Direct Temperature Measurements Research Articles

Direct measurement of hydrate equilibrium temperature in CO2 and CO2 rich fluids with low water content

A high-pressure experimental setup was used to obtain experimental data on the hydrate equilibrium (melting) temperature (HET) of hydrates formed from low water content CO2 and CO2 rich mixtures. A novel method was used to measure hydrate formation temperature in addition to melting temperature directly at realistic temperature/pressure conditions encountered in transport by pipelines or ship. The method can be used to evaluate the likelihood of hydrate formation in pipelines/ships transporting pure CO2 and CO2 coming from capture processes as well as from high CO2 content produced gas. The data generated from the measurement can also be used to investigate the kinetics of hydrate formation and dissociation in low water content fluids at pipeline/ship conditions. This paper details the experimental equipment, methods, test fluids and results. Experimental results are compared against predictions of the simplified cubic plus association equation of state (sCPA-EoS) coupled with the van der Waals and Platteeuw solid solution theory.

A metaheuristic-based method for photovoltaic temperature computation under tropical conditions

Tropical climates have favorable irradiation levels for the development of photovoltaic systems; however, high temperatures have a negative impact on the efficiency of solar cells. Since direct measurement of cell temperature is not common, mathematical models are needed to make predictions. Numerous models have been documented, highlighting the challenge of applying a universal model to different climatic conditions. The main contribution of this study is the proposal of a metaheuristic algorithm to accurately compute the temperature of solar cells. This method is simple and effective in exploring numerous potential states of the reference parameters (i.e., irradiance and ambient temperature). Data collected over a 23-month period in two photovoltaic installations with an output power of 2.2 MW of multicrystalline silicon technology were used to develop the proposed method and validate it. The proposed model was compared with 19 previously reported models in the literature. Compared to the model recommended by the International Electrotechnical Commission (IEC Standard 61215-1), the mean square error, mean absolute error (MAE) and mean absolute percentage error were reduced by 4.9, 4.8, and 2.4 times, respectively. The accuracy of the proposed method is demonstrated by MAE errors ranging from 0.56 °C to 1.88 °C, obtained by considering three different daily profiles of irradiance and ambient temperature. Therefore, the proposed method is recommended to more accurately calculate the temperature of the photovoltaic cell in tropical areas.

Thermal Protection of Piezoelectric Actuators Using Complex Electrical Power Measurements and Simplified Thermal Models

This article describes a method for estimating the temperature of high-power piezoelectric actuators when a direct temperature measurement is impractical. The heat flow is estimated from the real component of the electrical power; then, the temperature is estimated by a transfer function that approximates the thermal response of the system. The transfer function can be derived analytically from a lumped-element approximation or calibrated experimentally by using a system identification method. The proposed method is demonstrated on a piezoelectric stack actuator used in a high-speed nanopositioning device. A second-order transfer function estimates the temperature to within 3 <inline-formula xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink"><tex-math notation="LaTeX">$^{\circ }$</tex-math></inline-formula> C of a reference measurement for a range of operating conditions. The proposed method is suitable for protecting piezoelectric actuators in applications where direct temperature measurement is impractical, for example, due to space or wiring constraints.

A multispectral radiometry method for measuring the normal spectral emissivity and temperature

A multispectral radiometry method was developed to simultaneously determine normal spectral emissivity of continuum spectra and temperature of materials. Linear dependence assumption would be a constraint to associate the spectral emissivity to the temperature when spectral radiance for various spectrum was measured within small temperature differences. The methodology was evaluated for different parameter constraints, and validated by seven emissivity hypothesis models. To verify the reliability of the experimental device and the multispectral radiometry method, the spectral emissivities of graphite at high temperatures were verified that the deviations between the official experimental data and the results in this work are all less than 5 %. Besides, the spectral emissivity and temperature of the graphite-carbon fiber composite in the spectral range of 0.3–2.5 μm at 1473–1873 K were measured. The temperature uniformity of the sample front surface was evaluated, and the relative error of the temperature distribution is less than 2 %. The uncertainties of the spectral emissivity and temperature in the studied spectrum are less than5.0 % and 6.0 %, respectively. The method is useful for accurately measuring the sample spectral emissivity without direct temperature measurements at high temperatures.

In-situ measurement and control of the tool-workpiece interface temperature during friction stir processing of 304/304L stainless steel

Friction stir processing of 304/304L stainless steel is an area of interest for repair of spent nuclear fuel canisters. To enable repair without canister deflection or fracture, it is necessary to define the limitations for the depth of the processing zone which will be critically dependent on the thermal history of the material. This work provides the first direct measurement of the interface temperature for friction stir processing of steel. The measured temperature is in the range of 850–1050 °C which is 20–30 % higher than previously reported values. Notably, the peak temperature occurs at the pin tip which is attributed to a higher sticking fraction and subsequently higher strain rate near the tool axis of rotation. Furthermore, a clear correlation between the temperature, grain size, and hardness is established within a single weld nugget and across different processing conditions. In the future, this data may lead to improved process modelling through direct validation and allow for property optimization through direct microstructure control.

Determining subsurface temperature & lithospheric structure from joint geophysical-petrological inversion: A case study from Ireland

High quality maps of the geothermal gradient and temperature are essential when assessing geothermal potential for a region. However, determining geothermal potential is a challenge as direct measurements of in situ temperature are sparse and individual geophysical methods are sensitive to a range of parameters, not solely temperature. Here, we develop a novel approach to determine the geothermal gradient using a new joint geophysical-petrological inversion where seismic velocities and density in the mantle are related to temperature and bulk composition within a thermodynamic framework. Large datasets of phase velocities of seismic surface-waves are now incorporated into the inversion, and provide essential constraints on the lithospheric thickness and temperature, which shape the crustal geotherms to a significant extent. We also include all available measurements of the surface heat flow, radiogenic heat production (RHP) and thermal conductivity within the crust, to further constrain the temperature and geothermal gradient, in particular in the top few kilometres of the crust. We use Ireland as a case study and show how our new methodology can reproduce the results of previous work but also improve on them, thanks to the complementary sensitivities of the full range of data. Lithospheric and crustal thicknesses have primary controls on the temperature gradient, with areas of thinner lithosphere showing higher geothermal gradients. In some locations, anomalously warm geotherms result from high RHP within crustal granitic rocks, mudstone and shales. RHP is above continental averages across all Ireland, likely due to a crust with mostly felsic lithology. The new methodology provides a robust workflow for determining the geothermal potential in areas with limited direct temperature measurements, facilitating knowledge creation for the transition to sustainable energy sources and energy self-sufficiency.

Characterization on the thermal field inside IGBT cells during switching based on TCAD modeling and Thermoreflectance imaging

—Temperature characterization of power semiconductors is a hot topic in power electronics. Nevertheless, the transient temperature field inside an IGBT cell is highly difficult to measure. In this study, we presented a method combining metallographic technology and Thermoreflectance Imaging (TRI) to measure the temperature distribution inside IGBT cells during switching. First, the IGBT module was prepared to achieve a well longitudinal section and its electrical characteristics were verified. Subsequently, the double-pulse test was performed on the IGBT sample and the temperature distributions along the ground section were measured through TRI. The result indicates that the temperature along the cross-section can be observed through TRI. The experimental results are confirmed to be consistent with the TCAD simulations on electro-thermal behavior. The proposed method for the first time achieves the direct temperature measurement inside the cells of power devices on a micro-nano temporal-spatial scale, and it can serve as an effective tool for analysis like temperature evaluation, aging analysis and TCAD modeling.

Distribution of Ground Temperature in the Geothermal Manifestation Area of Lompio, Donggala Regency, Central Sulawesi Province

The distribution of non-volcanic geothermal energy is widely found on the island of Sulawesi, one of which is in Lompio Village, Sirenja District, Donggala Regency, Central Sulawesi Province. It is important to study the geothermal potential in the village in order to learn how the geothermal system works. This study aims to identify the distribution pattern of temperature distribution in shallow soil depths as a manifestation of the geothermal system below the surface and its relation to geothermal manifestations that appear on the surface. This research was carried out through a series of field observations and direct soil temperature measurements in the study area using a thermometer. The results show that the distribution pattern of land temperature distribution in the high-temperature zone is associated with the presence of geothermal manifestation points on the surface (hot springs). The association of temperature and manifestation is possible because the presence of hot springs is an indication of a weak zone for the release of hydrothermal fluid from the geothermal system, which is correlated with the geological structure in the research area.

Direct Temperature Measurements of Cardiac Stent during MRI Examinations

Nowadays, Magnetic Resonance Imaging (MRI) is considered the gold standard for imaging the brain, spinal cord, musculoskeletal system, head and neck, and complex congenital heart malformations; consequentially, the number of MRI scans in patients with implantable electronic devices has simultaneously increased. During the entire length of the MRI exam, patients are exposed to electromagnetic fields with different characteristics (static, low frequency, radiofrequency fields), which are related to different risks. The scarce available literature about MRI-induced heating on cardiac stents suggests that excessive temperature rise occurs only in unfavorable cases. Ideally, RF safety assessment could be performed during the anamnestic process, but this simulation process’s results are too slow to be performed before patient MRI examination. In this context, we developed a dedicated measurement set-up by focusing our target on the measurement of the heating of a cardiac stent during an MRI examination. Results for the temperature rise trend along the entire stent length during a clinical MRI protocol are shown together with the local Specific Absorption Rate (SAR) values and cumulative equivalent minutes at 43 °C (CEM43°C), in order to ensure the safety of patients with MR-conditional devices, also with a view to not inappropriately preclude their access to MRI scans. The obtained results show that the maximum temperature rise (4.12 °C) is within the limit of 5 °C stated in the stent manual for 15 min of continued scanning with the specific conditions. The maximum temperature rise was in correspondence with the stent tips and calculated SAR confirms the fact that two hotspots are present near the tips of the stent. Finally, the calculated CEM43°C remained well below the proposed threshold for muscle tissue.

Absolute thermometry of human brown adipose tissue by magnetic resonance with laser polarized 129Xe

BackgroundAbsolute temperature measurements of tissues inside the human body are difficult to perform non-invasively. Yet, for brown adipose tissue (BAT), these measurements would enable direct monitoring of its thermogenic activity and its association with metabolic health.MethodsHere, we report direct measurement of absolute BAT temperature in humans during cold exposure by magnetic resonance (MR) with laser polarized xenon gas. This methodology, which leverages on the sensitivity of the chemical shift of the 129Xe isotope to temperature-induced changes in fat density, is first calibrated in vitro and then tested in vivo in rodents. Finally, it is used in humans along with positron emission tomography (PET) scans with fluorine-18-fluorodeoxyglucose to detect BAT thermogenic activity during cold exposure.ResultsAbsolute temperature measurements, obtained in rodents with an experimental error of 0.5 °C, show only a median deviation of 0.12 °C against temperature measurements made using a pre-calibrated optical temperature probe. In humans, enhanced uptake of 129Xe in BAT during cold exposure leads to background-free detection of this tissue by MR. Global measurements of supraclavicular BAT temperature, made over the course of four seconds and with an experimental error ranging from a minimum of 0.4 °C to more than 2 °C, in case of poor shimming, reveal an average BAT temperature of 38.8° ± 0.8 °C, significantly higher (p < 0.02 two-sided t test) than 37.7 °C. Hot BAT is also detected in participants with a PET scan negative for BAT.ConclusionsNon-invasive, radiation-free measurements of BAT temperature by MRI with hyperpolarized 129Xe may enable longitudinal monitoring of human BAT activity under various stimulatory conditions.

Temperature Measurement of Trapped, Thermally Sensitive Single Particles in an Optical Trap Using Raman Spectroscopy.

Single particles trapped in an optical trap may experience temperature elevation, yet direct measurement of temperature and its distribution inside the optical trap of several to hundreds of microns in size remains a big challenge. We introduce a method that can measure the temperature inside a universal optical trap (UOT) using Raman spectroscopy of single trapped particles of high thermal conductivity. We measured temperature and temperature distributions inside the UOT using Raman shifts of single-walled carbon nanotubes (SWCNTs) and micron-sized diamonds (MSDs), which are heated by trapping laser beams directly or indirectly, depending on the location of the particle in the trap. We show that the temperature at the center of the UOT is much lower than the temperature along the hollow beams that form a hollow, cage-shaped UOT. In the range of the trapping laser power of 200-2950 mW, the surface temperature of particles trapped at the center of a UOT changes from 322 K to 830 K, correspondingly. This result gives a heating rate as a high thermal-absorbing particle trapped in the center of the UOT with 18.3 ± 0.4 °C/100 mW. In addition, the temperature gradient outside the UOT was also characterized by trapping SWCNT particles outside the UOT. Results show that when a light-absorbing particle is trapped for the study of material property, phase transitions, surface equilibrium process, chemical reactions, etc., this method can be used to measure temperature distribution and its variations in the trap and its surroundings.

Experimental Investigation of Temperature Distribution in the Chips, Workpiece and Cutting Tool During Machining Operations

High temperature values are encountered during machining processes and these high temperature values have negative influences on the tool, workpiece, chip formation mechanisms, the process efficiency and the quality of surface of the machined parts. These negative influences can be reduced drastically with the use of appropriate cutting tool with suitable depth of cut during machining operations. The studies of these thermal fields in machining are necessary and very important for the development of new technologies aiming to increase the tool lives and to reduce production costs. This work centers on measurement of temperatures in the chips, cutting tool and workpiece during turning and drilling operations using uncoated high-speed steel and coated cemented carbide cutting tools at different cutting speeds and depths of cut to ascertain the more suitable cutting tool and feed rate during machining operations. Although, the direct temperature measurement at the chip-tool interface are very complex, the turning experiments were performed on a lathe machine at varying turning speeds and depths of cut, while the drilling operation was performed on a drilling machine at different turning speeds and depths of cut. All the experiments were carried out at the mechanical Engineering workshop of Federal University of Technology, Owerri. The temperature values of chip, cutting tool and workpiece when working on brass, high-carbon steel and stainless steel were measured using digital thermocouples. The results obtained showed that uncoated high-speed steel cutting tool could not cut stainless steel and high-carbon steel at very high turning speed and depth of cut due to the excessive heat it generated at the contact area, and at very low cutting speed the temperature of the cutting tools were higher than the workpiece irrespective of the cutting tool till an increased cutting speed where temperature of workpiece became higher than the cutting tool. It is recommended that coated cemented carbide on hard materials be used during turning and drilling to ensure a negligible increase in temperature while machining, also monitor speed for required finishing and extended tool life.

Estimating Permafrost Distribution Using Co‐Located Temperature and Electrical Resistivity Measurements

AbstractAssessing the lateral and vertical extent of permafrost is critical to understanding the fate of Arctic ecosystems under climate change. Yet, direct measurements of permafrost distribution and temperature are often limited to a small number of borehole locations. Here, we assess the use of co‐located shallow temperature and electrical resistivity tomography (ERT) measurements to estimate at high‐resolution the distribution of permafrost in three watersheds underlain by discontinuous permafrost. Synthetic modeling shows that co‐located temperature and ERT measurements allow for supervised classification schemes that provide 60% higher accuracy compared to unsupervised methods. Linking resistivity and size of the identified permafrost bodies to surface observations, we show that tall vegetation (&gt;0.5 m) and gentle slopes (&lt;15°) are related to warmer and smaller permafrost bodies, and a more frequent occurrence of taliks.

Direct measurement of internal temperatures of commercially-available 18650 lithium-ion batteries

Direct access to internal temperature readings in lithium-ion batteries provides the opportunity to infer physical information to study the effects of increased heating, degradation, and thermal runaway. In this context, a method to insert temperature sensors into commercial 18650 cells to determine the short- and long-term effects through characterization testing is developed. Results show that sensor insertion only causes a decrease in capacity of 0.5–2.3%, and an increase in DC resistance of approximately 15 mΩ. The temperatures of the modified cells are approximately 0.5 °C higher than the control cells, the difference between the internal and external temperature readings of the modified cells is approximately 0.4 °C, and the modified cells exhibit the same temperature behavior and trend during cycling as the control cells. The cells are able to operate and collect data for 100–150 cycles before their capacities fade and resistances increase beyond what is observed in the control cells. The results of the testing show that cells modified with internal temperature sensors provide useful internal temperature data for cells that have experienced little or no cyclic aging.

Thermal induced deflection in atomic force microscopy cantilevers: analysis & solution

Atomic force microscopy (AFM) cantilevers are commonly made from two material layers: a reflective coating and structural substrate. Although effective, this can result in thermally induced cantilever deflection due to ambient and local temperature changes. While this has been previously documented, key aspects of this common phenomenon have been overlooked. This work explores the impact of thermally induced cantilever deflection when in- and out-of-contact, including the topographic scan artefacts produced. Scanning thermal microscopy probes were employed to provide direct cantilever temperature measurement from Peltier and microheater sources, whilst permitting cantilever deflection to be simultaneously monitored. Optical lever-based measurements of thermal deflection in the AFM were found to vary by up to 250% depending on the reflected laser spot location on the cantilever. This highlights AFM’s inherent inability to correctly measure and account for thermal induced cantilever deflection in its feedback system. This is particularly problematic when scanning a tip in-contact with the surface, when probe behaviour is closer mechanically to that of a bridge than a cantilever regarding thermal bending. In this case, measurements of cantilever deflection and inferred surface topography contained significant artefacts and varied from negative to positive for different optical lever laser locations on the cantilevers. These topographic errors were measured to be up to 600 nm for a small temperature change of 2 K. However, all cantilevers measured showed a point of consistent, complete thermal deflection insensitivity 55% to 60% along their lengths. Positioning the reflected laser at this location, AFM scans exhibited improvements of up-to 97% in thermal topographic artefacts relative to other laser positions.

Dynamic optical spectroscopy and pyrometry of static targets under optical and x-ray laser heating at the European XFEL

Experiments accessing extreme conditions at x-ray free electron lasers (XFELs) involve rapidly evolving conditions of temperature. Here, we report time-resolved, direct measurements of temperature using spectral streaked optical pyrometry of x-ray and optical laser-heated states at the High Energy Density instrument of the European XFEL. This collection of typical experiments, coupled with numerical models, outlines the reliability, precision, and meaning of time dependent temperature measurements using optical emission at XFEL sources. Dynamic temperatures above 1500 K are measured continuously from spectrally- and temporally-resolved thermal emission at 450–850 nm, with time resolution down to 10–100 ns for 1–200 μs streak camera windows, using single shot and integrated modes. Targets include zero-pressure foils free-standing in air and in vacuo, and high-pressure samples compressed in diamond anvil cell multi-layer targets. Radiation sources used are 20-fs hard x-ray laser pulses at 17.8 keV, in single pulses or 2.26 MHz pulse trains of up to 30 pulses, and 250-ns infrared laser single pulses. A range of further possibilities for optical measurements of visible light in x-ray laser experiments using streak optical spectroscopy are also explored, including for the study of x-ray induced optical fluorescence, which often appears as background in thermal radiation measurements. We establish several scenarios where combined emissions from multiple sources are observed and discuss their interpretation. Challenges posed by using x-ray lasers as non-invasive probes of the sample state are addressed.

Investigation of post mortem brain, rectal and forehead temperature relations

It is well known that magnetic resonance (MR) imaging is temperature sensitive, which is highly relevant for post mortem examinations. Therefore, the determination of the exact temperature of the investigated body site, e.g. the brain, is crucial. However, direct temperature measurements are invasive and inconvenient. Thus, in view of post mortem MR imaging of the brain, this study aims at investigating the relation between the brain and the forehead temperature for modelling the brain temperature based on the non-invasive forehead temperature. In addition, the brain temperature will be compared to the rectal temperature.Brain temperature profiles measured in the longitudinal fissure between the brain hemispheres, as well as rectal and forehead temperature profiles of 16 deceased were acquired continuously. Linear mixed, linear, quadratic and cubic models were fitted to the relation between the longitudinal fissure and the forehead and between the longitudinal fissure and the rectal temperature, respectively.Highest adjusted R2 values were found between the longitudinal fissure and the forehead temperature, as well as between the longitudinal fissure and the rectal temperature using a linear mixed model including the sex, environmental temperature and humidity as fixed effects.The results indicate that the forehead, as well as the rectal temperature, can be used to model the brain temperature measured in the longitudinal fissure. Comparable fit results were observed for the longitudinal fissure-forehead temperature relation and for the longitudinal fissure-rectal temperature relation. Combined with the fact that the forehead temperature overcomes the problem of measurement invasiveness, the results suggest using the forehead temperature for modelling the brain temperature in the longitudinal fissure.

Vapor-liquid equilibria in the 1-methylpyrrolidine + 1-butylimidazole binary system: Experimental measurements and theoretical modelling

In this study, a comprehensive investigation of the 1-methylpyrrolidine + 1-butylimidazole binary system was conducted to establish a valuable foundation for process design. Isobaric binary vapor − liquid equilibrium (VLE) data was measured (80 data points) at 50.0, 20.0, 10.0, and 7.5 kPa using dynamic equilibrium cell (VLE 602) and found that no azeotrope existed throughout the entire operating pressure range. Thermodynamic consistency was validated using the Redlich − Kister area test (9.56801%). The vapor pressure of 1-butylimidazole was determined through direct measurement (12 data points) of the equilibrium temperature at different pressures and the Antoine equation parameters were regressed based on the acquired data. The VLE data were regressed using maximum likelihood (ML) method, and binary interaction parameters (BIP) were estimated for NRTL–HOC, UNIQUAC, Van Laar, and Wilson models. The model validation demonstrated consistency between calculated and experimental values for temperature and mole fraction of the vapor phase. In addition, dipole moment (μ) values were evaluated by quantum chemical calculations using the Hartree–Fock (HF) method through GAMESS package. The density (12 data points), the sound velocity (12 data points), the refractive index (3 data points), and the normal boiling points (3 data points) were also measured for binary mixtures and pure components.

Flow Activation Energy Estimation by Thermo‐Rheological Method

AbstractPolymer and many other flows exhibit non‐Newtonian rheological behavior. For some materials, the thermal dependence of viscosity is also essential to be established. It can be described by considering an activation energy, estimated by using the viscosity measurements at different temperatures. Nevertheless, the test temperatures must be reliable and accurate. An annular measuring device (TRAC: Thermo‐Rheo Annular Cell) is previously proposed for highly robust temperature measurement and viscosity identification by inverse method, which exploits the viscous dissipation in the flow. This work explains how critical viscosity points, identified thanks to the TRAC, can be used to estimate the activation energy with different approaches involving the principle of time‐temperature superposition. Thanks to the thermal characteristics of the annular flow, the thermal dependence of viscosity can also be estimated from direct temperature measurements to perform fast analysis, without using inverse method.

Inverse Thermal Analysis as a Tool for Optimizing Concentrated Solar Energy Elaboration of Wear Resistant Surface Layers

Concentrated Solar Energy (CSE) processing is considered a promising renewable energy source technique for elaborating thick, wear-resistant claddings onto metallic surfaces of large dimensions that are expected to operate in heavy duty applications, such as excavator shovels, mineral crushers, etc. However, the prediction of surface processing effects on the microstructure and the properties of the main construction base metal are of crucial importance, as they are commonly required in all surface modification techniques. Thus, the present study is focused on the inverse thermal analysis and parametric modeling of heat deposition associated with CSE surface processing of metals. In this preliminary attempt, experimental findings that concern the elaboration of TiC- and chromium carbide-reinforced clads onto common steel base metals were used to quantify the evaluation of the temperature histories within the volume of workpieces undergoing solar heating, where direct temperature measurements contain uncertainties and/or are not even possible. Results of prototype inverse thermal analyses of heat transfer in processed layer-substrate systems are presented, demonstrating the general aspects of a parametric model for thermal analysis and simulation.