Double Addition Research Articles

Comparison study of the flux pinning enhancement of YBCO superconductor with BZO and BZO + Y2O3 mixed phase additions

Adding nanophase defects to YBa2Cu3O7-δ (YBCO) superconductor thin films is well-known to enhance flux pinning, resulting in an increase in current density (Jct). While many previous studies focused on single phase additions, the addition of several phases simultaneously shows promise in improving current density by combining different pinning mechanisms. This paper compares the effect of the addition of two insulating, nonreactive phases of barium zirconium oxide (BZO) and yttrium oxide Y2O3, both as a single addition of BZO and as a double addition in conjunction with Y2O3. Processing parameters vary the target composition volume percent of BZO from 2-6 vol. %, while maintaining 3 vol. % Y2O3, and the remaining vol. % YBCO. Pulsed laser deposition produced thin films on LaAlO3 (LAO) and SrTiO3 (STO) substrates at various deposition temperatures. Comparison of strong and weak flux pinning mechanisms, current densities, critical temperatures, and microstructures of the resulting films will be presented. Films produced from the 2 vol. % BZO + 3 vol. Y2O3 doped YBCO target at a deposition temperature of 825 °C attained the highest current density. The addition of second phase Y2O3 impacted the film microstructure, resulting in more isotropic behavior when compared to the YBCO films doped with only BZO.

Isolation and molecular cytogenetic characterization of a wheat - Leymus mollis double monosomic addition line and its progenies with resistance to stripe rust.

A common wheat - Leymus mollis (2n = 4x = 28, NsNsXmXm) double monosomic addition line, M11003-4-3-8/13/15 (2n = 44 = 42T.a + L.m2 + L.m3), with stripe rust resistance was developed (where T.a represents Triticum aestivum chromosome, L.m represents L. mollis chromosome, and L.m2/3 represents L. mollis chromosome of homoeologous groups 2 and 3). The progenies of line M11003-4-3-8/13/15 were characterized by cytological observation, specific molecular markers, fluorescence in situ hybridization (FISH), and genomic in situ hybridization (GISH). Among the progenies, there existed five different types (I, II, III, IV, and V) of chromosome constitution, the formulas of which were 2n = 44 = 42T.a + 1L.m2 + 1L.m3, 2n = 43 = 42T.a + 1L.m2, 2n = 43 = 42T.a + 1L.m3, 2n = 42 = 42T.a, and 2n = 44 = 42T.a + 2L.m2, respectively. Field disease screening showed that types I and III showed high resistance to stripe rust, while types II, IV, and V were susceptible. Leymus mollis was almost immune to stripe rust, whereas the wheat parent, cultivar 7182, was susceptible. Therefore, we concluded that the stripe rust resistance originated from L. mollis. These various lines could be further fully exploited as important disease resistance materials to enrich wheat genetic resources.

Impact of the Fenton-like treatment on the microbial community of a diesel-contaminated soil

Fenton-like treatment (FLT) is an ISCO technique relying on the iron-induced H2O2 activation in the presence of additives aimed at increasing the oxidant lifetime and maximizing iron solubility under natural soil pH conditions. The efficacy of FLT in the clean-up of hydrocarbon-contaminated soils is well established at the field-scale. However, a better assessment of the impact of the FLT on density, diversity and activity of the indigenous soil microbiota, might provide further insights into an optimal combination between FLT and in-situ bioremediation (ISB). The aim of this work was to assess the impacts of FLT on the microbial community of a diesel-contaminated soil collected nearby a gasoline station. Different FLT conditions were tested by varying either the H2O2 concentrations (2 and 6%) or the oxidant application mode (single or double dosage). The impact of these treatments on the indigenous microbial community was assessed immediately after the Fenton-like treatment and after 30, 60 and 90 d and compared with enhanced natural attenuation (ENA). After FLT, a dramatic decrease in bacterial density, diversity and functionality was evident. Although in microcosms with double dosing at 2% H2O2 a delayed recovery of the indigenous microbiota was observed as compared to those subjected to single oxidant dose, after 60 d incubation the respiration rate increased from 0.036 to 0.256 μg CCO2 g−1soil h−1. Irrespective of the oxidant dose, best degradation results after 90 d incubation (around 80%) were observed with combined FLT, relying on double oxidant addition, and bioremediation.

Synthesis of 8-substituted 1,5-diazabicyclo[3.2.1]octane derivatives via double aza-Michael addition of homopiperazine to 3-trifluoroacetyl-4H-chromenes

The reaction of homopiperazine with 2-trifluoroacetyl-1H-benzo[f]chromenes affords 2-(1,5-diazabicyclo[3.2.1]octan-8-yl)-3-(trifluoromethyl)-2,3-dihydro-1H-benzo[f]chromen-3-ols, while 3-trifluoroacetyl-4H-chromenes give 2-[2-(1,5-diazabicyclo[3.2.1]octan-8-yl)ethyl]phenols. Both reactions are the first examples of synthesis of 1,5-diazabicyclo[3.2.1]octane core via double Michael addition and include cascade Michael addition/pyran ring opening/Michael addition.

Cross-linking behavior and dielectric properties of SiCN precursor

The SiCN precursor was prepared by cross-linking process using polysilazane (PSZ) as raw materials. The cross-linking behavior and dielectric properties of SiCN precursor were analyzed. The results indicated that the main reactions during cross-linking process were double bond addition reaction, hydrosilylation reaction, dehydrogenation coupling reaction and transamination reaction. The SiCN precursor was made up of Si-C-N network structure and the main chemical bonds were Si-C, Si-N and C-C. The appropriate cross-linking temperature of SiCN precursor was 600°C. Furthermore, the increasing content and crystallization degree of free carbon could improve the dielectric properties of SiCN precursor.

Impact of litter quantity on the soil bacteria community during the decomposition of Quercus wutaishanica litter.

The forest ecosystem is the main component of terrestrial ecosystems. The global climate and the functions and processes of soil microbes in the ecosystem are all influenced by litter decomposition. The effects of litter decomposition on the abundance of soil microorganisms remain unknown. Here, we analyzed soil bacterial communities during the litter decomposition process in an incubation experiment under treatment with different litter quantities based on annual litterfall data (normal quantity, 200 g/(m2/yr); double quantity, 400 g/(m2/yr) and control, no litter). The results showed that litter quantity had significant effects on soil carbon fractions, nitrogen fractions, and bacterial community compositions, but significant differences were not found in the soil bacterial diversity. The normal litter quantity enhanced the relative abundance of Actinobacteria and Firmicutes and reduced the relative abundance of Bacteroidetes, Plantctomycets and Nitrospiare. The Beta-, Gamma-, and Deltaproteobacteria were significantly less abundant in the normal quantity litter addition treatment, and were subsequently more abundant in the double quantity litter addition treatment. The bacterial communities transitioned from Proteobacteria-dominant (Beta-, Gamma-, and Delta) to Actinobacteria-dominant during the decomposition of the normal quantity of litter. A cluster analysis showed that the double litter treatment and the control had similar bacterial community compositions. These results suggested that the double quantity litter limited the shift of the soil bacterial community. Our results indicate that litter decomposition alters bacterial dynamics under the accumulation of litter during the vegetation restoration process, which provides important significant guidelines for the management of forest ecosystems.

Phase stabilization of ammonium nitrate by double addition of potassium nitrate and melamine

Methods for providing stabilization of ammonium nitrate and expanding the application field of this oxidizing agent in gas-generating compositions used for various purposes were sought for. The results of a study of the physicochemical properties of ammonium nitrate with a melamine–potassium nitrate double additive introduced by mechanical mixing and crystallization from an aqueous (nonaqueous) solution at the boiling point are presented. The phase diagrams of the ammonium nitrate–melamine and ammonium nitrate–melamine–potassium nitrate systems, based on the results of a differential-thermal analysis, demonstrated that a phase-stable ammonium nitrate can be formed by using the method of crystallization from an aqueous (nonaqueous) solution at the boiling point. The resulting samples were examined by IR spectroscopy and X-ray diffraction analysis, and a conclusion was made that a new thermodynamically stable phase can be formed in the system with individual additives, and the introduction of a double additive leads to a combined effect: a thermodynamically stable crystal structure is formed, with the simultaneous slowing down of the nucleation and growth of a new phase in the course of a phase transformation.

Practical Singly and Doubly Electrophilic Aminating Agents: A New, More Sustainable Platform for Carbon-Nitrogen Bond Formation.

Given the importance of amines in a large number of biologically active natural products, active pharmaceutical ingredients, agrochemicals, and functional materials, the development of efficient C-N bond-forming methods with wide substrate scope continues to be at the frontier of research in synthetic organic chemistry. Here, we present a general and fundamentally new synthetic approach for the direct, transition-metal-free preparation of symmetrical and unsymmetrical diaryl-, arylalkyl-, and dialkylamines that relies on the facile single or double addition of readily available C-nucleophiles to the nitrogen atom of bench-stable electrophilic aminating agents. Practical single and double polarity reversal (i.e., umpolung) of the nitrogen atom is achieved using sterically and electronically tunable ketomalonate-derived imines and oximes. Overall, this novel approach represents an operationally simple, scalable, and environmentally friendly alternative to transition-metal-catalyzed C-N cross-coupling methods that are currently used to access structurally diverse secondary amines.

Annulation of five-membered cyclic enols with 3-aryl-2H-azirines: Catalytic versus non-catalytic cycloaddition

A copper(I)-NHC-catalyzed annulation of 5-membered cyclic enols of furan, thiophene and indene family with 3-aryl-2H-azirines has been developed to provide a rapid access to furo[3,4-b]pyrrole, thieno[3,4-b]pyrrole, indeno[1,2-b]pyrrole derivatives. The reaction proceeds via a copper-initiated NC2 azirine bond cleavage with the retention of the CN double bond in the annulation product. The reaction of tetronic acids with 3-aryl-2H-azirines can also proceed under catalyst-free conditions, through a double addition of the enol to the azirine, but this route provides poor yields of the annulation products. This is the first example of the NC2 bond cleavage in 2-unsubstituted 2H-azirines in the absence of a transition metal catalyst.

Samarium‐Catalyzed Diastereoselective Double Addition of Phenylphosphine to Imines and Mechanistic Studies by DFT Calculations

AbstractThe catalytic hydrophosphination of imines represents the most straightforward and atom‐economical strategy for the preparation of α‐aminophosphines, which are useful as biologically active molecules and ligands for catalysis. The first catalytic protocol for the rapid and high‐yielding hydrophosphination of common imines enabled by an ene–diamido samarium methoxide catalyst was developed. The reaction allowed the efficient and diastereoselective synthesis of various bis(α‐amino)phosphines through the double addition of PhPH2 to common imines. The catalytic reaction has a relatively wide substrate scope and offers high diastereoselectivities (up to 99:1 dr for meso products) and high yields (up to 97 %). DFT calculations disclosed an inner‐sphere mechanism involving unprecedented activation of a Sm−O bond by a phosphine and stabilization of the addition intermediates by the metal center.

Influence of retardation and acceleration of setting time on the efficiency of water defluoridation by calcined gypsum

Fluoride ion (F−) removal technologies from water (defluoridation) suffer from cost and/or efficiency drawbacks. The hugely available low-cost calcined gypsum (plaster of paris) represents a material of choice, especially in the developing countries. Partially soluble calcined gypsum introduces Ca2+ and SO4 2− into the water. In this work, the influence of tartaric acid, paracetamol, polyvinyl alcohol and Zn/Al layered double hydroxide additives (either retarders or accelerators) on defluoridation of water by calcined gypsum was studied. These additives act as retarders to the calcined gypsum setting and, hence, delay or disturb the crystallization of gypsum, offering the time for the crystallization of fluoro-compounds containing calcium, fluoride, phosphate and silicate. The more retarded the setting time, the more the Ca2+ is introduced in the solution, and hence, the more efficient the defluoridation process. The values of ΔG 0 are negative for all additives, indicating the spontaneity of the fluoride removal process. The results of X-ray diffraction, Fourier transform infrared and scanning electron microscopy of the produced gypsum supported this interpretation.

Influences of Na2O and K2O Additions on Electrical Conductivity of CaO-MgO-Al2O3-SiO2 Melts

The present study investigated the influences of Na2O and K2O additions on electrical conductivity of blast furnace type CaO-MgO-Al2O3-SiO2 melts by the four-electrode method. Both the single addition of Na2O or K2O and the double additions of Na2O and K2O were studied. It was found that electrical conductivity monotonously increased as the amount of Na2O addition was gradually increased, whereas, when K2O was added, there was a continuous decrease of electrical conductivity. With melts containing both Na2O and K2O, electrical conductivity first decreased but then increased when Na2O was gradually substituted for K2O while keeping the molar fractions of other components constant. In other words, the mixed-alkali effect took place in CaO-Mg-Al2O3-SiO2-ΣR2O melts.

Synthesis of tricyclic ring systems: [2+2] ketene addition reaction for preparation of tricyclic ketone, alcohol, and lactone derivatives

The addition of dichloroketene to 1,4-cyclohexadiene was examined. Dichloroketene, which was easily prepared from trichloroacetyl chloride and Zn–Cu, reacted with 1,4-cyclohexadiene in the presence of POCl3 to afford novel racemic products of single addition (5) and double addition (6). The adducts 6 and 7 were reacted separately with MCPBA (meta-chloroperbenzoic acid), H2O2, LiAlH4, and cis-diol 10 was reacted with PCC (pyridinium chlorochromate) to afford lactone, alcohol, and ketone derivatives likely to exhibit biological activity. The structures of all the racemic molecules mentioned in the article were determined from 1H NMR, 13C NMR, MS, and IR data.

1,3-Dialkynyl- and 1,3-Dialkenylisobenzofurans: New π-Extended Congeners Prepared by Double Nucleophilic Addition of Alkynyllithiums to o-Phthalaldehyde

Efficient synthetic route to 1,3-dialkynyl- and 1,3-dialkenylisobenzofurans, new π-extended congeners of isobenzofurans, was reported. A three-step protocol including double nucleophilic additions of alkynyllithiums to o-phthalaldehyde and selective oxidation enables us to prepare various functionalized π-extended isobenzofurans. The photophysical properties of these π-extended isobenzofurans are also evaluated.

Influences of Na<sub>2</sub>O and K<sub>2</sub>O Additions on Electrical Conductivity of CaO-SiO<sub>2</sub>-(Al<sub>2</sub>O<sub>3</sub>) Melts

The present study investigated the influences of Na2O and K2O additions on electrical conductivity of blast furnace type CaO-MgO-Al2O3-SiO2 melts by the four-electrode method. Both the single addition of Na2O or K2O and the double additions of Na2O and K2O were studied. It was found that electrical conductivity monotonously increased as the amount of Na2O addition was gradually increased, whereas, when K2O was added, there was a continuous decrease of electrical conductivity. With melts containing both Na2O and K2O, electrical conductivity first decreased but then increased when Na2O was gradually substituted for K2O while keeping the molar fractions of other components constant. In other words, the mixed-alkali effect took place in CaO-Mg-Al2O3-SiO2-ΣR2O melts.

Air-induced double addition of P(O)–H bonds to alkynes: a clean and practical method for the preparation of 1,2-bisphosphorylethanes

An air-induced double addition of diphenyl phosphine oxide to various alkynes is reported.

Tryptophan Lyase (NosL): A Cornucopia of 5'-Deoxyadenosyl Radical Mediated Transformations.

Tryptophan lyase (NosL) is a radical S-adenosyl-l-methionine (SAM) enzyme that catalyzes the formation of 3-methyl-2-indolic acid from l-tryptophan. In this paper, we demonstrate that the 5'-deoxyadenosyl radical is considerably more versatile in its chemistry than previously anticipated: hydrogen atom abstraction from Nα-cyclopropyltryptophan occurs at Cα rather than the amino group with NosL Y90A and replacing the substrate amine with a ketone or an alkene changes the chemistry from hydrogen atom abstraction to double bond addition. In addition, the 5'-deoxyadenosyl radical can add to the [4Fe-4S] cluster and dithionite can be used to trap radicals at the active site.

Dibenzofuran-based C2-Symmetric Chiral Diamines: Their Synthesis and Chiral Recognition Properties

The highly enantioselective synthesis of a dibenzofuran-based C2-symmetric chiral diol has been accomplished by the double enantioselective addition of diethylzinc to dibenzo[b,d]furan-4,6-dicarbaldehyde using a chiral 1,4-amino alcohol as a ligand. Among a series of chiral secondary diamines derived from the C2-symmetric chiral diol, the chiral diamine with two pyrenyl groups can effectively separate enantiomeric 1H NMR signals of various racemic acids.

High‐performance elliptic curve cryptography processor over NIST prime fields

This study presents a description of an efficient hardware implementation of an elliptic curve cryptography processor (ECP) for modern security applications. A high-performance elliptic curve scalar multiplication (ECSM), which is the key operation of an ECP, is developed both in affine and Jacobian coordinates over a prime field of size p using the National Institute of Standards and Technology standard. A novel combined point doubling and point addition architecture is proposed using efficient modular arithmetic to achieve high speed and low hardware utilisation of the ECP in Jacobian coordinates. This new architecture has been synthesised both in application-specific integrated circuit (ASIC) and field-programmable gate array (FPGA). A 65 nm CMOS ASIC implementation of the proposed ECP in Jacobian coordinates takes between 0.56 and 0.73 ms for 224-bit and 256-bit elliptic curve cryptography, respectively. The ECSM is also implemented in an FPGA and provides a better delay performance than previous designs. The implemented design is area-efficient and this means that it requires not many resources, without any digital signal processing (DSP) slices, on an FPGA. Moreover, the area–delay product of this design is very low compared with similar designs. To the best of the authors’ knowledge, the ECP proposed in this study over F p performs better than available hardware in terms of area and timing.

Molecular cytogenetics identification of a wheat –Leymus mollisdouble disomic addition line with stripe rust resistance

Leymus mollis (Trin.) Pilg. (2n = 4x = 28, NsNsXmXm) possesses a number of valuable genes against biotic and abiotic stress, which could be transferred into common wheat background for wheat improvement. In the present study, we determined the karyotypic constitution of a wheat - L. mollis double disomic addition line, M11003-4-4-1-1, selected from the F5 progeny of a stable wheat - L. mollis derivative M39 (2n = 56) × Triticum aestivum cultivar 7182, by morphological and cytogenetic identification, GISH (genomic in situ hybridization), FISH (fluorescent in situ hybridization), molecular markers analysis, and stripe rust resistance evaluation. Cytological studies demonstrated that M11003-4-4-1-1 had a chromosome karyotype of 2n = 46 with 23 bivalents, while GISH and FISH analysis indicated that this line contained 42 common wheat chromosomes and two pairs of L. mollis chromosomes. DNA markers showed that the alien chromosomes from L. mollis belonged to homoeologous groups 5 and 6. Evaluation of the agronomic traits revealed that M11003-4-4-1-1 was resistant to stripe rust at the adult stage, while the plant height was reduced and the 1000-grain weight was increased significantly. Therefore, the new line M11003-4-4-1-1 could be exploited as an important bridge material in chromosome engineering and wheat breeding.