This work provides insights into the role of heating rate in the foaming ability of glass foams produced from discarded glass bottles. The pore-forming agents used were calcium carbonate and ornamental stone processing waste (SW), the latter being assessed for the first time for this purpose. Glass foams were produced with different contents of pore-forming agents: 1-5 wt% CaCO3 and 1-15 wt% SW. Higher SW contents were necessary due to the relatively lower concentration of carbonate minerals contained (about 15 wt% of dolomite). The powdered raw materials were homogenized and uniaxially pressed (20 MPa) to obtain cylindrical samples, which were dried (110 °C/24 h) and fired at 900 °C with a holding time of 30 min. The effect of different heating rates on the foamability of samples, in the range of 3–20 °C/min, was investigated. The samples were compared for volumetric expansion, bulk density, porosity, thermal conductivity, compressive strength, and pore size distribution profile. The optimized contents of pore formers were in the range of 1-3 wt% CaCO3 and 5-10 wt% SW, producing foams with properties compared to commercial ones, including porosities between 75% and 90%, thermal conductivities between 0.04 and 0.07 W/m.K, and compressive strength between 1.0 and 4.3 MPa. The thermal conductivity was shown to be highly dependent on the total porosity of the samples and little influenced by the pore size, while the compressive strength was shown to be strongly influenced by both. The variation in the heating rate proved to be less influential for the samples with the above-mentioned optimized pore-formers contents. However, for contents close to the lower limit (1 wt% CaCO3 and 5 wt% SW), heating rates equal to or greater than 10 °C/min are recommended to improve the foamability. Preliminary results of the foam crystallization effect after sintering were also presented. Although the bulk crystallization of soda-lime glass is widely known, the literature on its crystallization in powder form is little explored. The crystallization of glass foams plays an important role in the recyclability of waste generated in its processing into different formats, since foamability is lost. The results show the crystallization of quartz, devitrite, and wollastonite in all samples. Although pore-forming agents do not appear to act as nucleating agents, they do favor the crystallization of devitrite.
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