Insight into performance and lifetime of ecofriendly pollution barriers in landfill for emergency: A thermogravimetric analysis for novel polymer materials

Abstract

The novel polymer barrier wall is an in-situ remediation technology designed to effectively control the migration of pollution and prevent the diffusion of pollutants by blocking, sealing, or altering the direction of groundwater flow. With its advantages of rapid chemical reaction (achieving 95 % strength within 15 min) and portable equipment suitable for narrow and rugged emergency sites, this innovative polymer barrier demonstrates promising prospects for practical application. Hence, ensuring the long-term durability of new materials under corrosive and high-temperature leachate conditions is crucial. In this study, a comprehensive investigation was conducted on the corrosion and thermal aging performance of novel polymer materials. Firstly, the mechanical tensile properties of the polymer materials were examined after immersion in leachates, aiming to elucidate the degradation mechanism underlying these properties. Subsequently, thermogravimetric (TG) analysis was performed on the polymer materials immersed in various leachates. And the thermal stability and oxidation stability of novel materials were investigated using a thermogravimetric analyzer coupled with a Fourier transform infrared spectrometer (TG-FTIR). Based on the results obtained from thermal analysis, the service life of polymer materials under different pollutants was ultimately predicted utilizing the Arrhenius model. The findings indicate that the novel polymer materials exhibit commendable durability and pose little risk of causing secondary pollution.