Smoke Suppression Properties of Fe2O3 on Intumescent Fire-Retardant Coatings of Styrene–Acrylic Emulsion

Abstract

The intumescent flame-retardant coatings were prepared using ammonium polyphosphate (APP), pentaerythritol (PER), melamine (MEL), styrene–acrylic emulsion, and iron oxide yellow (FeOOH) as the base material. A cone calorimeter (CCT), smoke density meter (SDA), and scanning electron microscope (SEM) were employed to investigate the smoke suppression and flame retardancy of FeOOH in intumescent fire-retardant coatings. The thermal degradation performance of intumescent fireproofing coatings with varying FeOOH content was investigated through thermogravimetric analysis (TGA). The structure of the carbon slag in the CCT test was analyzed using a scanning electron microscope (SEM). The results of the cone calorimeter (CCT) experiments demonstrated that FeOOH significantly reduced the heat release rate (HRR), total heat release rate (THR), smoke production rate (SPR), and total smoke release rate (TSR) of the coating, while simultaneously increasing the carbon residue rate of the coating. The smoke density analysis (SDA) results demonstrate that adding FeOOH can effectively reduce smoke generation, regardless of whether a pilot flame is used. TGA results demonstrate that FeOOH can enhance the weight of coke residue at elevated temperatures. SEM results indicate that incorporating FeOOH resulted in a more compact coke residue. According to these findings, among all the samples, those containing 2 wt% FeOOH showed low levels of HRR, THR, SPR, and TSR and high levels of SOD, which proves that FeOOH can be used as a smoke inhibitor in flame-retardant coatings.