The parallel mechanism exhibits high stiffness and excellent dynamic response, making it ideal for high-precision applications. In our early work, a novel 6-DOF redundant parallel posture mechanism with four limbs for solar wing docking has been proposed; each limb consists of three links and four joints. This paper primarily focuses on optimization design of the mechanism. The calculation of workspace volume reveals that factors influencing the range of posture adjustment include dynamic platform parameters, static platform parameters, the drive trajectory of each kinematic pair, and the angles between each kinematic pair. A sensitivity analysis was conducted to examine the impact of each parameter on the range of posture adjustment. To reduce computational complexity and improve analysis efficiency, a combined approach of single-factor analysis and response surface methodology (RSM) is used in the paper. Single-factor analysis is utilized to evaluate the effect of each parameter on the posture adjustment range. Based on these results, RSM is used to establish a regression model for parameters; thereby, the optimal parameter combination for the mechanism is determined. The regression coefficient R2 = 0.9374 attests to the validity of the proposed model. Finally, a comparison of the posture adjustment range before and after optimization is presented, providing a foundation for the practical application of the redundant parallel mechanism. This paper introduces a novel structural design concept aimed at resolving the conflict between heavy loads and compact sizes in redundant parallel mechanisms while providing valuable insights for miniaturized design.