We realize efficient operation of the first Stokes (1240.3 nm) and the second Stokes (1485.8 nm) in external cavity diamond Raman lasers (DRLs) through efficient cavity coupling management and study their output performance. Firstly, an output pulse energy of 0.26 mJ at the first Stokes is generated and the slope efficiency is 84.3%, which closely approaches the quantum limit of 85.8%. Secondly, an output pulse energy of 0.26 mJ at the first Stokes and 0.18 mJ at the second are generated simultaneously. The total Raman output pulse energy is 0.44 mJ with a slope efficiency of 73.0%. To our knowledge, this is the highest slope efficiency in dual-wavelength external cavity DRLs. At the maximum pump level, by managing the cavity coupling, the energy ratio of the second Stokes to the first can be changed from 0.69 to 1.92. Highly efficient operation in external cavity DRLs is very important in practical applications, such as remote sensing, scanning lidar and laser range finding.
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