Background This study explores the flexural behavior of unfired and fired one-way slabs constructed from reinforced ferronickel slag-based alkali-activated concrete (AAC). Despite growing interest in AAC as a sustainable alternative to ordinary Portland cement (OPC), limited research exists on large-scale structural elements, particularly under post-fire conditions. Methods Four slabs (2.1 × 0.9 × 0.18 m3) were tested: two made of AAC and two of OPC concrete with comparable compressive strengths. In each group, one slab served as a reference and was tested under monotonic four-point bending in its original state. The other was exposed to a standard fire curve on the tensioned side, then cooled to ambient conditions before mechanical testing. Additional analyses, including mercury intrusion porosity (MIP) and scanning electron microscopy (SEM), were conducted to evaluate fire-induced microstructural changes in the AAC slabs. Results The AAC slabs demonstrated a load capacity 6% lower than OPC slabs. However, AAC slabs exhibited better post-fire retention of stiffness and ductility. Microstructural analysis revealed increased porosity and microcracking in AAC after fire exposure, which influenced its mechanical performance. Conclusions The results suggest that ferronickel slag-based AAC can provide comparable performance to OPC concrete in flexural applications, with enhanced retention of stiffness and ductility after fire exposure. These findings support the viability of AAC for structural applications while highlighting its resilience under post-fire conditions.
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