Strength Of Dipolar Interaction Research Articles

Rational Design of A-Site Cation for High Performance Lead-Free Perovskite X-Ray Detectors.

Design of hypotoxic lead-free perovskites, e.g. Bismuth(Bi)-based perovskites, is much beneficial for commercialization of perovskite X-ray detectors due to their strong radiation absorption. Nevertheless, the design principles governing the selection of A-site cations for achieving high-performance X-ray detectors remain elusive. Here, seven molecules (methylamine MA, amine NH3, dimethylbiguanide DGA, phenylethylamine PEA, 4-fluorophenethylamine p-FPEA, 1,3-propanediamine PDA, and 1,4-butanediamine BDA) and calculated their dipole moments and interaction strength with metal halide (BiI3) are selected. The first-principles calculations and related spectroscopy measurements confirm that organic molecules (DGA) with large dipole moments can have strong interactions with perovskite octahedron and improve the carrier transport between the organic and inorganic clusters. Consequently, zero-dimensional single crystal (SC) (DGA)BiI5∙H2O is synthesized. The (DGA)BiI5∙H2O SCs demonstrate an exceptional carrier mobility-lifetime product of 6.55×10-3cm2V-1, resulting in the high sensitivity of 5879.4µCGyair -1cm-2, featuring a low detection limit (4.7nGyairs-1) and remarkable X-ray irradiation stability even after 100 days of aging at a high electric field (100Vmm-1). Furthermore, the (DGA)BiI5∙H2O SCs for imaging, achieving a notable spatial resolution of 5.5lpmm-1 are applied. This investigation establishes a pathway for systematically screening A-site cations to design low-dimensional SCs for high-performance X-ray detection.

Reduced energies for thin ferromagnetic films with perpendicular anisotropy

We derive four reduced two-dimensional models that describe, at different spatial scales, the micromagnetics of ultrathin ferromagnetic materials of finite spatial extent featuring perpendicular magnetic anisotropy and interfacial Dzyaloshinskii–Moriya interaction. Starting with a microscopic model that regularizes the stray field near the material’s lateral edges, we carry out an asymptotic analysis of the energy by means of [Formula: see text]-convergence. Depending on the scaling assumptions on the size of the material domain versus the strength of dipolar interaction, we obtain a hierarchy of the limit energies that exhibit progressively stronger stray field effects of the material edges. These limit energies feature, respectively, a renormalization of the out-of-plane anisotropy, an additional local boundary penalty term forcing out-of-plane alignment of the magnetization at the edge, a pinned magnetization at the edge, and, finally, a pinned magnetization and an additional field-like term that blows up at the edge, as the sample’s lateral size is increased. The pinning of the magnetization at the edge restores the topological protection and enables the existence of magnetic skyrmions in bounded samples.

Effect of the dipolar interaction on the dynamic hysteresis of properties of 2D-nanodisks: In-plane driving field case

The effect of the dipolar interaction strength on the dynamical hysteresis behavior of the nanodisk is investigated within the Heisenberg model and Monte Carlo simulation. The system is under the effect of the dynamical periodic sinusoidal magnetic field. It has been shown that dipolar interaction strength can induce dynamical phase transition and the transition from the fully dynamically ordered ground state to the weak dynamically ordered ground state. Besides, it has been shown that rising dipolar interaction raises the hysteresis loop area for higher temperatures and a linear relationship between the peak positions of the hysteresis loop area and the temperature locations of the peaks obtained.

Structural Aspects of Ambient-Temperature Densification of Highly Crack-Resistant Borosilicate and Aluminoborosilicate Glasses: Two Case Studies Examined by Solid-State NMR.

The structural aspects of ambient-temperature densification via pressurization at 25 GPa were studied by solid-state NMR for two case studies: An alkaline earth boroaluminosilicate glass with the composition 6CaO-3SrO-1BaO-10Al2O3-10B2O3-70SiO2 (labeled SAB) and a sodium magnesium borosilicate glass with the composition 10Na2O-10MgO-20B2O3-60SiO2 (labeled MNBS). For SAB glass, cold pressurization results in significant increases in the average coordination numbers of both boron and aluminum, in line with previous results found in hot-compressed alkali aluminoborosilicate glasses. In addition, 27Al/11B dipolar recoupling experiments reveal a significant decrease in the 11B/27Al dipolar interaction strength upon pressurization, suggesting that the higher-coordinated boron and aluminum species experience weaker magnetic interactions. While this is an expected consequence of the longer internuclear distances involving higher coordination states, the magnitude of the effect also is consistent with a decrease of average B-O-Al internuclear connectivity. By conjecture, a decreased B-O-Al connectivity may present a mechanism of plastic flow inhibiting crack initiation in aluminoborosilicate glasses. In the case of the MNBS glass, no change in the average boron coordination number was observed within experimental error; however, densification increases the extent of B-O-Si connectivity at the expense of small ring structures with dominant B-O-B connectivity. With regard to boron coordination, the data obtained for both case studies differ from those previously found in a series of alkali borosilicate glasses, which had shown an unexpected decrease in N4 upon increased pressure. The results of the present study highlight the importance of changes of medium-range order regarding densification.

Micromagnetic simulations of emergent monopole defects and magnetization reversal in connected and dipolar Square Artificial Spin Ice

Artificial spin ice (ASI) structures have garnered significant attention due to their unique properties including emergent magnetic monopoles, phase transitions, and collective switching dynamics. In this study, we employ micromagnetic simulations to investigate the magnetic microstates and magnetization reversal dynamics of square ASI with varying connectivity. In particular, we explore an intermediate or a quasi-connected system where the connectivity is altered without significantly changing the strength of dipolar interactions through the introduction of narrow gaps at the vertices. Our results reveal distinct differences in the populations of different vertex types during magnetic reversal for lattices with varying connectivity. These results suggest the possibility of engineering ASI systems in which specific vertex types can be repeatably accessed through adjustments in lattice connectivity.

Directed assembly of small binary clusters of magnetizable ellipsoids.

We report the effect of shape anisotropy and material properties on the directed assembly of binary suspensions composed of magnetizable ellipsoids. In a Monte Carlo simulation, we implement the ellipsoid-dipole model to calculate the pairwise dipolar interaction energy as a function of position and orientation. The analysis explores dilute suspensions of paramagnetic and diamagnetic ellipsoids with different aspect ratios in a superparamagnetic medium. We analyze the local order of binary structures as a function of particle aspect ratio, medium permeability, and dipolar interaction strength. Our results show that local order and symmetry are tunable under the influence of a uniform magnetic field when one component of the structure is dilute with respect to the other. The simulation results match previously reported experiments on the directed assembly of binary suspension of spheres. Additionally, we report the conditions on particle aspect ratios and medium properties for various structures with rotational symmetries, as well as open and enclosed structures under the influence of a uniform magnetic field.

Effect of the dipolar interaction on the dynamic hysteresis properties of 2D-nanodisks: out of plane driving field case

We have systematically investigated the effect of dipolar interaction strength on the dynamical hysteresis behavior of the in-plane uniaxial anisotropic nanodisk system modeled by the classical Heisenberg model under the effect of the time-dependent external out-of-plane periodic magnetic field. Dynamical hysteresis loops, as well as hysteresis quantities (hysteresis loop area, coercive field, remanent magnetization), have been examined both in-plane and out-of-plane magnetization components by means of Monte Carlo simulation based on Metropolis Algorithm. Our simulation results suggest that the response of the in-plane and out-of-plane components of the magnetization have different hysteresis characteristics. For instance, while the out-of-plane component of the magnetization has ordinary dynamically disordered hysteresis curves, bowtie-shaped hysteresis loops have been obtained for the in-plane component of the magnetization. Disappeared dynamical order has been observed with the rising strength of the dipolar interaction.

Anisotropic inflation in dipolar Bose–Einstein condensates

Early during the era of cosmic inflation, rotational invariance may have been broken, only later emerging as a feature of low-energy physics. This motivates ongoing searches for residual signatures of anisotropic space-time, for example in the power spectrum of the cosmic microwave background. We propose that dipolar Bose–Einstein condensates (BECs) furnish a laboratory quantum simulation platform for the anisotropy evolution of fluctuation spectra during inflation, exploiting the fact that the speed of dipolar condensate sound waves depends on direction. We construct the anisotropic analogue space-time metric governing sound, by linking the time-varying strength of dipolar and contact interactions in the BEC to the scale factors in different coordinate directions. Based on these, we calculate the dynamics of phonon power spectra during an inflation that renders the initially anisotropic Universe isotropic. We find that the expansion speed provides an experimental handle to control and study the degree of final residual anisotropy. Gravity analogues using dipolar condensates can thus provide tuneable experiments for a field of cosmology that was until now confined to a single experiment, our Universe.

Macroscopic sample shape effect on pulse electron double resonance (PELDOR) signal

Pulse electron double resonance (PELDOR), also called double electron–electron resonance (DEER), is a technique capable of measuring the strength of electron spin dipolar interactions, revealing spin–spin distance distributions in ordered and disordered solid materials. Previous work has shown that PELDOR signals acquire an out-of-phase component under conditions of high electron spin polarization, such as at low temperatures and high fields. In this paper, we show theoretically and experimentally that the size and sign of this effect depends on the macroscopic shape of the sample and its orientation in the external magnetic field. This effect is caused by dipolar interactions between distant spins and provides new insights into the fundamental physics of PELDOR.

Melting of electronic/excitonic crystals in 2D semiconductor moiré patterns: A perspective from the Lindemann criterion

Using the Lindemann criterion, we analyzed the quantum and thermal melting of electronic/excitonic crystals recently discovered in two-dimensional (2D) semiconductor moiré patterns. We show that the finite 2D screening of the atomically thin material can suppress (enhance) the inter-site Coulomb (dipolar) interaction strength, thus inhibits (facilitates) the formation of the electronic (excitonic) crystal. Meanwhile, a strong enough moiré confinement is found to be essential for realizing the crystal phase with a wavelength near 10 nm or shorter. From the calculated Lindemann ratio which quantifies the fluctuation of the site displacement, we estimate that the crystal will melt into a liquid above a critical temperature ranging from several tens Kelvin to above 100 K (depending on the system parameters).

Evidence of Individual Superspin Relaxation in Diluted Fe3O4/Hexane Ferrofluids.

We used dc magnetization and ac susceptibility to investigate the magnetic relaxation of ferrofluids made of 8 nm average-diameter Fe3O4 nanoparticles dispersed in hexane. Samples of different concentrations (δ) spanning two orders of magnitude ranging from 0.66 to 0.005 mg (Fe3O4)/mL (hexane) were used to vary the interparticle interaction strength. Our data reveal a critical concentration, δc = 0.02 mg/mL, below which the ferrofluid behaves like an ideal nanoparticle ensemble where the superspins relax individually according to a Néel-Brown activation law τ(T) =τ0expEBkBT with a characteristic time τo ~10-9 s. That is further confirmed by the observed invariance of the relative peak temperature variation per frequency decade ∆=∆TT·∆log(f), which stays constant at ~0.185 when δ < δc. At higher concentrations, between 0.02 and 0.66 mg/mL, we found that Δ exhibits a monotonic increase with the inverse concentration, 1δ, and the collective superspin dynamics is described by a Vogel-Fulcher law, τ(T) =τ0expEBkBT-T0. Within this regime, the dipolar interaction strength parameter T0 increases from T0 = 0 K at δc = 0.02 mg/mL to T0 = 14.7 K at δ = 0.66 mg/mL.

Structural impact of niobium oxide on lithium silicate glasses: Results from advanced interaction-selective solid-state nuclear magnetic resonance and Raman spectroscopy

While niobium-containing oxide glasses are used in many technological applications, especially optical glasses, the exact structural role of Nb and its impact on the structure of covalent/ionic oxide glasses remain incompletely understood. In the present study, this issue is addressed for Nb2O5-containing lithium silicate glasses using 7Li, 29Si, and 93Nb magic-angle-spinning (MAS) and advanced NMR methods sensitive to 7Li–7Li and 7Li–93Nb magnetic dipole-dipole interactions, accompanied by molecular dynamics (MD) and Monte-Carlo (MC) simulations. In glasses along the compositional line (1–y)Li2Si2O5–yNb2O5, 29Si MAS-NMR spectra reveal a gradual silica network repolymerization with increasing y, indicating that the accommodation of the niobium oxide component into the glassy network requires on average about 0.7 equivalents of lithium oxide. Significant 7Li–93Nb interactions were also detected and quantified by Rotational Echo Saturation Pulse Double Resonance (RESPDOR) experiments. Consistent with this finding, profound changes in the local environments of the lithium ions and their spatial distributions are observed in 7Li satellite transition (SATRAS) spectra and 7Li dipolar spin echo decays, whereas 93Nb NMR and Raman spectra suggest the formation of six-coordinated NbO6 polyhedra with both, corner- and edge-sharing connectivity. Results obtained on glasses along a second composition line, SiO2–[(Li2O)1.4(Nb2O5)], confirm the above-described structural concepts. The average homo- and heteronuclear dipolar interaction strengths as expressed by the second moments M2(Li-Li) and M2(Li-Nb) are consistent with random spatial distributions of the lithium and niobium species, with a tendency towards Nb clustering at higher concentrations. All of these results suggest that niobium oxide adopts a network former role in these glasses. The current study defines a comprehensive general strategy for elucidating the structural impact of NMR active intermediate oxides incorporated into silicate glasses.

Förster Blockade and Excitation Transfer Behaviors of Two-Photon Rabi Oscillations of Exciton–Biexciton Levels in Coupled Quantum Dots

We provide a theoretical study for the dynamical behavior of two-photon Rabi oscillations in two coupled quantum dots. Each dot is a three-level quantum system (ground, one-exciton, and biexciton states). We describe the optical dynamics within the density matrix formalism framework. The two-photon Rabi oscillations are found to be significantly affected by the strength of the interdot dipolar interaction. Using a detuned laser pulse with an exciton state of the driven quantum dot in our numerical simulations, a direct coherent excitation between the biexciton states can be established, but whether Rabi oscillations can be observed depend mainly on the strength of the dipolar interaction and bandwidth of the excitation laser. When the strength of the dipolar coupling is less than the excitation laser bandwidth, the time-dependent populations of the various two biexciton states of the system exhibit coherent oscillations with several frequencies. However, as we increase the dipolar coupling strength, the population transfer between the quantum dots levels amazingly becomes forbidden, and the excitation gets trapped at the initial state. The reduction of the influence of the dipolar interaction leads to a manipulation of two-photon Rabi oscillation in an ultrashort timescale (∼ps), opening possibilities to achieve ultrafast quantum state control and quantum logic gate generation.

Surfactant-driven optimization of iron-based nanoparticle synthesis: a study on magnetic hyperthermia and endothelial cell uptake.

This work examines the effect of changing the ratio of different surfactants in single-core iron-based nanoparticles with respect to their specific absorption rate in the context of magnetic hyperthermia and cellular uptake by human umbilical vein endothelial cells (HUVEC). Three types of magnetic nanoparticles were synthesized by separately adding oleic acid or oleylamine or a mixture of both (oleic acid/oleylamine) as surfactants. A carefully controlled thermal decomposition synthesis process led to monodispersed nanoparticles with a narrow size distribution. Spherical-shaped nanoparticles were mainly obtained for those synthesized with oleic acid, while the shape changed upon adding oleylamine. The combined use of oleic acid and oleylamine as surfactants in single-core iron-based nanoparticles resulted in a substantial saturation magnetization, reaching up to 140 A m2 kg-1 at room temperature. The interplay between these surfactants played a crucial role in achieving this high magnetic saturation. By modifying the surface of the magnetic nanoparticles using a mixture of two surfactants, the magnetic fluid hyperthermia heating rate was significantly improved compared to using a single surfactant type. This improvement can be attributed to the larger effective anisotropy achieved through the modification with both (oleic acid/oleylamine). The mixture of surfactants enhances the control of interparticle distance and influences the strength of dipolar interactions, ultimately leading to enhanced heating efficiency. Functionalization of the oleic acid-coated nanoparticles with trimethoxysilane results in the formation of a core-shell structure Fe@Fe3O4, showing exchange bias (EB) associated with the exchange anisotropy between the shell and the core. The biomedical relevance of our synthesized Fe@Fe3O4 nanoparticles was demonstrated by their efficient uptake by human umbilical vein endothelial cells (HUVECs) in a concentration-dependent manner. This remarkable cellular uptake highlights the potential of these nanoparticles in biomedical applications.

Quantum droplets with topological textures in a dipolar condensate

We investigate a spin–orbit coupled Bose–Einstein condensate containing both dipolar and non-dipolar components. Combined with Rashba spin–orbit coupling, the competition between contact and dipolar interaction reveals four distinctive exotic phases: droplet lattice phase, stripe phase, oblique stripe phase, and labyrinthine stripe phase. In particular, we adopt a condensate order parameter ansatz to characterize the superstripe phase in a harmonic trap through minimizing the analytical total energy. Furthermore, we find that the energy analysis of the dipolar condensate in the trap uncovers a higher order transition from lattice to stripe phases when contact interaction increases. Our results demonstrate the possibility for physicists to realize a wealth of controllable configurations in spin–orbit coupled dipolar condensates, including droplet lattice with topology and superstripe adjusted by changing the strength of contact and dipolar interactions. The topological phases we predict in this work can be realized by using state-of-the-art techniques in ultracold atomic experiments of chromium, erbium, or dysprosium condensates.

Modelling Conformational Flexibility in a Spectrally Addressable Molecular Multi-Qubit Model System.

Dipolar coupled multi-spin systems have the potential to be used as molecular qubits. Herein we report the synthesis of a molecular multi-qubit model system with three individually addressable, weakly interacting, spin centres of differing g-values. We use pulsed Electron Paramagnetic Resonance (EPR) techniques to characterise and separately address the individual electron spin qubits; CuII , Cr7 Ni ring and a nitroxide, to determine the strength of the inter-qubit dipolar interaction. Orientation selective Relaxation-Induced Dipolar Modulation Enhancement (os-RIDME) detecting across the CuII spectrum revealed a strongly correlated CuII -Cr7 Ni ring relationship; detecting on the nitroxide resonance measured both the nitroxide and CuII or nitroxide and Cr7 Ni ring correlations, with switchability of the interaction based on differing relaxation dynamics, indicating a handle for implementing EPR-based quantum information processing (QIP) algorithms.

A -type antiferromagnetic order in the Zintl-phase insulator EuZn2P2

Zintl phases, containing strongly covalently bonded frameworks with separate ionically bonded ions, have emerged as a critical materials family in which to couple magnetism and strong spin-orbit coupling to drive diverse topological phases of matter. Here we report the single-crystal synthesis, magnetic, thermodynamic, transport, and theoretical properties of the Zintl compound EuZn2P2 that crystallizes in the anti-La2O3 P-3m1 structure, containing triangular layers of Eu2+ ions. In-plane resistivity measurements reveal insulating behavior with an estimated bandgap of Eg=0.11eV. Comparing Eu magnetic ordering temperatures across trigonal EuM2X2 (M=divalent metal, X=pnictide) shows that EuZn2P2 exhibits the highest ordering temperature, with variations in TN correlating with changes in expected dipolar interaction strengths within and between layers and independent of the magnitude of electrical conductivity. These results provide experimental validation of the cytochemical intuition that the cation Eu2+ layers and the anionic (M2X2)2- framework can be treated as electronically distinct subunits, enabling further predictive materials design.

Efficient Continuation Methods for Computing Ground States of Quasi-2D Rotating Dipolar Bose-Einstein Condensates

We study efficient continuation methods for computing the ground state solution of quasi-2D rotating dipolar Bose-Einstein condensates (BECs). First, the highly accurate spectral collocation method is used to discretize the governing Gross-Pitaevskii equation (GPE). Then, we modify the two-level continuation scheme for 3D dipolar BECs described in Jeng et al. (2014) to develop a single-parameter continuation method for quasi-2D rotating dipolar BECs, where the chemical potential is treated as the continuation parameter. Further, by adding the ratio of dipolar interaction strength to contact interaction strength as the second continuation parameter, we propose an efficient two-parameter continuation method which can effectively show the change of the ground-state vortex structures as the dipolar interaction strength gradually increases. Moreover, we also study linear stability analysis for the GPE. Sample numerical results on quasi-2D rotating dipolar BECs are reported.

Tailoring heat dissipation in linear arrays of dipolar interacting magnetic nanoparticles

The main aim of the present work is to analyse the effect of dipolar interaction strength $\lambda$, particle size $D$ and temperature $T$ on the hysteresis mechanism in ordered arrays of magnetic nanoparticles (MNPs) using computer simulations. The anisotropy axes of the MNPs are assumed to have random orientation to mimic the real system. In the absence of thermal fluctuations and dipolar interaction, the hysteresis follows the Stoner and Wohlfarth model irrespective of $D$, as expected. The hysteresis loop area is minimal for particle sizes $D \approx8-16$ nm at $T=300$ K and $\lambda=0.0$, indicating the dominance of superparamagnetic character. Switching magnetic interaction on is able to move the MNPs from superparamagnetic to a ferromagnetic state even at room temperature; therefore, magnetic interaction of enough strength enhances the hysteresis loop area. Interestingly, the hysteresis loop area is significant and is the same as that of Stoner and Wohlfarth particle even $T=300$ K and negligible dipolar interaction for ferromagnetic MNPs ($D>16$ nm). The coercive field $\mu^{}_oH^{}_c$ and blocking temperature $T^{}_B$ also get enhanced with an increase in $\lambda$ and $D$. The rigorous analysis of the coercive field $\mu^{}_oH^{}_c$ vs temperature data also reveals significant deviation from $T^{3/4}$ dependence of $\mu^{}_oH^{}_c$ because of dipolar interaction. The amount of heat dissipated $E^{}_H$ and $\mu_oH^{}_c$ decrease rapidly with $T$ for $D\approx 8-16$ nm and $\lambda\leq0.6$. On the other hand, $E^{}_H$ and $\mu^{}_oH^{}_c$ depend weakly on $T$ with $D>16$ nm, even in the weak dipolar limit. The present work should provide a better understanding of magnetic hyperthermia to researchers working on this subject. For physicists, it would be interesting to test experimentally the results described in this article.

Supersolid phases of lattice dipoles tilted in three dimensions

By means of quantum Monte Carlo simulations we study phase diagrams of dipolar bosons in a square optical lattice. The dipoles in the system are parallel to each other and their orientation can be fixed in any direction in the three-dimensional space. Starting from experimentally tunable parameters like scattering length and dipolar interaction strength, we derive the parameters entering the effective Hamiltonian. Depending on the direction of the dipoles, various types of supersolids (e.g., checkerboard, stripe) and solids (checkerboard, stripe, diagonal stripe, and an incompressible phase) can be stabilized. Remarkably, we find a cluster supersolid characterized by the formation of horizontal clusters of particles. These clusters order along a direction at an angle with the horizontal. Moreover, we find what we call a grain-boundary superfluid. In this phase, regions with solid order are separated by extended defects---grain boundaries---which support superfluidity. We also investigate the robustness of the stripe supersolid against thermal fluctuations. Finally, we comment on the experimental realization of the phases found.