Sedimentary Sequence Research Articles

Датирование современной осадочной толщи краевых бассейнов Восточного Мурмана (Кольский полуостров) на примере губ Ярнышная и Зеленецкая

The authors have studied sediment genesis in the Kola Peninsula bays, the most popular and developed part of the coastal shelf by the population. The main tool used is the method of radioisotope chronology of sedimentary layers based on changes in the specific activity of the natural isotope 210Pb and technogenic 137Cs. It has been revealed that the marginal basins of Murman are characterized by monotonous sedimentation in recent centuries. The average sedimentation rate is 0.15—0.17 cm/year. The sedimentary sequence is composed of silty-pelite-sized material. It has been established that the role of ice rafting in the formation of bottom sediment in coastal bays has decreased over the past centuries.

Delineating aquitard characteristics within a Silurian dolostone aquifer using high-density hydraulic head and fracture datasets

Fractured aquifers are heterogeneous due to the variable frequency, orientation, and intersections of rock discontinuities. A ~100-m-thick Silurian dolostone sequence provides a bedrock aquifer supplying the city of Guelph, Canada. Here, fracture network characteristics and associated influences on hydraulic head were examined using several data types obtained from 24 cored holes in a study that is novel for the quantity and quality of data. High (50–90°) angle joint orientations, heights, and terminations relative to bedding features were determined from acoustic televiewer logs and outcrop scanlines. These data were compared to high-resolution hydraulic head profiles showing head loss over depth-discrete intervals identifying zones with lower vertical hydraulic conductivity. This study reveals that the marl-rich Vinemount Member, traditionally considered the principal aquitard, corresponds to head loss in only 62% of the 24 boreholes. The vertical position of head loss varies across the 90-km2 study area and occurs in any of the lithostratigraphic units of the Lockport Group. Within this sedimentary sequence, aquitards are laterally discontinuous or “patchy” at variable depths and relate to: (1) the frequency of the high-angle joints; (2) shorter joint height; and (3) the type of joint terminations. The head loss occurs in thin (2–2.5 m) intervals where the frequency of the high-angle joints is low. Where a large proportion of small joints cross-cut marl bedding planes, head loss is negligible, suggesting that the vertical hydraulic conductivity is not reduced. Overall, these findings are potentially applicable to assessing aquitard and cap rock integrity in carbonate sedimentary sequences worldwide.

The Origin and Nature of Magnetic Particles From Soils and Sediments Constrained by Hydrodynamics and Geochemistry Around a Tropical Lagoon System

AbstractMagnetic iron oxides are commonly enriched in soils and sediments on Earth's surface. Magnetic properties are widely employed in soil taxonomy, sediment tracing and paleoclimate reconstruction as indicators of associated pedogenic and depositional processes. However, in coastal regions, frequent shifts in pedogenesis and diagenesis accompanied by changes in hydrodynamic and geochemical conditions from land to sea can influence the formation and preservation of magnetic particles in sediment sequences. To discern the origin and nature of magnetic particles driven by these processes, we systematically examined soils and sediments around a tropical lagoon that has been closing for two hundred years. We found that the finest superparamagnetic particles are enriched along with hematite from inland soils with high‐Fe and high‐Al backgrounds, which was driven by pedogenesis. Single‐domain ferrimagnetic particles are enriched along with amorphous iron oxides in the lagoon with high‐Mg and high‐Mn backgrounds, which was driven by early diagenesis in quiet and reducing depositional environments. Coarse titanomagnetite particles are strongly enriched in inshore sediments with high‐Si and high‐Ti backgrounds, which was driven by seawater elutriation. However, magnetic particles in barrier bar soils have mixed features depending on the neighboring environment. Identifying magnetic particles derived from different soils and sediments in tropical coastal regions can assist in tropical coastal paleoclimate and paleoenvironment reconstruction on the basis of magnetic properties along coastal sediment sequences.

Episodic fluid charging and mixing triggers calcite-bearing agates in the Permian Emeishan Basalt, SW China

ABSTRACT Agate, a distinctive form of banded chalcedony, derives its characteristic appearance from the deposition of silica and the presence of impurities. A significant variety of agate-bearing calcite was identified in the Permian Emeishan Basalt located in the southwestern Sichuan Basin. This calcite-bearing agate provides valuable insights into the complex interplay and evolution of fluids and minerals. This study aims to provide a detailed description and analysis of the microscopic textural and geochemical characteristics of the agate, while elucidating the sequence of mineral deposition, fluid properties, and the genetic mechanism underlying its formation. The findings reveal that the agate primarily consists of lamellar calcite and banded chalcedony, exhibiting a variety of textures, thicknesses, and colours. Through the analysis of the transformation and precipitation of epidote and allanite, and the identification of four types of calcites and five micro-silica textures, it has been confirmed that the early stage of fluid in geodes involved the mixing of meteoric water with post-magmatic hydrothermal fluid. The middle and late stages involve the mixing of magmatic-hydrothermal fluid with organic-acid fluid. The charging of silica-rich hydrothermal fluids and the generation of hydrocarbons from organic matter cause fluctuations in SiO2 concentration, pH, and crystallization rates, contributing to the diversity of silica minerals, such as chalcedony and quartz. The interlayered growth observed between chalcedony and calcite is attributed to secondary metasomatism, which occurs after the dehydration and transformation of chalcedony due to increasing temperatures. Notably, the internal texture of the agate is somewhat influenced by pressure variations caused by the episodic charging of the fluid.

Mineralisation controls for the diverse Cape manganese occurrences, South Africa

Abstract The Cape Fold Belt, comprising folded sedimentary sequences from predominantly the Palaeozoic Cape Supergroup, hosts a multitude of manganese occurrences and mineral deposits, many of which were subject to historical mining activity. Although size, grade and quality issues negate their modern-day exploitation for the steel-making process, the mechanisms by which Mn has enriched at these sites holds scientific value for our understanding of low-temperature Mn (bio-)geochemical cycling. Deposits located within the Cape Fold Belt comprise structure-hosted Mn deposits and a little described class of Mn mound deposits associated with chalybeate thermal springs (temperature = 41 to 48°C). Although the relationships between the two remain tenuous, detailed study of both classes provides insight into the conditions that favour Mn accumulation in the near-surface and sub-aerial environments. Comparisons between the physicochemistry of manganiferous- and non-manganiferous thermal springs suggest that manganese solubility is favoured by warm, acidic and slightly reducing fluids with elevated salinity. Transport, and associated fluid focusing typically within highly permeable sandstone units, serves to locate Mn mineralisation in near-surface structurally-complex trap sites that provide both accommodation space and conditions that are sufficiently oxidising. Where manganiferous spring waters spill out at surface, oxidation is caused by contact with atmospheric O2 to form Mn mound deposits, and ambient Mn-oxidising microbiota (e.g., genus Ramlibacter, and members of Burkholderiales, Rhodocyclaceae, and Oxalobacteraceae) are likely to play a role in enhancing the kinetics of this process. Relative to the structure-hosted deposits, these Mn mound deposits are typically lower grade (higher iron content) and relatively friable (high porosity and fine grain sizes). Supergene and diagenetic processes can lead to localised upgrade of the Mn mound material, although typically not to ore grade.

Depositional, stratigraphic and structural controls on the geometry of Montney Formation reservoirs: Lower Triassic, northeast British Columbia, northwest Alberta

Abstract The Lower Triassic Montney Formation is a world-class unconventional hydrocarbon reservoir that spans the border of northeast British Columbia and northwest Alberta. Integrated sedimentological and ichnological analyses suggest that the Montney Formation was deposited in a predominantly prodeltaic setting that was commonly influenced by both river flood and storm processes. Riverine processes include the local occurrence of normally- and inversely-graded siltstone and sandstone interbeds, interpreted as the record of sediment-laden hyperpycnal flows. Episodic storms are recorded by the local occurrence of hummocky cross-stratified interbeds, as well as normally graded, parallel and wave-ripple laminated beds, which are commonly draped by structureless carbonaceous mudstones. These mudstone drapes represent river-flood-derived fluid muds that collapsed from hypopycnal plumes following the passage of the storms and suggest the intimate linkage between storms and heightened fluvial discharge. The basin in which the Montney Formation was deposited began as three sub-basins, northern, central and southern, each of which experienced different patterns of subsidence and uplift that varied both spatially and temporally during sedimentation. Subsidence of the northern sub-basin was compartmentalized by deep seated faults that provided accommodation for the basal sequence of the Montney Formation, Sequence 1. Subsequent fault movement resulted in reduced accommodation in the northern sub-basin and accelerated subsidence in the central sub-basin, providing accommodation for deposition of Sequence 2, the basal sequence in the central sub-basin. The northern sub-basin remained paleotopographically elevated throughout deposition of Sequence 2 and early Sequence 3 successions, and these younger units did not extend beyond the northern limit of the central sub-basin. During subsequent deposition of the late Sequences 3 and Sequence 4 successions, compartmentalization between the north and central sub-basin was greatly reduced and these intervals were deposited relatively more uniformly along-strike. The unconventional and conventional reservoirs in both the northern and central sub-basins occur at the scale of systems tracts within the four depositional sequences of the Montney Formation. Reconstructing the depositional history of the component systems tracts of Sequence 1 through early Sequence 3 reveals the dynamic interplay between syndepositional tectonism, fluctuating relative sea-level and deltaic depositional processes in controlling the character, geometry and distribution of prolific Montney Formation reservoirs. The recognition of these key geological controls enhances predictability in this valuable resource and may be applicable to other fine-grained reservoirs elsewhere.

Stratigraphic-chemostratigraphic assessment of early dolomitization and associated phosphogenesis of the Ediacaran-Cambrian Salitre Formation, Irecê Basin, Brazil

During the Precambrian − Cambrian transition, the occurrence of phosphogenesis and the rise in atmospheric oxygen levels are closely linked to the proliferation of life. However, the mechanisms associated with these phenomena and their underlying causes are not well understood. The Irecê Basin represents the remnants of intracratonic marine environments that document the Neoproterozoic sea flooding of West Gondwana. This study presents an integrated analysis of sedimentary facies and chemostratigraphy through high-resolution sampling of pristine limestones and dolomites from the Salitre Formation in east-central Brazil. The aim is to explore the relationship between environmental settings and phosphatized stromatolites by combining detailed facies descriptions with isotopic and geochemical data. A total of fifteen lithofacies types are identified and grouped into seven major facies associations. These associations reveal a depositional stacking pattern defined by flooding surfaces and transgressive–regressive cycles, allowing for the division of the Salitre Formation into two depositional sequences. The basal sequence includes sedimentary phosphorite deposits intimately associated with widespread dolomitization levels at the top. Here, we describe a combination of two major processes for the dolomitization model of the Salitre Formation, with a contribution of evaporative environment settings related to a sabkha, and the influence of a meteoric mixing zone. Furthermore, three stages of phosphogenesis have been identified, with two of them interpreted as early diagenetic deposition associated with stromatolites and early cementation, and the last one associated with a late stage of phosphogenesis. The combined analysis of REY patterns, 87Sr/86Sr ratios, and geochemical results suggests a significant continental influence on both dolomitization and phosphogenesis. The identification of depositional settings and stratigraphic patterns for these deposits is crucial for the understanding of phosphogenesis during the Ediacaran, which may have been influenced by the continentalization of the marine environments forced by the intracratonic marine setting and the tectonic evolution at the end of the Neoproterozoic Era.

Lime reactivity and overburning: the case of limestones belonging to Tuscan Nappe sequence (NW Tuscany, Italy)

This study examines limestone properties and calcination process to enhance product quality. Limestone burning produces lime (CaO, calcium oxide) and carbon dioxide (CO2). Lime is a substance highly reactive and turns into slaked lime (Ca(OH)2, calcium hydroxide) when exposed to water. Six limestone samples from Tuscan Nappe sedimentary sequence, outcropping in the Monti d’Oltre Serchio area (NW Tuscany, Italy), were selected and calcined at different temperatures (800, 900, 1000 and 1100 °C). The obtained lime was slaked, and chemical, mineralogical and petrographic analyses were conducted to study its reactivity during slaking process. Key factors influencing lime reactivity were identified: calcination temperature/time and limestone characteristics (chemical and mineralogical composition). The lime reactivity was measured through the rate of lime hydration reaction. Results showed that higher reactivity in lime, lower calcination temperature. The increase in temperature and time leads to an increase of CaO grain size and, consequently, to a decrease in reactivity. Temperature increase has a more significant effect on the increasing of grain size and reactivity than time. The optimal calcination temperature was found to be 900 °C, like that of ancient limekilns. The study emphasized the close link between lime reactivity and chemistry/mineralogy of limestone. Overall, the research provides insights for improving limestone calcination processes and obtaining superior products.

Late Quaternary history of the Kerch Strait — the stratotype region for the Black Sea

The Kerch Strait has periodically connected to the Black, Azov, and Caspian seas throughout its Late Quaternary history. The strait's deposits reflect the changes in the natural environment of the entire Ponto-Caspian region, which are a response to global climate change. Several studies have been done on the region's stratigraphy, biostratigraphy, geomorphology, and paleogeography. However, most of the current knowledge about the paleogeography of the area is based on the analysis of empirical data collected more than 25 years ago, and due to the lack of detailed geochronological studies, many palaeogeographical problems remain unresolved.This paper presents a reconstruction of environmental change in the Kerch Strait during the Late Quaternary. The reconstruction is based on the results of a comprehensive study of the sedimentary sequences in the Kerch Strait carried out by the author and colleagues over the past ten years. The study examines the deposits of two stratotype sections of the Karangatian (Eemian) transgression and the four boreholes’ sections in Tuzla Island in the central part of the strait.A biostratigraphic division of the Upper Quaternary deposits of the Kerch Strait was carried out based on a malacofaunal study. Mollusc assemblages corresponding to various paleogeographic stages of development were identified, and their paleoecological characteristics were described. Luminescence and radiocarbon ages made it possible to determine the time intervals of established paleogeographic stages in the strait's history. Detailed luminescence dating of the Karangatian transgression sediments of the Eltigen and Tuzla stratotype sections has been carried out for the first time.Six main stages in the Kerch Strait natural environment development were established in the Late Quaternary and correlated with global and regional climatic events: Karangatian, with three stages (MIS 5e-c); Tarkhankutian (MIS 5a); Post-Karangatian (MIS 4); Surozh (MIS 3); Neoeuxinian, with two stages (MIS 2); and Chernomorian (MIS 1). Two episodes of the Caspian waters flowing through the Kerch Strait into the Black Sea were identified in MIS 5c and at the end of MIS 2.

ESR chronology of the Quaternary sedimentary sequence of the Shinaimiao borehole in Hebi City, Henan Province, China

It is very important to distinguish the strata of different periods in the Quaternary period, especially the Middle Pleistocene and Late Pleistocene strata, for stratigraphic division, depositional environmental analysis and climate evolution analysis. In this study, the Shinaimiao (SNM) borehole sequence in Hebi City, Henan Province (China) was established by both electron spin resonance (ESR) and magnetostratigraphy methods. Both Al (eighteen samples) and Ti-Li (eight out of the eighteen samples) centers were measured using the Multiple Aliquots Additive Dose (MAAD) method. In addition, hundreds of magnetostratigraphic samples were measured to determine the precise position of the Matuyama/Brunhes (M/B) boundary. The results show that: (1) The equivalent dose (DE) values of the Al and Ti-Li centers are consistent within the error range, demonstrating that the Multiple Center (MC) approach has worked. (2) The ESR dating results are consistent with the order of sedimentation (the ages get older with depths) and with magnetostratigraphic results of the B/M boundary within the error range, indicating that the ESR ages obtained from the Al and Ti-Li centers are reliable in this study. (3) By comprehensive analysis of the dating results and lithology characteristics, the stratigraphic ages of the SNM borehole with a depth of 126.93 m spans from Neogene to Holocene, but part of the early Pleistocene strata are missing.

River profile and relict landscape analysis reveal the Cenozoic geomorphic evolution of the Nihewan Basin in North China

The Nihewan Basin, renowned for the numerous world-class Paleolithic sites and diverse mammalian fauna preserved in its sedimentary sequence, is a key area for studying early human evolution in East Asia. Despite extensive studies on the fluvial-lacustrine basin sediments, the evolution and formation process and mechanism of the Nihewan Basin and Nihewan Paleolake remain unclear. Here we assess the spatial pattern and recent history of rock uplift of the Liuleng Shan, one of the main bedrock mountain ranges encompassing the Nihewan Basin, using river profile and topographic analysis. The transient topography of the Liuleng Shan is characterized by two generations of elevated non-lithological slope-break knickpoints that delimit the uplifted Dianziliang and Tangxian relict landscape surfaces, suggesting two episodes of accelerated rock uplift during the Cenozoic. We link the first phase of rapid rock uplift to the initiation of the central and northeastern portions of the North Liuleng Shan Fault (NLSF) during the opening of the Shanxi Graben System in the Late Miocene, implying the initiation of the Nihewan Basin at this time. We propose that the dextral transtensional southwestern portion of the NLSF formed and propagated northeastward at around 4.2 Ma, and was responsible for the second phase of surface uplift. This phase of deformation also terminated the Tangxian planation process and led to the further subsidence of the Nihewan Basin. Accordingly, drainage rearrangement and fault activity hydrologically closed the Nihewan Basin, resulting in the development of the Nihewan Paleolake. Our findings outline a timeline for the geomorphic evolution of the Nihewan Basin and Nihewan Paleolake, highlighting the dominant role of tectonics in their formation.

A climate change from icehouse to greenhouse following Huronian glaciation: Evidence from long-term storm deposits of the Paleoproterozoic Hutuo Group in the North China Craton

The Hutuo Group was deposited from 2.14 to 2.0 Ga in Wutai Mountain, North China Craton. This group is composed of the Doucun and Dongye subgroups, which are likely contemporaneous heterotopic facies. The Hutuo Group displays well-known positive to negative drifts of inorganic carbon isotopes, large-scale stromatolitic carbonates, and red beds in epigenetic environments. Twelve storm-deposited lithofacies were identified in the Dongye Subgroup, which changes from sandstones, siltstones, and mudstones of the Qingshicun and lower Wenshan formations to carbonates of the upper Wenshan, Hebiancun, Jian’ancun, Daguanshan, Huaiyincun, Beidaxing, and Tianpengnao formations from bottom to top. The above sedimentary sequence transformation indicates a gradual transformation from terrigenous storm deposits in the Qingshicun and Wenshan formations to endogenous or mixed-source storm deposits in the Hebiancun, Jian’ancun, Daguanshan, and Huaiyincun formations. Additionally, coastal and shallow-marine storm deposits are revealed from sedimentary structures, including hummocky cross-stratification, intraclasts or boulder clays exhibiting radial or chrysanthemum-shaped stacking, and sinuous or torn stromatolites. These storm deposits, occurring with oolitic and stromatolitic carbonates of mid-low latitudes or tropical-subtropical zones, are characterized as tropical storm deposits. Based on reported ages, we propose that such tropical storms started from ca. 2.1 Ga and lasted for over 40 Myr. The long-term storm deposits indicate high temperatures and intense water circulation during the greenhouse climate. A climate change from icehouse to greenhouse is also evident by the extensive distribution of carbonates, evaporates, and organic-rich shales above the glacial diamictites in multi-cratons, and was probably driven by the transformative evolution of the atmosphere.

Fabrication of TC4 and Ti48Al bimetals by plasma arc additive manufacturing： Microstructure and mechanical properties

Plasma arc additive manufacturing (PAAM) was applied to fabricate TC4 and Ti48Al (gamma titanium aluminide) bimetals in this work. The impact of deposition sequence on the microstructure and mechanical properties of two groups of bimetals (TC4-Ti48Al, first deposited TC4, then Ti48Al; Ti48Al-TC4, first deposited Ti48Al, then TC4) was investigated. The results show that the ultimate tensile strengths of two groups of bimetals exhibit significant differences, with 158.4 MPa for TC4-Ti48Al and 232.3 MPa for Ti48Al-TC4, the reason for this disparity is the difference in microstructure at the transition zone, which is attributed to heat input and Marangoni convection. The phase transformation evolution of TC4-Ti48Al transition zone is (major α2 + minor α)→ (major α2 + minor γ) → (major γ + minor α2), and (major α2 + minor α) → (major α + minor α2) for Ti48Al-TC4. The formation mechanism of transition zones and relationship between the microstructure characteristics and mechanical properties of two groups of bimetals were further discussed. Overall, the property of Ti48Al-TC4 was superior, and this work provides a promising new method for the preparation of TC4 and Ti48Al bimetals.

STRUCTURE AND FORMATION OF MUD VOLCANOES IN THE SOUTH CASPIAN BASIN ACCORDING TO SEISMIC DATA

The South Caspian Basin (SCB) constitutes a classic province to study mud volcanoes and their associated processes. About 280 active mud volcanoes have been documented in the offshore and the onshore areas of Azerbaijan, emitting water, hydrocarbons (oil and mainly methane), and fluidized muds that transport solid fragments from deep sedimentary sequences. Seismic characteristics of mud volcano systems in the Azerbaijan area of the SCB are used to address: (1) the nature of the mud volcano source layer, (2) the internal geometry of the feeder systems, and (3) the processes associated with shale mobilization and extrusion. We confirm that the source layer is mainly the Maykop Suite (Oligocene–Lower Miocene), which is a thick (up to 3 km) and deep (>10 km) clayey sequence rich in organic matter. This layer was quickly buried due to basin subsidence and the rapid deposition (since the Middle Miocene) of thick fluvio-lacustrine sediments of the Productive Series (Upper Miocene–Upper Pliocene), which contributed to the creation of high pore pressures and the transformation of organic matter into methane (through thermal cracking). Since the Middle Miocene, and more importantly during the Upper Pliocene, the Maykop shales mobilized due to an increase in shear stresses and pore pressures, which promoted a decrease in effective stresses and, as a consequence, facilitated the achievement of critical state conditions in the shales that began to flow. This process repeated over time, allowed multiple pulses of shale mobilization to originate (as in a loading piston system). Shale piercing transporting deep-sourced fluids (and hydrocarbons) was carried out through fractures in the outer arc of anticlines, forming subvertical feeder systems. The mobilized hydrocarbons and fluids also recharged some of the younger and more permeable layers of the Productive Series, creating shallower reservoirs in the vicinities of the mud volcano structures.

Sedimentology and stratigraphy of lower Cretaceous fluvial to shallow marine deposits on the central Atlantic passive margin: The Aaiun-Tarfaya Basin, Morocco

This paper presents the first integrated regional outcrop-based sedimentological study of the northern Aaiun-Tarfaya Basin located in Morocco (NW Africa). The Lower Cretaceous Tan-Tan Formation has been subdivided into six new members and placed within a sequence stratigraphic framework that includes two incomplete depositional sequences. Strong thickness variations of individual lithostratigraphic units from north to south suggest differential subsidence during sedimentation and/or the existence of major topography on the basal unconformity that the succession onlaps. The results provide valuable insights into the timing of local tectonics in the Western Anti-Atlas and the control on the evolution of the sedimentary system. Deposition of each of these six units is interpreted to be the result of a complex interplay between an overall eustatic sea-level rise during the early Cretaceous, sediment delivery controlled by tectonic movements in the Western Anti-Atlas and Reguibat Shield and periods of differential subsidence in the basin. The results document the style of evolution of a back-stepping wave-dominated system feeding into the Central Atlantic during the passive margin phase. The improved facies and depositional models together with improved understanding of the evolution of the delta have significant implication for exploring the deep-water equivalents offshore.

Topology Selectivity of a Conformationally Flexible Precursor by Selenium Doping

Conformational arrangements within nanostructures play a crucial role in shaping the overall configuration and determining the properties, for example in covalent/metal organic framework (COF/MOF) synthesis. In on-surface synthesis, conformational diversity often leads to uncontrollable or disordered structures. Therefore, exploration on controlling and directing the conformational arrangements is significant in achieving desired nanoarchitectures. In this study, a conformationally flexible precursor 2,4,6-tris(3-bromophenyl)-1,3,5-triazine (mTBPT) was employed, and a random phase consisting of C3h and Cs conformers was first obtained after deposition of mTBPT on Cu(111) from room temperature (RT) to ~365 K as expected. By low coverage (0.01 ML) selenium (Se) doping, we achieved the selectivity of the C3h conformer greatly and improved the nanopore structural homogeneity. The ordered 2D metal organic nanostructure from mTBPT could be fulfilled by Se doping from RT to ~365 K, and the deposition sequence of mTBPT and Se did not make any difference. Through the combination of high-resolution scanning tunneling microscopy and non-contact atomic force microscopy, we explored the regulation of the conformationally flexible mTBPT on Cu(111) and achieved the high topology selectivity by low coverage Se doping. Density functional theory calculations revealed the energy regulation of organometallics before and after Se doping at atomic level. These results could enrich the on-surface synthesis toolbox of conformationally flexible precursors, for the design of complex nanoarchitectures, and for future development of engineered nanomaterials and nanodevices. Figure 1

Innovative imaging of iron deposits using cross‐gradient joint inversion of potential field data with petrophysical correlation

AbstractThis study demonstrates the application of the cross‐gradient joint inversion method to investigate iron mineralization zones within a volcano‐sedimentary environment. The presence of minerals with intense contrasts in density or magnetic susceptibility, such as hematite or magnetite, facilitates modelling the distribution of ore bodies with depth. Our approach involves establishing a unified interpretation of reconstructed density and susceptibility models through both independent and joint inversion with sparsity regularization in conjunction with a petrophysical model resulting from core data. This approach provides an ideal strategy to uncover the realistic geologic setting of iron ore deposits. We initially simulated a synthetic model closely resembling real‐case scenarios to assess the efficacy of the cross‐gradient joint inversion algorithm in comparison to independent inversion. Subsequently, the inversion algorithms were implemented on gravity and magnetic data, collected over an area of 500 × 600 m2 in Shavaz iron‐bearing deposits located in the central Iranian block. The primary iron oxide–apatite type mineralization in the study area is associated with the Nain–Dehshir–Baft fault as a NW–SE trending strike‐slip fault. Although both inversion methods yield satisfactory models, incorporating the cross‐gradient constraint in joint inversion resulted in a more constrained delineation of iron–oxide ore deposits in the fault system. This improvement facilitates the differentiation between hematite and a small percentage of magnetite, providing a more accurate estimation of ore depth. Inversion results suggest that the magnetite mineralization is coated with extensive hematite mineralization and both are positioned relatively within the same depth interval, covered by approximately a 15–25 m sequence of sediments.

The Paleoproterozoic Trans-Australian Orogen: Its magmatic and tectonothermal record, links to northern Laurentia, and implications for supercontinent assembly

The 2.1−1.79 Ga Trans-Australian and Canadian Trans-Hudson orogens preserve a common record of Himalayan-scale orogenesis and voluminous Cordilleran-style magmatism behind which turbidite-dominated sedimentary sequences evolved in a backarc or retroarc foreland setting. Successive cycles of subduction retreat and advance drove the orogenic process, culminating in continent-continent collision and closure of a shared and formerly contiguous ocean basin—the Paleoproterozoic Diamantina and Manikewan oceans. Cordilleran-style arc magmatism in proto-Australia commenced along the southern reaches of the Diamantina Ocean with emplacement of the 2005−1975 Ma Dalgaringa Batholith along the leading edge of the Pilbara Craton (Gascoyne Province) before both it and its host craton docked against the Yilgarn Craton, resulting in the Glenburgh Orogeny. After a brief episode of post-kinematic granitic magmatism from 1965 Ma to 1945 Ma, tectonic activity switched to the opposing margin of the Diamantina Ocean in what is now northern Australia, where three more cycles of upper plate orogenesis and Cordilleran-style magmatism occurred from 1890 Ma to 1850 Ma, 1840 Ma to 1810 Ma, and 1810 Ma to 1760 Ma along a convergent continental margin extending from the Kimberley and Pine Creek regions southward through the Mount Isa domain into the eastern Gawler Craton. Batholiths developed along this margin include granites of both low- and high-Sr/Y composition, with the more adakitic varieties interpreted to have been intruded during periods of enhanced asthenospheric upwelling accompanying the opening of one or more slab windows following slab breakoff, tearing, and/or subduction of an actively spreading oceanic ridge. Terminal collision between the North and South Australian (Mawson) cratons at ca. 1790 Ma brought this succession of subduction-related events to a close, although neither this event nor the corresponding Trans-Hudson Orogen need equate to final assembly of the Nuna supercontinent. Instead, the 1870 Ma peak in global compilations of magmatic and detrital zircon ages may be interpreted more simply as the result of elevated tectonism and magmatism along a Paleoproterozoic Cordilleran-style continental plate margin that was transcontinental in scale and continued uninterrupted from proto-Australia into northern Canada and beyond.

Holocene ecosystem and temperature development inferred from invertebrate remains in Zminje Jezero (Dinaric Alps, Montenegro)

AbstractLake Zminje Jezero (1535 m a.s.l.) in Montenegro was studied for chironomid and other aquatic invertebrate remains in a sediment sequence dating back to 12,000 calibrated 14C years before present (cal yr BP), providing, to our knowledge, the first lake-sediment record studied for chironomids and other associated chitinous aquatic invertebrate remains in the Dinaric Alps. Changes in chironomid and other invertebrate remains along the record make it possible to constrain changes of relevant environmental variables for aquatic invertebrates in the lake including temperature, oxygen availability, trophic status and water depth. The results suggest moderate changes in trophic conditions with chironomid assemblages indicating meso- to eutrophic conditions during the analysed interval. Invertebrate assemblages were typical for lakes with relatively high oxygen availability with a minor trend during the middle to late Holocene to conditions observed in lakes that are more hypoxic. A change in temperature is suggested in the earlier part of the record when the share of chironomid taxa adapted to warmer conditions increased, at the Younger Dryas to Holocene transition, whereas later no particularly pronounced shifts in temperature-sensitive taxa were observed. July air temperatures were estimated based on chironomid assemblages using a transfer function based on calibration data consisting of 117 lakes sampled in the Swiss Alps and northern Switzerland. The results suggest that temperatures rapidly increased by 5 °C at the onset of the Holocene (11,500 cal yr BP) leading to a relatively warm early to mid-Holocene and thereafter slightly decreased during the late Holocene. Reconstructed temperatures are discussed together with a previously published pollen record for our study site and are broadly consistent with other chironomid-based temperature reconstructions from Central, Eastern and Southern Europe. From ca. 3000 cal yr BP sedimentation rates increased and from ca. 500 cal yr BP onwards pollen data suggest that the vegetation and lake catchment were affected by human activities, possibly influencing chironomid and other invertebrate assemblages in the lake and thereby also reconstructed temperatures. Overall, our results show that combining analyses of chironomid and other invertebrate assemblages can provide valuable insights into long-term environmental changes and can provide temperature reconstructions for small mountain lakes in the Balkans, such as Zminje Jezero.

Orbital forcing and paleoenvironmental changes across the upper Ordovician glaciation-lower Silurian hot shale in the Risha gas field, northeast Jordan

This paper presents a comprehensive analysis of sedimentary successions and paleoenvironmental indicators in two wells, Rh3 and Rh46, located in NE Jordan, within the context of the Ordovician-Silurian boundary transition. By integrating spectral analysis, cyclostratigraphy and sedimentary architecture, significant shifts and cyclical patterns are identified, shedding light on paleoenvironmental changes and orbital forcing dynamics. The study reveals distinct lithological and geochemical signatures at the Risha/Mudawwara (Hirnantian/Rhuddanian) boundary, indicative of major shifts in depositional environments. Analysis of Milankovitch cycles suggests orbital forcing as a driver of sedimentary cyclicity, with implications for understanding climatic variations during the Ordovician-Silurian transition. Spectral analysis revealed significant cycles with different periodicities. Testing the sediment accumulation rates (SAR) revealed an optimum SAR at 5.9 and 4.6 cm/kyr in Rh3 and Rh46 wells, respectively. A new refined astronomical time scale (ATS) is created based on the 100 kyr eccentricity cycle. The new ATS assigns the Risha Formation to the Hirnantian age and revealed a probable time gap at the base of Risha Formation of about 0.3 myr in Rh46 well; deposition of the Risha Formation commenced at 444.88 myr and 444.58 myr in Rh3 and Rh46 wells, respectively, with sedimentation continuing up to the Ordovician/Silurian boundary at 443.07 myr. The Ordovician/Silurian transition experienced shortening in the obliquity and precession cycles. The tuned data show that the 41, 36 and 31 kyr obliquity cycles, in addition the 21, 19 and 16 kyr precession cycles, were recognised. Furthermore, 740, 425, 250, 147 and 100 kyr eccentricity cycles were also recognised. Notably, the study identifies the glacial/fluvioglacial Risha Formation is bounded by g4-g3 eccentricity nodes coinciding with Hirnantian stage boundaries that correspond to significant geological events, such as the Late Ordovician Mass Extinction and the Hirnantian glaciation events. The g4-g3 eccentricity cycle is estimated to be 1.8 myr. Surprisingly, the lower Silurian OAE coincided with the g4-g3 eccentricity node at the Ordovician/Silurian transition. Additionally, the application of DYNOT modelling has elucidated sea-level fluctuations and their relationship with sedimentary sequences, highlighting the role of tectonic and climatic factors in shaping the sedimentary architecture. Furthermore, the investigation of Th/U and Th/K ratios provides insights into marine and terrestrial depositional settings.