Magnetic Sector Research Articles

Influence of Emotional Marketing and Sharia Marketing on Consumer Decisions in Purchasing Waqf Policy Insurance Products (Case Study at PT Asuransi Syariah Keluarga Indonesia)

Abstract. The development of sharia economics and finance has experienced significant developments in recent years. This is marked by several main developments in the financial sector and sharia financial instruments, which are increasingly varied and diversifying to meet the diverse needs of the public or customers. One of the sharia financial institutions that is experiencing development is sharia insurance. The sharia insurance industry has become an integral part of modern society's lives. In the midst of the various choices of sharia insurance products, innovation in sharia insurance products combined with waqf instruments is one of the good things for the expansion of sharia financial instruments. Companies marketing waqf insurance policies face increasingly complex challenges to understand, reach, and win the hearts of consumers. The decision to purchase a waqf policy insurance product no longer only revolves around financial considerations but also includes emotional dimensions and deep religious values. This research aims to determine the influence of emotional marketing and sharia marketing on consumer decisions in purchasing policy waqf insurance products using the method used by researchers, namely associative research with a quantitative approach. This research used a sample of 40 respondents with 19 questionnaire statements. In this study, the model used uses a linear regression model involving more than one independent variable or predictor (multiple linear regression). This research shows that, partially or simultaneously, the emotional marketing and sharia marketing variables are stated to have a significant influence on consumer decisions in purchasing waqf insurance policies. This is obtained from the coefficient of determination value in the very strong category, which is between 0.80 and 1,000, with an adjusted R square result of 0.818, or around 81.8%, influencing consumer decisions and the remaining 18.2% being influenced by other variables outside of this research.
 Keywords: Emotional Marketing, Sharia Marketing, Consumer Decisions, Waqf Insurance Policies.

Enhancing single-cell encapsulation in droplet microfluidics with fine-tunable on-chip sample enrichment

Single-cell encapsulation in droplet microfluidics is commonly hindered by the tradeoff between cell suspension density and on-chip focusing performance. In this study, we introduce a novel droplet microfluidic chip to overcome this challenge. The chip comprises a double spiral focusing unit, a flow resistance-based sample enrichment module with fine-tunable outlets, and a crossflow droplet generation unit. Utilizing a low-density cell/bead suspension (2 × 106 objects/mL), cells/beads are focused into a near-equidistant linear arrangement within the double spiral microchannel. The excess water phase is diverted while cells/beads remain focused and sequentially encapsulated in individual droplets. Focusing performance was assessed through numerical simulations and experiments at three flow rates (40, 60, 80 μL/min), demonstrating successful focusing at 40 and 80 μL/min for beads and cells, respectively. In addition, both simulation and experimental results revealed that the flow resistance at the sample enrichment module is adjustable by punching different outlets, allowing over 50% of the aqueous phase to be removed. YOLOv8n-based droplet detection algorithms realized the counting of cells/beads in droplets, statistically demonstrating single-cell and bead encapsulation rates of 72.2% and 79.2%, respectively. All the results indicate that this on-chip sample enrichment approach can be further developed and employed as a critical component in single-cell encapsulation in water-in-oil droplets.

Advancing scalable and controllable multi-core droplet generation with double disturbance flow focusing.

At present, a variety of active and passive methods for generating microdroplets with different morphologies are available. Microcapsules with multi-core or compartment structures not only exhibit characteristics such as encapsulation, isolation, and leak prevention, but also possess specific functions, including enhanced buffering performance and superior heat transfer characteristics. Nevertheless, the high-throughput manufacturing of controllable multi-core droplets remains a significant challenge, constrained by the complexity of the equipment, the inconvenience of control, and the high cost. This study introduces a novel flow focusing method that integrates biphasic excitation to produce uniformly distributed double-emulsion droplets with a controlled number of cores at high throughput. The breakup of coaxial jets has been studied under different excitation frequencies, amplitudes, and flow rates of inner and outer liquids, with a particular focus on the change of the droplet morphology as the controllable parameter varies. By applying excitation to both the inner and outer jets in the weak coupling mode, our technique exhibits promising outcomes in achieving uniformity and controllability in the number of cores of the generated droplets. The scaling laws of the compound droplet size have been obtained, providing theoretical guidance for practical applications. The proposed biphasic excitation approach enhances the precision and efficiency of droplet generation processes in a range of applications, including pharmaceuticals, biotechnology, and materials science.

A Comparative Assessment of the Distribution of Joule Heating in Altitude as Estimated in TIE‐GCM and EISCAT Over One Solar Cycle

AbstractDuring geomagnetically active times, Joule (or frictional) heating in the Lower Thermosphere‐Ionosphere is a significant source of thermal energy, greatly affecting density, temperature, composition and circulation. At the same time, Joule heating and the associated Pedersen conductivity are amongst the least known parameters in the upper atmosphere in terms of their quantification and spatial distribution, and their parameterization by geomagnetic parameters shows large discrepancies between estimation methodologies, primarily due to a lack of comprehensive measurements in the region where they maximize. In this work we perform a long‐term statistical comparison of Joule heating as calculated by the NCAR Thermosphere‐Ionosphere‐Electrodynamics General Circulation Model (TIE‐GCM) and as obtained through radar measurements by the European Incoherent Scatter Scientific Association (EISCAT). Statistical estimates of Joule heating and Pedersen conductivity are obtained from a simulation run over the 11 year period spanning from 2009 until 2019 and from radar measurements over the same period, during times of radar measurements. The results are statistically compared in different Magnetic Local Time sectors and Kp level ranges in terms of median values and percentiles of altitude profiles. It is found that Joule heating and Pedersen conductivity are higher on average in TIE‐GCM than in EISCAT for low Kp and are lower than EISCAT for high Kp. It is also found that neutral winds cannot account for the discrepancies between TIE‐GCM and EISCAT. Comparisons point toward the need for a Kp‐dependent parameterization of Joule heating in TIE‐GCM to account for the contribution of small scale effects.

A Numerical Investigation on the Formation of the Stalling of the Cross‐Polar Jet in Midnight Thermospheric Winds

AbstractThermospheric winds usually flow from noon to the midnight inside the polar cap and spill further equatorward around midnight, due to the combined effects of solar radiation‐driven pressure gradient and ion drag. Recent observations from the Scanning Doppler Imager at Poker Flat indicated a distinct feature that the cross‐polar jet stalls over short horizontal distances around the magnetic midnight. However, the mechanisms responsible for the occurrence of stalling have not been well understood. In this study, we investigated the physical mechanisms of the stalling of the cross‐polar jet based on the Thermosphere Ionosphere Electrodynamics General Circulation Model simulations. The model reproduced the general stalling features at midnight over a short horizontal distance. The occurrence of stalling is mainly associated with Joule heating, which enhances the neutral temperature and then turns winds poleward by the pressure gradient force, and ion‐neutral coupling, which drags neutral winds westward in the pre magnetic local time midnight sector and contributes to the poleward turning of the meridional winds by the poleward Coriolis force. Meanwhile, the stalling region has a large latitudinal range and depends on the interplanetary magnetic field (IMF). Under southward IMF Bz, thermospheric winds are likely to stall at lower latitudes associated with strong ionospheric convection. The stalling of the cross‐polar jet in the midnight thermospheric winds has UT/longitude dependence, which could be associated with the orientation of the alignment of geomagnetic and geographic poles with respect to ionospheric convection.

Constructing Carrollian field theories from null reduction

In this paper, we propose a novel way to construct off-shell actions of d-dimensional Carrollian field theories by considering the null-reduction of the Bargmann invariant actions in d +1 dimensions. This is based on the fact that d-dimensional Carrollian symmetry is the restriction of the (d + 1)-dimensional Bargmann symmetry to a null hypersurface. We focus on free scalar field theory and electromagnetic field theory, and show that the electric sectors and the magnetic sectors of these theories originate from different Bargmann invariant actions in one higher dimension. In the cases of massless free scalar field and d = 4 electromagnetic field, we verify the Carrollian conformal invariance of the resulting theories, and find that there appear naturally chain representations and staggered modules of Carrollian conformal algebra.

Relativistic particle measurement in jupiter’s magnetosphere with Pix.PAN

Pix.PAN is a compact cylindrical magnetic spectrometer, intended to provide excellent high energy particle measurements under high rate and hostile operating conditions in space. Its principal design is composed of two Halbach-array magnetic sectors and six Timepix4-based tracking layers; the latest hybrid silicon pixel detector readout ASIC designed. Due to Pix.PAN’s compact and relatively simple design, it has the potential to be used for space missions exploring with measurements of unprecedented precision, high energy particles in radiation belts and the heliophere (solar energetic particles, anomalous and galactic cosmic rays). In this white paper, we discuss the design and expected performance of Pix.PAN for COMPASS (Comprehensive Observations of Magnetospheric Particle Acceleration, Sources, and Sinks), a mission concept submitted to NASA’s Call “B.16 Heliophysics Mission Concept Studies (HMCS)” in 2021 that targets the extreme high energy particle environment of Jupiter’s inner radiation belts. We also discuss PixPAN’s operational conditions and interface requirements. The conceptual design shows that is possible to achieve an energy resolution of<12% for electrons in the range of 10 MeV-1 GeV and<35% for protons between ∼\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$\\sim $$\\end{document}200 MeV to a few GeV. Due to the timestamp precision of Timepix4, a time resolution (on an instrument level) of about 100 ps can be achieved for time-of-flight measurements. In the most intense radiation environments of the COMPASS mission, Pix.PAN is expected to have a maximum hit rate of 44MHzcm2\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$\\frac{\ ext {MHz}}{\ ext {cm}^2}$$\\end{document} which is below the design limit of 360MHzcm2\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$\\frac{\ ext {MHz}}{\ ext {cm}^2}$$\\end{document} of Timepix4. Finally, a sensor design is proposed which allows the instrument to operate with a power budget of 20W without the loss of scientific performance.

Foreign Aid’s Effect on Political Risks for Foreign Direct Investment: A Literature Review

The last decade has seen an increasing focus on the involvement of the private sector in international sustainable development, particularly in high-risk jurisdictions. This involvement encompasses a broad spectrum, incorporating innovative private sector instruments—now acknowledged as ODA-eligible by the OECD—as well as traditional tools of external official support to developing countries, which remain the primary contributors to ODA flows. This literature review aims to consolidate the academic exploration of the enduring classic foreign aid tools' impact on the political risks associated with foreign direct investment (FDI), and identifies prevalent limitations while suggesting approaches to overcome these challenges.The first section delineates the central theme and rationale behind the literature selection process, utilizing the Google Scholar database to contextualize the research within a comprehensive framework. The subsequent section categorizes and compares the most relevant studies based on formal criteria and methodological parameters. Sections three and four critically assess the scholarly contributions in conceptualizing the mitigating influence of foreign aid in general, focusing on its impact on specific political risks such as expropriation, terrorism, and corruption. The concluding section delves into studies that explore foreign aid and foreign direct investment flows from China, the largest non-Western donor.A bibliometric analysis reveals a noteworthy disparity between research attention and policymaking focus on the subject matter. Notably, the selected papers fail to comprehensively cover the full spectrum of primary extra-legal and legal-governmental political risks for transnational businesses. Scholars' assessments of foreign aid's mitigating effect often lack differentiation between grants and loans or between flows directed to different sectors, as well as the distinction between aid routed through public institutions and bypassing them. Notably absent is a comprehensive analysis encompassing the complete range of 'established' Western and emerging non-Western aid providers, or an exploration of aid flows from non-OECD countries other than China. Most research focuses on Africa and fails to differentiate between recipients based on fragility, income levels, or other relevant categorizations. Moreover, the researchers have yet to delve into data post the COVID-19 outbreak, a critical period that significantly altered perceptions of political risk, foreign aid, and FDI flows. The literature review illuminates a research gap awaiting substantial exploration.

Abnormal Sub‐Auroral Ion Drifts (ASAID) Developed in the Postmidnight (1–4) Magnetic Local Time Sector in 2013

AbstractWe investigate the Abnormal Sub‐Auroral Ion Drifts (ASAID) developed in the postmidnight (1–4) magnetic local time sector in 2013. Shown by the Defense Meteorological Satellite Program F15 horizontal ion velocity measurements, we specified 21 antisunward (eastward) ASAID flow channels (FCs) based on their respective underlying polar convections. Overall, the polar convection formed a two‐cell pattern with its convection axis tilted in the morning‐evening direction because of the underlying BY &lt; 0 conditions. Its dawn cell intruded into the duskside from the dawnside where the eastward ASAID flows were streaming antisunward, opposite to the dawn cell sunward convection flows. Mostly, the ASAID FC appeared in the coinciding ring‐current–related ionospheric trough and flow‐stagnation–related main ionospheric trough in the South American sector because of the favorable conditions created by the South Atlantic Magnetic Anomaly promoting also the development of Stable Auroral Red (SAR) arc. Rarely observed, the ASAID FC was associated with the SAR arc detected over Rothera. Detected in the Mid Pacific longitude sector, a pair of northern‐southern ASAID FCs demonstrated northern‐southern conjugacy. With correlated observations, demonstrating magnetosphere‐ionosphere conjugacy, the inward (earthward) ASAID electric (E) field could also be investigated. These reveal the ASAID E field's fast‐time development by short‐circuiting when the hot‐ring‐current—cold‐plasmasphere interface developed and became impacted by finite Larmor radius effects because of the earthward intrusion of hot ring current protons. The ASAID E field's inner‐magnetosphere environment was characterized by the hot zone where heating was generated by low‐frequency waves and auroral kilometric radiations.

Antisunward Streaming Westward Sub‐Auroral Ion Drifts (SAID) Developed in the Postmidnight (1–4) Magnetic Local Time Sector During 2013

AbstractIn this study, we have surveyed the Defense Meteorological Satellite Program F15 plots of horizontal ion velocity measurements for the calendar year of 2013 and specified 15 antisunward (westward) sub‐auroral ion drifts (SAID) detections taken in the 1–4 magnetic local time (MLT) sector based on their respective underlying polar convections. We find that during these 15 SAID events, the strong duskside westward polar plasma convection extended across the midnight meridian into the postmidnight 1–4 MLT sector making there the westward SAID flows streaming antisunward. These antisunward (westward) SAID flows were observed only once as a northern‐southern conjugate pair over the Mid Pacific and repeatedly in the South American longitude sector's wider region. We could correlate six antisunward (westward) SAID flows with their respective nearby outward SAID E fields observed by one of the Van Allen Probe (VAP) satellites in the inner magnetosphere. These provided two strong correlations depicting inner‐magnetosphere—topside‐ionosphere conjugate observations and four weak correlations. The VAP observations illustrate (a) the newly‐formed outward SAID E field and (b) its plasma environment still showing (c) the signatures of short‐circuiting across (d) the newly‐formed plasmapause appearing with (e) the hot zone on the earthward/tailward side and sometimes with (f) a localized heat source. Implying different underlying heating mechanisms, the hot zone and the heat source were associated with energetic plasma particles accelerated by plasma turbulence, low‐frequency waves including electromagnetic ion cyclotron waves, and/or auroral kilometric radiation bursts.

Influence of Alfvén Ion–Cyclotron Waves on the Anisotropy of Solar Wind Turbulence at Ion Kinetic Scales

The power spectra of the magnetic field at ion kinetic scales have been found to be significantly influenced by Alfvén ion–cyclotron (AIC) waves. Here, we study whether and how this influence of the AIC wave depends on the θVB angle (the angle between the local mean magnetic field and the solar wind velocity direction). The wavelet technique is applied to the high time-resolution (11 vectors per second) magnetic field data from WIND spacecraft measurements in a fast solar wind stream associated with an outward magnetic sector. It is found that around the ion kinetic scales (0.52 Hz–1.21 Hz), the power spectrum in the parallel angular bin 0∘&lt;θVB&lt;10∘ has a slope of −4.80±0.15. When we remove the left-handed polarized AIC waves (with normalized reduced magnetic helicity smaller than −0.9) from the fluctuations, the spectral index becomes −4.09±0.11. However, the power spectrum in the perpendicular angular bin 80∘&lt;θVB&lt;90∘ changes very little during the wave-removal process, and its slope remains −3.22±0.07. These results indicate that the influence of the AIC waves on the magnetic spectral index at the ion kinetic scales is indeed dependent on θVB, which is due to the anisotropic distribution of the waves. Apparently, when the waves are removed from the original data, the spectral anisotropy weakens. This result may help us to better understand the physical nature of the spectral anisotropy around the ion scales.

Noninvertible anomalies in SU(N) × U(1) gauge theories

We study 4-dimensional SU(N) × U(1) gauge theories with a single massless Dirac fermion in the 2-index symmetric/antisymmetric representations and show that they are endowed with a noninvertible 0-form {overset{sim }{mathbb{Z}}}_{2left(Npm 2right)}^{upchi} chiral symmetry along with a 1-form {mathbb{Z}}_N^{(1)} center symmetry. By using the Hamiltonian formalism and putting the theory on a spatial three-torus mathbbm{T} 3, we construct the non-unitary gauge invariant operator corresponding to {overset{sim }{mathbb{Z}}}_{2left(Npm 2right)}^{upchi} and find that it acts nontrivially in sectors of the Hilbert space characterized by selected magnetic fluxes. When we subject mathbbm{T} 3 to {mathbb{Z}}_N^{(1)} twists, for N even, in selected magnetic flux sectors, the algebra of {overset{sim }{mathbb{Z}}}_{2left(Npm 2right)}^{upchi} and {mathbb{Z}}_N^{(1)} fails to commute by a ℤ2 phase. We interpret this noncommutativity as a mixed anomaly between the noninvertible and the 1-form symmetries. The anomaly implies that all states in the torus Hilbert space with the selected magnetic fluxes exhibit a two-fold degeneracy for arbitrary mathbbm{T} 3 size. The degenerate states are labeled by discrete electric fluxes and are characterized by nonzero expectation values of condensates. In an appendix, we also discuss how to construct the corresponding noninvertible defect via the “half-space gauging” of a discrete one-form magnetic symmetry.

Design and performance evaluation of novel magnetic tristable wave energy converter

To realize efficient broadband wave-energy conversion, this study proposes a point-absorber wave energy converter with a novel magnetic tristable mechanism (NMT-PAWEC). The tristable mechanism consists of coaxial inner and outer magnetic rings. The outer magnetic ring features two types of sector magnets with opposite poles. The motion control equations of the NMT-PAWEC are established using the Cummins equation and the equivalent magnetic charge method. The preferred parameter region of the novel tristable mechanism was investigated, and the energy-conversion performance of the NMT-PAWEC under regular waves was analyzed. The results show that the NMT-PAWEC with shallower potential wells can easily achieve inter-well oscillation under low-amplitude waves, with higher energy harvesting efficiency, and a wider frequency and work-damping band. Through a nonlinear bifurcation dynamics analysis, the causes of fluctuations and sudden changes in the output power under low-amplitude waves were revealed. Furthermore, the capture width ratio and annual average power of the South China Sea were considered. The influence of optimized PTO parameters on the energy-conversion performance of the NMT-PAWEC in regular and irregular waves was further discussed. In general, the efficient broadband power output capabilities demonstrate the excellent applicability of NMT-PAWEC.

Dynamic Assembly of Strong and Conductive Carbon Nanotube/Nanocellulose Composite Filaments and Their Application in Resistive Liquid Sensing.

The continuous flow assembly of colloidal nanoparticles from aqueous suspensions into macroscopic materials in a field-assisted double flow focusing system offers an attractive way to bridge the outstanding nanoscale characteristics of renewable cellulose nanofibrils (CNFs) at scales most common to human technologies. By incorporating single-walled carbon nanotubes (SWNTs) during the fabrication process, high-performance functional filament nanocomposites were produced. CNFs and SWNTs were first dispersed in water without any external surfactants or binding agents, and the resulting nanocolloids were aligned by means of an alternating electric field combined with extensional sheath flows. The nanoscale orientational anisotropy was then locked by a liquid-gel transition during the materials assembly into macroscopic filaments, which greatly improved their mechanical, electrical, and liquid sensing properties. Significantly, these findings pave the way toward the environmentally friendly and scalable manufacturing of a variety of multifunctional fibers for diverse applications.

Extraction of Silicon-Containing Nanoparticles from an Agricultural Soil for Analysis by Single Particle Sector Field and Time-of-Flight Inductively Coupled Plasma Mass Spectrometry.

The increased use of silica and silicon-containing nanoparticles (Si-NP) in agricultural applications has stimulated interest in determining their potential migration in the environment and their uptake by living organisms. Understanding the fate and behavior of Si-NPs will require their accurate analysis and characterization in very complex environmental matrices. In this study, we investigated Si-NP analysis in soil using single-particle ICP-MS. A magnetic sector instrument was operated at medium resolution to overcome the impact of polyatomic interferences (e.g., 14N14N and 12C16O) on 28Si determinations. Consequently, a size detection limit of 29 ± 3 nm (diameter of spherical SiO2 NP) was achieved in Milli-Q water. Si-NP were extracted from agricultural soil using several extractants, including Ca(NO3)2, Mg(NO3)2, BaCl2, NaNO3, Na4P2O7, fulvic acid (FA) and Na2H2EDTA. The best extraction efficiency was found for Na4P2O7, for which the size distribution of Si-NP in the leachates was well preserved for at least one month. On the other hand, Ca(NO3)2, Mg(NO3)2 and BaCl2 were relatively less effective and generally led to particle agglomeration. A time-of-flight ICP-MS was also used to examine the nature of the extracted Si-NP on a single-particle basis. Aluminosilicates accounted for the greatest number of extracted NP (~46%), followed by NP where Si was the only detected metal (presumably SiO2, ~30%).

A novel ground-potential monochromator design

An electron monochromator design is presented as an instrumental development for electron energy loss spectroscopy (EELS) and imaging in (scanning) transmission electron microscopy ((S)TEM). The main purpose of this development is enhancing the energy resolving power in spectroscopy and filtering. In addition, it helps reducing the effect of the objective lens’ chromatic aberration Cc in imaging and therefore, enhancing the spatial resolving power of electron microscopes. General estimates for the performance of a monochromator in energy distribution and the resulting usable beam currents are given. The special monochromator design presented is a ground-potential monochromator based on magnetic sector fields. The monochromator generates a spatially and angular un-dispersed spot and has no mechanically actuated parts in the filter sections. The optics can be operated at electron acceleration voltages from 30kV to 300kV and shows an energy resolving power of better than 2⋅10−7 relative to the primary electron energy. The actual device is designed to be retro-fittable to microscopes from various manufacturers.

Development of a field-deployable analytical workflow for determining current status and indicative human health risks at a historic dl-POPs hotspot

This paper introduces an integrated workflow that effectively evaluates environmental and health risks of dioxin-like Persistent Organic Pollutants (dl-POPs) at industrial hotspot regions. The developments of validated, cost effective and user-friendly analytical strategies which can be field deployable are quintessential for routine monitoring of dl-POPs, particularly in developing countries. This study addresses the lacunae by enabling an exclusive gas chromatography triple quadrupole mass spectrometer based analytical workflow substituting conventional magnetic sector high resolution mass spectrometer technique and validated the methodology as per the European Union regulation 644/2017. The viable monitoring utility of the methodology for predicting enviro-food-health nexus was field-tested by analyzing fish and sediment samples from the Eloor-Edayar industrial belt, a solitary POPs hotspot in India. The profiles of congeners indicate that dl-POPs were formed through precursor pathways, suggesting the potential release of chlorinated precursor species from surrounding industrial area as the root cause. Fish samples from hotspots were observed to have 8 times higher levels of polychlorinated dibenzo-p-dioxin/furans (PCDD/Fs) and 30 times higher levels of polychlorinated biphenyls (PCBs) than the control sites. A strong statistically significant (p < 0.05) positive correlation was observed between dl-POPs levels in fish and sediment samples at the study site and the Biota sediment accumulation factors for PCDD/Fs and dl-PCBs ranged from 0.019 to 0.092 and 0.004 to 0.671 respectively. The estimated weekly intake from fish consumption in the study region was observed to be 3 to 24 times higher than the maximum levels set by the European food safety authority (2 pgTEQ kg−1bwweek−1). Hence, the periodic surveillance of dl-POPs employing user friendly/validated confirmatory tools stands highly imperative to safeguard human health and environment. Keywords: Dioxin and PCBs, GC-MS/MS, POPs Hotspot, Biota-sediment accumulation factor, Correlation analysis, Health risk assessment.

Simultaneous Ion Swarm Profiling and Ion Mobility Measurement using Ion Cameras.

When operated as a standalone analytical device, traditional drift tube ion mobility spectrometry (IMS) experiments require high-speed, high-gain transimpedance amplifiers to record ion separations with sufficient resolution. Recent developments in the fabrication of charge-sensitive cameras (e.g., IonCCD) have provided key insights for ion beam profiling in mass spectrometry and even served as detectors for miniature magnetic sector instruments. Unfortunately, these platforms have comparatively slow integration times (multiple ms), which largely precludes their use for recording ion mobility spectra, where sampling rates into the 10s of kHz are generally required. As a result, experiments that simultaneously probe the longitudinal and transverse mobility of an injected species using an array detector have not been reported. To address this duty-cycle mismatch, a frequency encoding strategy is used to evaluate ion swarm characteristics, while directly capturing ion mobility information using the Fourier transform. This apparatus described allows the ion beam to be profiled over the full course of the experiment and establishes the foundation to examine axial and longitudinal drift velocities simultaneously.

Determining the oxygen detection limit with magnetic sector dynamic secondary ion mass spectrometry (SIMS)

Dynamic SIMS is often used in evaluating the concentration of impurities in solids because of its high sensitivity and depth profiling capabilities with good depth resolution and high throughput. Continuous ion beam sputtering with a high-density primary beam provides high sensitivity and reduced background contribution from residual gases within the analytical chamber. Numerical simulations along with the data acquired in the real depth profiling experiment show a good agreement of the simple model, assuming that the surface uptake of the oxygen under Cs bombardment depends on the Cs surface retention concentration. In cases where high depth resolution is desired, requiring a low primary ion beam energy, a background subtraction option will help provide better detection limits. It is proposed to perform the background subtraction based on the difference between the continuous and interleaving sputtering modes of dynamic SIMS. The experiments performed on different instruments using different sputtering rate conditions (and different impact energies) show the power function dependence of oxygen detection limit on the reversed sputter rate variation or sputtering beam density. The proposed detection limit dependence curve can be used for analytical specifications benchmarking in most magnetic sector SIMS instruments.

Toward Operando Structural, Chemical, and Electrochemical Analyses of Solid-State Batteries Using Correlative Secondary Ion Mass Spectrometry Imaging.

The global transition from fossil fuels to green energy underpins the need for efficient and reliable energy storage systems. Advanced analysis and characterization of battery materials is not only important to understand fundamental battery properties but also crucial for their continued development. A deep understanding of these systems is often difficult to obtain through only pre- and/or post-mortem analyses, with the full complexity of a battery being hidden in its operational state. Thus, we have developed an operando methodology to analyze solid-state batteries (SSBs) structurally as well as chemically before, during, and after cycling. The approach is based on a specially designed sample holder, which enables a variety of electrochemical experiments. Since the entire workflow is performed within a single focused ion beam scanning electron microscope equipped with an in-house developed magnetic sector secondary ion mass spectrometer, we are able to pause the cycling at any time, perform analysis, and then continue cycling. Microstructural analysis is performed via secondary electron imaging, and the chemical mapping is performed using the secondary ion mass spectrometer. In this proof-of-concept study, we were able to identify dendrites in a short-circuited symmetric cell and to chemically map dendritic structures. While this methodology focuses on SSBs, the approach can directly be adapted to different battery systems and beyond. Our technique clearly has an advantage over many alternatives for battery analysis as no transfer of samples between instruments is needed and a correlation between the microstructure, chemical composition, and electrochemical performance is obtained directly.