We report on the dc characteristics of an InGaP/ GaAs <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">0.57</sub> P <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">0.28</sub> Sb <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">0.15</sub> /GaAs double heterojunction bipolar transistor (DHBT). In comparison with control InGaP/GaAs single heterojunction bipolar transistors (SHBTs), the DHBT shows a lower turn-on voltage (V <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">BE, on</sub> ) by ~ 70 mV, a lower knee voltage up to J <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">c</sub> ~ 40 kA/cm <sup xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</sup> , and less temperature-sensitive current gain. The validity of reciprocity in the Gummel plot suggests no potential spikes at the emitter/base and base/collector (BC) junctions of the DHBT. By considering the differences, in terms of the built-in voltage of the BC junction, the Fermi level in the base, and the renormalized energy gap of the base, between the GaAsPSb DHBT and the control InGaP/GaAs SHBT, we conclude that the heavily p-doped GaAs <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">0.57</sub> P <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">0.28</sub> Sb <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">0.15</sub> base and the lightly n-doped GaAs collector are in weakly type-II band alignment with a conduction and valence band offset of 44 and 221 meV, respectively. These findings indicate that GaAsPSb is a promising base material for DHBTs operating at high temperature and low V <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">BE, on</sub> conditions without suffering from the collector current blocking.