Conductive Multi-walled Carbon Nanotubes Research Articles

Facile Incorporation of Carbon Nanotubes into the Concrete Matrix Using Lignosulfonate Surfactants

One of the ways to turn concrete into smart concrete involves the incorporation of conductive fillers. These fillers should be evenly distributed in the matrix to enable the charge propagation necessary for sensing. To homogenize the mixture, typical surface-active chemical compounds are routinely employed. Unfortunately, their presence often negatively impacts the characteristics of concrete. In this work, we show that conductive multi-walled carbon nanotubes (MWCNTs) can be included in the concrete matrix by using off-the-shelf lignosulfonate-based plasticizers. These plasticizers showed a much-improved capability to disperse MWCNTs compared to other routinely used surfactants. They also prevented a significant deterioration of the consistency of the mixture and inhibited the acceleration of the hydration process by MWCNTs. In concretes with MWCNTs and lignosulfonate-based plasticizers, the mechanical properties were largely preserved, while the nanocomposite became electrically conductive. Consequently, it enabled evaluation of the condition of the material by electrical impedance measurements.

Investigating the structural and electromagnetic properties of ZnFe2O4@MWCNTs nanocomposites

This study introduces ZnFe2O4@MWCNTs nanocomposites (ZF@MWCNTs NCs), developed using ZnFe2O4 magnetic nanoparticles (ZFNPs) and multi-walled carbon nanotubes (MWCNTs) via a simple, cost-effective, and scalable ultrasonic process. The design involves ZFNPs acting as an electromagnetic (EM) skeleton or magnetic shell surrounding a conductive MWCNT core, optimizing microwave absorption. By combining the magnetic properties of ZFNPs and the electrical conductivity of MWCNTs, the quasi-core-shell structure achieves excellent impedance matching and synergistic dielectric/magnetic loss. Comprehensive characterization was performed, including X-ray diffraction (XRD) for crystal structure, field emission scanning electron microscopy (FESEM) with energy-dispersive X-ray spectroscopy (EDS) for morphology and elemental analysis, Fourier transform infrared (FT-IR) spectroscopy for structural identification, vibrating sample magnetometers (VSM) for magnetic properties, and vector network analyzers (VNA) for dielectric properties. Among the five synthesized weight ratios, M4 sample exhibited the best reflection loss (RL) under the X-band at −47.16 dB with a thickness of 2.33 mm and under the Ku-band at −24.40 dB with a thickness of 1.53 mm. These nanocomposites demonstrated 99.99 % wave dissipation under both X- and Ku-bands, making them highly effective microwave absorbers. This work provides a promising approach for developing high-performance microwave-absorbing materials.

Piezoelectric Properties of As-Spun Poly(vinylidene Fluoride)/Multi-Walled Carbon Nanotube/Zinc Oxide Nanoparticle (PVDF/MWCNT/ZnO) Nanofibrous Films.

Conductive multi-walled carbon nanotubes (MWCNTs) as well as piezoelectric zinc oxide (ZnO) nanoparticles are frequently used as a single additive and dispersed in polyvinylidene fluoride (PVDF) solutions for the fabrication of piezoelectric composite films. In this study, MWCNT/ZnO binary dispersions are used as spinning liquids to fabricate composite nanofibrous films by electrospinning. Binary additives are conducive to increasing the crystallinity, piezoelectric voltage coefficient, and consequent piezoelectricity of as-spun films owing to the stretch-enhanced polarization of the electrospinning process under an applied electric field. PCZ-1.5 film (10 wt. % PVDF/0.1 wt. % MWCNTs/1.5 wt. % ZnO nanoparticles) contains the maximum β-phase content of 79.0% and the highest crystallinity of 87.9% in nanofibers. A sensor using a PCZ-1.5 film as a functional layer generates an open-circuit voltage of 10 V as it is subjected to impact loads with an amplitude of 6 mm at 10 Hz. The piezoelectric sensor reaches a power density of 0.33 μW/cm2 and a force sensitivity of 582 mV/N. In addition, the sensor is successfully applied to test irregular motions of a bending finger and stepping foot. The result indicates that electrospun PVDF/MWCNT/ZnO nanofibrous films are suitable for wearable devices.

Liquid metal induced segregated-like electromagnetic shielding composites with excellent photothermal conversion and strain sensing capacities

The development of multifunctional electromagnetic interference (EMI) shielding materials has garnered significant attention, yet achieving flexible composites that integrate EMI shielding, thermal conductivity, and other functionalities under low filler loading remains a challenge. This study presents a novel flexible composite with segregated structure prepared via a simple co-mixing and hot-pressing method. By selectively distributing conductive Liquid metal (LM) and Multi-wall carbon nanotube (CNT) on the surface of Polyurethane (TPU) particles, a continuous and compact conductive network is successfully constructed, enabling the attainment of a high EMI shielding effectiveness of 80.2 dB and a thermal conductivity of 4.8 W m−1 K−1 even at low LM loadings. Furthermore, the composite exhibits low-voltage-driven Joule heating performance, excellent photothermal conversion efficiency, and promising potential for wearable sensor applications. The combination of these outstanding properties highlights the great potential of LM-based composites for next-generation wearable devices.

Electrothermal-Assisted Photothermal Lubrication Surfaces for Continuous Anti-Icing/Deicing in Multiple Low-Temperature Environments.

Solving the problem of ice accumulation on solid surfaces is of great significance to the economic development of the country and the safety of people's lives. In this work, a coating with multifunctional photothermal/electrothermal solid-state lubrication (PEL) for anti-icing/deicing was prepared in layers based on the intrinsic properties of silicone oil and paraffin wax in combination with conductive graphite and multiwalled carbon nanotubes. Silicone oils and paraffins are used as lubricating media giving the coating excellent lubricity, which results in a water sliding angle (SA) of only 12° on the PEL surface. Meanwhile, PEL shows favorable static and dynamic ice resistance at low temperatures; at -10 °C, the freezing time of water droplets on the PEL surface is extended by at least 4 times compared to the bare substrate. Furthermore, PEL also offers highly efficient photothermal and electrothermal deicing performance, which can effectively remove the accumulated ice at a light intensity of 0.6 kW/m2 or an EPD of 0.1 W/cm2. Meanwhile, the synergistic deicing mechanism of photothermal and electrothermal was verified at -20 °C. Interestingly, the coating shows heat-assisted healing ability due to the phase change characteristic of paraffin wax, which allows the coating to regain lubricating properties after mechanical abrasion. Therefore, this work provides a reliable way for the design of stable all-weather anti-icing/deicing strategies at low temperatures.

High-Energy Polynitrogen N10 Stabilized on Multi-Walled Carbon Nanotubes.

The synthesis of stable polynitrogen compounds with high-energy density has long been a major challenge. The cyclo-pentazolate anion (cyclo-N5 -) is successfully converted into aromatic and structurally symmetric bipentazole (N10) via electrochemical synthesis using highly conductive multi-walled carbon nanotubes (MWCNTs) as the substrate and sodium pentazolate hydrate ([Na(H2O)(N5)]·2H2O) as the raw material. Attenuated total refraction Fourier transform infrared spectroscopy, Raman spectroscopy, X-ray diffraction, X-ray photoelectron spectroscopy, transmission electron microscopy, and density functional theory calculations confirmed the structure and homogeneous distribution of N10 in the sidewalls of the MWCNTs (named MWCNT-N10-n m). The MWCNT-N10-2.0 m is further used as a catalyst for electrochemical oxygen reduction to synthesize hydrogen peroxide from oxygen with a two-electron selectivity of up to 95%.

Coupled effect of MWCNTs concentration and induced pore structures on compressive performance and elastic modulus of ultra-high toughness cementitious composites: Experimental and theoretical studies

Due to the superior mechanical properties and electrical conductivity of multi-walled carbon nanotubes (MWCNTs), their integration into cementitious composites can improve compressive strength and self-sensing capabilities. However, balancing high mechanical strength with high conductivity is challenging as high MWCNT dosages can impede strength development. We addressed this by studying the effect of MWCNTs concentration (0–1.1 wt% of cementitious binders) and induced pore structures on the compressive performance and elastic modulus of ultra-high toughness cementitious composites (UHTCC), both experimentally and theoretically. It was found that as the MWCNTs concentration increased, the porosity continued to increase, while the compressive strength fluctuated. Two failure patterns were identified, i.e., quasi-brittle failure and ductile failure. Analysis showed MWCNTs could promote cement binder hydration, increasing matrix density but the strength development was curbed by increased porosity. A balance was achieved at 0.7 wt% MWCNTs. Further investigations using the Eshelby-Mori-Tanaka method discussed how MWCNT concentration, mechanical properties, distribution, porosity, and pore geometry influenced the elastic modulus. Ultimately, we developed a UHTCC-MWCNT composite with 1.1 wt% MWCNTs, which exhibited substantial improvements in compressive strength (44.85 MPa) and conductivity (9.78✕10−3 S/m), showing increases of 22.18 % and 18,132.6 % respectively, compared to the reference group.

Development and preparation of novel nano-enhanced organic eutectic phase change materials for low-temperature solar thermal applications

ABSTRACT Thermally reliable and stable eco-friendly Phase change materials are of significant aid in thermal energy storage technology, leading to improved energy utilization and reliability of the system. This study develops two novel organic eutectic PCM of Lauric acid – Margaric acid (LM) and Myristic acid – Margaric acid (MM), which are chemically stable and thermally compatible for latent heat energy storage. LM eutectic mixture had a melting temperature of 52.66°C with a latent heat of 163.68 J/g, and MM eutectic mixture had its melting temperature at 44.79°C and a latent heat of 197.31 J/g. The phase change temperatures were favorable for low temperature solar thermal applications with good latent heat capacity. The thermal characteristics of these eutectic mixtures are further enhanced with the dispersion of highly conductive Multi walled carbon nanotubes (MWCNT) at three different mass fractions (.5%, 1% and 1.5% by weight). Nano enhancement could achieve exceptional thermal conductivity enhancement in MM eutectic mixture by 110.6% and 83.73% in LM eutectic mixture. Thermogravimetric analysis and Fourier-transform infrared spectroscopy analysis ensured the thermal and chemical stability of the eutectic mixtures. The optical absorption characteristics were extensively enhanced with nano particle addition, which is highly preferable in solar thermal applications.

Multiwall carbon nanotube-hyperbranched polymaleimide core–shell nanowires with hierarchical porous and polar structure as sulfur host for sustainable lithium-sulfur batteries

Lithium–sulfur (Li–S) batteries have gained considerable attention as a promising alternative to current advanced batteries because of their low cost, natural abundance, high energy density, and environmental benignity of sulfur. The commercial application of Li–S batteries is being seriously impeded by the shuttle effect of lithium polysulfides (LiPSs) and the sluggish reaction kinetics of solid phase transformation. Herein, a novel composite material (PPI@MWCNT-Y) with a hierarchical porous skeleton and polar channel is prepared as a sulfur host using a convenient in-situ one-pot polymerization. PPI@MWCNT-Y is composed of conductive mesoporous multi-wall carbon nanotubes (MWCNTs) core and a microporous hyperbranched polymaleimide (PPI) shell formed by the self-polymerization of N,N′-1,4-phenylenedimaleimide (PDM). The mesoporous and conductive channels in PPI@MWCNT-Y improve the redox kinetics of the active materials by serving as a fast electron and Li-ions transportation pathway. The microporous structure and abundant adsorption sites (N and O atoms) within the PPI@MWCNT-Y served as physical and chemical barriers, preventing the loss of LiPSs, and suppressing the shuttle effect. Consequently, the S/PPI@MWCNT-38 composite exhibited a high discharge capacity of 1338 mAh g−1 at 0.2 C and a low-capacity decay rate of 0.088% for 400 cycles at 1 C.

Modified Carbon Nanotubes Favor Fibroblast Growth by Tuning the Cell Membrane Potential.

As is known, carbon nanotubes favor cell growth in vitro, although the underlying mechanisms are not yet fully elucidated. In this study, we explore the hypothesis that electrostatic fields generated at the interface between nonexcitable cells and appropriate scaffold might favor cell growth by tuning their membrane potential. We focused on primary human fibroblasts grown on electrospun polymer fibers (poly(lactic acid)─PLA) with embedded multiwall carbon nanotubes (MWCNTs). The MWCNTs were functionalized with either the p-methoxyphenyl (PhOME) or the p-acetylphenyl (PhCOMe) moiety, both of which allowed uniform dispersion in a solvent, good mixing with PLA and the consequent smooth and homogeneous electrospinning process. The inclusion of the electrically conductive MWCNTs in the insulating PLA matrix resulted in differences in the surface potential of the fibers. Both PLA and PLA/MWCNT fiber samples were found to be biocompatible. The main features of fibroblasts cultured on different substrates were characterized by scanning electron microscopy, immunocytochemistry, Rt-qPCR, and electrophysiology revealing that fibroblasts grown on PLA/MWCNT reached a healthier state as compared to pure PLA. In particular, we observed physiological spreading, attachment, and Vmem of fibroblasts on PLA/MWCNT. Interestingly, the electrical functionalization of the scaffold resulted in a more suitable extracellular environment for the correct biofunctionality of these nonexcitable cells. Finally, numerical simulations were also performed in order to understand the mechanism behind the different cell behavior when grown either on PLA or PLA/MWCNT samples. The results show a clear effect on the cell membrane potential, depending on the underlying substrate.

Piezo-tribo-electric nanogenerator based on BCZT/MCNTs/PDMS piezoelectric composite for compressive energy harvesting

BackgroundThis work has developed a novel piezo-tribo-electric nanogenerator (P-TENG) that is capable of converting mechanical energy into electrical energy when operating in compressive mode. MethodsAn arch-shaped P-TENG device was formed using an optimal piezoelectric polymer composite, which was fabricated using a polydimethylsiloxane (PDMS) matrix that was modified with piezoelectric (Ba0.85Ca0.15) (Ti0.90Zr0.10)O3 (BCZT) ceramic particles and electrically conductive multi-walled carbon nanotubes (MCNTs). A high filler loading of BCZT (40, 50, 60 wt%) and 3 wt% of MCNTs was formed into a 0–3 connectivity composite. ResultsThe P-TENG device containing 50 wt% BCZT exhibited the highest electrical output (VOC ∼ 39.7 V, ISC ∼ 1.9 µA, and maximum power ∼ 157.7 µW), compared to the other composites, when subjected to an alternating compressive load of 500 N at a 1 Hz frequency. ConclusionsThis research provides new composite formulations for elastomeric-based energy generators that are responsive to low frequency mechanical oscillations.

Mechanical and electromagnetic interference shielding properties of natural fiber reinforced polymer composite with carbon nanotubes addition

AbstractMechanical and electromagnetic interference (EMI) shielding properties are investigated for developed synthesized green composite. The varying content of kenaf fiber‐reinforced high‐density polyethylene (HDPE) composite has been fabricated using microwave‐assisted compression molding techniques with and without the addition of multi‐walled carbon nanotubes (MWCNTs). X band range has been used for EMI shielding characterization. Optimization for mechanical strength has been done using tensile test, impact test, and translaminar fracture toughness test. Fractography by scanning electron and optical microscopy concluded that interfacial adhesion between kenaf fiber and HDPE matrix and the degree of ductility of the matrix are primary governing factors for change in mechanical properties. The differential scanning calorimetry confirmed no change in the degree of crystallization of the matrix with the addition of MWCNTs. Composite with EMI shielding effect above 30 dB along with superior mechanical properties is obtained at 16% (v/v) kenaf fiber content with the addition of 5% (wt.) conductive MWCNTs for possible application in electronic equipment casing, overhead bin, or unmanned aerial vehicles.

Review of: "According to this, the thermal conductivity of multi-walled carbon nanotubes individually is more than 300 mK/W."

Review of: "According to this, the thermal conductivity of multi-walled carbon nanotubes individually is more than 300 mK/W."

Laser additive manufacturing of shape memory biopolymer bone scaffold: 3D conductive network construction and electrically driven mechanism

IntroductionThe electro-actuated shape memory polymer scaffold has gained increasing attentions on the utilization of minimally invasive surgery for bone defect repair, which requires to construct an efficient conductive network to accomplish electrical-to-thermal conversion from conductive fillers to the entire matrix evenly. ObjectivesIn this study, multiwall carbon nanotube (MWCNT) was convective self-assembled on the ZnO tetrapod (t-ZnO) template, where MWCNT was controlled to disperse uniformly and regulated to contact with each other effectively due to the immersion capillary force during the evaporation loss of the convective self-assembly process, leading to an interwoven layer on the t-ZnO surface. MethodsThe prepared t-ZnO@MWCNT assembly was embedded in the poly(L-lactic acid)/thermoplastic polyurethane (PLLA/TPU) scaffold fabricated via selective laser sintering to construct a 3D conductive MWCNT network for improving the electro-actuated shape memory properties. ResultsIt was observed that the interconnected MWCNT formed a 3D conductive network in the matrix without significant aggregation, which boosted the electrical-to-thermal properties of the scaffold, and the scaffold containing t-ZnO@MWCNT assembly possessed better electro-actuated shape memory properties with shape fixity of 98.0% and shape recovery of 98.8%. ConclusionThe scaffold exhibited improved electro-actuated shape memory properties and mechanical properties and the osteogenic inductivity was promoted with the combined effect of t-ZnO and electrical stimulation.

Polypyrrole@CNT@PU Conductive Sponge-Based Triboelectric Nanogenerators for Human Motion Monitoring and Self-Powered Ammonia Sensing.

Elastic sponges are ideal materials for triboelectric nanogenerators (TENGs) to harvest irregular and random mechanical energy from the environment. However, the conductive design of the elastic materials in TENGs often limits its applications. In this work, we have demonstrated that an elastic conductive sponge can be used as the triboelectric layer and electrode for TENGs. Such an elastic conductive sponge is prepared by a simple way of adsorbing multiwalled carbon nanotubes and monomers of pyrrole to grow conductive polypyrroles on the surface of an elastic polyurethane (PU) sponge. Due to the porous structure of the PU sponge and the conductive multiwalled carbon nanotubes (MWCNTs), PPy on the surface of PU could provide a large contact area to improve the output performance of TENGs, and the conductive sponge-based TENG could generate an output of open-circuit voltage of 110 V or a short-circuit current of 12 μA, respectively. The good flexibility of the conductive PU sponge makes the TENG harvest the kinetic energy of disordered motion with different amplitudes, allowing for human motion monitoring. Furthermore, the porous structure of PU and the synergistic effects of PPy and MWCNTs enable the conductive sponge to sense NH3 as a self-powered NH3 sensor. This work offers a simple way to construct a flexible TENG system for random mechanical energy harvesting, human motion monitoring, and self-powered NH3 sensing.

A soft tactile sensing array with high sensitivity based on MWCNTs-PDMS composite of hierarchically porous structure

The advancement of wearable tactile sensors that involves with high sensitivity under ultra-low pressures is crucial for varieties of human-machine interactive applications, like smart phones, healthcare monitoring, and electronic skins. Here in this paper, a soft capacitive tactile sensing array is introduced based on hierarchically porous multi-walled carbon nanotubes (MWCNTs)-polydimethylsiloxane composite, which leads to sensitivity improvement attributing to a synergistic effect of the hierarchically porous elastomer and conductive MWCNTs supplements. The proposed device exhibits superior pressure-sensing performances, with high sensitivity (3.58 kPa−1) under small mechanical stimuli (<80 Pa), broad measuring range (0–265 kPa), fast response time (<45 ms), good repeatability, minimum limit of detection (<10 Pa), as well as low-hysteresis, allowing efficient sensing of pressure from all types of sources, from vulnerable signals such as human breathing, artery and venous pulses, and soft human finger touch to possible brutal variations such as sudden change of object weight or prompt collide. Moreover, extensive body attached experiments confirm that the soft tactile sensing array is fully human compatible and capable for a variety of human-machine interfaces and health monitoring applications.

Enhanced Energy Harvesting Performance of Triboelectric Nanogenerators via Dielectric Property Regulation.

Triboelectric nanogenerators (TENGs) hold great application prospects and research values in the field of energy harvest. The friction layer of TENGs plays an important impact role in their output performance. Therefore, composition modulation of the friction layer is of great significance. In this paper, the xMWCNT/CS composite films with multiwalled carbon nanotubes (MWCNTs) as a filler and chitosan (CS) as a matrix were prepared and a TENG based on the xMWCNT/CS composite films (xMWCNT/CS-TENG) was constructed. The introduction of the conductive filler MWCNT significantly improves the dielectric constant of the films due to the Maxwell-Wagner relaxation. As a result, the output performance of the xMWCNT/CS-TENG is greatly enhanced. The best values of an open-circuit voltage of 85.8 V, a short-circuit current of 8.7 μA, and a transfer charge of 29 nC were obtained in the TENG with an optimum MWCNT content of x = 0.8 wt % under an external force of 50 N and a frequency of 2 Hz. The TENG can sensitively perceive human activities such as walking. Our results evidence that the xMWCNT/CS-TENG is a flexible, wearable, and eco-friendly energy collector, holding great prospects in health care and body information monitoring.

Laser-Formed Sensors with Electrically Conductive MWCNT Networks for Gesture Recognition Applications.

Currently, an urgent need in the field of wearable electronics is the development of flexible sensors that can be attached to the human body to monitor various physiological indicators and movements. In this work, we propose a method for forming an electrically conductive network of multi-walled carbon nanotubes (MWCNT) in a matrix of silicone elastomer to make stretchable sensors sensitive to mechanical strain. The electrical conductivity and sensitivity characteristics of the sensor were improved by using laser exposure, through the effect of forming strong carbon nanotube (CNT) networks. The initial electrical resistance of the sensors obtained using laser technology was ~3 kOhm (in the absence of deformation) at a low concentration of nanotubes of 3 wt% in composition. For comparison, in a similar manufacturing process, but without laser exposure, the active material had significantly higher values of electrical resistance, which was ~19 kOhm in this case. The laser-fabricated sensors have a high tensile sensitivity (gauge factor ~10), linearity of >0.97, a low hysteresis of 2.4%, tensile strength of 963 kPa, and a fast strain response of 1 ms. The low Young's modulus values of ~47 kPa and the high electrical and sensitivity characteristics of the sensors made it possible to fabricate a smart gesture recognition sensor system based on them, with a recognition accuracy of ~94%. Data reading and visualization were performed using the developed electronic unit based on the ATXMEGA8E5-AU microcontroller and software. The obtained results open great prospects for the application of flexible CNT sensors in intelligent wearable devices (IWDs) for medical and industrial applications.

Electrochemical Biosensing of L-DOPA Using Tyrosinase Immobilized on Carboxymethyl Starch-Graft-Polyaniline@MWCNTs Nanocomposite

The electrochemical behavior of the immobilized tyrosinase (Tyrase) on a modified glassy carbon electrode with carboxymethyl starch-graft-polyaniline/multi-walled carbon nanotubes nanocomposite (CMS-g-PANI@MWCNTs) was investigated. The molecular properties of CMS-g-PANI@MWCNTs nanocomposite and its morphological characterization were examined by Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), and field emission scanning electron microscopy (FESEM). A simple drop-casting method was employed to immobilize Tyrase on the CMS-g-PANI@MWCNTs nanocomposite. In the cyclic voltammogram (CV), a pair of redox peaks were observed at the potentials of +0.25 to -0.1 V and E°' was equal to 0.1 V and the apparent rate constant of electron transfer (Ks) was calculated at 0.4 s-1. Using differential pulse voltammetry (DPV), the sensitivity and selectivity of the biosensor were investigated. The biosensor exhibits linearity towards catechol and L-dopa in the concentration range of 5-100 and 10-300 μM with a sensitivity of 2.4 and 1.11 μA μΜ-1 cm-2 and limit of detection (LOD) 25 and 30 μM, respectively. The Michaelis-Menten constant (Km) was calculated at 42 μΜ for catechol and 86 μΜ for L-dopa. After 28 working days, the biosensor provided good repeatability and selectivity, and maintained 67% of its stability. The existence of -COO- and -OH groups in carboxymethyl starch, -NH2 groups in polyaniline, and high surface-to-volume ratio and electrical conductivity of multi-walled carbon nanotubes in the CMS-g-PANI@MWCNTs nanocomposite cause good Tyrase immobilization on the surface of the electrode.

Preparation and Properties of Nano Platinum/Carbon Nanotubes/Bacterial Cellulose Conductive Hydrogel Electrode Films

Using the natural nanomesh structure of bacterial cellulose (BC), the good conductivity of multi-walled carbon nanotubes (MWCNTs) and the good electrocatalytic activity of nano platinum (PtNPs), a three-way porous conductive hydrogel of PtNPs and BC was designed. The infiltrating and doping of MWCNTs on BC thin films was realized by ultrasonic assisted electrophoretic deposition process, which ensured the dual characteristics of ionic and electronic conduction of electrode films. The adsorption capacity of BC for chloroplatinic acid and the strong reductivity of sodium borohydride were also used to realize the high-load PtNPs recombination on MWCNTs/BC porous layered conductive hydrogel electrode films. By testing the electrochemical performance of PtNPs/MWCNTs/BC conductive hydrogel electrode film and characterization of microstructure, the electrode film not only has high electroactive area, low surface charge transfer resistance and good diffusion permeability and other electrochemical characteristics, but also shows high catalytic activity for glucose in PBS solution. The most important finding is that the electrode film can selectively catalyze glucose in oxygen-rich PBS solution. The porous layered structure of PtNPs/MWCNTs/BC electrode membrane and the high load dispersion of PtNPs are the reasons for the selective catalytic ability of PtNPs/MWCNTs/BC conductive hydrogel electrode membrane, which can be used for the implanted surface glucose fuel cell.