Incorporating multi-solid wastes to prepare foam ceramics has attracted widespread attention due to its excellent characteristics and environmental protection. In this study, foam ceramics were prepared by sintering method using recycled waste concrete powder (RWCP) and waste glass power (WGP) as the major material, Na2CO3 as foaming agent and borax as fluxing agent. The effect of sintering temperature on the physical properties and pore structure of foam ceramics were studied. The phase transformation and reaction mechanism were also discussed. The results reveal that when the RWCP content was 40%, the WGP content was 60% and the sintering temperature was 890 °C, the foam ceramics showed the best overall performance. The compressive strength, bulk density, water absorption and porosity were 2.39MPa, 0.83g/cm3, 8.27% and 66.68%, respectively. At this time, the pore size distribution was optimal, and mesopore occupied the vast majority. The fractal dimension of pore reached the minimum of 1.09. In addition, The XRD results showed that WGP and RWCP gradually depolymerized and reconstructed under the action of flux. Then the foam ceramics with mullite, pyroxene and wollastonite as the main phases were formed. The experimental results showed that it was feasible to prepare foam ceramics using RWCP. This study can provide a new train of thought for the reuse of RWCP.