Counterintuitive Behavior Research Articles

When the "Matchmaker" Does Not Have Your Interest at Heart: Perceived Algorithmic Harms, Folk Theories, and Users' Counter-Strategies on Tinder

On online platforms, algorithms help us build and manage our relationships. However, their invisible interventions might also pose harm to these connections. Dating platforms offer a prime example where, despite extensive research on human-inflicted harm, the potential harm from the algorithms themselves, and user strategies for mitigating them, remains largely unexplored. In our analysis of 7,043 reviews and interviews with 30 Tinder users, we unveiled how users perceive algorithmic harm as damaging self-esteem, sabotaging potential relationships, encouraging antisocial behavior, and misrepresenting or marginalizing certain identities. We introduce a new algorithmic folk theory, the "conflict of interest" theory, perceived to perpetuate these harms. This theory encapsulates users' sense of a contradiction between the dating platform's promise of finding the perfect partner (leading to discontinued use of Tinder) and its commercial interest in retaining users to increase revenue. Users suspected various algorithmic processes pursuant to this theory, such as (a) throttling profile visibility, (b) manipulating users' matches, and (c) recommending large quantities of profiles that will not lead to matches. They also described various strategies in resistance or defense of these suspected algorithmic processes, such as engaging in counter-intuitive behaviour to disrupt the unfavorable algorithmic processes or leveraging location based filtering for match variety and safety. We conclude by discussing how the perceived algorithmic harms can inform the development of new algorithmic implementations that balance both user and company interests.

Counter-intuitive effect of the degree of cure of epoxy resins on the compressive strength of continuous fibre composites

It has been observed that some epoxy resins exhibit the greatest elastic stiffness when not fully cured. In this study, this counter-intuitive resin behaviour (stiffness) is shown to be reflected in the compressive strength of associated epoxy fibre composites. A reduction of up to 30% in both properties can be observed when going from incomplete conversion to complete cure. The Budiansky and Fleck compressive failure criterion (Budiansky and Fleck, 1993) is, in this study, proven to be both qualitative and quantitative in its relevance for describing the reduction in compressive strength. This study is of particular importance to engineers and manufacturers of composites, as the conventional belief is that optimum performance is achieved with a complete cure.

Managerial Blurring of Employee Goals

Many researchers and practitioners believe that the lack of specificity of employee goals is detrimental to the effectiveness of performance management in firms. Using an inductive grounded theory approach, this study identifies two managerial factors that could impact negatively goal specificity in real-life corporate environments. First, ‘goal blurring’ is a counterintuitive purposeful managerial behavior that results in blurred employee goals being set during annual reviews. Second, ‘specifying capability’ incorporates factors that can result in a lower level of specificity of employee goals with no purposeful intent. The findings reveal two main reasons managers set less specific goals: (1) limited capability and (2) choice to purposefully blur employee goals to maintain flexibility in evaluating their subordinates. While non-purposeful blurring occurs because of circumstances that make setting specific goals difficult and limit the capabilities of managers to do so, purposeful blurring of goals occurs with the main aim of maintaining flexibility in evaluating employees. As a result, blurred goals are set for employees despite managers’ awareness of the benefits of setting specific goals, which is supported by extensive research and management practice. Our work reveals the purposeful managerial blurring of employee goals, a phenomenon that has a significant impact on firm performance, though it has not been previously identified as such, or explained.

Insights into the band gap anomalies of certain bismuth-based chalcogenides through ab initio calculations of structural and electronic properties

Unlike other conventional metal chalcogenides, where the Perdew-Burke-Ernzerhof (PBE) functional tends to underestimate band gaps, bismuth (Bi) chalcogenides, particularly Bi selenides, exhibit a counterintuitive behaviour with band gap predictions that closely align with experimental results. In this study, we report this anomaly in the band gap prediction of specific Bi-based chalcogenides. The structures of these compounds are of significant interest because their electronic band gaps match well with the reported experimental results when using the PBE functional. This unexpected and counterintuitive deviation, observed in this class of materials, offers valuable insights for material scientists studying compounds in this category.

Designing Plastrons for Underwater Bubble Capture: From Model Microstructures to Stochastic Nanostructures.

Bubbles and foams are often removed via chemical defoamers and/or mechanical agitation. Designing surfaces that promote chemical-free and energy-passive bubble capture is desirable for numerous industrial processes, including mineral flotation, wastewater treatment, and electrolysis. When immersed, super-liquid-repellent surfaces form plastrons, which are textured solid topographies with interconnected gas domains. Plastrons exhibit the remarkable ability of capturing bubbles through coalescence. However, the two-step mechanics of plastron-induced bubble coalescence, namely, rupture (initiation and location) and subsequent absorption (propagation and drainage) are not well understood. Here, the influence of 1) topographical feature size and 2) gas fraction on bubble capture dynamics is investigated. Smaller feature sizes accelerate rupture while larger gas fractions markedly improve absorption. Rupture is initiated solely on solid domains and is more probable near the edges of solid features. Yet, rupture time becomes longer as solid fraction increases. This counterintuitive behavior represents unexpected complexities. Upon rupture, the bubble's moving liquid-solid contact line influences its absorption rate and equilibrium state. These findings show the importance of rationally minimizing surface feature sizes and contact line interactions for rapid bubble rupture and absorption. This work provides key design principles for plastron-induced bubble coalescence, inspiring future development of industrially-relevant surfaces for underwater bubble capture.

Ricardo’s Law of Comparative Advantage in Bronze Age, Iron Age, and Early Historic Mainland Southeast Asian Metallurgy: Copper-base Metal Production, Exchange, and Consumption Behaviours at Khao Sai On, Nil Kham Haeng, Non Pa Wai, Phromthin Tai, Sab Champa, and Tha Kae in Central Thailand

Since its late 1970s to early 1980s discovery, the Khao Wong Prachan Valley (KWPV) of central Thailand has been assumed to have been a major supplier of copper in Bronze Age, Iron Age, and Early Historic Southeast Asia. KWPV was the first regional metal production system to be characterised by lead isotope (LI) analysis in the late 2000s, revealing a coherent signature easily distinguished from subsequent analyses of production systems at Phu Lon (northern Thailand) and the Vilabouly Complex (central Laos). Despite KWPV’s scale of production, its LI signature has scarcely been detected at Bronze Age metal consumption sites in nearby northeast Thailand and not at all in Iron Age assemblages. We study copper production and copper/bronze consumption behaviours of Iron Age and Early Historic sites in KWPV’s immediate vicinity: Khao Sai On, Phromthin Tai, Tha Kae, and Sab Champa. Khao Sai On and Phromthin Tai production signatures are highly consistent with those previously established, while the uranogenic tendency at Tha Kae explains outliers from Bronze Age Non Pa Wai and Nil Kham Haeng. Analysis of consumption assemblages reveals little to no consistency with local production signatures. This tendency was tested with LI Iron Age and Early Historic datasets for Ban Khu Muang, Ban Mai Chaimongkol, Ban Pong Manao, and Ban Pong Takhob. The pattern is clear: central Thai populations imported copper/bronze, potentially from the Vilabouly Complex or production loci with closely comparable signatures. We examine this counterintuitive behaviour inductively using Ricardo’s Law of Comparative Advantage combined with a technological appreciation of the relatively low productivity of central Thai primary copper production. This suggests central Thailand’s unattached copper producers freely exchanged copper for exotic goods (bronze, glass, semi-precious stone), with potentially poor terms of exchange, from their desire to participate in wider regional trends in conspicuous consumption.

Bubbles enable volumetric negative compressibility in metastable elastocapillary systems

Although coveted in applications, few materials expand when subject to compression or contract under decompression, i.e., exhibit negative compressibility. A key step to achieve such counterintuitive behaviour is the destabilisations of (meta)stable equilibria of the constituents. Here, we propose a simple strategy to obtain negative compressibility exploiting capillary forces both to precompress the elastic material and to release such precompression by a threshold phenomenon – the reversible formation of a bubble in a hydrophobic flexible cavity. We demonstrate that the solid part of such metastable elastocapillary systems displays negative compressibility across different scales: hydrophobic microporous materials, proteins, and millimetre-sized laminae. This concept is applicable to fields such as porous materials, biomolecules, sensors and may be easily extended to create unexpected material susceptibilities.

Observing Majorana fermion dynamic properties on a NISQ computer

Majorana particles are of particular interest due to their profound property of being their own anti-particles and potential applications for quantum computers. However, studying the dynamics of Majorana particles experimentally has proven to be challenging, with many unanswered questions about their behaviors. In this paper, we demonstrate that an improved discrete-time quantum walks (DTQW) on a Noisy Intermediate-Scale Quantum (NISQ) computer can be used to construct a well-defined Majorana fermion. Through this approach, we can observe the behaviors of Majorana particle propagation both in (1 + 1)- and (3 + 1)-dimensions. A counter-intuitive dynamic behavior of the non-vanishing expectation value of velocity and position with zero expectation value of momentum from the superposition of positive and negative energy solution is observed for the first time in NISQ. Our findings provide a promising avenue for experimentally studying the dynamical properties of Majorana particles.

Parametric optimization of selected auxetic structures

Auxetic materials exhibit an interesting, counterintuitive behavior—when subjected to uniaxial tension, they stretch laterally, and when uniaxially compressed, they shrink laterally. In contrast to conventional materials, in auxetics, the value of Poisson’s ratio is negative. Behavior of auxetic materials is an effect of their internal structures. The auxetic effect depends mostly on the geometry of their internal unit cells and not on the properties of the bulk material. This paper presents the results of parametric optimization of selected two-dimensional auxetic unit cells with the aim to identify the geometrical parameters which exhibit the strongest influence on the value of Poisson’s ratio in each unit cell, and to identify geometries which exhibit the strongest auxetic effect. The optimization was conducted through numerical simulation with the use of the finite element method in commercial software. Response surface optimization and multi-objective genetic algorithm (MOGA) were applied. Obtained candidate geometries were verified via additional FEM analyses and confirmed to have improved auxetic effect and reduced equivalent stress. 5 × 5 structures composed of reference and optimized geometries of analyzed unit cells were subjected to similar analyses and it was confirmed that the optimization of singular unit cells caused an improvement of auxetic effect and reduction in equivalent stress in regular structures composed of multiple unit cells.

Bone osteon-like structures: A biomimetic approach towards multiscale fiber-reinforced composite structures

Natural materials show astonishing mechanical properties, despite their rather poor building blocks. This counterintuitive behavior can be traced back to their hierarchical organization that enhances the properties of the building blocks. A classic example is bone: lightweight, stiff, strong, yet tough. This property combination is attributed particularly to the microstructure, where osteons deflect and arrest cracks. In this work, we mimic the bone microstructure with fiber-reinforced composites: we perform a numerical parametric study, by varying the layup of the osteon-like structures (OLS) and interconnecting layers representing the interstitial bone lamellae, and we manufacture and test single OLS as proof of concept. Results show the key role of OLS and interconnecting layers in deflecting and arresting cracks, whereas the combination of diverse materials affects the elastic properties. Finally, the introduction of hollow OLS, not affecting fracture toughness, might be used to expand the material functionality, paving the way toward novel multifunctional composites.

Effect of different strut thickness on the mechanical behaviour of 3D printed auxetic structures

In the recent era, the demand for structure design and materials that have mechanical properties to absorb high energy absorption and fracture resistance is growing exponentially. In order to meet the demand for intently designed structures, various structures have been designed and made. Among different design structures, auxetic design structures emerged as a flexible design that fulfilled the needs available in different application fields such as aerospace, defence, biomedical, structural, sponge mops, and many more. The main advantage of auxetic design structure is to show the property of negative Poisson’s ratios (NPR). The materials with NPRexhibit unusual and counterintuitive mechanical behaviour. It means the materials become flatter when stretched. This property allows them to exhibit exceptional mechanical characteristics that make them ideal for a wide range of applications. Further, fabrication techniques were also impacted by the mechanical performance of the auxetic structure. In the context of different fabrication techniques, 3D printing was found to be the most effective method to induce significant mechanical strength in the fabricated parts.Therefore, the present work focuses on the fabrication of auxetic structures using fused deposition modelling (FDM), and FDM is a kind of 3D (Three Dimensional) printing technique. Furthermore, experiments were performed with variations in strut wall thickness ranging from 0.4 to 1.2mm. In order to evaluate the mechanical performance of fabricated structures, compressive testing was performed on the Universal Testing Machine (UTM). In addition, the effect of different strut wall thicknesses on compressive mechanical behaviour was evaluated. The results showed that the maximum compressive strength, compressive Young’s modulus, compressive yield strength, energy absorption capacity, and plateau stress were found to increase with the increase in strut wall thickness.

Transfer of ANS-Like Drugs from Micellar Drug Delivery Systems to Albumin Is Highly Favorable and Protected from Competition with Surfactant by "Reserved" Binding Sites.

Micellar drug delivery systems (MDDS) for the intravenous administration of poorly soluble drugs have great advantages over alternative formulations in terms of the safety of their excipients, storage stability, and straightforward production. A classic example is mixed micelles of glycocholate (GC) and lecithin, both endogenous substances in human blood. What limits the use of MDDS is the complexity of the transitions after injection. In particular, as the MDDS disintegrate partially or completely after injection, the drug has to be transferred safely to endogenous carriers in the blood, such as human serum albumin (HSA). If this transfer is compromised, the drug might precipitate─a process that needs to be excluded under all circumstances. The key question of this paper is whether the high local concentration of GC at the moment and site of MDDS dissolution might transiently saturate HSA binding sites and, hence, endanger quick drug transfer. To address this question, we have used a new approach, which is time-resolved fluorescence spectroscopy of the single tryptophan in HSA, Trp-214, to characterize the competitive binding of GC and the drug substitute anilinonaphthalenesulfonate (ANS) to HSA. Time-resolved fluorescence of Trp-214 showed important advantages over established methods for tackling this problem. ANS has been the standard "model drug" to study albumin binding for decades, given its structural similarity to the class of naphthalene-containing acidic drugs and the fact that it is displaced from HSA by numerous drugs (which presumably bind to the same sites). Our complex global fit uses the critical approximation that the average lifetimes behave similarly to a single lifetime, but the resulting errors are found to be moderate and the results provide a convincing explanation of the, at first glance, counterintuitive behavior. Accordingly, and largely in line with the literature, we observed two types of sites binding ANS at HSA: 3 type A, rather peripheral, and 2 type B, likely more central sites. The latter quench Trp-214 by Förster Resonance Energy Transfer (FRET) with a rate constant of ≈0.4 ns-1 per ANS. Adding millimolar concentrations of GC displaces ANS from the A sites but not from B sites. At incomplete ANS saturation, this causes a GC-induced translocation of ANS from A to the more FRET-active B sites. This leads to the apparent paradox that the partial displacement of ANS from HSA increases its quenching effect on Trp-214. The most important conclusion is that (ANS-like) drugs cannot be displaced from the type-B sites, and consequently, drug transfer to these sites is not impaired by competitive binding of GC in the vicinity of a dissolving micelle. The second conclusion is that for unbound GC above the CMC (9 mM), ANS equilibrates between HSA and GC micelles but with a strong preference for free sites on HSA. That means that even persisting micelles would lose their cargo readily once exposed to HSA. For all MDDS sharing this property, targeted drug delivery approaches involving them as the nanocarrier would be pointless.

Creep Versus Consolidation in Tunnelling Through Squeezing Ground—Part A: Basic Time Effects

Although squeezing ground may undergo rapid convergences following tunnel excavation, its behaviour is often markedly time dependent due to creep or consolidation. The effects of creep and consolidation on shield tunnelling are comparatively evaluated in two companion papers, with the aim of demonstrating their qualitative similarities and distinctive features. The present, first paper investigates the basic time effects, placing focus on the time development of ground deformations and the complex interaction between ground, tunnel boring machine (TBM) and tunnel support during excavation and during construction standstills. The presented numerical simulations indicate several qualitative similarities between the two mechanisms of time dependency, in respect of the time development of ground deformations, the counter-intuitive behaviour of increasing shield loading with increasing rate of advance under certain conditions, as well as the thoroughly adverse effect of the additional time-dependent deformations taking place during construction standstills on the shield loading. However, they also underscore two prominent differences resulting from the fundamentally different nature of creep (a purely mechanical rheological process) and consolidation (a coupled hydromechanical process): first, the consistently more extensive plastic yielding in consolidating ground, which is partially associated with the seepage forces exerted by the pore water on the solid rock constituents. Second, the role of seepage forces as a potential destabilising agent, particularly for the tunnel face, which does not happen in the case of creep and may be critical for shield and cutterhead jamming. Building upon these investigations, the companion paper compares creep and consolidation with respect to the transferability of experiences about the required thrust force to tunnels of different diameter or to adjacent tunnels.

Unraveling Reactivity Differences: Room-Temperature Ring-Opening Metathesis Polymerization (ROMP) versus Frontal ROMP.

In this study, we explore the distinct reactivity patterns between frontal ring-opening metathesis polymerization (FROMP) and room-temperature solventless ring-opening metathesis polymerization (ROMP). Despite their shared mechanism, we find that FROMP is less sensitive to inhibitor concentration than room-temperature ROMP. By increasing the initiator-to-monomer ratio for a fixed inhibitor/initiator quantity, we find reduction in the ROMP background reactivity at room temperature (i.e., increased resin pot life). At elevated temperatures where inhibitor dissociation prevails, accelerated frontal polymerization rates are observed because of the concentrated presence of the initiator. Surprisingly, the strategy of employing higher initiator loading enhances both pot life and front speeds, which leads to FROMP rates exceeding prior reported values by over 5 times. This counterintuitive behavior is attributed to an increase in the proximity of the inhibitor to the initiator within the bulk resin and to whether the temperature favors coordination or dissociation of the inhibitor. A rapid method was developed for assessing resin pot life, and a straightforward model for active initiator behavior was established. Modified resin systems enabled direct ink writing of robust thermoset structures at rates much faster than previously possible.

Crowding induced switching of polymer translocation by the amalgamation of entropy and osmotic pressure

The translocation of polymers is omnipresent in inherently crowded biological systems. We investigate the dynamics of polymer translocation through a pore in free and crowded environments using Langevin dynamics simulation. We observed a location-dependent translocation rate of monomers showcasing counterintuitive behavior in stark contrast to the bead velocity along the polymer backbone. The free energy calculation of asymmetrically placed polymers indicates a critical number of segments to direct receiver-side translocation. For one-sided crowding, we have identified a critical crowding size revealing a nonzero probability of translocation toward the crowded-side. Moreover, we have observed that shifting the polymer toward the crowded-side compensates for one-sided crowding, yielding an equal probability akin to a crowder-free system. In two-sided crowding, a slight variation in crowder size and packing fraction induces a polymer to switch its translocation direction. These conspicuous yet counter-intuitive phenomena are rationalized by minimalistic theoretical arguments based on osmotic pressure and radial entropic forces.

Organochlorine Insecticide-Dicofol Resilience in Soil Ecosystems: Sorption, Persistence, and Fate Investigations

ABSTRACT Understanding of dicofol’s behavior in soil is crucial for more precise pest control and minimal environmental effect. Therefore, the goal of this study was to assess how the physicochemical characteristics of 10 selected soils effects the sorption and degradation of dicofol behavior. The behavior of dicofol, including its adsorption and desorption properties as well as its rates of hydrolysis and photolysis degradation, was thoroughly examined via definitive studies. Standard batch equilibration mode for sorption revealed that it was dependent on the physical and chemical properties of the soil. Exothermic and spontaneous adsorption processes, which were characterized by a negative Gibbs free energy value, were convincingly proven by thermodynamic study. The current investigation’s ΔG estimations varied from −18.6 kjmol−1 for soil-6 to −24.25 kjmol−1 for soil-9. The soil-7 with a notable organic matter content (1.81%) showed the maximum adsorption, and subsequently producing a C-type isotherm that was analyzed using a linear and Freundlich model. An analytical process using UV-VIS spectrophotometry to determine the fate of dicofol in soil matrices. Hydrolysis and photolysis studies yielded minimum half-lives of 13.4 and 1.32 days, respectively. It has been demonstrated that dicofol molecules interact strongly with soils, principally via physio-sorption mechanisms. In contrast to its strong soil affinity and permanence, dicofol exhibits a counterintuitive behavior that makes it vulnerable to sunlight-induced deterioration. Future studies will concentrate on enhancing these pathways to assist sustainable pesticide management strategies and creative pollution mitigation techniques.

Mechanism of Nitrous Oxide Activation in C(sp2)-O Bond Formation Reactions Catalyzed by Nickel Complexes.

Recent groundbreaking experimental reports demonstrated that Ni complexes bearing a bidentate- or tridentate-bipyridine-based ligand can be used to activate N2O for use as an O-transfer agent in C(sp2)-O bond formation reactions under mild experimental conditions. In this work, quantum chemical calculations are used to shed light on the mechanism through which such metal complexes catalytically activate nitrous oxide, providing new fundamental insights into the development of novel catalysts for N2O revalorization. As a case study, we consider the recent work by Cornella and co-workers (Nature, 2022, 604, 677) concerning the synthesis of phenols from aryl halides at room temperature, which requires the use of an external reducing agent. Our results suggest that the metal center remains in its Ni(II) oxidation state throughout the whole catalytic cycle, despite the presence of various redox steps in the mechanism and the Ni ability to maneuver between a number of oxidation states. This counterintuitive behavior is made possible by the ligand redox activity in the catalytic process, which involves accepting electrons from the reducing agent. Several possible pathways are systematically investigated, each associated with distinct activation modes, kinetics, and reaction outcomes. The governing factors in dictating the preferred path lie in the electronic nature of the ligand (strong vs weak field) and its geometric structure (specifically, the number of coordinating arms). These characteristics play a pivotal role in determining whether the process follows a catalytic or stoichiometric route and can be in principle modulated for the design of new metal complexes with tailored redox properties and reactivity.

Effects of dilatation and turbulence on tangential strain rates in premixed hydrogen and iso-octane flames

The tangential strain rate in premixed flames impacts significantly the flame surface area generation and thus the combustion process. Studies on incompressible isotropic turbulence have revealed that the mean tangential strain rate at material and iso-scalar surfaces is positive and exhibits a universal value when normalized by the Kolmogorov time. This is associated with the preferential alignment of the surface normal with the most compressive principal strain rate. The present study investigates such effects in premixed hydrogen and iso-octane flame kernels using direct numerical simulations. It is shown that the normalized mean tangential strain rate of the investigated flames has a very similar value compared with the incompressible flows. However, in the reaction zone, the flame surface normal aligns preferentially with the most extensive principal strain rate. Furthermore, this alignment depends on the reaction progress variable and the Lewis number, while the tangential strain rate remains independent of these parameters. Such counter-intuitive behaviour is systematically investigated by decomposing the effects of dilatation and residual solenoidal turbulence. It is found that the solenoidal turbulence influences significantly the tangential strain rate. A general effect of turbulence on the tangential strain rate is identified, which is consistent with incompressible flows and independent of the Lewis number and the reaction progress variable. This is a remarkable finding indicating that models of the tangential strain rate developed based on incompressible flows apply also to premixed flames with different Lewis numbers, and, for the modelling, only the solenoidal turbulence should be considered.

Chalcogen Atom Size: A Key Parameter in Modulating Carbonyl Compound Properties.

Exchanging oxygen in the functional group C=O (i. e., carbonyl) for the less electronegative Group 16 elements, sulfur or selenium, unexpectedly enhances the electronegativity of the C=X group in π-conjugated molecules and reduces the molecular π HOMO-LUMO energy gap. Quantum-chemical analyses revealed that the steric size of the chalcogen atom X is at the origin of this seemingly counterintuitive behavior. This tuning of the chemical properties of carbonyl compounds by varying the chalcogen atom size in the C=X bond can be applied in many fields of chemistry. This concept article delineates several useful applications in the fields of organocatalysis, supramolecular chemistry, and photo(electro)chemistry.

Observer effect, quasi-probabilities and generalized Specker's boxes.

Quantum non-locality and contextuality can be simulated with quasi-probabilities, i.e. probabilities that take negative values. Here, we show that another quantum phenomenon, the observer effect, admits a quasi-probabilistic description too. We also investigate post-quantum observer effects based on the Specker's triangle scenario. This scenario comprises three observables, with the possibility of measuring two simultaneously. Represented as three boxes with a hidden ball, this scenario exhibits counterintuitive behaviour: regardless of the chosen pair of boxes, one box always contains the ball. Moreover, the scenario demonstrates a strong observer effect. When an observer selects and opens the first box, finding it empty, the ball is guaranteed to be in the second box, thereby allowing the observer to determine the ball's location among the remaining two boxes. We extend this scenario to include additional boxes and multiple balls. By employing negative probabilities, we demonstrate amplification of the observer effect. This article is part of the theme issue 'Quantum contextuality, causality and freedom of choice'.