Mineralisation controls for the diverse Cape manganese occurrences, South Africa

Abstract

Abstract The Cape Fold Belt, comprising folded sedimentary sequences from predominantly the Palaeozoic Cape Supergroup, hosts a multitude of manganese occurrences and mineral deposits, many of which were subject to historical mining activity. Although size, grade and quality issues negate their modern-day exploitation for the steel-making process, the mechanisms by which Mn has enriched at these sites holds scientific value for our understanding of low-temperature Mn (bio-)geochemical cycling. Deposits located within the Cape Fold Belt comprise structure-hosted Mn deposits and a little described class of Mn mound deposits associated with chalybeate thermal springs (temperature = 41 to 48°C). Although the relationships between the two remain tenuous, detailed study of both classes provides insight into the conditions that favour Mn accumulation in the near-surface and sub-aerial environments. Comparisons between the physicochemistry of manganiferous- and non-manganiferous thermal springs suggest that manganese solubility is favoured by warm, acidic and slightly reducing fluids with elevated salinity. Transport, and associated fluid focusing typically within highly permeable sandstone units, serves to locate Mn mineralisation in near-surface structurally-complex trap sites that provide both accommodation space and conditions that are sufficiently oxidising. Where manganiferous spring waters spill out at surface, oxidation is caused by contact with atmospheric O2 to form Mn mound deposits, and ambient Mn-oxidising microbiota (e.g., genus Ramlibacter, and members of Burkholderiales, Rhodocyclaceae, and Oxalobacteraceae) are likely to play a role in enhancing the kinetics of this process. Relative to the structure-hosted deposits, these Mn mound deposits are typically lower grade (higher iron content) and relatively friable (high porosity and fine grain sizes). Supergene and diagenetic processes can lead to localised upgrade of the Mn mound material, although typically not to ore grade.