Craton Margin Research Articles

Magmatic-hydrothermal origin for Carlin-type Au deposits: Evidences from in-situ S-Pb isotopic compositions of sulfides, the Chang’an Au deposit, southern Ailaoshan tectonic zone

The Chang’an Au deposit is a large Au deposit located in the south of the Ailaoshan-Red River tectonic zone, southwestern margin of the South China block. The deposit exhibit characters similar to Carlin-type Au deposits in Nevada and Dian-Qian-Gui “Golden Triangle”, including tectonic evolution (deformed and rifted cratonic margins), orebody controlled by lithology and structure and invisible Au ionically bound in arsenian pyrite and pyrite. Mineralization is controlled by a strike-slip fault and occurs as barren milky quartz veins, disseminated gold-bearing pyrite and arsenopyrite in the Early Paleozoic sandstone, siltstone and limestone. Gold is invisibly and ionically bound in arsenopyrite and pyrite or locally occurs as isolated native gold crystals (micron scale). Wall rock alteration includes sulfide, silicic, sericite and decarbonized alterations. Three hydrothermal mineralizing stages (I, II, III) can be identified: milky quartz-pyrite (I), quartz-sericite-pyrite-arsenopyrite (II) and dolomite-calcite-quartz (III). Different from those deposit in Dian-Qian-Gui, numerous plutons intruded in and around the mine. The syenite dikes are pyritized, thus, formed prior to the mineralization while lamprophyre dikes are unaltered and crosscut by the syenite dikes. The syenite dikes yielded zircon U − Pb ages of ca. 35.8 Ma and the lamprophyre yielded similar Ar-Ar age of ca. 36.6 Ma, largely constraining the age of Au mineralization. In situ S–Pb isotopic compositions for ore pyrite and arsenopyrite were measured by fs-LA-MC-ICP-MS. Sulfides from Chang’an show a uniform range from –6.4‰ to + 4.6‰, a typical characteristic of magmatic-derived S. Such sulfur isotopic compositions are similar to those of sulfides from Carlin-type Au deposits, but different from those of sulfides from orogenic-type deposit, which commonly exhibit a wide range of δ34S values. Pb isotopic ratios of pyrite and arsenopyrite are similar to those of the intrusive rocks in the deposit with more radiogenic Pb, suggesting that the metal is probably sourced from the coeval intrusive rocks and sedimentary wall rocks. Combined with the low Au concentrations of the sedimentary wall rocks, Au in the Chang’an deposit are probably sourced from the intrusive rocks. Differences between the Chang’an deposit and typical orogenic-type Au deposit include: (1) Orebodies in the Chang’an deposit exhibit transitional contact relationship with the host rocks and boundaries between them are defined by cut-off grade while these boundaries in typical orogenic-type deposits are clearly defined. (2) Sulfidized and decarbonized alterations are quite significant in the Chang’an deposit but commonly absent in typical orogenic-type deposits. (3) The Chang’an deposit have lower CO2 contents of ore-forming fluids and more shallow ore-forming depth relative to typical orogenic-type deposits. Based on the ore deposit geology, dating and isotopic data, the Chang’an mineralization is similar to typical Carlin-type gold deposit, formed by ore fluids originated from a deep magmatic S source in an post-collisional intracontinental setting at ca. 36 Ma.

Refining the depositional model of the lower Permian Carynginia Formation in the northern Perth Basin: anatomy of an ancient mouth bar

The late early Permian coincided with a short-lived cold episode in Western Australia, which occurred long after the demise of late Paleozoic ice sheets, and is manifested by conspicuous dropstones in corresponding marine strata. In the northern Perth Basin, this time interval is represented by the Carynginia Formation, which has long been regarded as a record of low-energy marginal-marine sedimentation. The low-diversity body-fossil content and impoverished trace-fossil assemblages in the formation were recognised as evidence of low salinities, low dissolved-oxygen levels and high suspended-sediment concentrations presumably related to freshwater influxes into a restricted basin. However, sedimentary facies indicative of river processes have yet to be documented to explain the sedimentological and paleontological character of the formation. This study examines an overlooked sandstone-rich interval of the Carynginia Formation in the Irwin Sub-basin, a marginal half graben faulted against crystalline basement of the Yilgarn Craton and forming part of a series of late Paleozoic intracratonic rift basins in Western Australia. Facies analysis indicates that the lower part of the interval is dominated by storm-generated deposits containing extraformational pebbles and boulders. These deposits are interpreted as recording lower-shoreface sedimentation under the influence of seasonal sea ice, and constitute a shallower, sandstone-rich equivalent of mudstone-prone strata that otherwise characterise the Carynginia Formation. The upper part of the interval consists of river-borne deposits representing friction-dominated deposition of a river-mouth bar, the first direct record of deltaic sedimentation in the Carynginia Formation. The stratal organisation of mouth-bar bedsets is likely the result of successive sediment-laden pulses related to seasonal floods in a shallow marine basin, and the autogenic evolution of the mouth-bar complex in response to fluctuating river discharge and compensational stacking. Formative runoff events were arguably responsible for reductions in salinity and the introduction of turbid buoyant plumes into the shallow sea that were adverse to faunal development. A fluvial influence may explain the sedimentary character and fossil content of coeval mudstone-prone formations in Western Australian rift basins, especially in the vicinity of cratonic margins. KEY POINTS The lower Permian (late Artinskian–Kungurian) mudstone-prone Carynginia Formation in the northern Perth Basin has long been regarded as the record of low-energy, marginal-marine conditions in a cold-water seaway. The low-diversity fossil content in the lower part of the formation indicates stressed physico-chemical conditions influenced by freshwater, sediment-laden influxes. The described mouth-bar deposits are the first direct evidence of deltaic sedimentation in the Carynginia Formation, demonstrating that river outflows likely controlled water chemistry and impacted faunal development.

U–Pb Dating of Apatite, Titanite and Zircon of the Kingash Mafic–Ultramafic Massif, Kan Terrane, Siberia: from Rodinia Break-up to the Reunion with the Siberian Craton

Abstract The initial stage of Rodinia supercontinent break-up occurred at about 750 Ma. It preceded formation of the Irkutsk and Franklin large igneous provinces (LIPs) at 712 ± 2 to 739 ± 8 Ma. These LIPs were emplaced within the formerly connected Laurentian and Siberian cratons. The Kingash massif is located in the Precambrian Kan terrane in direct contact with the Siberian Craton at its southwestern boundary. It has been linked to an important suite of mafic–ultramafic intrusions that border the southern margin of the Siberian craton, and that have been inferred to belong to the Irkutsk LIP. The massif is also significant, because it hosts platinum group element (PGE)–Cu–Ni-rich mineralization and is the only large deposit in the region. However, despite numerous dating attempts, the age of the massif had not been resolved. A significant difficulty is post-magmatic recrystallization at amphibolite facies that affected the rocks of the massif. In this study we used U–Pb dating of zircon, titanite and apatite from rocks of the Kingash massif and cross-cutting granite and monzonite veins. The oldest igneous zircon grain of the Kingash massif analysed by laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) yields an age of c. 750 Ma, taken as a tentative age of magmatism. Dating of multiple grains of metamorphic zircon by chemical abrasion isotope dilution thermal ionization mass spectrometry yielded 564·8 ± 2·2 Ma, which is in agreement with LA-ICP-MS titanite ages of 557 ± 19, 565 ± 35 and 551 ± 17 Ma. Apatite of two different samples showed ages of 496·4 ± 7·9 and 497·0 ± 1·8 Ma (LA-ICP-MS), which are interpreted as the time when the terrane cooled below the closure temperature of apatite. Using our new data we suggest that at the time of the Irkutsk–Franklin LIP event the Kan terrane was a part of Rodinia, then it separated from either Siberia or Laurentia during the break-up of Rodinia and finally collided with Siberia at 560 Ma, the time of regional amphibole-facies metamorphism.

A reappraisal of legacy reflection seismic data from the western margin of the Kaapvaal craton, South Africa, with implications for Mesozoic-Cenozoic regional tectonics

The 150 km long, 6 s TWT, 2D seismic profile KBF03A, which was acquired in 1994 and lies near the western edge of the Kaapvaal craton in South Africa, has been reprocessed using standard reflection seismic processing methods. The results exhibit a significant improvement in the imaging quality of the subsurface features and an evident boost in the signal-to-noise ratio. The improved seismic data, combined with application of seismic attributes, integration with surficial geological and geophysical maps, and computation of velocity tomograms, has revealed previously undetected structural features within the supracrustal sequences underlying the profile. In particular, the Phanerozoic sediments found along the profile, comprising exclusively Kalahari Group and Dwyka Group deposits, are disrupted by multiple folds of varying wavelengths (~1–10 km) and variably oriented normal and thrust faults. Additionally, the effect of the Moshaweng fault, previously characterised as a listric fault extending to depths of >10 km, on the Phanerozoic sediments has been further constrained to suggest repeated extensional reactivations and a more recent (<1 Ma) inversion. Considerations of the eastern end of the profile have suggested links between some of the observed structural features and the nearby ~146 Ma Morokweng impact structure, the lateral expanse of which is poorly constrained in the literature. The collection of these newly imaged features is interpreted as evidence for multiple Late Mesozoic to Cenozoic tectonic events, including polyphasic reactivation of basement structures, under both extensional and compressional stress regimes. By analysing these newly detected features, our study not only provides new insight into the neotectonic evolution of the Phanerozoic sediments along the western margin of the Kaapvaal craton, but also demonstrates the utility in reprocessing legacy data and reveals its untapped potential.

Meso-Neoproterozoic arc-related sediments of the Xiahe Group in the Qinling block, central China: Implications for the paleogeographic reconstruction of Rodinia

The Meso-Neoproterozoic Rodinia supercontinent formed a coherent large landmass, which was later dispersed over all current major continents and a number of microcontinents. The Qinling block is a Precambrian continental mass, located in the Qinling orogenic belt, which marks the junction of the North China and South China cratons. In this paper, we present a systematic study of the petrology, whole-rock geochemistry and geochronology of metasedimentary rocks from the Xiahe Group, which is a key unit of the Precambrian basement in the Qinling block, to constrain the paleogeographic reconstruction of Rodinia. The studied metasedimentary rocks have detrital zircon ages of 3054–1082 Ma that peak at 1172 Ma and 1582 Ma. The protoliths of the metasedimentary rocks are mainly shales and wackes with maximum depositional ages from 1147 to 1082 Ma, representing a part of a continental arc-related sedimentary sequence. Combining our results with existing data, we propose that their protoliths constituted a sedimentary series including an older sequence of basement and a younger sequence with depositional ages between 1262 and 840 Ma. The detritus that is older than 1266 Ma was sourced from the continental margin of the Indian craton, which was part of the Columbia supercontinent. There was a Paleo-Mesoproterozoic continental nucleus in the Qinling block that split from the margin of the Indian craton during the breakup of Columbia. The source rocks for the younger detritus were arc magmatic rocks in the Qinling block, which formed in a continental arc by oceanic lithosphere subduction during the assembly of Rodinia. A sequence of oceanic subduction beneath the continental nucleus of the Qinling block (1262–981 Ma), arc-continent collision between the continental nucleus and the Indian craton (981–911 Ma), continuous subduction of oceanic crust beneath the block with formation of a mature volcanic arc (929–833 Ma), and continental rifting (833–774 Ma) during the formation of the Qinling block was identified. The block faced the Neoproterozoic ocean during the assembly of Rodinia, and finally rifted off the supercontinent during its breakup to form an isolated arc terrane

Early Neoproterozoic Metapicrite–Basalt Association of the Angara Region, Yenisei Ridge: Petrogeochemical Composition, Tectonic Settings, and Pb–Zn Mineralization

In the Angara part of the Yenisei Ridge, a sequential section of the metapicritic–basalt sequence and overlying carbonate rocks of the Gorevskaya Formation is established. This section is considered as a single volcanic–sedimentary complex formed at the Late Mesoproterozoic–Early Neoproterozoic boundary in the riftogenic marginal–continental paleobasin in the southwestern Siberian Craton. It is proposed to introduce the metapicrite–basaltic sequence into the stratigraphic legend of the Shirokaya Group of the western Yenisei Ridge under the name “Nizhnerechinskaya Sequence”. In the studied section, metamorphosed picrobasalts and picrites predominate in the lower part of the Nizhnerechinskaya Sequence, while the middle and upper parts consist mainly of basalts containing Pb–Zn mineralization (Stepanovsky ore occurrence). At the contact with carbonate deposits of the Gorevskaya Formation, an alternation of volcanogenic rocks and terrigenous–carbonate sediments and metabasaltic sills are observed. The petrochemical and trace-element composition of metavolcanic rocks has much in common, which indicates the paragenetic relationship of rocks of this high-Mg rock association. All these rocks are enriched in Fe and Ti, while metabasalts and metagabbros show elevated alkalinity and P2O5 content. In terms of total alkalinity, metabasalt–picrobasalts deviate from the normal petrochemical series towards the subalkaline series, which correlates with their elevated Ti content. Basites enriched in alkalis, especially, in potassium and corresponding to trachybasalts are observed among them. The contents of incompatible trace elements clearly increase from picrites to basalts and reach maximum in trachybasalts, which show 1.5–3 times enrichment in high-field strength elements compared to the basalts. The paragenetic nature of the considered association is supported by the similar REE distribution patterns: (La/Yb)n = 6–7 at Eu/Eu* = 0.9–1. The Late Mesoproterozoic–Early Neoproterozoic rifting of the Earth’s crust in the Angara region led to the opening of the marginal–continental sea basin, where basalt-picrite volcanism occurred simultaneously with accumulation of terrigenous–carbonate sediments, including ore–bearing (Pb–Zn) rocks of the Gorevskaya Formation, which host the Gorevskoye Pb–Zn deposit. The basin under consideration is interpreted as a relict rift-related paleobasin on the western margin of the Siberian craton, while the volcanic–sedimentary Nizhnerechinskaya Sequence is considered as the lower potential stratigraphic level of the base-metal mineralization in the Gorevsky ore field.

Antiquity and tectonic lineage of Japanese Islands: New discovery of Archean–Paleoproterozoic Complex

A new rock complex has been discovered from the Tsuwano area of Southwest Japan. This granitic rock complex namely, Tsuwano Complex contains foliated granitic gneiss, massive granitoids, and metaquartzite, forming a distinct unit at the westernmost end of the east-west elongate Maizuru Terrane. The above-mentioned litho-assemblage is characteristically different in appearance from the typical rocks of the Maizuru Terrane as well as the surrounding Jurassic and Permian accretionary rocks. We report here the zircon U-Pb LA-ICP-MS geochronological data of the rocks of this Tsuwano Complex. The comprehensive geochronological data indicate that this complex is much older than the surrounding rocks of the Maizuru Terrane. Zircon cores of the granitic gneiss yield possible magmatic age at ca. 2700 and 2500 Ma, while rim parts show a possible metamorphic age of ca. 1850 Ma. Associated dioritic to tonalitic granitoids also show a comparable age of crystallization at ca. 1850 Ma, indicating Neoarchean granitic rocks suffering a thermal overprinting and associated granitoid magmatism at Paleoproterozoic era. The exposed metaquartzite also yielded Neoarchean detrital zircon grains with the calculated maximum age of deposition at ca. 2430 Ma. While, all the other studied rocks including the grayish granitoids, felsic tuff, and metagabbro yield Paleozoic to Mesozoic ages. This is the first discovery of a Precambrian basement rock complex from the Japanese main islands. Based on the present geochronological dataset, we propose for a correlation and paleo-positioning of these basement rocks on the East Asian cratonic margin and a possible tectonic model of its evolution.

Multidisciplinary Modeling of Mantle Lithosphere Structure Within the Superior Craton, North America

AbstractNew 3D multi‐azimuthal receiver function analysis identified four regional seismic discontinuities dipping at 7–13° within the mantle of the Superior craton of North America; most are discordant to known major upper crustal structures. Widely observed crustal‐scale structures with near‐vertical axial planes striking east‐west indicate that the most recent and dominant phase of folding and horizontal shortening strain occurred during the Kenoran (D2) crustal deformation concurrent with Au‐mineralization and peak metamorphism at 2.72–2.66 Ga. Two mantle discontinuities strike 065° and 249°, dipping to the southeast and northwest, respectively. These strikes roughly parallel the northern margin of the Superior craton and some intra‐cratonic features such as the axis of the Quetico Basin. Two discontinuities strike 355° and 187°, dipping to the east and west, respectively, and parallel to the western margin of the craton. Our new observations reveal neither moderately dipping, east‐west striking discontinuities nor coherent eclogitic layers characteristic of modern plate tectonic subduction zones. Prominent east‐ and west‐dipping mantle structures relate best to a Paleoproterozoic (Trans‐Hudson) deformation, which is rarely observed in the crust. A new analysis of mantle xenoliths and xenocrysts indicates that carbonatitic metasomatism predominates above some discontinuities where strongly localized conductivity occurs whereas kimberlitic metasomatism predominates below the discontinuities in the broadly conductive mantle.

Specifics of the Caledonian Collision in the Ol’khon Region (Lake Baikal, Russia)

Abstract—Analysis of geochemical, geochronological, and new geophysical data on metasedimentary and igneous rocks of the Ol’khon region has made it possible to substantiate: (1) the absence of products of the Caledonian suprasubduction magmatism from the adjacent part of the Siberian craton and (2) the presence of a product of this magmatism in the Anga–Talanchan island arc, namely, the Krestovsky massif with gabbro-diorite to granite phases. This suggests subduction of the Paleoasian oceanic crust under the island arc before the collision. The geophysical data showed a steep sinking of the Siberian craton margin. This sinking and the supposed contrary movement and rotation of the Siberian craton prevented the appearance of a subduction zone beneath the craton during the collision but caused the wide development of fault plates in the fold belt at the late collision stage. The residue of oceanic crust slab was pressed out along the fault planes near the surface and formed a row of gabbro-pyroxenite massifs of the Birkhin Complex in the fold belt, where syncollisional granitic melts (Sharanur Complex) formed at the same time. The interaction of two contrasting melts gave rise to the Tazheran and Budun alkaline syenite massifs and alkaline metasomatites of the Birkhin and Ulanganta gabbroid massifs.

Subduction: The recycling engine room for global metallogeny

The formation of ore deposits, within mineral systems that represent highly anomalous concentrations of economic elements in localized parts of the Earth’s crust, first requires an enriched and available source of those elements. In early Earth history, initial enrichment in the upper mantle was arguably through mantle plumes that even recycled metals from the core-mantle boundary. From the Mesoarchean onwards, the development of plate tectonics allowed subduction processes to be increasingly important in both recycling of elements from the upper mantle into the lower crust and from there into the upper crust where mineral deposits could form and be exploited. The most obvious expression of this recycling process is the direct association of porphyry-high-sulfidation epithermal-skarn Cu-Au-Ag +/- Mo systems and inboard fractionated granite-associated Sn-W systems with magmatic-hydrothermal fluids derived from subduction-related magmas in convergent margins, where epithermal Au-Ag systems also developed due to high thermal gradients. Syn-subduction VMS Cu-Zn-Pb(Au) systems were accreted at convergent margins. Most orogenic gold systems relate to fluids released through devolatilization of down-going subduction slabs and overlying metal-rich sediment wedges. More indirect associations relate to the ability of subduction zones to cause structural damage and metasomatize and fertilize sub-continental mantle lithosphere along the margins of bordering craton margins. Orogen collapse in the final stages of the subduction-related orogenic event led to asthenosphere upwelling and formation of proximal intrusion-related and more distal Carlin-type gold systems in continental basins on the craton margins. During subsequent orogenic events, previously metasomatized and fertilized mantle lithosphere was reactivated to release hydrothermal fluids to form many of the orogenic gold systems in eastern China. Reactivation of the metasomatized lithosphere also resulted in development of post-subduction hybrid or alkaline magmas that generated giant magmatic Kiruna-type Fe-P, carbonatite-related REE-Nb or Cu-P, and lamproite-related diamond systems, together with magmatic-hydrothermal IOCG mineral systems near craton margins. Subduction-damaged craton margins and their rift-related marginal basins became the sites of formation of Zambian Copper Belt-type deposits and the craton margins were reactivated during subsequent rifting allowing intrusion of giant Ni-Cu mafic–ultramafic bodies along lithosphere-tapping fault zones at those margins. Thus, subduction acts as the recycling engine room or factory responsible for many of the global giant mineral systems that are currently exploited.

Decratonization by rifting enables orogenic reworking and transcurrent dispersal of old terranes in NE Brazil

Dispersion and deformation of cratonic fragments within orogens require weakening of the craton margins in a process of decratonization. The orogenic Borborema Province, in NE Brazil, is one of several Brasiliano/Pan-African late Neoproterozoic orogens that led to the amalgamation of Gondwana. A common feature of these orogens is that a period of extension and opening of narrow oceans preceded inversion and collision. For the case of the Borborema Province, the São Francisco Craton was pulled away from its other half, the Benino-Nigerian Shield, during an intermittent extension event between 1.0–0.92 and 0.9–0.82 Ga. This was followed by inversion of an embryonic and confined oceanic basin at ca. 0.60 Ga and transpressional orogeny from ca. 0.59 Ga onwards. Here we investigate the boundary region between the north São Francisco Craton and the Borborema Province and demonstrate how cratonic blocks became physically involved in the orogeny. We combine these results with a wide compilation of U–Pb and Nd-isotopic model ages to show that the Borborema Province consists of up to 65% of strongly sheared ancient rocks affiliated with the São Francisco/Benino-Nigerian Craton, separated by major transcurrent shear zones, with only ≈ 15% addition of juvenile material during the Neoproterozoic orogeny. This evolution is repeated across a number of Brasiliano/Pan-African orogens, with significant local variations, and indicate that extension weakened cratonic regions in a process of decratonization that prepared them for involvement in the orogenies, that led to the amalgamation of Gondwana.

Magmatic cannibalisation of a Permo-Triassic Ni-Cu-PGE-(Au-Te) system during the breakup of Pangea – Implications for craton margin metal and volatile transfer in the lower crust

The Ivrea Zone of NW Italy records the polyphased evolution of a magmatic sulfide mineral system, which occurred at multiple stages over a >80 Ma time interval. Between 290 and 250 Ma, a series of hydrated and carbonated ultramafic alkaline pipes containing Ni-Cu-PGE-(Te-Au) mineralisation was emplaced in the lower continental crust. At 200 Ma, a subsequent mineralising event occurred in association with the emplacement of the La Balma-Monte Capio (LBMC) intrusion. Modelling of the LBMC parental magma shows derivation from up to 60% partial melting of an anhydrous depleted juvenile mantle outside of garnet stability. The inferred composition of the parental melt is consistent with magmatism associated with the Central Atlantic Magmatic Province (CAMP). However, its tellurium-enriched composition together with the S-C-O isotope signature of the associated magmatic sulfide mineralisation (δ34S = +0.53 to +1.00‰; δ13C = −10.41 to −4.07‰; δ18O = +6.57 to +13.74‰) cannot be reconciled with the CAMP source. It is argued that the geochemical and isotopic signature of the LBMC intrusion reflects interaction and mixing of a primitive magma sourced from a juvenile source with localised domains enriched in carbonate and metal-rich sulfides located in the lower crust, consistent with the composition of the Permo-Triassic pipes. We propose that this interaction resulted in sulfide-supersaturation and enrichment in volatiles and metals of the LBMC magma. Upwards magma transport may have been facilitated by devolatisation of magmatic carbonate from the pipes and the generation of a CO2 supercritical fluid that acted as buoyancy aid for the dense sulfide liquid. Evidence of this magmatic interaction informs on the first-order processes that control enhanced metallogenic fertility along the margins of lithospheric blocks. The scenario depicted here is consistent with reactivation and enrichment of a Gondwana margin Ni-Cu-PGE-(Te-Au) mineral system during the breakup of Pangea.

Lateral flow of thick continental lithospheric mantle during tectonic quiescence

The amalgamation of continental blocks naturally results in a lithosphere with lateral variations in thickness due to the juxtaposition of thicker cratonic and thinner orogenic lithospheres, which in turn evolve together through time. After the amalgamation, this mosaic of continental blocks can experience longstanding periods of relative tectonic quiescence until the next tectonic event, for instance continental rifting. Using geodynamic numerical models, we explored the internal deformation of the continental lithosphere during periods of tectonic quiescence taking into account lateral variations of lithospheric thickness. We observed that the orientation of lateral flow of the thick cratonic lithosphere depends primarily on the compositional density contrasts (Δρ) between the asthenosphere and continental lithospheric mantle and on the width of the juxtaposed mobile belt lithosphere. In the case of mobile belts wider than 300 km, the margin of the thick craton flows towards (or underplates) the base of the thin lithosphere when Δρ ≥ 32−48 kg/m3, whereas for smaller Δρ values, the thick cratonic margin flows away from mobile belt, preserving a sharp thickness variation. For mobile belts narrower than 300 km, the Δρ threshold between underplate or outward behavior decreases with the mobile belt width. Underplating of cratonic lithosphere beneath the thin lithosphere is efficient in mobile belts narrower than 300 km and for higher Δρ, which allows them to cool, thicken and stiffen. Lateral flow of cratonic lithosphere is not efficient to underplate wide mobile belts thoroughly, so the latter are influenced by asthenospheric heat for prolonged periods and thus remain less rigid. Therefore, we propose that protracted tectonic quiescence of supercontinents can develop lithospheric rheological inheritances that may or may not facilitate post-quiescence continental lithospheric rifting.

Geochemical Characteristics of Quartzite in Parts of Paleoproterozoic Dhanjori Group, Singhbhum Craton, Eastern India: Implications for Provenance and Paleoweathering

Abstract Singhbhum craton preserves the records of sedimentation, magmatism, and tectono-thermal events from Mesoarchaean to Neoproterozoic. The Dhanjori Group (DG), located on the northeast margin of the Singhbhum craton, comprises of a variety of rocks including quartz pebble conglomerate, quartzite, schist, interlayered with mafic to intermediate and rarely acidic lava flows, tuff and agglomerate. Petrography and geochemical characteristics of the Dhanjori quartzite have been undertaken to interpret paleoweathering and provenance characteristics. Studied quartzites are made up of abundant quartz, feldspar, mica, and lithic fragments. With the help of geochemical data, the studied quartzites are classified as quartz-arenites and sub-arkoses. In addition to the A-CN-K plot, various chemical indices such as the chemical index of weathering (CIW), chemical index of alteration (CIA), and plagioclase index of alteration (PIA) indicate moderate to intense chemical weathering of the provenance under semi-humid climatic conditions. Rare earth element (REE) chondrite normalized patterns of the studied samples illustrate enriched light rare earth elements (LREEs) (LaN/SmN = 3.11 – 6.19), depleted heavy rare earth elements (HREEs) (GdN/YbN = 0.35 – 3.12) and negative Eu anomaly (Eu/Eu* = 0.55 - 0.87, ~ 0.68). Such patterns are similar to that of the upper continental crust (UCC). In the discrimination function diagram, studied samples of the Dhanjori Group fall in quartzose sedimentary field. In addition, La/Sc vs. Th/Co and La-Th-Sc diagrams, various ratios like Th/Sc (~0.61), La/Sc (~4.42), Th/Co (~0.03), La/Co (~0.11), and Cr/Th (~141.62) imply a mixed provenance for the studied samples. Hence, it has been inferred that the meta-sediments and orthoamphibolites of the older metamorphic group, Singhbhum granitoid complex, as well as associated Archaean metavolcanic suites, would have acted as the probable source rocks for the studied Dhanjori quartzites.

Ultramafic intrusions hosting Ni–Cu sulfide mineralization along a suture zone in the southwestern margin of the Amazonian craton, Brazil: Examples from Morro Sem Boné, Morro do Leme and their satellite intrusions

This research paper describes several medium-to small-sized ultramafic intrusions located along the Mesoproterozoic Guaporé Suture Zone in the southwestern margin of the Amazonian craton. Apart from minor sheared zones, ultramafic rocks have igneous minerals and textures largely preserved. Metamorphic parageneses of metapelites and amphibolites of country rocks, as well as those from sheared zones of the ultramafic intrusions, are indicative of the amphibolite facies of regional metamorphism. Intersections of disseminated to massive sulfides consisting mainly of pyrrhotite and pyrite are common in the metamorphosed volcanic and sedimentary country rocks. The ultramafic intrusions consist mainly of olivine cumulates with high MgO contents (up to 45.9 wt%) and Mg# (up to 0.84), consistent with the composition of their most primitive olivine (Fo93). The crystallization sequence, dominated by olivine, orthopyroxene and chromite, together with ratios and patterns of incompatible trace elements of ultramafic cumulates, support the interpretation that they originated from a high-MgO magma partially contaminated with crustal rocks. Sulfide mineralization in the ultramafic intrusions comprises different styles of magmatic sulfides associated with cumulate rocks, including contact-type, stratabound-type and conduit hosted mineralization. Significant intersections of interstitial to net-textured sulfides consisting of pyrrhotite, pentlandite and chalcopyrire have variable but generally low Ni–Cu-PGE contents (e.g., ~20 m at 0.5 wt% Ni, 0.1 wt% Cu, and 0.5 ppm Pt+ Pd). The range of tenors of Ni, Cu, Pt and Pd, from moderate to very low, is interpreted as resulting from varying efficiency of equilibration of sulfide xenomelts incorporated from the sulfide-bearing country rocks. The Ni–Cu-PGE mineralized ultramafic intrusions are interpreted to belong to a network of magma conduits and staging magma chambers intruding the sulfide-bearing volcanic-sedimentary sequence. Our results indicate an additional prospective belt of high-MgO Ni–Cu-PGE sulfide mineralized intrusions located in a cratonic margin in Brazil.

Tectonic juxtaposition of plume and subduction derived magmatic sequences in the Bababudan greenstone terrane, western Dharwar Craton, India: Constraining crustal accretion processes in a Neoarchean subduction-collision orogeny

Archean greenstone belts in the Western Dharwar Craton preserve important clues on Early Earth geodynamics. Here we investigate the ultramafic-mafic metavolcanic rock sequences from the Santaveri Formation of Bababudan greenstone terrane to address the tectonic evolution, mantle dynamics and crustal growth processes of western Dharwar Craton. The ultramafic volcanic rocks are geochemically classified as komatiite-picrite-basanites, whereas the mafic volcanic rocks correspond to magnesian andesite -Niobium-enriched basaltic andesite association. The pristine mineralogy for these ultramafic volcanic rocks is overprinted by tremolite-actinolite-biotite assemblage marking greenschist facies of metamorphism. The komatiites include Al-undepleted, Al-depleted and Ti-enriched types and share overlapping geochemical characteristics with the picrites. The basanites are distinguished as alkaline ultramafic rocks with total alkali content >3 wt% and MgO > 18 wt%. The coherent association of komatiite-picrite-basanite suggests pervasive plume-lithosphere interaction and complies with polybaric melting of a chemically heterogeneous mantle plume through a subduction-modified sub-continental lithospheric mantle at a rifted cratonic margin. Our results substantiate the role of an Archean mantle refertilized by subduction-driven recycling of Mesoarchean supracrustals concurrent with the onset of subduction event at ≥3.2 Ga. The mafic rocks were derived through melting of a hot oceanic slab and mantle hybridization. The xenocrystic zircon grains from komatiite suggest lower crustal inheritance and reworking of basement gneisses by ascending ultramafic melts. The 3177 Ma magmatic age obtained from these zircon grains indicate a Mesoarchean magmatic event in the genesis of the basement gneisses. The emplacement of komatiite-picrite-basanite association and magnesian andesite -Niobium-enriched basaltic andesite lithologies envisages a post 3.1 Ga Neoarchean crustal growth over Mesoarchean protocontinent of WDC. This crust generation episode can be translated in terms of plume-driven bottom-up and subduction-driven top-down tectono-magmatic processes at continental rift and ocean-continent convergence set-up respectively. Geochemical characteristics and petrogenetic aspects suggest that the studied volcanic supracrustals of Bababudan greenstone terrane encapsulate a Neoarchean subduction-collision orogenic system comprising plume-derived komatiite-picrite-basanite and subduction-derived magnesian andesite -niobium-enriched basaltic andesite magmatic sequences tectonically juxtaposed during Neoarchaen (~2.7 Ga) subduction-accretion-collision event.

Oxidation state and metasomatism of the lithospheric mantle beneath the Rae Craton, Canada: strong gradients reflect craton formation and evolution

We present the first oxidation state measurements for the subcontinental lithospheric mantle (SCLM) beneath the Rae craton, northern Canada, one of the largest components of the Canadian shield. In combination with major and trace element compositions for garnet and clinopyroxene, we assess the relationship between oxidation state and metasomatic overprinting. The sample suite comprises peridotite xenoliths from the central part (Pelly Bay) and the craton margin (Somerset Island) providing insights into lateral and vertical variations in lithospheric character. Our suite contains spinel, garnet-spinel and garnet peridotites, with most samples originating from 100 to 140 km depth. Within this narrow depth range we observe strong chemical gradients, including variations in oxygen fugacity (ƒO2) of over 4 log units. Both Pelly Bay and Somerset Island peridotites reveal a change in metasomatic type with depth. Observed geochemical systematics and textural evidence support the notion that Rae SCLM developed through amalgamation of different local domains, establishing chemical gradients from the start. These gradients were subsequently modified by migrating melts that drove further development of different types of metasomatic overprinting and variable oxidation at a range of length scales. This oxidation already apparent at ~ 100 km depth could have locally destabilised any pre-existing diamond or graphite.

Geological conditions, reservoir evolution and favorable exploration directions of marine ultra-deep oil and gas in China

By analyzing the structural background, petroleum geological conditions, and typical regional (paleo) oil and gas reservoirs in marine ultra-deep oil and gas regions in China, this paper reveals the evolution processes of the marine ultra-deep oil and gas reservoirs and the key controlling factors of accumulation. The marine ultra-deep oil and gas resources in China are buried at depth of greater than 6000 m, and are mainly distributed in the Precambrian and Lower Paleozoic strata in the Sichuan, Tarim and Ordos cratonic basins. The development of marine ultra-deep source rocks in China is controlled by cratonic rifts and cratonic depressions with the background of global supercontinent breakup-convergence cycles. The source rocks in Sichuan Basin have the most developed strata, followed by Tarim Basin, and the development strata and scale of Ordos Basin needs to be further confirmed. The marine ultra-deep reservoir in China is dominated by carbonate rocks, and the reservoir performance is controlled by high-energy sedimentary environment in the early stage, superimposed corrosion and fracture in the later stage. The regional caprocks are dominated by gypsum salt rocks, shale, and tight carbonate rock. The ultra-deep oil and gas fields in China have generally experienced two stages of oil-reservoir forming, cracking (or partial cracking) of paleo-oil reservoirs, and late finalization of cracked gas (or highly mature to over mature oil and gas). The oil and gas accumulation is controlled by static and dynamic geological elements jointly. Major hydrocarbon generation center, high quality and large-scale reservoir resulted from karstification of high energy facies belt, thick gypsum rock or shale caprock, and stable trapping and preservation conditions are the key factors for accumulation of ultra-deep oil and gas. We propose three favorable exploration directions, i.e. the areas around intracratonic rift and intracratonic depression, and craton margin.

Transition from alluvial to wave-tide-dominated Meso-Neoarchean shelf sedimentation in the Mankarchua Quartzite, Singhbhum craton, eastern India

The Mankarchua Quartzite is a 300 m thick arenite-dominated succession developed on the southwestern margin of the Singhbhum craton, eastern India. Detrital zircon dates available from the succession suggest the age of the youngest population at 2.9 Ga. The arenite dominant succession with very low degree of deformation or metamorphic overprint preserves the depositional primary sedimentary structures and petrography for reconstruction of depositional setting and tectonic setting with considerable clarity. We classified the Mankarchua Quartzite into three members, namely, in the ascending order, the Rajabasa Member, the Timi Member and the Gurusanga Member. Facies analysis on the succession identifies eleven sedimentary facies that can be related to basin margin alluvial fan, wave-/tide-dominated lower shoreface to shelf transitional environments. The entire succession represents a lower order transgressive sequence presumably controlled by tectono-eustatic base level rise and drowning of a continental shelf. Three members can be related to higher order cycles that are likely to have resulted from local scale basin margin tectonics. Paleocurrent patterns corroborate to the alluvial fan/braided stream and wave-/tide-dominated depositional settings. The succession records transition in a narrow interval from coarse-grained conglomerate-pebbly sandstone to sandstone-siltstone-mudstone dominated facies associations in a Meso-Neoarchean drowning shelf.

Tracking halogen recycling and volatile loss in kimberlite magmatism from Greenland: Evidence from combined F-Cl-Br and δ37Cl systematics

Kimberlite magmatism occurs as a result of volatile fluxed melting of the convecting upper mantle underlying cratonic lithospheric mantle regions. During passage to the Earth's surface, proto-kimberlite magma can interact with, and assimilate, variably enriched cratonic mantle producing hybrid melts consisting of asthenospheric and cratonic mantle components including contributions from metasomatic domains. The halogen elements (F, Cl, Br, I) and chlorine isotope ratios (37Cl/35Cl) are increasingly used as tracers of recycled crustal materials within the Earth's mantle yet are only rarely reported in analyses of kimberlites. As a result, the origin and distribution of halogens in kimberlite magmas is poorly constrained. Here, we present novel, combined elemental (F, Cl, Br) and isotopic (δ37Cl) halogen data for 14 fresh kimberlite samples from the North Atlantic Craton (NAC) of West and South-West Greenland.The F composition of kimberlites from the NAC appears to be controlled by melting in the convecting upper mantle with minimal effect from interaction with metasomatized lithospheric mantle or volatile loss during or after emplacement. By contrast, Cl and Br in the studied samples have undergone significant devolatilization during kimberlite dyke emplacement and post-emplacement processes, whereby up to 99% of the original halogen budget was removed.Whilst all the studied kimberlites broadly follow the same geochemical pattern, there exists some regional variability in their halogen systematics. The northern NAC kimberlite samples from Majuagaa have mantle-like δ37Cl values of −0.2 to −0.5‰ [versus SMOC (standard mean ocean chloride)]. In contrast, kimberlite dykes from Nigerdlikasik and Pyramidefjeld near the southern craton margin display positive δ37Cl values of +0.4‰ to +1.3‰, in addition to a relative Cl and Br enrichment, which is consistent with the assimilation of recycled crust-derived halogens by the kimberlite magmas. The data support a scenario in which recycled halogens were sampled either from within an OIB-type reservoir in the convecting mantle or through interaction with subduction-modified lithospheric mantle reservoir during eruption. We prefer a scenario in which the ascending kimberlite magmas assimilated Cl-rich, metasomatized regions within cratonic mantle lithosphere.