Concentration Factor Research Articles

Fatigue Behavior of Medium Entropy Alloys AlCrFe<sub>2</sub>Ni<sub>2</sub> and AlCrFe<sub>2</sub>Ni<sub>2</sub>Mo<sub>0.1 </sub>- A Comparison with Super Duplex Steel 1.4517

In the present study the notched fatigue behavior of two multi-phase medium entropy alloys (MEAs) AlCrFe2Ni2 and AlCrFe2Ni2Mo0.1 was characterized by three-point-bending (3-PB), along with a super-duplex steel 1.4517 as a reference material. An analytical approach for characterizing the fatigue notch factor (kf), based on grain size analysis in combination with finite element modelling (FEM) was used, relating the theory of critical distances (TCD) to the grain size of the material. To validate the approach, for the reference steel, the fatigue notch factor was also determined experimentally by comparing the fatigue behavior of notched and smooth specimens, resulting in an experimentally determined fatigue notch factor (kf) ~ 1.07. The numerically and analytically estimated notch effects increase with decreasing average grain size and vary between ~ 1.07 for the coarse-grained reference material – in very good agreement with the experimental results – and ~ 1.35 for the much more fine-grained AlCrFe2Ni2Mo0.1 medium entropy alloy. Note that these values are significantly lower than the stress concentration factor (kt) ~ 1.58, associated with the notch geometry. Fatigue endurance limits were measured at a fatigue stress ratio R ~ 0.1 (unidirectional stress), but were converted to fatigue amplitudes at R = -1 (σa, R-1, fully reversed stress), to be able to make due comparisons with available literature data, by using the elliptical relationship. The resulting fatigue endurance limit amplitudes for specimens surviving at least 2E+06 cycles for a minimum of three tested samples and including notch effects are σa, R-1 ~ 508 MPa for the AlCrFe2Ni2 alloy, σa, R-1 ~ 540 MPa for the AlCrFe2Ni2Mo0.1 alloy modification and σa, R-1 ~ 400 MPa for the reference super-duplex steel, putting the analyzed MEAs into a very competitive position compared to Cobalt containing multi-phase high or medium entropy alloys as well as commercially available steels.

The energy dissipation of a test-charge particle within a dense, degenerate electron- positron-ion plasma

The energy loss of a moving test-charge particle is studied in a degenerate quantized plasma, whose constituents are the electrons, positrons, and ions. The electrons and positrons are assumed to be quantized and degenerate species, whereas positive ions are treated classically. Relying on the kinetic formalism, an expression for the test-charge potential is derived with a modified dielectric response function involving the ion-acoustic oscillations. The energy loss or stopping power is solvedas a function of a test-charge speed, which is significantly affected by the positron concentration, the electron and positron quantization factors and plasma parameters. It is examined that quantization and quantum parameters lead to the enhancement of energy loss in an electron-positron-ion (EPI) dense plasma. The present findings may prove useful to understand the test-charge response in degenerate dense plasmas, where electrons and positrons are quantized in the strong magnetic fields.

Investigation of heavy metals uptake in root-shoot of native plant species adjoining wastewater channels.

Metal pollution in water, soil, and vegetation is an emerging environmental issue. Therefore, this study investigated the abundance of heavy metals (HMs) within roots and shoots of native plant species i.e., Bromus pectinatus, Cynodon dactylon, Poa annua, Euphorbia heliscopa, Anagallis arvensis, and Stellaria media grown in the adjoining area of municipal wastewater channels of a Pakistani city of Abbottabad. HMs concentrations (mg L-1) in municipal wastewater were: chromium (Cr) (0.55) > nickel (Ni) (0.09) > lead (Pb) (0.07) > cadmium (Cd) (0.03). Accumulation of HMs in both roots and shoots of plant species varied as B. pectinatus > C. dactylon > P. annua > E. heliscopa > A. arvensis > S. media. Irrespective of the plant species, roots exhibited higher concentrations of HMs than shoots. Higher amount of Cr (131.70 mg kg-1) was detected in the roots of B. pectinatus and the lowest amount (81 mg kg-1) in A. arvensis, Highest Cd concentration was found in the shoot of B. pectinatus and the lowest in the E. heliscopa. The highest concentration of Ni was found in the roots of S. media (37.40 mg kg-1) and the shoot of C. dactylon (15.70 mg kg-1) whereas the lowest Ni concentration was achieved in the roots of A. arvensis (12.10 mg kg-1) and the shoot of E. heliscopa (5.90 mg kg-1). The concentration of HMs in individual plant species was less than 1000 mg kg-1. Considering the higher values (> 1) of biological concentration factor (BCF), biological accumulation co-efficient (BAC), and translocation factor (TF), B. pectinatus and S. media species showed greater potential for HMs accumulation than other species. Therefore, these plants might be helpful for the remediation of HM-contaminated soil.

Notch corrosion fatigue behaviour and simplified strain energy density-based notch fatigue life assessment of Grade-A shipbuilding steel

Corrosion fatigue is a key challenge in lifecycle management of ship hull structures. Although sea wave fatigue stresses are linear-elastic, highly-damaging elastic–plastic conditions occur at geometrical discontinuities or notches. Estimation of notch stress-strains to characterize notch fatigue behaviour conventionally requires large computational efforts. Also, constant strain energy density (SED), as a driving force, is far more effective in realistic applications versus constant stress and strain fatigue life approaches. Identified research gaps were the development of a simplified SED approach for fatigue life assessment of hole-notched structures. Fatigue studies were conducted on hole-notched specimens of Grade-A shipbuilding steel in air and corrosion mediums. Strong synergistic interactions of corrosion and fatigue damage mechanisms were studied by scanning electron microscope (SEM) fractography. Notch corrosion fatigue life was reduced by 70% from notch air fatigue life due to environmental effect. Two new parameters are proposed to improve the efficiency of notch fatigue life assessment, namely “fatigue notch strain energy density concentration factor (K_SED) and “fatigue notch toughness”. This improved fatigue life assessment method was demonstrated as equally reliable but much simpler to implement, eliminating the complex computational analysis. This improved method has promising applications in real-time structural health monitoring (SHM) of ship hull structures.

Potential ecological risk by metals in Sepetiba bay (SE Brazil): Exporting metals to the oceanic region

Sepetiba Bay (SB) is one of the Brazilian coastal regions most impacted by anthropogenic activities due to increased population density, the installation of tourist and industrial mega-developments, and essential port, agricultural and fishing activities. Given the great concern about its environmental quality, several studies have focused on it, especially since the 1980s. This study aims to analyze the current ecological risk by potentially toxic elements (PTEs) in the bottom sediments of Sepetiba Bay (SB). The work integrates numerous variables (physicochemical, textural, and geochemical) analyzed at 73 stations in SB and the transition area to Ilha Grande Bay. The results show that the sediments in the eastern-inner region of Sepetiba Bay, along the Itacuruçá coast, and in some areas near the Marambaia Barrier Island (MBI) are severely polluted by Cd (4.47 mg kg−1) > Sn (7.31 mg kg−1) > Zn (824 mg kg−1) > Co (12.50 mg kg−1) > Pb (36.6 mg kg−1) > Cr (65.0 mg kg−1) > Fe (4.98 %) > Ni (21.4 mg kg−1) > V (66.0 mg kg−1), (maximum values), and highly polluted by U (2.8 mg kg−1) > Mn (857 mg kg−1) > Sb (0.32 mg kg−1) > Tl (0.63 ppm) > Hg (170 μg kg−1) > As (11.2 mg kg−1), maximum values. The pollution load index (PLI) and contamination degree (Cdeg) indexes also indicate considerable to very high contamination, indicating severe pollution in that zone. The Potential Ecological Risk Index (PERI) suggests high (160≤RI < 320) and very high (RI ≥ 320) ecological risk in the inner and middle areas of Sepetiba Bay by Cd > Hg > Cu > Co > Pb > Sn > Tl > Ni. Relatively low pH and Eh values were identified in the inner region of Sepetiba Bay, indicating eutrophication processes. A comparison of the concentration factors in the surface sediments of SB in 2009–2011 and 2022 suggests that there has been a general increase in contamination by metals, namely Fe, Mn, Pb, Co, Cr, Ni, U, V, and Hg. Although metals accumulate more pronounced in the inner and the most impacted marginal areas of Sepetiba Bay, their enrichment factors (EF) indicate an increase in contamination in the outer sector. Metals are being imported from the nearby oceanic region, where there is a dredging site, to the outer sector of Sepetiba Bay. Thus, the choice of dredged spoil disposal sites and how contaminated dredged material is deposited needs to be better addressed and is still a challenging task. This aspect often results in problems being transferred from one region to another. The results suggest that mitigation measures must be adopted to prevent the situation from worsening.

Scattering of SH waves by elliptical cavity and type-III crack in deep anisotropic geology

Most of the underground rock formations are anisotropic, and the study of the dynamic response of anisotropic geology containing internal defects is necessary for the development of underground tunnels or caverns. In this paper, the wave function expansion method, the complex function method, and the Green's function method are used to solve the problem of scattering of SH waves in anisotropic rock in the presence of elliptical cavity and type-III crack. Boundary conditions for solving the problem are given using the conformal transformation method, and crack in the medium is constructed using the "crack cutting" technique. The scattered wave field generated by the crack is constructed based on the Green function method, and the displacement and stress fields in the model are obtained by the wave field superposition principle in the case of SH wave incidence. The dynamic stress concentration factor (DSCF) on the boundary of the elliptical cavity and the dynamic stress intensity factor (DSIF) at the crack tip are derived. The correctness of the method is verified by degenerating it to a classical analytic solution. Finally, the effects of the anisotropic strength of the rock mass, the dimensions of the cavern, and the incidence angle and wave number of the SH wave on the DSCF and DSIF are analyzed by numerical calculations in both the frequency and time domains. The results show that the anisotropy of the rock mass, the shape of the cavern and the defects of the surrounding medium have a great influence on the dynamic response of the underground structures, which should be given enough attention in the development and design of deep underground caverns or tunnels.

Fatigue enhancement of welded thin-walled tubular joints made of lean duplex steel

In the present work, the fatigue strength and enhancement techniques of welded thin-walled (wall thickness of t = 2 mm) square hollow section (SHS) joints made of lean duplex stainless steel (grade EN 1.4162) are experimentally and numerically studied. Experimental fatigue tests were carried out on gas metal arc-welded tubular X-joints subjected to fully reversed (applied stress ratio of R = −1) constant amplitude in-plane bending moment. Geometrical improvement techniques were investigated by applying fully penetrating fillet welds and using structural reinforcements. The applications of high-frequency mechanical impact (HFMI) treatment were examined in the context of further enhancing the fatigue strength of the geometrically improved joints. In addition to the experimental work carried out in this study, the fatigue test data of welded thin-walled SHS and rectangular hollow section (RHS) joints were extracted from literature. Structural stress concentration factors were numerically and analytically obtained to validate the fatigue assessment model for welded thin-walled tubular joints using the structural hot-spot stress method. In addition, the effective notch stress (ENS) concept with the reference radius of rref = 0.05 mm was implemented. Compared to the joints in the as-welded state, fatigue strength improvements of 1.53–2.7 were found in the geometrically improved joints. On the other hand, the HFMI treatment did not lead to an additional increase in the fatigue strength capacity of the studied AW joints. The CIDECT guidelines for the structural hot-spot stress method were found conservative for thin-walled joints (t < 3 mm) and could be recommended for fatigue design.

Assessing local stresses in scanned fillet weld geometry using bagged decision trees

This study addresses the limitations of current parametric equations and artificial neural networks (ANNs) in accurately predicting the stress concentration factor (SCF) of fillet welded joints stemming from the simplification of their real weld profiles. To improve the accuracy, this study introduces bagged trees for estimating local stresses. The dataset used as the foundation for training the bagged trees is extracted from the actual weld geometry of T-shaped joints. It is created via a digitalization process involving the extraction of actual geometric parameters from the joints, which are transformed into finite element models (FEMs). These models are then employed to determine the ratio between the simulated sectional stress and the nominal stress (σsec/∆σnom) under an axial loading condition. A comprehensive comparison is carried out among existing parametric equations, ANNs, and the proposed bagged trees. The results emphasize the inadequacy of idealized geometry models in accurately determining local stresses for real weld profiles. In contrast, bagged trees are a promising method for accurately computing sectional weld stresses (σsec) within real weld geometry.

An artificial neural network model for determining stress concentration factors for fatigue design of tubular T-joint under compressive loads

PurposeThe stress concentration factor (SCF) is commonly utilized to assess the fatigue life of a tubular T-joint in offshore structures. Parametric equations derived from experimental testing and finite element analysis (FEA) are utilized to estimate the SCF efficiently. The mathematical equations provide the SCF at the crown and saddle of tubular T-joints for various load scenarios. Offshore structures are subjected to a wide range of stresses from all directions, and the hotspot stress might occur anywhere along the brace. It is critical to incorporate stress distribution since using the single-point SCF equation can lead to inaccurate hotspot stress and fatigue life estimates. As far as we know, there are no equations available to determine the SCF around the axis of the brace.Design/methodology/approachA mathematical model based on the training weights and biases of artificial neural networks (ANNs) is presented to predict SCF. 625 FEA simulations were conducted to obtain SCF data to train the ANN.FindingsUsing real data, this ANN was used to create mathematical formulas for determining the SCF. The equations can calculate the SCF with a percentage error of less than 6%.Practical implicationsEngineers in practice can use the equations to compute the hotspot stress precisely and rapidly, thereby minimizing risks linked to fatigue failure of offshore structures and assuring their longevity and reliability. Our research contributes to enhancing the safety and reliability of offshore structures by facilitating more precise assessments of stress distribution.Originality/valuePrecisely determining the SCF for the fatigue life of offshore structures reduces the potential hazards associated with fatigue failure, thereby guaranteeing their longevity and reliability. The present study offers a systematic approach for using FEA and ANN to calculate the stress distribution along the weld toe and the SCF in T-joints since ANNs are better at approximating complex phenomena than standard data fitting techniques. Once a database of parametric equations is available, it can be used to rapidly approximate the SCF, unlike experimentation, which is costly and FEA, which is time consuming.

Stress Concentration Factors of Concrete-Filled Double-Skin Tubular K-Joints

Tubular joints are important connecting parts of a welded steel tube structure. The S-N curves based on the hot spot stress (HSS) method are often used to evaluate the fatigue life of tubular joints in practical engineering. The stress concentration factor (SCF) is a key parameter to calculate HSS. In this paper, stress concentration tests of hollow-section and concrete-filled double-skin tubular (CFDST) K-joints were carried out, respectively, and then finite element models of K-joints considering the weld were established. The developed models were validated with the experimental results. The influence of key geometrical parameters, such as the diameter ratio of brace to chord β, the diameter to thickness ratio of chord γ, the wall thickness ratio of brace to chord τ, brace angle θ, and hollow section ratio ζ on the distribution and key position of SCFs along the weld toe, was discussed. Parametric studies were conducted to obtain the calculating equations for the SCF values of CFDST K-joints. The results demonstrate that infill concrete can effectively reduce SCFs along the weld on the chord. When the hollow section ratio was reduced to 0.317, the SCF was reduced by 77.2%. Notably, the SCF reduction rate was sensitive to γ and θ, with a decrease observed as γ increased. The hollow section ratio ζ had a less pronounced effect on SCF distribution patterns, but as ζ decreased, the chord’s stiffness improved, suggesting a potential approach to enhance joint performance. The distribution of SCFs is similar for joints of the same type but different geometric configurations. The innovatively integrated hollow section ratio in the CFDST design equation significantly simplifies and enhances the precision of SCF calculations for CFDST K-joints.

Controllable concentric electric field line distribution for simultaneous separation of DNA

An approach for the controllable separation and concentration of nucleic acid using a circular nonuniform electric field was proposed and developed. Using six different lengths of DNA molecules as standard samples, the distribution of the gradient electric field was increased from the outer circular electrode to the inner rod-shaped electrode, contributing to the migration of DNA molecules at a velocity gradient towards the region with the strongest inner electric field. The DNA molecules were arranged in a distribution of concentric circles that aligned with the distribution of concentric equipotential lines. The concentration of DNA multiplied with the alternation of radius. As a result, this platform allowed simultaneous DNA separation, achieving a resolution range of 1.17–3.03 through an extended electrophoresis time, resulting in enhanced concentration factors of 1.08–6.27. Moreover, the manipulation of the relative height of the inner and outer electrodes enabled precise control over the distribution and the deflection degree of electric field lines, leading to accurate control over DNA deflection.

The Cultivation of Spirulina maxima in a Medium Supplemented with Leachate for the Production of Biocompounds: Phycocyanin, Carbohydrates, and Biochar

Cyanobacteria are microorganisms that grow rapidly in an aquatic medium, showing the capacity of accumulations of biocompounds subsequently converted into value-added biocompounds. The cyanobacterium Spirulina maxima can produce pigments besides accumulating significant amounts of carbohydrates and proteins. An alternative to reducing biomass production costs at an industrial scale is the use of landfill leachate in the growing medium, as well as the mitigation of this pollutant. The objective of this work was to cultivate Spirulina maxima in a medium supplemented with leachate, using the design of experiments to evaluate the effects of leachate concentration (% v/v), light source, and light intensity in an airlift photobioreactor, analyzing them as a response to the productivity of biomass, phycocyanin, carbohydrates, and biochar. The highest values of productivity (mg L−1d−1) were 97.44 ± 3.20, 12.82 ± 0.38, 6.19 ± 1.54, and 34.79 ± 3.62 for biomass, carbohydrates, phycocyanin, and biochar, respectively, adjusted for experiment 2 with the factors of leachate concentration (5.0% v/v), light source (tubular LED), and luminosity (54 µmol m−2 s−1), respectively. The use of leachate as a substitute for macronutrients in Zarrouk’s medium for the cultivation of Spirulina maxima is a viable alternative in the production of biocompounds as long as it is used at an appropriate level.

A randomized controlled clinical trial of concentrated growth factor combined with sodium hyaluronate in the treatment of temporomandibular joint osteoarthritis

ObjectiveTo investigate the effect of concentrated growth factor (CGF) combined with sodium hyaluronate (SH) on temporomandibular joint osteoarthritis (TMJOA).MethodsSixty patients with TMJOA who were diagnosed by cone-beam computed tomography (CBCT) between March 2020 and March 2023 at the Stomatological Hospital of Xi’an Jiaotong University were randomly divided into a control group (n = 30) and an experimental group (n = 30). The patients in the experimental group were treated with CGF + SH, and those in the control group were treated with SH only. The visual analogue scale (VAS) score indicating pain in the temporomandibular joint (TMJ) area; the Helkimo Clinical Dysfunction Index (Di); and changes in condylar CBCT at the first visit and 2 weeks, 3 months and 6 months after treatment were recorded. The CBCT data of the patients in the experimental and control groups were collected, and the three-dimensional CBCT image sequences were imported into Mimics Medical 19.0 software in DICOM format for condylar reconstruction.ResultsThe VAS scores at 2 weeks, 3 months and 6 months after treatment were significantly lower in the experimental group than in the control group (P < 0.05), and the pain in the experimental group was significantly relieved. The Di was significantly lower in the experimental group than in the control group (P < 0.05), and the clinical function of the TMJ improved. After treatment, the CBCT score was significantly lower in the experimental group than in the control group (P < 0.05), and the condylar bone cortex was obviously repaired. Observation of the condylar bone cortex by three-dimensional reconstruction showed the same results as those obtained by CBCT.ConclusionCGF combined with SH is effective in the treatment of TMJOA and can improve muscle pain, TMJ pain, Impaired TMJ function, Impaired range of movement, Pain on movement of the mandible and promote bone repair.The registration number (TRN)ChiCTR2400082712.The date of registrationApril 5, 2024.

Spatiotemporal variation in methylmercury and related water quality variables in a temperate river under highly dynamic hydrologic conditions

The understanding of the essential environmental factors affecting the spatiotemporal variation in methylmercury (MeHg) in river water is limited to date, despite its importance for predicting the effect of ongoing climate change on MeHg accumulation in freshwater ecosystems. This study aimed to explore the variation in MeHg concentration and related environmental factors in the downstream zone of the Yeongsan River under highly dynamic hydrologic conditions by using water quality and hydrologic data collected from 1997 to 2022, and Hg and MeHg data collected from 2017 to 2022. The mean concentration of unfiltered MeHg was 35.7 ± 13.7 pg L−1 (n = 24) in summer and 26.7 ± 7.43 pg L−1 (n = 24) in fall. Dissolved oxygen (DO), conductivity, nitrate, and dissolved organic carbon (DOC) were determined to be the most influential variables in terms of MeHg variation based on the partial least squares regression model, and their effects on the MeHg concentration were negative, except for DOC. Heatmaps representing the similarity distances between temporal trends of hydrologic and water quality variables were constructed to determine fundamental factors related to the time-based variations in DO, conductivity, nitrate, and DOC using a dynamic time warping algorithm. The heatmap cluster analysis showed that the temporal trends of these variables were closely related to rainfall variation rather than irradiance or water temperature. Overall, biogeochemical factors directly related to in situ methylation rate of Hg(II)—rather than transport of Hg(II) and MeHg from external sources—mainly control the spatiotemporal variation of MeHg in the downstream zone of the Yeongsan River.

Analytical prediction and numerical verification of stress concentration profile around an in-situ tow break in resin-impregnated filament-wound composites

A new empirical analytical approach is developed for predicting the stress concentration profile around an in-situ tow break in filament-wound composites. A shear-lag analysis is firstly performed to solve for the perturbational axial displacement of the broken tow and resultant debonding lengths. Solution of stress field caused by tangential load on the surface of an elastic half space is then utilized in combination with superposition principle to obtain the overload magnitudes in the neighboring tows. Subsequently, high-fidelity finite element analysis on a representative uni-directional laminate model under different stress states is performed, and excellent overall agreement is observed between analytical and numerical predictions. The proposed method takes into account essential aspects such as transversely isotropic material properties, in-situ stress states and their effect on the interfacial frictional forces in the debonded interfaces, and thus provides a convenient way to evaluate the stress concentration factors in damaged filament-wound composites. In addition, this approach can be applied to yield auxiliary failure evaluation criteria for statistical strength prediction or finite element modeling of filament-wound composites or similar structures.

Ultra-stable foam enabled by nano silica engineering for foam concrete improvement

Foam concrete is increasingly applied in construction due to its lightweight, good thermal insulation and fire resistance, and environmental sustainability, while its low strength limits its further popularization and applications. To enhance the stability and performance of foam concrete, amphiphilic nano silica (ANS) was employed in this study to modify the sodium dodecyl sulphate (SDS) based foaming agent. Then, the designed foam was utilized to fabricate foam concrete, of which the micro/macro performance was analysed in detail. The results showed that ANS-modified foam exhibited superior stability with a thicker foam wall thickness, contributing to the enhancement of foam stability within the cement matrix. The foam concrete with ANS exhibited higher strength compared to the control groups. The analysis of pore structures revealed that the ANS modification led to a more rounded and homogeneous pore configuration, characterized by an increased proportion of small and medium-sized pores and a decreased average pore size. The increase in pore roundness was accompanied by a reduction in the number of sharp edges of the pores and therefore a reduction in the stress concentration factor, while the moderately sized pore also was more conducive to increasing strength due to its lower stress concentration. As a result, the strength of the concrete is significantly increased. These findings demonstrate the potential of ANS as an effective foam stabilizer for foam concrete production, leading to enhanced foam stability and improved mechanical properties of concrete.

Tailoring supramolecular solvents with phosphoryl groups for highly efficient extraction of chlorophenols in natural waters

BackgroundChlorophenols are routinely determined in aquatic systems to check compliance with the restrictive international legislations set for protection of human and aquatic life. Their control requires affordable analytical methods, particularly in labs at low- and medium-income countries. Liquid chromatography-UV detection is a convenient technique for this purpose, but the availability of suitable sample processing remains pending. Organic solvents are inefficient for extracting the whole range of chlorophenols whereas solid-phase extractions are expensive and labour-intensive. So, an efficient, fast and cheap extraction of chlorophenols, amenable to any lab, would help to cope with their worldwide analytical control in natural waters. ResultsA supramolecular solvent (SUPRAS) was tailored for providing mixed interaction mechanisms aimed at the efficient extraction of chlorophenols prior to LC-UV. The SUPRAS was synthesized from the self-assembly of hexylphosphonic acid under acidic conditions and consisted of sponge-like nanostructures made up of amphiphile and water. The phosphoryl (PO) group was selected as the major driver of the extraction because of its ability to act as halogen and hydrogen bond acceptor for chlorophenols. Additional interactions were hydrogen bonds from O–H amphiphilic groups and the surrounding water, and dispersion and CH-π interactions in the hydrocarbon chains. The number of binding sites in the SUPRAS could be modulated by addition of salt. The SUPRAS formed in situ in the sample, the extraction took 5 min, the concentration factor was around 220, quantification limits (0.1–0.3 μg L−1) were below the EU standards, and the method worked for natural waters. SignificanceA fast, low-cost, and organic solvent-free sample processing only requiring conventional lab equipment (stirrers and centrifuges) provided SUPRAS extracts that could be directly analyzed by LC-UV. SUPRAS synthesis occurred spontaneously in the water sample under addition of hexylphosphonic acid and the whole process required low skills. The method meets the analytical and operational performances for the analytical control of chlorophenols in natural waters and it is within the reach of any lab.

Tensile strength of particle reinforced composite with interfacial debonding

Strength prediction of a particle reinforced polymer composite (PRPC) is still challenging. Although a PRPC is overall isotropic, it is more difficult to predict its tensile strength accurately than a continuous fiber reinforced composite (CFRC). One reason for this difficulty is that the calculation of stress fields of the constituents in a PRPC are complicated. The other reason is that the strength of a PRPC is significantly affected by interfacial strength, which is hard to be measured directly. In our research, the discount of the composite strength after debonding is attributed to the intensifying stress concentration. Two stress concentration factors (SCFs) are derived respectively to characterize the stress fluctuations in the matrix caused by the embedded particle before and after debonding. Based on the micromechanics Bridging Model and the matrix true stress theory, these two SCFs can be applied to evaluate the interface strength and the ultimate tensile strength of the composite from the properties of its component materials. Illustrations are presented to verify the efficiency of our theory and analyze the main influencing factors on the strength of the PRPC, including mechanical properties of component materials, particle size and volume fraction.

Application of concentrated growth factor in mandibular third molar extraction: A protocol for systematic review and meta-analysis.

We will perform the systematic review to evaluate the effect of applying concentrated growth factor (CGF) on relieving postoperative complications and promoting wound healing following mandibular third molar extraction. The PubMed, Web of Science, Embase, Cochrane Library, China National Knowledge Infrastructure (CNKI), Wanfang Database, China Biology Medicine Disc (CBM), and VIP Databases will be comprehensively searched up to May 31, 2024. Randomized controlled trials (RCTs) examining the application of CGF after mandibular third molar extraction will be included. The protocol was registered in PROSPERO, and the registration ID was CRD42023463234. Two reviewers will conduct the literature search, eligible study selection, data extraction, and bias risk assessment (using the Cochrane Risk of Bias 2.0 tool). Data analysis will be performed with RevMan software (version 5.4). The results of this study will be available in a peer-reviewed journal. Our study will provide scientific evidence regarding the efficacy of applying CGF in mandibular third molar extraction.

Enhancing fatigue reliability prediction of offshore wind turbine jacket joints through individual uncertainties for each degree of freedom of stress concentration factor

This paper presents the fatigue reliability prediction for welded planar tubular joints of offshore fixed jacket support structures. A coupled model is employed to calculate the dynamic response of the jacket support structure under wind and wave loads. Stress concentration factors (SCFs) are evaluated using Efthymiou parametric equations, and the hot-spot stresses at eight locations on the chord and brace of the tubular joints are derived by summing the stress components from axial, in-plane, and out-of-plane actions. The stress distribution is determined using the rainflow counting method, fatigue damage from an S–N curve, and Miner’s rule. Uncertainties associated with the fatigue lifetime evaluation procedure are identified, quantified, and modeled. The focus is specifically given to modeling the uncertainty related to the SCFs, and a framework is proposed to evaluate the fatigue reliability of the joint by incorporating individual uncertainties for each degree of freedom of the SCFs (i.e., axial load crown, axial load saddle, in-plane bending moment, and out-of-plane bending moment). The results reveal that assuming the same uncertainty level (Coefficient of Variation of 0.2) as recommended by DNV-RP-C210 for each degree of freedom of the SCFs and including the uncertainty after obtaining the stress distribution from rainflow counting does not consistently yield conservative reliability index values, as it depends on the critical hot spot. It is essential to note that the simplified assumptions derived from the oil and gas sector may not directly translate to the offshore wind industry due to differences in loading conditions. A reduction of up to approximately 24% in the reliability index is observed for one critical hot spot, while an increase of up to 20% was observed for another. Overall, this paper provides valuable insights into the complex interplay of factors affecting the reliability of joints in offshore fixed jacket support structures, shedding light on the need for tailored approaches to address uncertainties in the specific context of the offshore wind industry.