Sedimentary Sequence Research Articles

Cooperative Use of N-Heterocyclic Carbenes and Thiols on a Silver Surface: A Synergetic Approach to Surface Modification.

Surface modification through the formation of a self-assembled monolayer (SAM) can effectively engineer the physicochemical properties of the surface/material. However, the precise design of multifunctional SAMs at the molecular level is still a major challenge. Here, we jointly use N-heterocyclic carbenes (NHCs) and thiols to form multifunctional hetero-SAM systems that demonstrate excellent chemical stability, electrical conductivity, and, in silico, catalytic activity. This synergistic effect is facilitated by the high surface mobility and electron-rich nature of NHCs, combined with the strong binding strength of thiols. Scanning tunneling microscopy, electrical conductivity, and scanning electron microscope measurements, as well as density functional theory calculations, were employed to explore the synergistic interactions in the supramolecular SAMs. The van der Waals integration of ballbot-type NHCs and thiols enables the SAMs to exhibit both superior surface anticorrosion properties (attributing to the shift in the d-band center) and low surface resistance originating from the band alignment. Moreover, we find that the deposition sequence of flat-lying NHCs and thiols results in SAMs with different configurations, which can further tune the mechanistic pathway in silico in the acetylene hydrogenation process. Our results provide essential molecular insights into the local electronic control of the new SAM/metal interface and the high stability of the emergent multifunctionality (NHC/thiol)-SAMs forming self-assembled lamellae structures in the nanometer regime.

First discovery of Antarctic amber

Here, we report the first discovery of Antarctic fossil resin (commonly referred to as amber) within a ~5 cm-thick lignite layer, which constitutes the top part of a ~3 m-long palynomorph-rich and root-bearing carbonaceous mudstone of mid-Cretaceous age (Klages et al.2020). The sedimentary sequence (Fig. 1) was recovered by the MARUM-MeBo70 seafloor drill rig at Site PS104_20 (73.57° S, 107.09° W; 946 m water depth) from the mid-shelf section of Pine Island trough in the Amundsen Sea Embayment, West Antarctica, during RV Polarstern Expedition PS104 in early 2017 (Gohl 2017; Fig. 1a). So far, amber deposits have been described from every continent except Antarctica (Langenheim 2003, Quinney et al. 2015; Fig. 1a).

High-resolution cyclic framework for the Songliao Basin in northeastern China, and its implications for sedimentation and organic matter enrichment

The study of fine-grained sedimentation has consistently concentrated on investigating the mechanisms and principles governing the enrichment of organic matter. However, the lack of unified stratigraphic framework has always existed as fine-grained sedimentation covers two distinct grain-size grades, namely, mud and silt, which has impeded the progress of subsequent production research. This study exemplified this issue by analyzing the first member of the Qingshankou Formation in the southern Songliao Basin. We established reconstructed gamma and density curves that mitigated filter noise interference, integrated high-resolution sequence results with astronomical cycle divisions, and created a high-frequency isochronous stratigraphic framework for clastic fine-grained sedimentation by leveraging the weak sensitivity of sandstone density curves and the robust stability in eccentricity cycle extraction. This approach addresses the inconsistencies in stratigraphic division methodologies and mismatched outcomes stemming from the use varying techniques to delineate mud and silt components within clastic fine-grained sedimentary sequences. Furthermore, it elucidates how tectonic-scale variations in sediment supply coupled with potential accommodation changes dictate macroscopic stacking patterns within strata, whereas climate fluctuations on orbital time scales govern sand-mud progradation degrees within these layers, culminating in periodic rhythmic characteristics characterized by vertical sand-mud interbedding. A model for stratigraphic development pertaining to lake delta systems constrained by a “synchronous heterotopy” paradigm is proposed for the southern Songliao Basin. The organic matter enrichment pattern aligns with its filling dynamics, indicating an “overfilling” type developmental pattern at lower strata levels where organic material predominantly originates from terrestrial plant debris external to the basin; this material accumulates primarily within silty zones along layers—with areas exhibiting heightened enrichment values slightly lagging behind short-eccentric maxima positions. In contrast, under an upper “balanced filling” type developmental framework, sources of organic matter are derived both internally and externally relative to the basin—exhibiting substantial heterogeneity—and regions marked by elevated organic matter concentrations are directly associated with locations identified as short-eccentric maxima.

The Central American Seaway: Do Magdalena Flocs Mimic Deep Water Neodymium?

A common assumption for the interpretation of seawater Neodymium isotopes is that the signal is a mixture of distally advected waters. A review of the local paleogeography and bedrock Nd isotopic composition (n = 712) of the largest drainage basins of the Caribbean Sea shows: (a) unradiogenic sedimentary and crystalline sequences in the cratonic-derived eastern Andes; (b) very radiogenic sequences in the western Andes and Panama Isthmus; and (c) intermediate values in between them (Cauca River drainage basin). These local signatures can be matched to the Miocene-Pliocene record of Ocean Drilling Project sites ODP-998, 999, and 1000, dating the arrival of major inter-Andean drainages to the Caribbean Sea. The birth of the Atrato River at 15 Ma, following closure of the Central American Seaway, delivered very radiogenic Nd isotopes to the Caribbean Sea (εNd: +5.5), while arrival of Magdalena River waters at 11 Ma brought very unradiogenic values (εNd << −8). Later excavation of the Cauca River canyon at ∼7 Ma added a moderately radiogenic source (εNd: +1.9), modulating Magdalena River signatures to the Caribbean Sea. Flocculates forming in tropical deltas and estuarine environments carried these signals in hyperpicnal flows to slowly mixing Caribbean bottom waters, mimicking distally advected water.

The Cretaceous of the Spanish Central System: a review of the lithostratigraphy, palaeontology and sequence stratigraphy, including new educational perspectives

The Southern part of the Spanish Central System is formed by both terrigenous and carbonate Cretaceous rocks that have been affected by intense dolomitization. They are part of the sediments deposited on the western margin of the Iberian Basin during the Cenomanian–Maastrichtian, the depositional architecture of which has been reconstructed through a detailed sequence stratigraphical study and analysis of its fossil record. It is formed by three large transgressive–regressive cycles in which the carbonate platform moves towards the West, while the terrigenous facies of its base decreases and the overlying clay facies, with gypsum, increases. The integration of sedimentological and palaeontological data and the identification of a set of parasequences has allowed the differentiation of 13 depositional sequences. This research has been essential to carry out modern geological mapping and provide society with a model that improves the economic geology and geotechnical exploration of these areas. Furthermore, this scientific progress has also impacted on the interest of society towards the geosciences and, especially, palaeontology. This has widened the scope for new research fields related to scientific outreach for the community and learning opportunities at different educational levels.

Heterogeneous interfaces of aluminum bronze/Inconel 718 dissimilar alloys under different wire arc directed energy deposition sequences

Abstract The layer-by-layer deposition strategy of additive manufacturing makes it ideal to fabricate dissimilar alloy components with varying functionality, which has promising application potential in a large number of industrial areas. In this study, two components composed of ERCuAl-A2 aluminum bronze (CuAl9) and Inconel 718 nickel-based superalloy were fabricated with different deposition orders by wire-arc directed energy deposition. Subject to changes in heat input and thermophysical properties of the substrate, the transition region of the deposited Cu–Ni component with the bottom half of CuAl9 and the top half of Inconel 718 is narrow and serrated. This region features a laminated intermetallic compound layer due to the convection and rapid cooling in the molten pool. In contrast, the Ni–Cu component deposited in the opposite order exhibits a 2 mm gradient transition zone. Within this region, a large number of diverse precipitates were found as well as regional variations in grain size due to the multi-layer partial remelting. Both two components show strong bonds and their tensile specimens tested along the vertical direction always fracture at the softer CuAl9 side. Excellent tensile properties along the horizontal direction were obtained for Cu–Ni (Ultimate tensile strength: 573 MPa, yield stress: 302 MPa, elongation: 22%), while those of Ni–Cu are much lower due to the existence of the solidification cracks in the transition zone. The results from this study provide a reference for the additive manufacturing of Cu/Ni dissimilar alloy components, as well as their microstructure and mechanical properties control.

GEOLOGICAL FEATURES AND HYDROCARBON POTENTIAL OF THE SOUTHEASTERN YEVLAKH-AGJABEDI DEPRESSION: A STRATIGRAPHIC AND STRUCTURAL OVERVIEW

The Southeastern part of Yevlakh-Agjabedi depression, situated within the Lesser Transcaucasian monocline, exhibits intricate geological structures and diverse sedimentary sequences crucial for hydrocarbon exploration. This study utilizes extensive geological mapping, stratigraphic profiling, and seismic exploration to delineate the basin’s structural elements and sedimentary formations. Key findings include the presence of Jurassic-Lower Cretaceous volcanogenic terrigenous and Upper Cretaceous volcanogenic carbonate rocks, which exhibit significant variations in thickness and distribution across the basin. The stratigraphic analysis reveals substantial Mesozoic sedimentary sequences that have undergone complex tectonic evolution, with notable implications for hydrocarbon potential. The Upper Cretaceous sediments, in particular, show promising conditions for hydrocarbon accumulation, with favorable paleostructural and lithostratigraphic traps identified. This comprehensive investigation enhances regional geological understanding and provides critical insights into the hydrocarbon exploration prospects within the South Caucasus region.

Metallogenic model of sandstone-hosted copper deposits: a case study from the Paleogene in Jiashi area, northwestern China

Sandstone-hosted copper deposits, a type of Sediment-Hosted Stratiform Copper (SSC) deposits, are widely distributed globally. While economically viable deposits of SSC are relatively scarce, they account for approximately 30 % of the world's total discovered copper resources. However, there is still a lack of comprehensive and in-depth research into the depositional and metallogenic models of these deposits. The Jiashi area of the Tarim Basin in northwestern China, known for its economically significant Paleogene SSC deposit, lacks in-depth studies on metallogenic processes. To address this, field profile observations were conducted to analyze the sedimentary evolution, sequence stratigraphy, and tectonism of the Paleogene strata in the Jiashi area. Combined with elemental geochemical analysis of samples, the provenance of sediment, and the source of metallogenic materials, a robust metallogenic model was established. The results reveal the influence of provenance for the origin of Paleogene copper-rich strata. Sedimentary evolution played a crucial role in controlling the distribution of copper and sulfur elements, as well as the spatial arrangement of metallogenic beds. Additionally, nappe movement potentially generated faults, allowing upward movement of basin fluids, which played a crucial role in the formation of copper deposits within sandstone-hosted systems. Thus, this study offers a comprehensive analysis of the metallogenic processes involved in sandstone-hosted copper deposits, thereby contributing significant insights to the broader research on SSC deposits worldwide.

Quaternary transgression process controlled by tectonic subsidence over the last 1.35 Ma: New insights from the eastern Bohai Sea

The Quaternary sedimentary history of the Yellow Sea and Bohai Sea offers significant insights into global sea-level changes. This history is intricately linked to tectonic subsidence. However, the process of the Quaternary transgressions of these areas remains controversial due to the lack of cores with comprehensive sedimentary sequences and reliable chronological frameworks in representative sites. This study evaluated the grain size, benthic foraminifera assemblages, quartz optically stimulated luminescence (OSL) dates, and magnetostratigraphy of Core CSH05 (102.4 m) from the eastern boundary of the Bohai Sea. By comparing these results with previous research, new insights were gained into sea-level changes and tectonic events in the Bohai Sea. The paleomagnetic analysis revealed the existence of Brunhes and Matuyama chrons in the core, including the Jaramillo and Cobb Mountain subchrons and Blake excursion. The boundary between the Brunhes and Matuyama chrons was determined at 57.2 m in the core, aligning with adjacent cores. The basal age of the core is estimated to be ~1.35 Ma. Thirteen sedimentary units (U1-U13), consisting of seven neritic deposits and six terrestrial/littoral deposit layers, were identified in the core through sedimentology and environmental proxies (grain size and benthic foraminifera), indicating alternating transgression-regression cycles. OSL samples suggest that the neritic deposits layer (16.2–20.6 m) probably originated during the early Marine Isotope Stage 3 (MIS3), exhibiting a weaker transgression than MIS5 and MIS1. The initial transgression (U13) dates back to no later than 1.35 Ma, representing the earliest documentation in the Bohai Sea. U11 shows a transgression to 1 Ma, aligning with results from adjacent cores, indicating that the Miaodao Island uplift experienced further subsidence between 1 and 0.83 Ma, allowing seawater to inundate the central basin of the Bohai Sea during high sea level periods. The current sea-land configuration structure emerged after 0.3 Ma due to the complete subsidence of the Miaodao Islands Uplift. The Quaternary transgressions in the Bohai Sea demonstrate a coupling relationship with the uplift of the Qinghai Tibet Plateau, glacial-interglacial cycles, and integration of the Yellow River. This study traces the initial transgression in the Bohai Sea to 1.35 Ma and provides a new detailed evolutionary model of the timing and routes for the Quaternary transgression of the Bohai Sea and Yellow Sea, thereby enhancing our understanding of sedimentary evolution and paleoenvironmental changes in the region.

Unveiling the paleosalinity constraints on southern peri-Pannonian Lower Miocene lacustrine systems in Serbia and Bosnia and Herzegovina: Lopare (Dinaride Lake System) versus Toplica basin (Serbian Lake System)

Early Neogene saline lakes were widely developed across Central Paratethys, particularly across its „Dinaride-Anatolide“ landbridge (area of Dinarides, Balkans). The constraints on Lopare (western part of Jadar block; eastern Bosnia and Herzegovina) and Toplica (Jastrebac Mt., central Serbia) Neogene paleolakes provide a better understanding of deep-time climate evolution. The study focused on early Neogene paleolacustrine configuration, paleogeography, and the factors affecting a considerable paleosalinity increase. The study integrated available records on the predominantly Lower Miocene sedimentary sequence by analyzing and interpreting several paleosalinity markers (inorganic geochemical proxies, mineralogical data). The constraints on paleosalinity markers are afterward coupled with rather complex tectonic inferences. The two wellbores drilled in the Lopare and Toplica basins expose Neogene sections from which the critical paleosalinity markers are extracted (drillhole depths up to 350 and 1000 m, respectively). The mineral searlesite (NaBSi2O5(OH)2), and high B/Ga, markers of alkaline and arid paleoenvironmental lacustrine conditions, suggested intense evaporation (frequent drought periods). The evaporation was associated with paleoclimatic conditions during the Miocene Climatic Optimum. The Early Neogene arid climate and frequent evaporation episodes resulted in significant salinization of the Lower Miocene Lopare lacustrine sequence. The salinity in the Lopare sequence changed its character between brackish and saline, as evidenced by S/TOC and Ca/(Ca + Fe) ratios (TOC—Total Organic Carbon). At the same time, the salinity in the early Toplica basin was significantly lower and characterized by freshwater and brackish environments. The salinity variations between Toplica and Lopare were further exposed by Fe/(Ca + Mg), (Al + Fe)/(Ca + Mg), and C-value, yielding the change in the (paleo)water column. These markers further indicated the influence of warm climate conditions, consistent with the Miocene paleoclimatic record. Regarding paleogeography and Early Neogene tectonics, the results showed that before the Middle Miocene Badenian transgression, the Paratethyan Sea had no interference with the investigated intramontane lacustrine basins.

Sourcing of the Oligocene to Pliocene sediments of the Ningnan Basin: Evidence for Tibetan Plateau growth and local faulting unravelled by detrital apatite fission‐track and U–Pb double dating

AbstractThe Cenozoic topographic growth of the Tibetan Plateau is a pulsed, polyphase process that still requires more constraints. The Cenozoic sedimentary record of the Ningnan Basin, a continental basin located adjacent to the northeastern margin of the Tibetan Plateau, is a key archive for recording the surface evolution of the Tibetan Plateau. This work reports new provenance data (apatite fission‐track, apatite U–Pb dating, and trace element analysis on the same individual grains) from the Oligocene–Pliocene sedimentary sequence that filled the Ningnan Basin. The data set shows variations in provenance patterns through the Miocene which are related to the tectonic evolution of the northeastern margin of the Tibetan Plateau. In contrast to a primary provenance from the Western Ordos Block (WOB) during the Oligocene, the Miocene sediments were mostly derived from the recycling of Mesozoic successions that occur along the northwestern Haiyuan Fault, documenting it was active in the last ca. 15 Myr. These sediments, in turn, were derived from different orogenic blocks but mainly from different segments of the Qilian Mountains. We show that the Late Miocene–Pliocene sediments were primarily derived from transpressional uplift along the Haiyuan Fault, which affected regions such as the Liupan Mountains. Progressive northeastward migration of tectonic stress since the Middle Miocene has induced extensive regional deformation in the northeastern Tibetan Plateau, particularly along the Haiyuan Fault. The provenance record of the neighbouring Cenozoic basins is a key archive for deciphering this tectonic evolution.

Erosional Response to Pleistocene Climate Changes in the Brazilian Highlands

AbstractPlio‐Quaternary climatic changes are considered to be a key driver of landscape evolution, but many unresolved questions remain, such as the extent of the impact of major climatic shifts such as the Mid‐Pleistocene Transition (MPT). Various geochronological methods are available to infer changes in surface processes over the Plio‐Quaternary, and Terrestrial Cosmogenic Nuclides (TCN) have proven to be one of the most efficient tools to reconstruct paleo‐denudation. Implementing these approaches requires very specific conditions, such as well‐preserved and extensive sediment sequences. Developing alternative methods to document the evolution of denudation is thus of major interest to retrieve information on the evolution of denudation in places where recent detrital sediment records are absent. We explore the evolution of landscape erosion over a 1 Ma timescale in an intra‐cratonic setting, the Espinhaço mountain range (Brazil), with a new data set of detrital cosmogenic nuclide concentrations (26Al–10Be). We observe a systematic disequilibrium in the 26Al/10Be ratio, which we interpret as resulting from the combination of soil mixing and a significant increase in the intensity of surface processes, close to the MPT. We discuss the different scenarios with respect to available local and global data concerning the relationships between climate evolution and erosion over this time period. Our results have important implications for the interpretation of the denudation rates derived from TCN concentrations under steady states assumption, in landscapes with low erosion rates, which have a long memory for surface processes history.

Geological and Geomorphological Characterization of the Anthropogenic Landslide of Pie de la Cuesta in the Vitor Valley, Arequipa, Peru

This study presents the geological and geomorphological characterization of the Pie de la Cuesta landslide, a large (>60 ha) slow-moving (up 4.5 m/month) landslide in Southern Peru. The landslide has been active since 1975 and underwent a significant re-activation in 2016; the mass movement has caused the loss of property and agricultural land and it is currently moving, causing further damage to property and land. We use a combination of historical aerial photographs, satellite images and field work to characterize the landslide’s geology and geomorphology. The landslide is affecting the slope of the Vitor Valley, constituted by a coarsening upward sedimentary sequence transitioning from layers of mudstone and gypsum at the base, to sandstone and conglomerate at the top with a significant ignimbrite layer interbedded within conglomerates near the top of the sequence. The landslide is triggered by an irrigation system that provides up to 10 L/s of water infiltrating the landslide mass. This water forms two groundwater levels at lithological transitions between conglomerates and mudstones, defining the main failure planes. The landslide is characterized by three main structural domains defined by extension, translation and compression deformation regimes. The extensional zone, near the top of the slope, is defined by a main horst–graben structure that transitions into the translation zone defined by toppling and disaggregating blocks that eventually become earth flows that characterize the compressional zone at the front of the landslides, defined by thrusting structures covering the agricultural land at the valley floor. The deformation rates range from 8 cm/month at the top of the slope to 4.5 m/month within the earth flows. As of May 2023, 22.7 ha of potential agricultural land has been buried.

Paleomagnetic Data Bearing on the Origin of the Supra‐ Subduction Zone Ophiolites in Southeast Anatolia and the Progressive Closure of the Neotethys Ocean in the Eastern Mediterranean

AbstractThe Late Cretaceous supra‐subduction zone (SSZ) ophiolites in SE Anatolia form two parallel belts: the northern ophiolitic belt, which was emplaced onto the Tauride platform and a second southern belt emplaced on the Arabian platform. There are controversial hypotheses about the geometry and tectonic process of these ophiolites, which are still not well understood. Here, we test three alternative tectonic models for; (a) One single ocean which is defined by the İzmir‐Ankara‐Erzincan Ocean; (b) A southern branch of the Neotethys Ocean; (c) Two separate oceanic basins, which are the Berit Ocean and the South Neotethys Ocean. We present paleomagnetic results from 161 sites focusing on the sheeted dyke complex, cumulate gabbros, extrusive and sedimentary sequences of the Upper Cretaceous ophiolites in the SE Anatolian region. We also sampled the unconformable cover units from Middle Eocene and Miocene sedimentary rocks to distinguish emplacement related tectonic rotations from post‐emplacement tectonic rotations. Our data indicate that the southern ophiolites (Hatay ophiolite, cumulate gabbro + lava) were formed at a paleolatitude of and those of the northern ophiolites (Göksun, İspendere, Guleman ophiolite, cumulate gabbro + lava) were formed at a paleolatitude of . We hypothesize that the northern ophiolites were derived from the Ocean in a NW‐SE directed subduction zone between the Taurides and the Bitlis Pütürge massif, while the southern ophiolites, in contrast, were formed in the South Neotethys Ocean in a NNW‐SSE directed subduction zone farther northeast of the Taurides. Both the ophiolites reached their present position during Late Cretaceous to Middle Miocene, affected by rigid‐block rotations almost in counterclockwise sense.

3D stochastic simulation of a deep-water turbidite system: An example from the Los Molles Formation, southern region of the Neuquén Basin, Argentina

A recurring challenge in geological modeling is bridging the gap between different scales. For example, difficulties arise when connecting outcrop data through production to exploration scale models. An object-based stochastic simulation was performed using outcrop data from the Arroyo La Jardinera area in the southern region of the Neuquén Basin, Argentina. This simulation involved four depositional sequences in a vertical succession that includes turbidites and associated deep marine facies. The aims of this study are (a) to determine the best geological model consistent with field and aerial image data; (b) to validate the application of object modeling to determine facies distribution; (c) to evaluate uncertainties from models based on scarce data. The studied interval covers a transgressive (J1) to regressive succession (J21, J22, and J23) of basin plain to slope depositional settings, featuring sandy and gravelly turbidite channels, turbidite lobes and interlobes, lobe fringes, and muddy slope and basin plain. Each depositional sequence model was constructed using specific input parameters for architectural elements, with lithological proportions based on sedimentary logs. The J1 sequence includes basin plain, lobe fringe, and minor lobe deposits; J21 features turbidite lobes, fringes, and subordinate channels; J22 accommodates turbidite channels scoured into muddy slope facies; and J23 encompasses gravelly and sandy turbidite channels carved on muddy slope facies. The geostatistical modeling of outcrop data has allowed building a quantitative sedimentological model useful for understanding subsurface facies heterogeneity in both exploration (vertical) and production (horizontal) scales.

Timing and geometry of the Chemehuevi Formation reveal a late Pleistocene sediment pulse into the Lower Colorado River

The Chemehuevi Formation is a distinctive 50−150-m-thick wedge-shaped Pleistocene sedimentary unit deposited by the Colorado River. It lines the perimeters of the river’s floodplains and bedrock canyons for more than 600 km between the mouth of the Grand Canyon and the delta region in the Gulf of California. The formation is composed of a basal tan to light-yellowish-brown and pale-orange mud-dominated facies overlain and interbedded by a light-yellow-brown sand-dominated facies. The unit is one of two extensively exposed aggradational packages in the Lower Colorado River corridor, in addition to a series of other smaller alluvial terrace deposits. The Chemehuevi Formation appears to represent the response of a fully integrated Colorado River system to a significant perturbation, in contrast to the Bullhead Alluvium, which is likely a unique result of Pliocene river integration. The aggradation of the Chemehuevi Formation in the Lower Colorado River corridor may be similarly due to a unique event in the Colorado River system, or it may instead be a well-preserved sedimentary sequence recording typical behavior of the Colorado River below the Grand Canyon in the late Pleistocene. As such, multiple causal mechanisms have been proposed, but no study to date has conclusively explained the Chemehuevi Formation. To help resolve its timing, duration, and origin, we applied post-infrared infrared stimulated luminescence, carbonate U-Th series, and zircon sensitive high-resolution ion microprobe U-Th series geochronology to determine the ages of key exposures of the unit over a wide spatial area. These new data demonstrate that the Chemehuevi Formation was deposited ca. 110−90 ka. The depositional ages collectively overlap, suggesting that deposition occurred rapidly relative to the resolution of the geochronometers. The new depositional timing coincides with a shift from glacial to interglacial conditions after the marine isotope stage 5-6 transition. This observation is consistent with a climate-induced sediment pulse as a causal mechanism, yet correlations with similar deposits in the Colorado River headwaters or in neighboring catchments appear elusive. Potentially, climate transitions between glacial and interglacial periods induced a sediment pulse from hillslopes of the Colorado River system that resulted in the Chemehuevi Formation. An alternative or additional explanation is that the Chemehuevi Formation represents release of lava dam−impounded sediment in the Grand Canyon. The surface geometry of the Chemehuevi Formation projects upstream to the approximate location of lava dams, and the largest possible lava dam impoundment (the Upper Prospect dam) is comparable in volume to the formation. The lava dam hypothesis appears to be a possible explanation for the Chemehuevi Formation. However, tying deposition to a specific lava dam or series of lava dams remains challenging due to discrepancies in timing and volume. The combined effects of a series of lava dams may have led to the Chemehuevi Formation, as the last Pleistocene lava dam eruption coincides with the onset of deposition. Alternatively, the formation may result from the combined effects of both regional climate transitions and the lava dams that created a transient reservoir to compound a climate transition−driven sediment pulse. The geochronologic data presented here do not allow us to distinguish between the lava dam or climate transition hypotheses but will need to be reconciled with any future proposed depositional model.

A Paleoenvironmental Reconstruction of Lake Vrana on the Island of Cres (Croatia) Based on the Geochemistry and Mineralogy of the Late Pleistocene and Holocene Sediments

A 7.4 m long sediment core has been retrieved from the central part of Lake Vrana on the island of Cres to reconstruct the paleoenvironmental conditions. Lake Vrana is the deepest freshwater lake in Croatia, located in the karst region of the eastern Adriatic coast. A dated sediment sequence in Lake Vrana of 4.4 m has spanned the past 16.4 kyr, and it featured a dynamic sediment deposition until the beginning of the Holocene, including strong sediment input and supply to the lake by runoff sediments of dolomitic origin from the catchment in the period 16.4–14.4 cal kyr BP. High organic carbon content, which originates from mixed terrestrial and aquatic origins in the periods 14.4–13.3 cal kyr BP and 12.7–11.7 cal kyr BP, indicates fluctuating lake levels in shallow water environments during the Late Glacial to Holocene transition. The Holocene sequence indicates the development of more stable conditions and continuous sediment deposition, characterized by an increasing trend of siliciclastic sediments delivered into the lake during the early Holocene (11.7–10 cal kyr BP) and dominantly from 8 to 4.4 cal kyr BP, indicating enhanced input and erosion, which coincides with the humid and pluvial period recorded in the central Mediterranean region. It is followed by sediments with high organic carbon content between 4.4 and 1.6 cal kyr BP, which points to higher lake productivity. Calcite sedimentation prevailed between 1.6 to 0.4 cal kyr BP, indicating stable deeper-lake conditions. Predominantly, siliciclastic sediments from 0.4 to 0.1 cal kyr BP pointed to erosion during the Little Ice Age (LIA), with enhanced precipitation and sediment discharge from the catchment. The re-establishment of calcite sedimentation has been observed over the last 100 years.

Lithogeochemistry of upper precambrian terrigenous rocks of Belarus. Communication 1. Bulk chemical composition, general features and anomalies

The first of two publications is devoted to the lithogeochemical features study of the pilot collection of the Upper Precambrian sandstones and siltstones samples, selected from four boreholes: Bogushevskaya 1, Bykhovskaya, Lepel 1 and Korminskaya (Belarus). This article analyzes the general features of their bulk chemical composition and shows the possibilities and limitations for further reconstructions. It has been established that the Riphean and the Vendian rocks included in the pilot collection, visually identified as sandstones, are actually quartz, feldspathic-quartz and arkose varieties with different cement types. The Vendian “siltstones” in their geochemical characteristics correspond to coarse- and fine-grained siltstones and, to a greater extent, mudstones with a predominance of illite, as well as various admixtures of berthierine, kaolinite and smectite. Considering the trace elements enrichment factors of these rocks a number of dissimilarities were identified, caused both by the source rocks composition and sedimentary environments changes. The data point position of the studied samples on the Zr/Sc–Th/Sc diagram suggests that the composition of all the Riphean and the Vendian rocks is dominated by first sedimentation cycle material. This suggests that the lithogeochemical characteristics of the rocks of the pilot collection quite correctly reflect similar features of the source rock complexes and can be used to reconstruct the paleogeodynamic and paleoclimatic factors that controlled the accumulation of the Riphean and the Vendian sedimentary sequences of Belarus.

Untapped Mineral Potential of Somaliland: A review

This comprehensive study explores the untapped mineral potential of Somaliland, a region rich in geological diversity and significant mineral deposits. By examining the intricate geology of Somaliland, including its ancient Precambrian basement and younger sedimentary sequences, the research uncovers valuable insights into the region's mineral wealth. Extensive exploration activities reveal substantial reserves of base metals, precious metals, industrial minerals, and gemstones, highlighting the region's promise for future mining endeavors. The findings underscore the strategic importance of Somaliland's mineral resources, offering a roadmap for sustainable development and economic growth through enhanced geological surveys, infrastructure investment, and robust regulatory frameworks. This article serves as a vital resource for geologists, investors, and policymakers interested in unlocking the mineral wealth of Somaliland and fostering regional development.

Eolian-fluvial succession in the Early Cretaceous from the Ordos Basin

Cretaceous eolian deposits are widely developed in North China, among which the Lower Cretaceous eolian (erg) sedimentary strata in the Ordos Basin are the most representative. Many studies have been conducted on eolian deposits in the Ordos Basin, especially the Luohe Formation; however, there is a lack of systematic sedimentology research and the corresponding research on the evolution of sedimentary facies. Therefore, to explore the Mesozoic drought events and the systematic evolution of the sub-tropical erg zone, this study reports the fluvial–eolian sedimentary sequences of the Early Cretaceous Luohe and Yijinhuoluo Formations in the Ordos Basin. Spatially, through detailed sedimentary lithofacies and structural analysis of different outcrops, the combination law of sedimentary facies can be determined. Based on this, a three-dimensional sedimentary model of erg is reconstructed. The erg environment is divided into three sub-environments: erg margin, erg margin–centre transition and erg centre. According to the evolution of the sedimentary facies, the sedimentary evolution from the Latef Jurassic to the Early Cretaceous in the Ordos Basin is divided into five stages. The Ordos Basin has experienced the delta, erg formation, erg deposition, erg shrinkage and evaporating salt-lake stages. The vertical sedimentary evolution indicates climatic oscillation in North China from the Late Jurassic to the Early Cretaceous. Under the control of the sub-tropical high belt, the Ordos Basin experienced a hot and arid climate during the Cretaceous, forming a widely distributed erg belt in the region. During this period, a small-scale climate shock occurred under the hot and arid background, changing the sedimentary environment.