Cone Calorimeter Research Articles

Radially and Axially Oriented Ammonium Alginate Aerogels Modified with Clay/Tannic Acid and Crosslinked with Glutaraldehyde.

Lightweight materials that combine high mechanical strength, insulation, and fire resistance are of great interest to many industries. This work explores the properties of environmentally friendly alginate aerogel composites as potential sustainable alternatives to petroleum-based materials. This study analyzes the effects of two additives (tannic acid and montmorillonite clay), the orientation that results during casting, and the crosslinking of the biopolymer with glutaraldehyde on the properties of the aerogel composites. The prepared aerogels exhibited high porosities between 90% and 97% and densities in the range of 0.059-0.191 g/cm3. Crosslinking increased the density and resulted in excellent performance under loading conditions. In combination with axial orientation, Young's modulus and yield strength reached values as high as 305 MPa·cm3/g and 7 MPa·cm3/g, respectively. Moreover, the alginate-based aerogels exhibited very low thermal conductivities, ranging from 0.038 W/m·K to 0.053 W/m·K. Compared to pristine alginate, the aerogel composites' thermal degradation rate decreased substantially, enhancing thermal stability. Although glutaraldehyde promoted combustion, the non-crosslinked aerogel composites demonstrated high fire resistance. No flame was observed in these samples under cone calorimeter radiation, and a minuscule peak of heat release of 21 kW/m2 was emitted as a result of their highly efficient graphitization and fire suppression. The combination of properties of these bio-based aerogels demonstrates their potential as substituents for their fossil-based counterparts.

Impact of rendering cover on thermal behavior of graphite-enhanced expanded polystyrene exposed to external radiation

This study explores the thermal behavior of graphite-enhanced expanded polystyrene (GEPS) both with and without a rendering cover during cone calorimeter testing. We designed a sample holder with inserted thermocouples to capture temperature variations at different levels. Without a cover, the sample remained unignited under radiant intensity of 25 kW m−2, experiencing a brief temperature rise followed by stabilization. At 50 kW m−2, ignition occurred after a period of steady temperature. However, at 75 kW m−2, the temperature soared rapidly without a stable phase, leading to swift ignition. With a cover, the temperatures for all tested scenarios ultimately stabilized without ignition, even though the recorded values exceeded the ignition point under high heat fluxes. This indicates that the protective mechanism of render lies mainly in isolating mass transfer. Increasing the render's thickness from 3 mm to 5 mm delayed and slowed the initial temperature rise but had little impact on the final steady temperatures. Based on the energy conservation principles, a steady temperature prediction model for liquified GEPS and rendering cover was established. Notably, the calculated outcomes closely align with the measured temperatures. These findings provide valuable insights into the fire safety characteristics of GEPS and the protective effects of rendering covers.

Eco-Friendly Polyurethane Foams Enriched with Waste from the Food and Energy Industries

In recent years, there has been considerable focus on ensuring that energy is used in the most efficient manner possible. This is due to the fact that globally, over 70% of energy is generated from fossil fuels. Consequently, the matter of designing and utilizing materials that will negate energy losses within the construction industry is of paramount importance. Simultaneously, the necessity for a sustainable approach to the design and production of materials is strongly emphasized. This paper presents an innovative approach to the use of a combination of mineral and plant-based fillers in polyurethane foam technology as a thermal insulation material with the potential to be used in construction to reduce energy consumption. Polyurethane composites containing fly ash from biomass combustion and the addition of rice, sunflower, and buckwheat husks as plant fillers were proposed. The structure of the obtained materials was studied, and the most important physical properties were analyzed. These included apparent density, dimensional stability, water absorption, and the effects of UV radiation and water influence on the carbon, hydrogen, nitrogen, and oxygen content. Moreover, the mechanical properties of the materials were investigated, including compressive strength and brittleness. Additionally, the foams were subjected to flammability tests using a cone calorimeter. Furthermore, additional parameters were determined, including the limiting oxygen index and the vertical and horizontal flammability tests. The results demonstrate the beneficial effects of combining mineral and vegetable fillers in polyurethane foam.

Synergistic effect of coal gangue on intumescent flame retardants

Abstract In order to improve the flame retardant properties of wood plywood, intumescent flame retardant coatings were prepared using melamine, borate, pentaerythritol and urea as the basic formulations and gangue as a modified additive. The flame retardancy of the samples was characterized using a cone calorimeter, scanning electron microscope, X-ray diffraction and thermogravimetric analysis. In addition, the study investigated the effect of gangue content on the properties of the prepared coatings. The results show that the doping of gangue in intumescent flame retardant coatings can improve the flame retardant effect of the coatings. Specifically, when the mass fraction of gangue was 8 wt%, the exothermic rate, total smoke production and total exothermic amount of the coating were significantly reduced. Moreover, the addition of gangue promoted the formation of a continuous and dense carbon layer structure during the combustion process of the coating, which produced a molten substance that effectively isolated oxygen and heat, thus strengthening the fire-retardant and heat-insulating properties of the coating. The results of this study provide valuable insights into the development of flame retardant coating formulations for wood plywood.

Fabrication of superior flame-retardant phosphorylated chitosan biobased porous composites reinforced by superhydrophobic silicone interpenetrating crosslinking networks

Chitosan-based porous materials have potential to develop into a new generation of high performance sustainable thermal insulation materials. In this study, hydrophobic and enhanced phosphorylated porous materials (PCSM) were constructed by the in-situ crosslinking of methytrimethoxylsilane (MTMS), and modified SiO2 nanoparticles (H-SiO2) were further incorporated into the crosslinking networks to fabricate superhydrophobic and reinforced PCSM-H-SiO2 porous composites. The morphology of PCSM-H-SiO2 porous materials exhibited special micro-nanoscale “pearl string-like” rough and interpenetrating pore wall structure, which endowed them superhydrophobicity and self-cleaning ability. The water contact angles (WCAs) of PCSM-H-SiO2 porous composites achieved up to 150o, and the compressive and specific moduli of PCSM2-H-SiO2–2 porous composite significantly increased to 11.0 MPa and 89.6 m2·s−2, 5.39 and 1.74 times higher than those of PCS porous material, respectively. The limited oxygen index (LOI) values of PCSM2-H-SiO2–2 porous composite were above 80 %. The cone calorimeter test result demonstrated the peak heat release rate and total heat release rate values of PCSM-H-SiO2–2 porous composite were lower than those of PCS porous material. The ultra-high flame-retardant PCSM-H-SiO2–2 porous composite with superhydrophobicity and excellent compressive property is a promising biodegradable thermal-insulation material as replacement of petroleum-based material.

Magnetic, self-heating and superhydrophobic sponge decorated with BN and CoFe2O4 for high-efficient cleanup of crude oil spills using facile co-precipitation strategy

Accidents involving petrochemical spills have repeatedly threatened the security of the eco-environment. The leaked crude oil exhibits poor fluidity, low adsorption efficiency, and urgent issues such as potential fire risks that require immediate attention. Herein, a multifunctional superhydrophobic sponge Si@CFO@BN@PU was prepared by a simple co-precipitation strategy based on BN and CoFe2O4. The results demonstrate that Si@CFO@BN@PU exhibits excellent superhydrophobic properties, with a water contact angle of 162° and a slide angle of less than 10°, and oil adsorption capacity ranging from 32.3 to 68.4 g/g. Furthermore, the modified sponge also possesses certain magnetic properties, allowing Si@CFO@BN@PU to be moved on the water surface via an external magnetic field and effectively adsorb floating oil. Meanwhile, the modified sponge exhibits excellent photothermal properties. The whole sponge can be heated up to 80 °C in just 60 s under simulated sunlight conditions, effectively reducing the adsorption time of viscous oil by 90 %. Moreover, the cone calorimeter test results demonstrate excellent fire safety of Si@CFO@BN@PU even after adsorption of petroleum. The peak heat release rate (pHRR), total heat release (TSR), maximum CO release rate, and maximum CO2 release rate have decreased by 37.8 %, 23.3 %, 45.4 %, and 34.1 %, respectively. Therefore, Si@CFO@BN@PU is an effective, safe and sustainable new adsorbent material with a wide range of applications in treating petrochemical spills.

Measuring the fire growth potential of combustible solids using a cone calorimeter

The fire growth rate of interior linings, furnishings, and construction materials is measured in full-scale fire tests such as the ASTM E84 Steiner Tunnel, the ISO 9705 room fire, and a passenger aircraft fuselage as the flame-spread rate, time-to-flashover, or time to incapacitation, respectively. The results are used to indicate the level of passive fire protection afforded by the combustible material or product in the test without providing any insight into the burning process. These large-scale tests require many square meters of product, are very expensive to conduct, and can exhibit poor repeatability–making them unsuitable for product development, quality control, product surveillance, or regulatory compliance. For this reason, smaller (0.01 m2) samples are tested in bench-scale fire calorimeters under controlled conditions, and these one-dimensional burning histories are correlated with the results of the two- and three-dimensional burning histories in full-scale fire tests by a variety of empirical and semi-empirical fire propagation indices, as well as analytic and computer models specific to the full-scale fire test. The approach described here defines the potential of a material to grow a fire in terms of cone calorimeter data obtained under standard conditions. The fire growth potential, λ (m2/J), is the coupled process of surface flame spread and in-depth burning that is defined as the product of ignitability (1/ E ign) and combustibility (Δ Q/Δ E) obtained from a combustion energy diagram measured in a cone calorimeter at an external radiant energy flux [Formula: see text] (W/m2) above the critical flux for burning, [Formula: see text]. However, the potential for fire growth, λ≡ (1/ Ei gn)(Δ Q/Δ E) is only realized as a hazard when the heat of combustion of the product per unit surface area, Hc (J/m2), is sufficient to grow the fire. The dimensionless fire hazard of a combustible product of thickness b is therefore, Π = λ Hc, while the fire hazard of the component materials is an average over the product thickness, π = Π/ b. The measurement of λ, Π, and π from combustion energy diagrams of heat release Q (J/m2) versus incident energy E (J/m2) is described, as well as a physical basis for a fire growth potential that provides simple analytic forms for λ in terms of the parameters reported in cone calorimeter tests. Experimental data from the literature show that rapid fire growth in full-scale fire tests of combustible materials occurs above a value of Π determined by the severity of the fire test.

Bio-based boards made of hazelnut shell and A. donax for indoor applications - A solution with good performance in case of fire

The present study investigated the reaction to fire of bio-based boards for indoor applications made of A. donax and hazelnut shells as aggregates. A sodium silicate solution was employed as the adhesive due to its several advantages. Among others, the possibility of moderating some of the main drawbacks of bio-based building composites, such as the resistance to fire. The considered materials were analysed both individually, to test their inherent properties, and when integrated into the composites, ensuring considerations about materials' influence on the final products’ properties. Two different test methods, using a cone calorimeter, were considered and performed. The results showed that the sodium silicate solution avoided flaming and smoking, in case of a constant heat application with and without an igniter (spark), demonstrating the benefit of its use in this type of bio-based composites. Overall, the particleboards demonstrated their ability to comply with fire behaviour consistent with the Class A1 requirements, while the bio-components on themselves were characterized by an intermediate fire risk propensity. Thus, the present study provided an effective solution to avoid one of the main drawbacks of bio-based composites. It demonstrated the feasibility of employing the proposed bio-based boards as indoor coating, with no risk to human life in case of fire.

Experimental investigation on the fire performance of wood bio-concrete using Cone Calorimeter

Nowadays, wood bio-concrete (WBC) can be seen as an alternative to reduce environmental impacts of the construction industry. The behavior of this material under fire conditions, however, is still poorly understood. In this sense, this work aims to investigate the behavior of wood bio-concrete under fire conditions. In this study, the wood shavings content varied from 40 to 90 %. A Mass Loss Cone Calorimeter with an incident heat flux of 50 kW/m2 was used to analyze the combustion and reaction to fire of WBCs. Then, properties such as heat release rate, total heat released, total mass loss, mass loss rate, effective heat of combustion, time to ignition and temperature of ignition were evaluated. Thermogravimetric analysis (TG) and scanning electron microscopy (SEM) were used to better explain the results from the Cone Calorimeter tests. The results showed that the cementitious matrix promoted the protection of the wood and no ignition was observed for the materials studied, excepted when 90 % of shavings were used. The lower the density of the bio-concrete, the higher the values of combustion properties. This study confirmed that, under high heat flux conditions, most of the WBCs did not exhibit characteristics that promote ignition or flame propagation.

Investigation of flame-retardant characteristics of natural flax coated with hydrothermally synthesized calcium borate and organic PDA

Flame-retardant behavior of flax fabric coated by calcium borate powders with clove-like and elongated morphologies was investigated by thermal analysis and cone calorimeter. PDA was used to form strong and uniform adhesion of calcium borate onto fabric. Thermal analysis showed a 20% of decrease in mass loss, while detected exothermic/endothermic peaks as a result of the degradation of fabric and PDA. Significant reductions in HRR, p-HRR, EHC and CO2 amount were observed for fabric coated by PDA and elongated calcium borate powder. PDA was carbonized at low temperatures and formed a char layer that prevented flame propagation. At the same time, calcium borate powder dilutes the flammable gases in the environment with the release of water within its body. Among the calcium borate powders, rod-like morphology showed the best flame-retardant performance.

Discrimination of slight thermal damage to hair for arson investigation

To determine whether a suspect was in close contact with the fire source at a fire site through slight thermal damage to hair, a cone calorimeter was employed to simulate fire scene conditions as a standard radiant source. The research focused on analyzing the thermal behavior of black hair and delving into the morphological characteristics of hair exhibiting slight thermal damage. At temperatures exceeding 240 °C, the proteins within the hair began to degrade. This degradation, in conjunction with tension along the hair shaft resulting from water loss, led to the formation of microcracks that could be detected through scanning electron microscopy (SEM) but eluded observation with an optical microscope (OM). It is noteworthy that the initial slight thermal damage was regularly located at the hair shaft but not the hair tip, which should be the key parts when exanimating hairs without obvious thermal damage. Additionally, during very short exposure, the appearance of typical slight thermal damage on fire is probabilistic events. Along with the increase of temperature, the organic compounds in hair were thermally degraded into NH3, SCO and carbon CO2, resulting in the typical traces of discoloration, expansion, blistering, and cracking presented at hair shafts and tips. The probability of encountering both slight and obvious thermal damage on hair increased with rising temperatures. By observing the traces on the easily overlooked part of the hair shaft, the research established a method to analyze and discriminate the slight thermal damage to hair at fire scene, which provide valuable references for confirming arson suspects.

A Comparative Study of Fire Code Classifications of Building Materials

Whether noncombustible or combustible construction is used, the presence of combustible materials is likely to be used for various reasons, such as interior finishes, flooring, and insulation. Consequently, how regulations consider the degree of combustibility in their fire classifications will influence the level of fire safety provided in these buildings and the exchanges between all actors in the construction sector. In North America, the regulation of combustibility is primarily governed by surface flame spread assessed through the Steiner tunnel test. While there is a growing prevalence of calorimetric methods globally, their incorporation into North American building codes remains notably limited. Based on ISO 5660-1 cone calorimeter test results of twenty commercially available North American building materials, a comparative study was conducted between the Canadian flame spread classification and the classifications in Japan, New Zealand and the European Union (Euroclass). The tests and their limitations are described herein, as well as the conceptual frameworks. The results suggest that as materials’ combustibility levels increase, the level of agreement between classifications decreases and remains binary. The choice between the material and system scales is crucial for determining the effective development and implementation of regulations.

Preparation of phosphorus-containing organic-hybrid layered double hydroxide as a flame retardant for thermoplastic polyurethane

Developing polymers with both flame-retardant and smoke-suppressing properties is a great challenge in the field of fire-safety thermoplastic polyurethane (TPU). This study involved synthesizing a synergistic organic-hybrid layered double hydroxide (O-LDH) and phosphorus/nitrogen-containing substance (PD) inspired by the observed synergistic effect between them. The incorporation of PD significantly enhanced the flame-retardant properties of TPU in conjunction with cobalt/aluminum- layered double hydroxide. The composite containing 10 wt% O-LDH achieved a limiting oxygen index of 26.5% and met the vertical burning V-0 rating. Moreover, the heat and smoke release were decreased compared to pure TPU in cone calorimeter tests. The systematic characterization of the synergistic flame-retardant mechanism emphasized the crucial contribution of cobalt and phosphorus species in catalyzing charring effects, resulting in the compact and highly carbonized char layer in the condensed phase. The incorporation of the hybrid flame retardant significantly enhanced the advancement of the flame-retardant TPU materials.

Thermal and Combustion Properties of Biomass-Based Flame-Retardant Polyurethane Foams Containing P and N.

Biomass has been widely used due to its environmental friendliness, sustainability, and low toxicity. In this study, aminophosphorylated cellulose (PNC), a biomass flame retardant containing phosphorus and nitrogen, was synthesized by esterification from cellulose and introduced into polyurethane to prepare flame-retardant rigid polyurethane foam. The combustion properties of the PU and PU/PNC composites were studied using the limiting oxygen index (LOI), UL-94, and cone calorimeter (CCT) methods. The thermal degradation behavior of the PU and PU/PNC composites was analyzed by thermogravimetric analysis (TGA) and thermogravimetric infrared spectroscopy (TG-IR). The char layer after combustion was characterized using SEM, Raman, and XPS. The experimental results showed that the introduction of PNC significantly improved the flame-retardant effect and safety of PU/PNC composites. Adding 15 wt% PNC to PU resulted in a vertical burning grade of V-0 and a limiting oxygen index of 23.5%. Compared to the pure sample, the residual char content of PU/PNC15 in a nitrogen atmosphere increased by 181%, and the total heat release (THR) decreased by 56.3%. A Raman analysis of the char layer after CCT combustion revealed that the ID/IG ratio of PU/PNC15 decreased from 4.11 to 3.61, indicating that the flame retardant could increase the stability of the char layer. The TG-IR results showed that PNC diluted the concentration of O2 and combustible gases by releasing inert gases such as CO2. These findings suggest that the developed PU/PNC composites have significant potential for real-world applications, particularly in industries requiring enhanced fire safety, such as construction, transportation, and electronics. The use of PNC provides an eco-friendly alternative to traditional flame retardants. This research paves the way for the development of safer, more sustainable, and environmentally friendly fire-resistant materials for a wide range of applications.

Synthesis of a syringaldehyde derivative to enhance the fire resistance and structural strength of epoxy resin

AbstractIn light of growing environmental apprehensions, the threat of global warming, and the depletion of oil reserves, it is advisable to opt for bio‐epoxy resins sourced from sustainable materials. In response to these issues, syringaldehyde (SH) flame retardant epoxy resin derivatives have been formulated and synthesized. Initially, SH was reacted with 4, 4‐diaminodiphenylmethane (DDM) to yield an intermediate compound, DDM‐SH. Subsequently, the inherently flame‐retardant curing agent (DDM‐SH‐DOPO) and the bio‐based epoxy monomer (DDM‐SH‐EP) were produced by reacting with DOPO and epichlorohydrin, respectively. These resulting compounds were then integrated into bisphenol A epoxy resin, enhancing its flame retardant and mechanical characteristics. The flammability was assessed through limiting oxygen index (LOI), UL‐94, and cone calorimeter tests. The DDM‐SH‐EP‐20/5 sample exhibits notable improvements. It elevates the LOI to 25.3%, achieving a UL‐94 rating to V‐0 and effectively reducing smoke and heat release from the epoxy resin. The ternary cross‐linking network formed between DGEBA, DDM‐SH‐EP, and DDM‐SH‐DOPO primarily contributes to this mechanical enhancement, DDM‐SH‐EP‐20/5 has excellent overall performance, bending strength and bending modulus are 103% and 108% higher than DGEBA/DDM. This study offers a viable solution for producing flame‐retardant epoxy resin with superior mechanical properties.

Smoke Suppression Properties of Fe2O3 on Intumescent Fire-Retardant Coatings of Styrene–Acrylic Emulsion

The intumescent flame-retardant coatings were prepared using ammonium polyphosphate (APP), pentaerythritol (PER), melamine (MEL), styrene–acrylic emulsion, and iron oxide yellow (FeOOH) as the base material. A cone calorimeter (CCT), smoke density meter (SDA), and scanning electron microscope (SEM) were employed to investigate the smoke suppression and flame retardancy of FeOOH in intumescent fire-retardant coatings. The thermal degradation performance of intumescent fireproofing coatings with varying FeOOH content was investigated through thermogravimetric analysis (TGA). The structure of the carbon slag in the CCT test was analyzed using a scanning electron microscope (SEM). The results of the cone calorimeter (CCT) experiments demonstrated that FeOOH significantly reduced the heat release rate (HRR), total heat release rate (THR), smoke production rate (SPR), and total smoke release rate (TSR) of the coating, while simultaneously increasing the carbon residue rate of the coating. The smoke density analysis (SDA) results demonstrate that adding FeOOH can effectively reduce smoke generation, regardless of whether a pilot flame is used. TGA results demonstrate that FeOOH can enhance the weight of coke residue at elevated temperatures. SEM results indicate that incorporating FeOOH resulted in a more compact coke residue. According to these findings, among all the samples, those containing 2 wt% FeOOH showed low levels of HRR, THR, SPR, and TSR and high levels of SOD, which proves that FeOOH can be used as a smoke inhibitor in flame-retardant coatings.

Preparation of bio-based trinity lignin intumescent flame retardant and its effect on burning behavior and heat transfer process of epoxy resin composites

The thermal insulation performance of intumescent coating coated on the surface of steel structure is of great significance to prevent the underlying steel structure from collapse in fire. Bio-based intumescent flame retardants gradually attract many attentions due to its environmental friendliness and rich natural sources. In this study, a new bio-based intumescent flame retardant trinity lignin intumescent flame retardant (TLI) is synthesized, which is added to epoxy resin (EP) to prepare EP/TLI epoxy intumescent coatings. The burning behavior of EP/TLI epoxy intumescent coatings is investigated by thermogravimetric (TG) analysis, limit oxygen index (LOI), vertical burning test and cone calorimeter test. Microscopic morphology of char layer is observed by scanning electron microscopy (SEM). The results show that when the TLI addition content is 20 wt% (EP/TLI-4), LOI reaches 26.5 %, UL-94 is V-0 rating. Compared to pure EP, the peak heat release rate (pHRR) and total heat release (THR) of EP/TLI-4 coating are reduced by 82.20 % and 78.27 %, respectively. The influence of chemical formulations, initial coating thickness and incident heat flux on heat transfer process of EP/TLI epoxy intumescent coatings is also investigated. At the same time, the thermal insulation mechanism of EP/TLI epoxy intumescent coating is presented.

An Empirical Correlation for Burning of Spruce Wood in Cone Calorimeter for Different Heat Fluxes

An Empirical Correlation for Burning of Spruce Wood in Cone Calorimeter for Different Heat Fluxes

Construction of fully bio‐based flame retardant and antibacterial coating on polyester fabric with chitosan and ammonium phytate

AbstractIn this work, a flame retardant and antibacterial coating was constructed on the surface of polyester (PET) fabric by a simple layer‐by‐layer self‐assembly method based on chitosan (CS) and ammonium phytate (APA). The introduction of the coating significantly improved the flame retardant, anti‐dripping, and antibacterial properties of PET fabrics. The PET fabric that has been treated exhibits a limiting oxygen index of 34.6%. During the vertical flame test, it forms an expanded char layer, reduces the damage length to 3.4 cm, and produces no molten drops. The cone calorimeter test results revealed that the peak heat release rate of the treated PET fabric decreased by 62.0%. Additionally, the finished PET fabric has significant antibacterial properties against Escherichia coli, a slight increase in tensile breaking strength, and a slight decrease in whiteness index. This study presents a fully bio‐based, simple, and effective method for flame retardant, anti‐dripping, and antibacterial finishing of PET fabrics.

An Evaluation of the Fire Safety of Waste Paper-Based Internal Finishing Materials Combined with Expandable Graphite According to Changes in Magnesium Hydroxide Content

Inflammable building finishing materials act as a major cause of fire propagation, and they, therefore, pose significant risks to life and can lead to property damage. To replace such flammable building finishing materials, many countries have established regulations limiting their use, which has led to extensive research on the development of flame-retardant building finishing materials. Such methods have included adding flame retardants to construction materials to reduce the heat release rate and total heat release. The present study aimed to enhance the fire performance of cellulose-based architectural finishing materials by creating a dual flame-retardant mixture using expandable graphite and magnesium hydroxide added to recycled paper waste. Specimen fabrication involves using a pressing method to apply uniform pressure to compress the mixture in a mold. The total heat release (THR), CO, and CO2 production of the produced specimens were measured using a cone calorimeter while varying the magnesium hydroxide additive ratio. The combustion gases were measured through NES 713 experiments to determine any changes in the Toxic Index corresponding to variations in the magnesium hydroxide content. The experiment results established a correlation between the magnesium hydroxide additive ratio and the total heat release, as well as the existence of variations in CO and CO2 production for the dual flame-retardant recycled paper material. A database for combustion gases was also obtained. It was confirmed that the fire performance was improved by confirming that the total heat release decreased by 52% from the previous one in the magnesium hydroxide content of 30 g, and it was confirmed that the inflection points of the Toxic Index value due to the change in CO and CO2 gas production occurred in the magnesium hydroxide content of 20 g due to the improvement of the fire performance. Through the ISO 5660-1 experiment data, we have secured data that can be used as foundational information for performance-oriented fire risk assessments, thereby ensuring the fire safety of cellulose materials that are vulnerable to fire.