i.e., 8–12 GHz). The study found that Ag@HGM along with SCF significantly improved the dielectric properties of the composites and enhanced the EMI shielding effectiveness of 34.6 dB. Thermal analysis indicates that the sample shows a high rate of heat dissipation and good thermal conductivity. The dynamic mechanical analysis has indicated that the composite has improved storage modulus, glass transition temperature, and activation energy.Highlights SCF and Ag@HGM epoxy composite is fabricated for EMI shielding application. Two steps: etching and electroless coating of HGM are used for silver coating. The addition of Ag@HGM has enhanced total SE from 27.4 to 34.6 dB. EM wave gets scattered, experiences internal reflections view SCF and Ag@HGM. Additionally, enhancement of thermal and mechanical properties is observed.

SiC skeleton‐reinforced highly oriented graphite with good thermophysical and electromagnetic shielding properties

AbstractThe design of multifunctional materials with good thermophysical and electromagnetic shielding properties is desirable to overcome overheating and electromagnetic interference (EMI) in electronic devices. In this study, three‐dimensional (3D) continuous SiC skeleton‐reinforced highly oriented graphite flake (GF@SiC) composites were fabricated by combining molten salt synthesis, heat treatment, and spark plasma sintering. When the SiC content was higher than 9 vol.%, a 3D continuous SiC skeleton was formed, which effectively constrained the cross‐plane thermal expansion of the GF@SiC composites. Highly oriented GFs endowed the composites with good thermal conductivity (TC) along the basal plane and effective EMI shielding in the X‐band. The composites with SiC concentrations of 9 vol.% exhibited an optimal comprehensive performance with a high TC of 322 W/m/K in the basal plane direction, a low thermal expansion value of 10.5 × 10−6/K in the through‐plane direction, and EMI shielding effectiveness of 36 dB. Our strategy provides a promising and practical approach for realizing graphite‐based composites to meet the current demands for electronic devices.

Morphology dependent EMI shielding performance of Ag-Ni core-shell nanowires

The proposed work reports a facile chemical reduction method for synthesizing the hierarchical silver-nickel core-shell nanowire structures with controllable morphologies by varying the Ag concentration. The growth of Ni shells around the Ag core to make thorny and smooth Ag-Ni core-shell nanowires is studied for addressing electromagnetic interference (EMI). The synthesized Ag-Ni nanowires show better EMI shielding effectiveness (SE) than Ni nanowires with much-improved absorption loss (SEA). Due to high electrical conductivity (8630 S cm−1), magnetic permeability (44.1 emu/g), and heterojunction core-shell interfaces, the bimetallic nanowires flakes exhibit exceptional average EMI SE of 90.5 dB in the X-band frequency range (8–12 GHz) with a thickness of 0.11 mm, taking specific EMI SE to 822.72 dB/mm. In addition, the EMI shielding performance of the smooth Ag-Ni nanowires showed a 45% enhancement in SEA with marginal change in reflection loss (SER) compared to the thorny ones, indicating high absorption of EM waves. The unique core-shell nanowires with high aspect ratio with tunable physical properties can be ideal candidates for futuristic applications in microwave absorption and electromagnetic interference shielding.

Scalable Production of Highly Conductive 2D NbSe2 Monolayers with Superior Electromagnetic Interference Shielding Performance.

Thin, flexible, and electrically conductive films are in demand for electromagnetic interference (EMI) shielding. Two-dimensional NbSe2 monolayers have an electrical conductivity comparable to those of metals (106-107 S m-1) but are challenging for high-quality and scalable production. Here, we show that electrochemical exfoliation of flake NbSe2 powder produces monolayers on a large scale (tens of grams), at a high yield (>75%, monolayer), and with a large average lateral size (>20 μm). The as-exfoliated NbSe2 monolayer flakes are easily dispersed in diverse organic solvents and solution-processed into various macroscopic structures (e.g., free-standing films, coatings, patterns, etc.). Thermal annealing of the free-standing NbSe2 films reduces the interlayer distance of restacked NbSe2 from 1.18 to 0.65 nm and consequently enhances the electrical conductivity to 1.16 × 106 S m-1, which is superior to those of MXenes and reduced graphene oxide. The optimized NbSe2 film shows an EMI shielding effectiveness (SE) of 65 dB at a thickness of 5 μm (>110 dB for a 48-μm-thick film), among the highest in materials of similar thicknesses. Moreover, a laminate of two layers of the NbSe2 film (2 μm thick) with an insulating interlayer shows a high SE of 85 dB, surpassing that of the 20-μm-thick NbSe2 film (83 dB). A two-layer theoretical model is proposed, and it agrees with the experimental EMI SE of the laminated NbSe2 films. The ability to produce NbSe2 monolayers on a tens of grams scale will enable their diverse applications beyond EMI shielding.