Cyanoacrylate Adhesives Research Articles

Fracture toughness in SPCC/CFRP hybrid laminates: Mode I and mode II perspectives

Hybrid composites using adhesive joints are gaining popularity in various industries as their various material combinations can create certain advantages. This research focuses on examining the mode I and mode II fracture toughness characteristics of the combined laminate between Steel Plate Cold Rolled Commercial (SPCC) metal and Carbon Fiber Reinforced Polymer (CFRP) composite processed using adhesive bonding. SPCC/CFRP hybrid laminate composites were manufactured with a variety of manufacturing options (A, B, and C) to find the most optimal method using two types of epoxy and cyanoacrylate adhesives, with two different bonding processes: secondary bonding and co-bonding. Fracture toughness values were measured through the Double Cantilever Beam (DCB) test for mode I and the End Notched Flexure (ENF) test for mode II. The test results showed that epoxy adhesives in the SPCC/CFRP adhesive joints provided better fracture toughness performance, especially when combined with the co-bonding technique. Specimens from manufacturing option C showed the highest GIC and GIIC values of 83.05 and 254.94 J/m2, respectively. These values increased by 58.98 % and 80.48 % compared to manufacturing options A and B in Mode I. Additionally, the GIIC value for manufacturing option C increased by 78.00 % and 66.76 % compared to manufacturing options A and B. The SPCC/CFRP hybrid laminates showed adhesive failure on the SPCC surface when using epoxy adhesive, whereas adhesive failure occurred on the CFRP surface with cyanoacrylate adhesive for the different manufacturing options.

Palatal Graft Harvesting Site Healing and Pain Management: What Is the Best Choice? An Umbrella Review

The use of free gingival graft (FGG) and connective tissue graft (CTG) from the palate are among the most predictable periodontal and peri-implant plastic surgery procedures. However, palatal harvesting causes severe discomfort in the palatal area in patients undergoing harvesting. The aim of this umbrella review is to evaluate which products or techniques can result in fewer side effects and less morbidity in patients. Systematic reviews, with meta-analysis or not, about postoperative pain and wound healing in patients undergoing surgery to remove a free gingival graft or connective tissue graft from the palatal region, published only in the English language, were electronically searched for on BioMed Central, Scopus, MEDLINE/PubMed, the Cochrane library databases, and PROSPERO register. Of 1153 titles, only 7 articles were included in this review. The reviews included suggest that the more effective interventions for patient-reported outcomes, particularly for pain management, are cyanoacrylate adhesives, platelet-rich fibrin, hyaluronic acid, and the use of palatal stents. Low-level laser therapy also demonstrated good results in palatal wound healing speed after FGG procedures. Also, topical agents were also described. Future studies and more high-quality randomized clinical trials are needed to provide clear descriptions and standardized procedures of interventions to obtain clear results.

Research and improvement of cyanoacrylate on bonding properties of silicone adhesive material

Cyanoacrylate adhesives represent the earliest discovered and most widely utilized adhesives known to date, boasting exceptional bonding properties such as the ability to cure at room temperature, rapid curing rates, and strong adhesion. However, shortcomings persist in practical applications, notably in addressing inert materials like silicone that pose challenges for ideal adhesion. To enhance the bonding performance of cyanate ester adhesives with silicone materials, this study delves into two aspects: modifying cyanate esters and pre-treating silicone surfaces to reduce surface energy. Following internal modifications, the maximum bonding strength to silicone sheets reached 2.33 MPa, while pre-treating the silicone substrate surface enabled a maximum bonding strength of 6.10 MPa. Utilizing SEM, ATR, EDS, and other analytical techniques, the mechanisms behind the improvement in silicone substrate bonding strength are characterized, revealing changes in properties pre- and post-treatment. This research paves a novel path and direction for future scientific investigations and advancements in adhesive formulation and enhancement.

STRAIN MEASUREMENT AND ADHESIVE SELECTION FOR STRAIN GAUGES ON CARBON ROVING IN TEXTILE-REINFORCED CONCRETE STRUCTURES

Textile-reinforced concrete (TRC) is a promising building material that meets modern environmental protection and sustainability requirements. For the widespread use of this innovative building material, empirical models based on material properties determined by laboratory tests are needed. This study investigated the ability to measure the strain of carbon rovings with small strain gauges during standard tensile tests. The measured values were compared and validated using the digital image correlation (DIC) method. Another component of this study is the investigation of a suitable adhesive for the application of the sensors to SBR-coated (styrene-butadiene rubber) carbon roving. Three test series with three different adhesives, cyanoacrylate adhesive, epoxy resin, and polychloroprene, were produced and tested for tensile strength. The validation tests showed that a strain loss occurs in the adhesive joint of the strain gauges. It was found that cyanoacrylate adhesives, such as M-Bond 200, suffered the lowest losses and are recommended for further investigations. The epoxy resin influences the stiffness of the carbon fibers at the contact surface too strongly, while the polychloroprene adhesive could not transfer the actual roving strain due to insufficient stiffness of the bond line.

STRAIN MEASUREMENT AND ADHESIVE SELECTION FOR STRAIN GAUGES ON CARBON ROVING IN TEXTILE-REINFORCED CONCRETE STRUCTURES

Textile-reinforced concrete (TRC) is a promising building material that meets modern environmental protection and sustainability requirements. For the widespread use of this innovative building material, empirical models based on material properties determined by laboratory tests are needed. This study investigated the ability to measure the strain of carbon rovings with small strain gauges during standard tensile tests. The measured values were compared and validated using the digital image correlation (DIC) method. Another component of this study is the investigation of a suitable adhesive for the application of the sensors to SBR-coated (styrene-butadiene rubber) carbon roving. Three test series with three different adhesives, cyanoacrylate adhesive, epoxy resin, and polychloroprene, were produced and tested for tensile strength. The validation tests showed that a strain loss occurs in the adhesive joint of the strain gauges. It was found that cyanoacrylate adhesives, such as M-Bond 200, suffered the lowest losses and are recommended for further investigations. The epoxy resin influences the stiffness of the carbon fibers at the contact surface too strongly, while the polychloroprene adhesive could not transfer the actual roving strain due to insufficient stiffness of the bond line.

Comparison of conjunctival pedicle flap to corneal fixation strength achieved by Tisseel® fibrin glue, ethyl cyanoacrylate adhesive, ReSure® hydrogel sealant, and conventional suturing with 8-0 VICRYL® ophthalmic suture.

To determine and compare the fixation strength of conjunctival pedicle flaps to cornea achieved via conventional ophthalmic suture and three different adhesive compounds. Ex vivo porcine globes. Following a 6 mm wide 500-micron-restricted depth lamellar keratectomy, conjunctival pedicle flaps were secured to the keratectomy site with either 8-0 VICRYL® suture or one of three adhesive products, including Tisseel® bioadhesive, ReSure® synthetic adhesive, or ethyl cyanoacrylate adhesive (n = 10 per surgical group). Adhesive application protocol varied by product based upon adhesive biocompatibility. Corneoconjunctival tissues were then harvested, clamped in a tensile testing device, and loaded at a rate of 1 mm/s under video surveillance until the point of failure. Peak load was determined for each test and used to compare fixation strength between samples. Forty conjunctival flaps were performed, with 6 omitted from evaluation due to dehiscence prior to tensile testing. Of the 34 flaps analyzed, 10 were secured with suture, 10 with cyanoacrylate, 8 with ReSure®, and 6 with Tisseel®. Flaps secured with suture withstood significantly higher applied tensile force compared with cyanoacrylate (p = .02474), ReSure® (p = .00000), and Tisseel® (p = .00002). Flaps secured with cyanoacrylate withstood significantly greater force than those secured with ReSure® and Tisseel® (p = .01194 and 0.01798, respectively). There was no significant difference in fixation strength between ReSure® and Tisseel® glue (p = .95675). Conjunctival pedicle flap fixation using 8-0 VICRYL® suture fixation was able to withstand significantly greater maximum tensile force compared to ReSure®, Tisseel®, or cyanoacrylate adhesives. Fixation strength achieved with cyanoacrylate adhesive was significantly greater than that achieved with ReSure® or Tisseel®.

Cyanoacrylate Adhesives Used for Topical Hemostasis A Systematic Review.

Introduction: In this systematic review the topical hemostatic properties of Cyanoacrylate Adhesives (CA) have been studied. Material and Method: Four major scientific databases (Embase, Scopus, PubMed, and Web of Science) were inquired, retrieving reviews and meta-analysis studies, clinical trials, experimental studies, and case reports that presented data regarding topical hemostasis and CA. English written articles, published in the last 10 years were collected. The last search was performed on the 1st of August 2023. Risk of bias in the included studies was assessed using study-design specific, evidence-based tools. Results: A summary focused on relevant information of all included studies was drafted and the results of the studies have been synthetized and compared. A total of 42 studies have been included in the review (14 reviews and meta-analysis, 11 clinical trials, 9 experimental studies and 8 case reports). CA exhibited important topical hemostatic capabilities, comparable with other performant hemostatic materials. Although most included studies concluded that CA were potent topical hemostatic agents, the high level of heterogeneity among the studies prevented us from performing a meta-analysis. Conclusion: The results of this review show that CA-based compounds represent an important line of research towards the perfect hemostatic material.

Experimental study of adhesive joints with mechanical interlocking of acrylonitrile butadiene styrene (ABS) parts fabricated for fused filament (FFF)

PurposeAdditive manufacturing has disadvantages, such as the maximum part size being limited by the machine’s working volume. Therefore, if a part more considerable than the working volume is required, the part is produced in parts and joined together. Among the many methods of joining thermoplastic parts, adhesives and mechanical interlocking are considered. This study aims to characterize and optimize mechanically stressed adhesive joints combined with female and male mechanical interlocking on acrylonitrile butadiene styrene (ABS) specimens made with fused filament fabrication (FFF) so that the joint strength is as close as possible to the strength of the base material.Design/methodology/approachThis study characterized the subject’s state of the art to justify the decisions regarding the experimental design planned in this research. Subsequently, this study designed, executed and analyzed the experiment using a statistical analysis of variance. The output variables were yield strength and tensile strength. The input variables were two different cyanoacrylate adhesives, two different types of mechanical interlock (truncated pyramid and cylindrical pin) and the dimensions of each type of mechanical interlock. This study used simple and factorial experiments to select the best adhesive and interlocking to be optimized using the response surface and the steep ascent method.FindingsThe two adhesives have no statistical difference, but they show different data dispersion. The design or yield stress was a determining factor for selecting the optimal specimen, with cylindrical geometry exhibiting higher resistance at initial failure. Geometry type is crucial due to the presence of stress concentrators. The cylindrical geometry with fewer stress concentrators demonstrated better tensile strength. Ultimately, the specimen with a mechanically reinforced joint featuring a cylindrical pin of radius 5.45 mm and height of 4.6 mm exhibited the maximum tensile and yield strength.Originality/valuePrevious research suggests that a research opportunity is the combination of bonding methods in FFF or fused deposition modeling, which is not a frequent topic, and this research to enrich that topic combines the adhesive with mechanically interlocked joints and studies it experimentally for FFF materials, to provide unpublished information of the performance of the adhesive joint with mechanical interlocking, to designers and manufacturers of this technology.

Effect of Different Chemical Surface Treatments on the Shear Bond Strength of Acrylic Teeth With Different High-Impact Denture Base Resins.

Introduction The debonding of acrylic teeth from the denture base, particularly in cases of prominent ridges, is a common problem faced by clinicians and patients. The present study was conducted to assess the effects of various chemical treatments on the shear bond strength (SBS) of acrylic teeth bonded to different high-impact denture base materials. Materials and methods The present in vitro study was conducted on 80 wax specimens with acrylic teeth bonded to two high-impact denture base materials (DPI Tuff (DPI Dental Products of India Ltd, Mumbai) and Trevalon HI (Trevalon HI, Dentsply, Karnataka)). The two main groups were further divided into four subgroups of 10 specimens each, depending on the chemical treatment at the ridge lap area of the tooth: control group without any chemical treatment, chemical surface treatment (CST) with dichloromethane and monomer mix, CST with ethyl acetate, and CST with acrylic adhesive cyanoacrylate. The SBS was tested using a universal testing machine (UTM). Analysis of variance (ANOVA) and post-hoc Tukey tests were used for statistical analyses. Results The mean SBS of Group A (DPI Tuff) was 111.75 Nas compared to 118 N in Group B (Trevalon HI). The differences were statistically significant (p<0.05). ANOVA and post-hoc Tukey's tests revealed significant differences between subgroups. The highest mean SBS was noted with a dichloromethane and monomer mix (1:1 volume), followed by the ethyl acetate, control, and cyanoacrylate subgroups. Conclusion The cross-linked acrylic teeth treated with a dichloromethane and monomer mixture (1:1 by volume), processed with Trevalon HI high-impact denture base resin had the highest SBS and thus were indicated for bonding teeth with the suggested denture base.

Removing Fractured Endodontic Files with a Tube Technique-The Strength of the Glued Joint: Tube-Endodontic File Setup.

One recommended technique for removing broken root canal instruments is to glue the fragment into a cannula adapted to it (i.e., the tube technique). The aim of the study was to determine the influence of the adhesive kind and length of the joint on the breaking force. During the investigation, 120 files (60 H-files and 60 K-files) and 120 injection needles were used. Fragments of broken files were glued into the cannula using one of three materials: cyanoacrylate adhesive, composite prosthetic cement, or glass ionomer cement. The lengths of the glued joints were 2 and 4 mm. After the polymerization of adhesives, a tensile test was carried out to find a breaking force. The results were statistically analyzed (p < 0.05). For 4 mm lengths of glued joints, the breaking force was higher than for 2 mm for both file types (K and H). In the case of K-type files, the breaking force was higher for cyanoacrylate and composite adhesives than glass ionomer cement. For H-type files, no significant difference in joint strength was found between binders at 4 mm, while at 2 mm, a much better connection was obtained for cyanoacrylate glue than prosthetic cements.

Interaction of Cyanoacrylate with Metal Oxide Surfaces (Cu, Al).

The front cover artwork is provided by Prof. Maus-Friedrichs' group at the Clausthal University of Technology. The image shows the molecular interaction formed at the interface between the adhesive cyanoacrylate and a natively oxidized copper or aluminium surface. Read the full text of the Research Article at 10.1002/cphc.202300076.

Nanosecond laser debonding of strong adhesives

ABSTRACT The goal of this paper is to determine whether laser-induced surface melting can generate adhesive debonding. Commercial cyanoacrylate and acrylic adhesives are used to attach an aluminum (Al) cylinder to a transparent polymethyl(methacrylate) (PMMA) plate, and then a variable force is applied to create an axially loaded butt joint. High energy nanosecond laser pulses at 1064 and 532 nm are directed through the transparent PMMA to be absorbed at the Al surface, causing transient localized heating that leads to joint failure. The dependence of this debonding on both laser fluence (energy per area) and applied force are investigated. Single shot debonding occurs at fluences on the order of 0.47 J/cm2 for 1064 nm and 0.29 J/cm2 for 532 nm pulses with an applied pressure of 0.22 MPa. Characterization of the Al surface before and after laser impact confirms that the debonding arises from surface melting and causes only slight changes to the Al surface. A simple model of the debonding process is developed to explain the dependence of the debonding on the applied load. Single laser pulses can generate instantaneous, relatively clean separation of bonded joints, suggesting that laser debonding may be a promising strategy to initiate deadhesion.

Evaluation of fibrin, cyanoacrylate, and polyurethane-based tissue adhesives in sutureless vascular anastomosis: a comparative mechanical ex vivo study

The stability of a microvascular anastomosis is an important prerequisite for successful tissue transfer. Advances in tissue adhesives are potentially opening new avenues for their use in sutureless microsurgical anastomosis, however they have not yet gained clinical acceptance. In this ex vivo study, a novel polyurethane-based adhesive (PA) was used in sutureless anastomoses and its stability compared with that of sutureless anastomoses performed with fibrin glue (FG) and a cyanoacrylate (CA). Stability was assessed using hydrostatic (15 per group) and mechanical tests (13 per group). A total of 84 chicken femoral arteries were used in this study. The time taken to create the PA and CA anastomoses was significantly faster when compared to the FG anastomoses (P < 0.001): 1.55 ± 0.14 min and 1.39 ± 0.06 min, respectively, compared to 2.03 ± 0.35 min. Both sustained significantly higher pressures (289.3 mmHg and 292.7 mmHg, respectively) than anastomoses using FG (137.3 mmHg) (P < 0.001). CA anastomoses (0.99 N; P < 0.001) and PA anastomoses (0.38 N; P = 0.009) could both withstand significantly higher longitudinal tensile forces compared to FG anastomoses (0.10 N). Considering the background of an in vitro study, the PA and CA anastomosis techniques were shown to be similar to each other and superior to FG, due to their stability and faster handling. These findings need to be validated and confirmed in further in vivo studies.

A Tough Hydrogel Adhesive for the Repair of Archeological Pottery.

Pottery is the oldest art and plays a landmark role in human civilization. The repair of ceramic relics often uses acrylic resins and cyanoacrylate adhesives. However, existing adhesives often take hours to get cured, and wet adhesion is not possible. We herein propose a redox initiator-triggered hydrogel adhesive, of which robust (∼700 J m-2) and wet adhesion with potsherds can be achieved within a few seconds. The high toughness lies in the self-limited delocalized rupture of the porous interface, and the wet adhesion is due to the hydrophilic precursor and its free radical polymerization. The hydrogel adhesive also exhibits high aging resistance for stable preservation of ∼400 annuals. We have applied the adhesive to the restoration of artifacts excavated from Yinxu, Anyang (∼1300 BC) and the Xia Jiao Shan site (∼4000 BC, Neolithic), and the adhesive is expected to be extended to applications beyond archeology.

Náhodná aplikace vteřinového lepidla do nosní dutiny u čtyřleté holčičky – návrh strategie léčby v ORL oblasti

Cyanoacrylate adhesives (“superglues”) are mainly used in households. They undergo a rapid anionic polymerisation after application and form a hard solid mass. We report a case of a 4-year-old girl who applied a random cyanoacrylate glue to her nose. The glue was successfully removed under general anaesthesia by gentle dissection using Freer raspatory without causing any damage to the nasal mucosa. To the best of our knowledge, only 3 cases of cyanoacrylate intranasal instillation have been published in the literature so far. The case study suggests an algorithm to guide ENT and paediatric clinicians in the future management of this type of unusual “superglue” injury in the ENT region. Key words cyanoacrylate glue – foreign body – superglue removal – management algorithm

A Revolutionary, Proven Solution to Vascular Access Concerns: A Review of the Advantageous Properties and Benefits of Catheter Securement Cyanoacrylate Adhesives

Intravascular catheters are widely used among hospitals; however, their failure rates are high, up to 50%, when secured by traditional techniques, such as tape and gauze. The use of catheter securement cyanoacrylate adhesives provides a unique approach to the issues surrounding the use of traditional securement techniques for vascular access devices by providing significant securement strength, barrier properties, antibacterial properties, hemostatic properties, and flexibility. The purpose of this research was to perform a thorough and systematic review of the current literature existing regarding the use of cyanoacrylate adhesive for the care and maintenance of vascular access devices.

Comparative evaluation of the efficacy of two medical grade adhesives for the retention of extraoral maxillofacial prosthesis

Introduction: The retention of an extraoral maxillofacial prosthesis poses a big challenge to the prosthodontist due to the complex and varied nature of facial defects. Several methods are available to enhance the retention of this prosthesis. This study was conducted to compare the efficacy of polysiloxane adhesives and n-butyl cyanoacrylate adhesives in providing retention for an extra-oral maxillofacial prosthesis. Materials and Methods: The samples were prepared by bonding silicone sheets with pigskin. These samples to be studied were divided into two groups of 20 samples each depending on the adhesive used for bonding the silicone sheets to the pigskin. Ten samples from each group were subjected to 180° and T-peel tests, respectively. Results: The results showed that the mean peel strength (PS) in the T peel test was higher for polysiloxane adhesive as compared to n-butyl cyanoacrylate adhesive, but the difference was not statistically significant. Whereas the mean PS in the 180° peel test was higher for n-butyl cyanoacrylate adhesive as compared to polysiloxane adhesive and the difference was statistically significant. Conclusion: The cyanoacrylate adhesives proved to be better in terms of PS.

Assessment of the Retinal Toxicity and Sealing Strength of Tissue Adhesives

ABSTRACT Purpose The purpose of this in vitro prospective nonrandomized study is to compare the toxicity and strength of cyanoacrylate and hydrogel adhesives on human retinal pigment epithelium (RPE) cells and porcine retina, respectively. Methods The toxicity of cyanoacrylate (histoacryl, dermabond, superglue), ReSure PEG, and Tisseel fibrin glue on human RPE cells was determined by growing RPE cells in vitro, applying the different adhesives to the cells, and monitoring for disruption of growth over 3 days. The relative strength of these adhesives was tested by gluing a 3 mm piece of foam to a porcine retina and determining the amount of force needed to break the attachment. Results 0.085 N of force was required to break the porcine retinal tissue (p = .913). Histoacryl adhesive exhibited high strength (0.247 N) and high RPE toxicity (0.55 mm inhibition zone after 24 hrs). The strength of Tisseel fibrin glue was 0.078 N while that of ReSure was only 0.053 N. Both Tisseel and ReSure were nontoxic to the RPE cells. Conclusions Tisseel VH fibrin sealant may provide the best option for sealing retinal breaks because of its high strength and low retinal toxicity.

Comparison between Tissue Adhesive Cyanoacrylate and Suture for Palatal Fibromucosa Healing: A Randomized Controlled Study.

Cyanoacrylate tissue adhesive is proposed to promote soft tissue healing in oral surgery and minimize complications (pain, inflammation, and bleeding) associated with wound healing by secondary intention. The objective was to compare cyanoacrylate tissue adhesive (test group) with suture (control group) in terms of postoperative complications, operative time, and wound healing in the palatal donor area after harvesting a de-epithelialized gingival graft. A randomized controlled clinical trial was performed in 24 patients randomly assigned to one of two study groups. Data were gathered on wound bleeding, operative time, postoperative pain, inflammation, hyperesthesia, necrosis, and donor area healing time. Operative time was almost 50% shorter in the tissue adhesive cyanoacrylate group, a significant between-group difference (p = 0.003). Spontaneous bleeding in the donor area during the first 24 h was observed in 11.1% of the tissue adhesive cyanoacrylate group versus 88.9% of the suture group—a significant difference. No significant between-group difference was observed in postoperative pain, inflammation, or degree of healing over time. There were no cases of hyperesthesia or wound necrosis. Utilization of tissue adhesive cyanoacrylate rather than suture in palatal de-epithelialized gingival graft harvesting reduces postoperative bleeding during the first 24 h, as well as the operative time.

Rapid and Robust Surface Treatment for Simultaneous Solid and Liquid Repellency.

A wide range of liquid and solid contaminants can adhere to everyday functional surfaces and dramatically alter their performance. Numerous surface modification strategies have been developed that can reduce the fouling of some solids or repel certain liquids but are generally limited to specific contaminants or class of foulants. This is due to the typically distinct mechanisms that are employed to repel liquids vs solids. Here, we demonstrate a rapid and facile surface modification technique that yields a thin film of linear chain siloxane molecules covalently tethered to a surface. We investigate and characterize the liquid-like morphology of these surfaces in detail as the key contributing factor to their anti-fouling performance. This surface treatment is extremely durable and readily repels a broad range of liquids with varying surface tensions and polarities, including water, oils, organic solvents, and even fluorinated solvents. Additionally, the flexible, liquid-like nature of these surfaces enables interfacial slippage, which dramatically reduces adhesion to various types of solids, including ice, wax, calcined gypsum, and cyanoacrylate adhesives, and also minimizes the nucleation of inorganic scale. The developed surfaces are durable and simple to fabricate, and they minimize fouling by both liquids and solids simultaneously.