Geochemical Characteristics of Quartzite in Parts of Paleoproterozoic Dhanjori Group, Singhbhum Craton, Eastern India: Implications for Provenance and Paleoweathering

Abstract

Singhbhum craton preserves the records of sedimentation, magmatism, and tectono-thermal events from Mesoarchaean to Neoproterozoic. The Dhanjori Group (DG), located on the northeast margin of the Singhbhum craton, comprises of a variety of rocks including quartz pebble conglomerate, quartzite, schist, inter-layered with mafic to intermediate and rarely acidic lava flows, tuff and agglomerate. Petrography and geochemical characteristics of the Dhanjori quartzite have been undertaken to interpret paleoweathering and provenance characteristics. Studied quartzites are made up of abundant quartz, feldspar, mica, and lithic fragments. With the help of geochemical data, the studied quartzites are classified as quartz-arenites and sub-arkoses. In addition to the A-CN-K plot, various chemical indices such as the chemical index of weathering (CIW), chemical index of alteration (CIA), and plagioclase index of alteration (PIA) indicate moderate to intense chemical weathering of the provenance under semi-humid climatic conditions. Rare earth element (REE) chondrite normalized patterns of the studied samples illustrate enriched light rare earth elements (LREEs) (LaN/SmN = 3.11–6.19), depleted heavy rare earth elements (HREEs) (GdN/YbN = 0.35–3.12) and negative Eu anomaly (Eu/Eu* = 0.55–0.87, ∼ 0.68). Such patterns are similar to that of the upper continental crust (UCC). In the discrimination function diagram, studied samples of the Dhanjori Group fall in quartzose sedimentary field. In addition, La/Sc vs. Th/Co and La-Th-Sc diagrams, various ratios like Th/Sc (∼0.61), La/Sc (∼4.42), Th/Co (∼0.03), La/Co (∼0.11), and Cr/Th (∼141.62) imply a mixed provenance for the studied samples. Hence, it has been inferred that the meta-sediments and ortho-amphibolites of the older metamorphic group, Singhbhum granitoid complex, as well as associated Archaean metavolcanic suites, would have acted as the probable source rocks for the studied Dhanjori quartzites.