Durability Of Materials Research Articles

Bulk Alloy Anodes for Sodium‐Ion Batteries

AbstractSodium‐ion batteries (SIBs) are considered a promising candidate for next‐generation energy storage systems due to the abundance of available sodium resources. The practical application of SIBs critically depends on developing durable electrode materials with high capacity and long lifespan, particularly when it comes to finding suitable anode materials. Alloy‐type anodes are appealing for their high capacities owing to the multiple electron transfer alloying reaction mechanism, making them ideal for high‐energy‐density SIBs. However, the huge volume change during charge/discharge process can cause the active material pulverization to detach from the current collector, leading to poor cycling performance, especially for bulk alloy anodes. Despite this challenge, recent progress in bulk or micro‐sized alloy anodes for SIBs have shown promise. This review highlights the up‐to‐date advancements and research on bulk alloy‐based anode materials for SIBs, including synthetic strategies and electrochemical performance. The crucial role of bulk alloy anodes in advancing SIB technology is discussed, along with a summary of research on bulk alloy‐type anodes and their compounds for sodium storage. Strategies to improve the electrochemical performance of bulk alloy‐based anode materials are also explored. Additionally, the potential of multi‐component alloys and high‐entropy alloys as future research directions for alloy‐based anodes is proposed.

Modification of opto‐electrical behavior of polyvinyl chloride by infusion of SrTiO3 nanofiller synthesized via green route

AbstractEnhancing the opto‐electrical properties of polymer is crucial for optoelectronic devices. This study emphasis the synthesis of strontium titanate (SrTiO3) nanoparticles using a green sol–gel method and incorporates them into polyvinyl chloride (PVC) to create nanocomposite films via solution casting. The structural, optical, thermal, and electrical properties of PVC with SrTiO3 at concentrations of 1, 3, and 5 wt.% were examined. Better crystallinity was obtained with filler incorporation. Fourier transform infrared shows the physical interaction between nanofiller and the matrix. SEM results suggested that SrTiO3 nanofiller are well distributed in PVC surface. UV–Vis spectroscopy was used to study optical behavior of the nanocomposites. Optical bandgap energy decreased from 3.2 to 2.5 eV with increased concentration of SrTiO3 in PVC matrix. Photoluminescence results show the reduction of electron hole recombination rate. The integration of SrTiO3 nanofiller into the PVC matrix improved the thermal stability, dielectric constant, and the overall performance of the prepared nanocomposite films, making them suitable for high‐temperature optoelectronic and energy storage applications. The green synthesis of SrTiO3 nanofiller also ensures the environmental benefits, high purity, and homogeneity, leading to consistent enhancements in the PVC/SrTiO3 composites. These improvements highlight their potential for advanced optoelectronic devices requiring efficient and durable materials.

Investigation of mechanical properties in FFF- produced PLA samples using the Erichsen test: application of definitive screening and RSM

Purpose This study aims to investigate how printing parameters affect the mechanical properties of specimens produced through fused filament fabrication, using the Erichsen test to assess deformation characteristics and material durability under stress. Design/methodology/approach Polylactic acid (PLA) specimens were printed and tested in accordance with the ISO 20482 standard. Definitive screening was conducted to identify the most influential process parameters. This study examined the effects of four key process parameters – number of layers, layer height, crossing angle and nozzle diameter – on force, distension, peak energy and energy to break. Each parameter was assessed at three levels and a large number of required experiments was managed by using response surface methodology (RSM). Findings This study revealed that the number of layers, layer height and crossing angle are the most significant factors that influence the mechanical properties of 3D-printed materials. The number of layers had the greatest impact on the peak force, contributing 44.25%, with thicker layers typically enhancing material strength. The layer height has a significant effect on energy absorption and deformation, with greater layer heights generally improving these properties. Nozzle diameter contributed only 1.10%, making it the least influential factor; however, its impact became more pronounced in interactions with other parameters. Originality/value This paper presents a comprehensive experimental investigation into the effects of process parameters on the crack strength and behavior of 3D-printed PLA specimens using the RSM method. The documented results can be used to develop optimization models aimed at achieving desired mechanical properties with reduced variation and uncertainty in the final product.

The Impact of Chlorinated Water and Sun Exposure on the Durability and Performance of Swimwear Materials.

Understanding the factors that affect how materials age is essential for creating a durable product with long-lasting properties. It is also important to prioritize defining aging parameters that reflect the real-world conditions the materials will encounter. For this study, a range of swimwear materials were selected consisting of a blend of polymer (polyamide/polyester) and elastane in varying ratios. In order to simulate aging conditions, materials were immersed in chlorinated outdoor pool water during the summer season, either in shade or the sun, for 200 and 300 h. The materials were tested for mass per unit area, thickness, tensile properties, and moisture management. A slight mass per unit area increase was observed, rising from 1.0% after 200 h of chlorine and sunlight exposure to 3.7% after 300 h. Thickness increased by 1.7% after 200 h and 3.2% after 300 h of chlorine exposure, with no significant effect of sunlight. Breaking force dropped by 12.4% after 200 h in chlorine and 8.2% in chlorine and sunlight, becoming more pronounced after 300 h (65.7% in chlorine and 65.1% in chlorine and sunlight). The overall moisture management capability declined from 0.4888 to 0.3457 after 200 h in chlorine and 0.3393 with sunlight, dropping further after 300 h to 0.3838 and 0.3253, respectively.

Utilization of Granulated Blast Furnace Slag in Cement Mortar: Performance Analysis Against M-Sand

This study aims to explore the feasibility of incorporating Granulated Blast Furnace Slag (GBFS) as a sustainable alternative to manufactured sand (M-Sand) in cement mortar, to enhance both environmental sustainability and mechanical performance. The research involves a systematic investigation where M-Sand is progressively replaced by GBFS at varying levels of 10%, 20%, 30%, 40%, and 50%. The effects of these replacements are evaluated through a series of tests that focus on the mortar's physical properties, as well as its compressive and tensile strengths. Experimental results reveal that replacing 30% of M-Sand with GBFS produces the most favorable outcomes, with the compressive strength of the mortar exceeding that of the control mix by 12% after 28 days. The tensile strength also showed marked improvements at this replacement level. However, when the replacement level exceeds 30%, both compressive and tensile strengths begin to diminish, indicating that excessive substitution may adversely affect the mortar's structural integrity. The findings of this study provide valuable insights into the optimal use of GBFS in cement mortar, demonstrating that a 30% substitution not only enhances strength characteristics but also contributes to more sustainable construction practices by reducing reliance on natural sand resources. This research supports the potential of GBFS as a viable material for improving the environmental profile and durability of cement-based materials.

Surface Corrosion‐Resistant and Multi‐Scenario MoNiP Electrode for Efficient Industrial‐Scale Seawater Splitting

AbstractThe construction of efficient and durable multifunctional electrodes for industrial‐scale hydrogen production presents a main challenge. Herein, molybdenum‐modulated phosphorus‐based catalytic electrodes (Mo‐NiP@NF) are prepared via mild electroless plating. Heteroatoms doping or heterostructures construction can reconfigure the intrinsic electronic structure of the pre‐catalyst and optimizes the key intermediates adsorption. Moreover, the (hypo/meta‐)phosphite anions (POxδ−) and molybdate ions (MoOxδ−) on the electrode surface of Mo‐NiP@NF afford resistance to chloride (Cl−) corrosion. Mo‐NiP@NF exhibits ultralow overpotentials of 278/550 and 282/590 mV at 1 A cm−2 during the hydrogen/oxygen evolution reaction (HER/OER) in alkaline simulated and real seawater, respectively, whereas catalytic overall seawater splitting (OWS) reach 1 A cm−2 at 1.96 and 1.97 Vcell. Remarkably, Mo‐NiP@NF maintains stable operation for 1500 h in OWS. The scalability of Mo‐NiP@NF allowing the assembly of proton exchange membrane (PEM) electrolyzer powered by photovoltaic energy, simulating a portable hydrogen‐oxygen respirator provides an oxygen/hydrogen flows of 160/320 mL min−1. Expanding further, the trace ruthenium‐loaded Mo‐NiP@NF catalyst sodium borohydride (NaBH4) hydrolysis achieving a hydrogen generation rate (HGR) of 11049.2 mL min−1 g−1. This work provides strategic innovations and optimization solutions for the economical and mild construction of multi‐scenario durable green energy conversion materials at industrial‐scale application.

Assessing the Tribological Impact of 3D Printed Carbon-Reinforced ABS Composite Cylindrical Gears

The tribological performance of carbon-reinforced acrylonitrile butadiene styrene (ABS) composites is very important in determining their suitability for advanced engineering applications. This study employs response surface methodology (RSM) to evaluate the effects of printing temperature and post-processing annealing on the wear resistance and frictional properties of these composites. A central composite design is used to systematically explore the interaction between these two factors, enabling the development of predictive models for key tribological parameters. The results reveal that both the coefficient of friction (COF) and wear are affected by printing and annealing temperatures, although in a non-linear manner. Moderate printing temperatures and lower annealing temperatures were found to reduce friction and wear, with annealing temperature having a more pronounced effect on wear. To further optimize these responses, the desirability approach was applied for predicting the optimal conditions. The optimal combination of input parameters for minimizing both COF and wear was found to be a printing temperature of 256 °C and an annealing temperature of 126 °C. This research provides valuable insights for optimizing additive manufacturing processes of carbon-reinforced ABS composites, contributing to enhanced material durability in practical applications.

Machinability characteristics study on hibiscus rosa-sinensis reinforced polymer composites using soft computing techniques

Abstract Understanding the drilling behaviour of composite materials is crucial for optimizing their manufacturing processes and enhancing their applicability across various industries. In this study, the drilling process of Hibiscus Rosa-Sinensis Polymer matrix composites is investigated due to the significance of investigating such advanced and sustainable composite materials for their potential applications. Hibiscus Rosa-Sinensis Fibers are extracted and processed from the outer bark of the hibiscus plant, are incorporated into polymer matrices in varying weight percentages (0 Wt%, 10 Wt%, 20 Wt%) to form discontinuously reinforced polymer composites. Samples with uniform dimensions of 150 × 75 × 15 mm, are used for the drilling operation using Ace Micromatic DTC-400 instrument. The project focuses on analysing the influence of key drilling input parameters such as Spindle speed, Feed rate and HRS (Hibiscus Rosa-Sinensis) Fiber weight percentage on the Thrust Force (N) and Torque (N-m) generated during drilling operations. Taguchi’s Design of Experiments with L27 orthogonal array is used to systematically optimize the input parameters to gain insights into the drilling behaviour of these composite materials. Further a second order mathematical model has been generated for Thrust Force and Torque using Response Surface Methodology (RSM). Thrust Force and Torque during drilling are measured using 9257 BA KISTLER Dynamometer coupled with DynoWare 2825 A software. The findings of this study not only contribute to a deeper understanding of the drilling process but also hold significant implications for industries reliant on composite materials. From aerospace to automotive sectors, where lightweight and durable materials are essential, to construction and renewable energy industries seeking sustainable alternatives, the application potential of hibiscus Rosa-Sinensis Fiber-reinforced composites is vast. By elucidating the intricate dynamics of drilling operations on these materials, this research paves the way for enhanced manufacturing processes and the development of advanced composite structures tailored to meet the demands of diverse industrial applications.

Effect of temperature and relative humidity on hydrolytic degradation of additively manufactured PLA: Characterization and artificial neural network modeling

Understanding the long-term durability of 3D-printed polymeric materials under varying temperature and humidity conditions is essential for expanding their industrial applications. Therefore, it is critical to assess the impact of degradation on mechanical properties such as tensile strength. In this study, we manufactured specimens with dual orientations by additive manufacturing-based 3D printing and subjected them to accelerated degradation under various temperature and humidity conditions to evaluate their durability in degradation environments. Mechanical properties significantly decreased under the most severe conditions, with a maximum reduction of 76.7 % observed in molecular weight. The deconvolution of the molecular weight distribution and its correlation with mechanical properties were thoroughly investigated. We derived an equation representing the relationship between the peaks obtained from deconvoluting the molecular weight distribution and the tensile strength. Furthermore, to expedite and simplify tensile strength assessment, we trained an artificial neural network (ANN) model using tensile test results to construct a predictive model. The ANN utilized temperature, humidity, printing angle, and time as input data, with tensile strength as the output. Validation of this model demonstrated the capability to predict tensile strength accurately under different temperature and humidity conditions.

Upcycling polyethylene into closed-loop recyclable polymers through titanosilicate catalyzed C-H oxidation and in-chain heteroatom insertion

Polyolefins are the most widely produced type of plastics owing to their low production cost and favorable properties. Their polymer backbone consists solely of inert C-C bonds, making them resistant and durable materials. Although this is an extremely useful attribute during their use phase, it complicates chemical recycling. In this work, different types of polyethylenes (PEs) are converted into ketone-functionalized PEs with up to 3.4% functionalized carbon atoms, in mild conditions (≤100 °C), using a titanosilicate catalyst and tert-butyl hydroperoxide as the oxidant. Subsequently, the introduced ketones are exploited as sites for heteroatom insertion. Through Baeyer-Villiger oxidation, in-chain esters are produced with yields up to 73%. Alternatively, the ketones can be converted into the corresponding oxime, which can undergo a Beckmann rearrangement to obtain in-chain amides, with yields up to 75%. These transformations allow access to polymers that are amenable to solvolysis, thereby enhancing their potential for chemical recycling.

Durability of a Metakaolin-Incorporated Cement-Based Grouting Material in High Geothermal Tunnels.

To improve the durability of cement-based grout in high geothermal tunnel grouting projects, metakaolin was incorporated to replace 8% of the cement. The permeability, chloride penetration, and sulfate and carbonate erosion tests were carried out on the grout cured at varying temperatures (20, 30, 40, 50, and 60 °C). It was shown that with the increase in curing temperature, the impermeability and resistance to chloride penetration initially increased and then decreased, reaching the highest values at 40 °C. Furthermore, the incorporation of metakaolin into grout enhanced the impermeability by 11.11-38.91% and resistance to chloride penetration by 12.23-12.77%. As attacked by sulfate, the surface spalling of the specimen was more obvious with the increase in the curing temperature and immersion time. Conversely, the appearance remained almost unchanged under carbonate erosion. As immersion time increased, both the antisulfate and anticarbonate erosion coefficients declined. The effect of curing temperature on erosion resistance was assessed via the relative antierosion coefficient. When immersed in sulfate, the coefficient achieved the highest value of 1.08 as cured at 30 °C, and in carbonate, the coefficient reached a maximum of 0.99 as cured at 40 °C. Through scanning electron microscopy and binarized images, it was verified that gypsum and ettringite were formed during sulfate attack, leading to volume expansion and cracking, consequently reducing the strength. Meanwhile, in the case of carbonate erosion, calcium hydroxide (CH) and calcium silicate hydrate gel (C-S-H) were dissolved and degraded, resulting in a large number and size of pores in the grout. The research results have certain theoretical significances and reference values for the application of cement-based grouting materials in high geothermal environments.

Insight into performance and lifetime of ecofriendly pollution barriers in landfill for emergency: A thermogravimetric analysis for novel polymer materials

The novel polymer barrier wall is an in-situ remediation technology designed to effectively control the migration of pollution and prevent the diffusion of pollutants by blocking, sealing, or altering the direction of groundwater flow. With its advantages of rapid chemical reaction (achieving 95 % strength within 15 min) and portable equipment suitable for narrow and rugged emergency sites, this innovative polymer barrier demonstrates promising prospects for practical application. Hence, ensuring the long-term durability of new materials under corrosive and high-temperature leachate conditions is crucial. In this study, a comprehensive investigation was conducted on the corrosion and thermal aging performance of novel polymer materials. Firstly, the mechanical tensile properties of the polymer materials were examined after immersion in leachates, aiming to elucidate the degradation mechanism underlying these properties. Subsequently, thermogravimetric (TG) analysis was performed on the polymer materials immersed in various leachates. And the thermal stability and oxidation stability of novel materials were investigated using a thermogravimetric analyzer coupled with a Fourier transform infrared spectrometer (TG-FTIR). Based on the results obtained from thermal analysis, the service life of polymer materials under different pollutants was ultimately predicted utilizing the Arrhenius model. The findings indicate that the novel polymer materials exhibit commendable durability and pose little risk of causing secondary pollution.

Fabrication and Tribology Properties of PTFE-Coated Cemented Carbide Under Dry Friction Conditions

PTFE coatings were deposited on YT15 carbide substrates using spray technology. A series of examinations were conducted, including the use of surface and cross-section micrographs to analyze the structural integrity of the coatings. The surface roughness, the adhesion force between the PTFE coatings and the carbide substrate, and the micro-hardness of the coated carbide were also evaluated. Additionally, the friction and wear behaviors were assessed through dry sliding friction tests against WC/Co balls. The test results indicated that while the PTFE-coated carbide exhibited a rougher surface and reduced micro-hardness, it also demonstrated a significant reduction in surface friction and adhesive wear. These findings suggest that the PTFE coatings enhance the overall wear resistance of the carbides. The lower surface hardness and shear strength of the coatings influenced the friction performance, leading to specific wear failure mechanisms, such as abrasion wear, coating delamination, and flaking. Overall, the deposition of PTFE coatings on carbide substrates presents a promising strategy to enhance their friction and wear performance. This approach not only improves the durability of carbide materials but also offers potential applications in industries where reduced friction and wear are critical for performance.

Carbon dioxide capture from open air using covalent organic frameworks.

Capture of CO2 from the air offers a promising approach to addressing climate change and achieving carbon neutrality goals1,2. However, the development of a durable material with high capacity, fast kinetics and low regeneration temperature for CO2 capture, especially from the intricate and dynamic atmosphere, is still lacking. Here a porous, crystalline covalent organic framework (COF) with olefin linkages has been synthesized, structurally characterized and post-synthetically modified by the covalent attachment of amine initiators for producing polyamines within the pores. This COF (termed COF-999) can capture CO2 from open air. COF-999 has a capacity of 0.96 mmol g-1 under dry conditions and 2.05 mmol g-1 under 50% relative humidity, both from 400 ppm CO2. This COF was tested for more than 100 adsorption-desorption cycles in the open air of Berkeley, California, and found to fully retain its performance. COF-999 is an exceptional material for the capture of CO2 from open air as evidenced by its cycling stability, facile uptake of CO2 (reaches half capacity in 18.8 min) and low regeneration temperature (60 °C).

Lattice Distortion Creates Enhancements in Photocatalytic and Electrocapacitive Performance of Sol–Gel‐Derived Cu‐Doped NiTiO3

A remarkable 35% enhancement in the photocatalytic and electrocatalytic abilities of an ilmenite nickel titanate (NiTiO3) material is reported. This boost in catalytic performance is achieved by simply creating a static distortion in the rhombohedral unit cell by replacing a small proportion of a small‐size nondegenerate Ni (69 pm) with a large‐size degenerate Cu (73 pm). The materials are synthesized by using a simple sol–gel method. The appropriate doping amount of Cu facilitates the better separation of intrinsic charge carrier pairs by inhibiting their recombination. The photocatalytic and electrochemical activities of durable materials in aqueous MB dye (10 ppm) and KOH (1 molar) electrolyte solutions are found to be directly associated with this improvement in inherent charge carrier transfer characteristics. The enhanced photodissociation of MB dye (42–56%) and specific capacitance (381–450 F g−1) in a KOH (1 molar) electrolyte are in full accord with the investigations carried out using crystallographic and optoelectronic analysis, charging–discharging measurements, and electrochemical impedance (EIS) spectroscopy investigations. Same material with high textural surface areas or controllable particle morphologies might show a far better photo/electrocatalytic performance in a variety of practical applications.

Assessing pavement characteristics: An in-depth evaluation of waste engine oil and Buton rock asphalt composite modified asphalt and its mixture

To investigate the cooperative influence of waste engine oil (WEO) and Buton rock asphalt (BRA) on asphalt characteristics, the WEO/BRA composite modified asphalt and its mixture with varied dosages were prepared. The high-, moderate-, and low-temperature assessments of WEO/BRA composite modified asphalt were conducted through temperature sweep tests, multiple stress creep and recovery (MSCR), and bending beam rheometer (BBR) tests. The softening point difference was used to analyze the storage stability of composite modified asphalt. Based on the Fourier transform infrared spectroscopy (FTIR) and fluorescence microscope (FM) test, the microscopic feature and chemical constitution of WEO/BRA composite modified asphalt were analyzed. Rutting test, low-temperature bending test, immersed Marshall test, freeze-thaw splitting test, and four-point fatigue bending test were carried out to verify the pavement properties of the WEO/BRA composite modified asphalt mixture. The results indicated that WEO improved the capability in low-temperature conditions and fatigue properties of asphalt modified with BRA. BRA enhanced the high-temperature property of asphalt modified with WEO. The synergistic effect of WEO, BRA, and neat asphalt was a physical reaction, and these modifiers were uniformly distributed in the asphalt. Meanwhile, WEO/BRA composite modified asphalt had excellent storage stability for the single modified asphalt. The test results of the asphalt mixture verified the results, indicating that WEO/BRA composite modified asphalt can be considered a new green and durable asphalt pavement material.

Marine durability of carbon black-filled polychloroprene: Effect of seawater ageing on network, tensile and fatigue properties

With the development of marine renewable energies, the durability of materials at sea is more than ever a major issue in reducing the risk of failure of offshore devices. In this aggressive environment, elastomers, and in particular polychloroprene (CR), have many applications because of their good damping and fatigue properties. However, these materials are subject to ageing in service, which leads to changes in their mechanical properties. The ageing of these materials in a marine environment has not been extensively studied, despite the need to predict components lifetimes. This paper investigates the mechanical and microstructural consequences of a carbon black-filled CR degradation when exposed to seawater. To this end, swelling, uniaxial tensile and fatigue tests are carried out on materials previously subjected to accelerated ageing in natural seawater. Particular attention is paid to understanding the physico-chemical phenomena involved, and analysing fracture and fatigue properties in relation to those of the macromolecular network.

Electrodeposition of Ni-WC composite coatings: formation, structure and properties

Currently, electroplating is actively developing, and one of its promising areas is the study of composite electrochemical coatings (CEC). They are of great interest to the industrial sector, especially for mechanical engineering, due to their unique properties. CEC contain microscopic particles as additives that can significantly improve coating properties such as hardness and wear resistance. This is especially important for the manufacturing of high-quality parts of industrial mechanisms. These areas can lead to new advances in the development of better and more durable materials. In this work, composite coatings of nickel-tungsten carbide were obtained by the method of electrodeposition. The deposition was carried out in a sulfuric acid electrolyte with different concentrations of tungsten carbide. Formation of composite coatings was carried out at a concentration of dispersed particles in a sulfate electrolyte of 10 g/L. The coatings have no pores or cracks. Nickel and tungsten carbide phases were detected in the coatings by X-ray phase and micro-X-ray spectral analyses. Inclusions of WC in the nickel matrix lead to an increase in the microhardness of the coating by 10–15 times. Wear resistance was assessed under dry sliding friction with reciprocating motion; a decrease in the volume of worn material by 2–3 times was noted when tungsten carbide was added into the nickel matrix.

ITZ properties of LWA surroundings in high strength mortar according to LWA/sand with relative humidity

The internal moisture content significantly influences the quality and durability of cement-based composite materials. However, reliable methods to analyze the moisture retention of concrete and mortar are lacking, particularly in relation to internal curing with lightweight aggregates (LWA). In this study, the internal moisture retention of mortar with different lightweight aggregate/sand (L/S) ratios was investigated while considering the absorption characteristics of LWA. Furthermore, the impact of internal moisture retention on the development of the interface transition zone (ITZ) between the LWA and cement matrix was analyzed. Additionally, compressive strength development was evaluated over different curing periods (3, 7, 28, 56, and 90 days) under internal curing conditions. The results showed that the L/S ratio, which is directly proportional to the amount of moisture absorbed, enhanced the compressive strength and plastic hardness, contributing to the development of depletion of internal moisture in the mortar was could be observed. The moisture consumption for different types of LWA was analyzed using CT scanning. XRD and SEM-EDS analyses confirmed the abundant presence of hydration products in the ITZ. This study demonstrates that the L/S ratio that considers the LWA absorption characteristics, can serve as a critical parameter for precisely correlating the curing time and compressive strength in internally cured mortars.

Electrochemical kinetic energy harvesting mediated by ion solvation switching in two-immiscible liquid electrolyte

Kinetic energy harvesting has significant potential, but current methods, such as friction and deformation-based systems, require high-frequency inputs and highly durable materials. We report an electrochemical system using a two-phase immiscible liquid electrolyte and Prussian blue analogue electrodes for harvesting low-frequency kinetic energy. This system converts translational kinetic energy from the displacement of electrodes between electrolyte phases into electrical energy, achieving a peak power of 6.4 ± 0.08 μW cm−2, with a peak voltage of 96 mV and peak current density of 183 μA cm−2 using a 300 Ω load. This load is several thousand times smaller than those typically employed in conventional methods. The charge density reaches 2.73 mC cm−2, while the energy density is 116 μJ cm−2 during a harvesting cycle. Also, the system provides a continuous current flow of approximately 5 μA cm−2 at 0.005 Hz for 23 cycles without performance decay. The driving force behind voltage generation is the difference in solvation Gibbs free energy between the two electrolyte phases. Additionally, we demonstrate the system’s functionality in a microfluidic harvester, generating a maximum power density of 200 nW cm−2 by converting the kinetic energy to propel the electrolyte through the microfluidic channel into electricity.