Cold Atmospheric Pressure Plasma Jet Research Articles

Synthesis of stabilizer-free, homogeneous gold nanoparticles by cold atmospheric-pressure plasma jet and their optical sensing property

Recently, cold atmospheric-pressure plasma has been studied extensively as an efficient and green method to synthesize gold nanoparticles (AuNPs). Although the characteristics of the AuNPs, especially their homogeneousness, depend very much on the plasma synthesis parameters, there is a lack of a study involving these parameters systematically. Moreover, most of AuNPs-cold-plasma synthesis reports so far either required organic capping agents or resulted in highly non-uniform AuNPs. In this work, we systematically study the effect of most important synthesis parameters— including distance from the plasma jet to the solution, gas flow rate, plasma frequency, volume and concentration of the precursor, plasma interaction time as well as the effect of the synthesis environment (humidity and temperature)—on the uniformity of the AuNPs. Through various characterization measurements, we show that homogeneous and highly stable intrinsic AuNPs with an average size of 45 nm can be obtained with optimized synthesis parameters and in the absence of a stabilizer. The synthesized AuNPs yield advanced optical sensing properties in comparison with commercial AuNPs and can be further applied in developing versatile and high-sensitivity biosensors.

Comparing Bactericidal Effect of Pulsed Flash Lamp and Continuous Sterilization UV Lamps with a Cold Atmospheric Pressure Plasma Jet on E. Coli Solid Growth Medium

Comparing Bactericidal Effect of Pulsed Flash Lamp and Continuous Sterilization UV Lamps with a Cold Atmospheric Pressure Plasma Jet on E. Coli Solid Growth Medium

Synergistic catalytic degradation of ciprofloxacin using magnetic carbon nanomaterial/NiFe2O4 promoted cold atmospheric pressure plasma jet: Influence of charcoal, multi walled carbon nanotubes and walnut shell

BackgroundCurrently, water polluted to antibiotics such as ciprofloxacin (CIP) has been a main concern for the ecosystem and environment. Hence, the removal of these emerging contaminants is essential. MethodIn this research, a hybrid process including magnetic carbon nanomaterial/NiFe2O4 promoted atmospheric non-thermal dielectric barrier discharge plasma jet (APJ) as an environmentally friendly hybrid system was evaluated for eliminating CIP from polluted synthetic effluent. Multi walled carbon nanotubes (MWCNTs), activated carbon formed using charcoal (ChAC), and the walnut shell was applied as the carbonous source. Besides, to solve the separation problem, the charcoal, as optimum sample, was magnetized with NiFe2O4 (ChAC/NiFe2O4) using the treatment solvothermal route. Characterizations of all carbon materials were carried out by X-ray diffraction, field-emission scanning electron microscopy, transmission electron microscopy, Brunauer-Emmett-Teller and Barrett-Joyner-Halenda and vibrating-sample magnetometer analyses. FindingThe degradation amount for 80 mg/L CIP gained 48.8, 80.8, and 98.1% over APJ system + walnut shell, MWCNTs, and ChAC, respectively, after 90 min at 15 kVp-p output voltage and 0.05 g/L of catalyst loading. The results showed the ChAC/NiFe2O4 (87.2%) had less removal than ChAC (98.1%), but it has magnetic properties that can facilitate the separation problem.

In vivo assessment of APPJ discharge on the earthworm: coelomic TAC and MDA levels, cell death, and tissue regeneration.

The effective medical applications of cold atmospheric pressure plasma jet (APPJ) have been reported by many researchers, including sterilization of liquid and solid surfaces, treatment of chronic wounds, treatment of cancer tumors, and blood clots. Therefore, in this study, we exposed Aporrectodea trapezoides and Eisenia fetida earthworms to APPJ discharge (0-30s) to evaluate the impacts on regeneration of missed segments, apoptosis, lipid peroxidation (LPo), catalase activity (CAT), total antioxidant capacity (TAC), total proteins, and protein profile. Results showed APPJ induced significant effects on regeneration ability of earthworms after 20 and 30s of exposure (p < 0.05). Atmospheric pressure plasma jet did not have significant effects on MDA content and TUNEL-positive cells, but this effect was significant for TAC and CAT in both species (p < 0.05). In conclusion, the present study revealed for the first time that regeneration of missed segments in earthworms can be stimulated by plasma treatment.

Periodic forced flow in a nanosecond pulsed cold atmospheric pressure argon plasma jet

This paper is devoted to the study of the argon flow modification in a cold atmospheric pressure plasma jet driven by nanosecond high voltage (HV) pulses, from single to multiple HV shots applications. A schlieren optical bench has been designed in order to visualize the argon flow downstream expansion in quiescent air, for moderate flow rates below 1 standard liter per minute. A coupled approach is used between charge coupled device (CCD) schlieren imaging and intensified CCD (ICCD) plasma plume imaging, both time-resolved. It is shown that the application of only one HV pulse (i.e. single HV shot) is enough to disturb the flow. The disturbed flow exhibits ripple propagation, on a timescale similar to the flow velocity. When operating in double HV shots, the second ionization wave can be used as a probe, to instantly visualize the flow structure any time after the first HV pulse application. For some flow rates, the ripple can increase in amplitude up to the point when it strongly deforms, or even stops, the plasma plume expansion, after which it is entrained by the flow and the plasma plume retrieves its full usual expansion. When a series of HV pulses are applied, the maximal disturbance of the flow is achieved for a certain pulse repetition frequency (PRF), specific of each flow rate. It is associated with ripples alternation in the plasma plume, in a 3D helical-like arrangement. For greater PRF, the ripples progressively vanish, and the flow is clearly less disturbed. Once the ripples have vanished, increasing further the PRF does not change the plasma plume and flow structures. We suggest that the repetitive plasma ignition mechanically forces the flow inside the capillary with consequences on the global flow structure, similarly to a forced backward-facing step flow with actuator.

Adhesion of water-based paint on plasma-treated high-density polyethylene sheets

In this study, high-density polyethylene (HDPE) surfaces were treated with plasma to enhance the adhesion of a water-based paint. A custom-built cold atmospheric pressure plasma jet (CAPPJ) device using a neon transformer as its power source was developed and used in the surface treatment. The jet nozzle of the device was made from polytetrafluoroethylene with two bare stainless-steel electrodes positioned laterally through the nozzle and opposite each other with a 1 mm gap. Gas was allowed to pass through the nozzle, exiting through a 1 mm diameter hole where a plasma jet is ejected through the arc from the electrodes. The effect of plasma treatment on HDPE surfaces was determined. Air and nitrogen were used as the process gases and exposure times were also varied. Hydrophilicity of the surface increased with longer plasma exposure with a corresponding 50% increase in surface free energy compared to the untreated surface. From Fourier transform infrared and x-ray photoelectron spectroscopy analysis, it was seen that plasma treatment introduced oxygen containing functionalities onto the surface. Increase in adhesion of a water-based paint was observed for plasma-treated HDPE sheets.

Cold atmospheric-pressure air plasma jet: Physics and opportunities

Cold atmospheric-pressure plasma jet generates rich reactive species including reactive oxygen species and reactive nitrogen species with gas temperature close to or at room temperature, which is very attractive for applications such as plasma medicine. However, under one atmospheric pressure, due to the high electron–neutral particles collision frequency (1011–12/s), it is difficult to generate atmospheric pressure plasma while keeping the gas temperature close to or at room temperature. Furthermore, when air rather than noble gases is used as working gas, due to the low energy levels of rotational and vibrational states of nitrogen and oxygen, it becomes extremely challenging to generate cold atmospheric pressure air plasma jet (CAAP-J) with gas temperature close to or at room temperature. Fortunately, after decades of research, several CAAP-Js have been reported. In this review, the state-of-the-art of the development of CAAP-Js is presented. The CAAP-Js are grouped into six categories based on their electrode configuration. A brief discussion on each group of the CAAP-Js is presented. Moreover, the physics of CAAP-Js is discussed, including the dynamics, the striation phenomenon, the temporal behavior of plasma parameters, and the nonequilibrium characteristic of CAAP-Js. Furthermore, the measurements of the reactive species generated by CAAP-Js are briefly reviewed. Finally, discussions and perspective of future research on CAAP-Js are presented.

Analysis of Discharge Characteristics of Cold Atmospheric Pressure Plasma Jet

In this article, the investigation has been carried out for the characterization of the proposed tapered geometry of dielectric barrier discharge (DBD)-based cold atmospheric pressure plasma jet (C-APPJ) on the basis of optical emission spectroscopy (OES) and imaging for different operating parameters, such as argon gas flow rates, applied voltages, and frequencies. The detailed characteristics for the formation of the plasma plume using argon as a working gas have been presented for a wide range of flow rates [1–3 standard liter per minute (SLM)] and frequencies (15–25 kHz). Increasing the pulse frequency, the length and the diameter of the plasma plume increase, while the length of the plasma plume increases when increasing the gas flow rate up to 2 SLM. Time-integrated images have been captured using the intensified charge couple device (ICCD) camera, which illustrates that the plasma plume comprises different emission layers of definite patterns. The propagation dynamics and formation of different emission layers of the plasma plume have also been investigated using the COMSOL Multiphysics simulation. It has been observed that the local electric field of 6 kV/cm is responsible for the propagation of the plasma bullet and the generation of the electron with an average energy of ~9 eV. OES has also been performed to understand the plasma chemistry and identify the reactive species in the C-APPJ. The discharge analysis and characteristics performed through experiment and simulation would certainly be helpful for the design and development of C-APPJ sources.

Inactivation of Escherichia coli using atmospheric pressure cold plasma jet with thin quartz tubes

In this study, the temporal evolution and electrical characteristics of atmospheric pressure cold plasma jet (APPJ) structures with different quartz tube wall thicknesses that used AC power were investigated via experimentation and simulation. The percentage increase of electron density based on the wall thickness was investigated. Based on the optimal electric field intensity distribution and flow field distribution, the quartz tube with the optimal wall thickness improved the electron density. We applied the optimized APPJ structures to inactivate E. coli. We demonstrated that the APPJ structures with thin-walled quartz tubes had better inactivation characteristics than those with thick-walled structures regardless of the duration of treatment. The electron density properties of APPJ structures with different quartz tube wall thicknesses have a prominent impact on the improvement in the killing rate in the sterilization processes.

Concise characterization of cold atmospheric pressure helium plasma jet

This article provides a concise methodology for the development of a cold atmospheric pressure plasma jet and its characterization. To optimize the plasma jet parameters for biological and industrial applications, it is highly necessary to thoroughly understand its characteristics. The major emphasis of this work is to utilize simple and advanced diagnostics systematically with low complexity in the post-data analysis and to obtain in situ information of plasma jet parameters. The detailed optimization methods and the effect of the applied voltage and gas flow rate to achieve the stable plasma jet of the desired dimensions are discussed. In addition, the effects of the gas flow rate on the discharge current profiles and filament behavior are provided. Moreover, optical techniques, such as optical emission spectroscopy and time-resolved fast imaging, are used for the characterization of plasma parameters, i.e., Texc and ne, in a simple way. The gas temperature along the length of the plasma jet is estimated using a K-type thermocouple. The discussed simple characterization techniques and range of parameters of our designed plasma source will be useful for the development and optimization of plasma jet sources for various biological and industrial applications. Furthermore, we have also discussed various applications where we can use the discoursed diagnostics for the system development as well as for characterization. As the characterization of cold atmospheric pressure plasma jets is a multiphysics study, this concise characterization report on the cold atmospheric pressure plasma aims to provide necessary information for early researchers.

Cold atmospheric pressure plasma jet prepares TiO2 coating on carbon fibre for field emission and explosive electron emission

As the ‘heart’ of high-current vacuum electronic devices, explosive emission cathodes play an important role in their applications. In this work, a titanium dioxide (TiO2)/carbon fibre cathode prepared by a cold atmospheric plasma jet is reported. TiO2 on the carbon fibre surface prepared by an atmospheric plasma jet is at the mixture of anatase and rutile phases. The field enhancement factor of the TiO2/carbon fibre cathode is 6681, which is over ten times higher than that of the carbon fibre cathode. Furthermore, the TiO2 coating slows the diode impedance collapse and decreases the cathode plasma expansion velocity from 1.5–2.0 to 1.0–1.5 cm µs−1, which is explained by a cathode plasma model. The surface of the TiO2/carbon fibre cathode is covered by 1.6 cm2 plasma, far exceeding that of the carbon fibre cathode (1.1 cm2), which enables uniform explosive electron emission. The obtained results show that TiO2/carbon fibre cathodes prepared by cold atmospheric plasma jets will be potential candidates as high-current explosive electron emitters.

Cold Atmospheric Pressure Plasma Technology for Modifying Polymers to Enhance Adhesion: A Critical Review

This review summarizes the results of cold atmospheric pressure plasma technology application in polymers surface treatment. Attention is given to results of changes in the hydrophilic property of polymer surfaces by incorporation of polar functional groups when exposed to atmospheric pressure plasma, depending on the time of treatment, applied voltage, gas flow rate, and distance from the surface. We have successfully developed a plasma device that is able to generate cold atmospheric pressure argon plasma of low temperature (20 – 26) ° C downstream using a high-voltage power source which can be widely used in materials processing. Therefore, a cost-effective system of generating a plasma jet at atmospheric pressure with potential applications has been developed. Cold atmospheric pressure plasma jet (CAPPJ) has shown a lot of applications in recent years such as in materials processing, surface modification, and biomedical materials processing. CAPPJ has been generated by a high voltage (0-20 kV) and high frequency (20-30 kHz) power supply.&lt;br/&gt; The discharge has been characterized by optical and electrical methods. In order to characterize cold atmospheric pressure argon plasma jet, its electron density, electron temperature, rotational temperature, and vibration temperature have been determined using the power balance method, intensity ratio method, Stark broadening method, and Boltzmann plot method, respectively. The improvement in hydrophilicity of the cold plasma-treated polymer samples was characterized by contact angle measurements, surface free energy analysis, Fourier transform infrared (FTIR) spectroscopy, and scanning electron microscopy (SEM). Contact angle analysis showed that the discharge was effective in improving the wettability of polymers after the treatment. Furthermore, atmospheric plasma can be effectively used to remove surface contamination and to chemically modify different polymer surfaces. The chemical changes, especially oxidation and cross-linking, enhance the surface properties of the polymers.

Improving detection of BSA protein by applying atmospheric pressure plasma jets in MALDI-TOF mass spectrometry

To enhance protein identification in mass spectrometry systems, plasma can be applied in the sample preparation step in addition to conventional use, which improves the ionization process. In the present study, cold plasma technology is evaluated to achieve highly sensitive detection of low analyte concentrations.Plasma treatments are performed by two different low-temperature atmospheric-pressure sources. The protein ion signal after plasma treatment is characterized by matrix-assisted laser desorption ionization time-of-flight mass spectrometry (MALDI-TOF MS). The sample preparation method, exposure time and gas type for bovine serum albumin (BSA) are optimized. Plasma characteristics are determined by optical emission spectroscopy (OES) method. Also, the temperatures of plasma environment and sample are measured during the treatment with a non-contact infra-red digital camera.The water-soluble BSA protein is irradiated by cold atmospheric-pressure plasma jet (CAP jet) and radio-frequency plasma jet (RF jet). Mass spectra showed that argon plasma treatment with two-layer method induced a significant increase in ion intensity of MALDI-TOF MS. Argon treated water-soluble BSA and powder BSA lead to ten-times and three-times enhancement of protein ion signals as compared to the control, respectively. Also, treatment with argon RF jet, increases the ion signal more than two-times.The results indicate that ion intensity of BSA treated with CAP jet is significantly higher than that of BSA treated with RF jet. This finding, in addition to frequency and geometry parameters, depends on more analyte protonation, resulting in more ion flux toward BSA surface. Further, two-layer technique is considered as an optimal sampling method for MALDI.

Energy transfer in interaction of a cold atmospheric pressure plasma jet with substrates

The energy flux of a nanosecond pulsed cold atmospheric pressure (CAP) plasma jet in contact with a substrate surface was measured to improve the understanding of the correlation between energy flux, flow dynamics and applied electrical power. The flow pattern properties of the CAP jet were imaged using Rayleigh scattering showing a transition from laminar to turbulent flow at Reynolds number of 700, significantly smaller than the conventional critical Reynolds number of 2040. The energy flux to the surface was determined using a passive thermal probe as a substrate dummy. As expected, the energy flux decreases with increasing distance to the nozzle. Measurements of the floating potential of the probe revealed a strong positive charging (up to 165 V) attributed to ion flux originating mainly from Penning ionization by helium metastables. Negative biasing of the probe doubled the energy flux and showed a significantly increased ion contribution up to a nozzle distance of 6 mm to the surface. For positive biasing an increased contribution of electrons and negative ions was only found at 3 mm distance. The relevance of particle transport to the surface is shown by switching from laminar to turbulent flow resulting in a decreased energy flux. Furthermore, a linear correlation of energy flux and input power was found.

Ar metastable densities (3P2) in the effluent of a filamentary atmospheric pressure plasma jet with humidified feed gas

The Ar(3P2) metastable density in the effluent of the cold atmospheric pressure plasma jet kINPen was investigated as a function of the feed gas humidity, the gas curtain composition, and the distance from the nozzle by means of laser atomic absorption spectroscopy. The filamentary character of the plasma jet was considered as the absorption signals are from single individual events. From the effective lifetime, the quenching coefficient for Ar(3P2) by water was determined. A maximum Ar(3P2) density of (6.0±0.7)×1013 cm−3 was obtained close to the nozzle for a feed gas humidity of 20 ppm. The densities near the nozzle decreased inversely proportional to the water content in the feed gas leveling off at approximately 1×1013 cm−3, independently from the gas curtain composition. With the addition of water to the feed gas, the excitation dynamics changed, and the production and lifetime of Ar(3P2) was reduced. The impact of Ar(3P2) on the reactive species composition in the effluent was found to be smaller than within the plasma zone inside the plasma jet device.

Spatially and temporally resolved H and OH densities in a nanosecond pulsed plasma jet: an analysis of the radical generation, transport, recombination and memory effects

Cold atmospheric pressure plasma jets (APPJs) enable the generation of a large flux of highly reactive species to heat sensitive substrates at near ambient temperatures. Nonetheless, the experimental determination of reactive species inside APPJs, while exceedingly important, has not been reported in significant detail. In this work, we report the time-resolved axial density of hydroxyl (OH) and hydrogen radicals (H) in an APPJ device and its effluent operating in a He–H2O mixture using 1D laser induced fluorescence (LIF) and two-photon absorption LIF (TALIF). The results show that H and OH are mainly generated between the electrodes in the APPJ rather than by the guided streamer. The produced H and OH inside the jet are convectively transported to the jet effluent and determine the H and OH densities in jet effluent. The dominant production and destruction mechanisms of H and OH were obtained from a 0D model. The different production mechanisms of H and OH can explain the change in memory effect observed for OH (and not for H) for varying pulse repetition rates of the plasma generation.

Enhancement Propagation of Protocorms in Orchid (Cymbidium tracyanum L. Castle) by Cold Atmospheric Pressure Air Plasma Jet

Propagation of orchid (Cymbidium tracyanum L. Castle) treated by using an air cold atmospheric pressure plasma jet at room temperature was investigated. The peak-to-peak voltage discharge and flow rate of the air atmospheric pressure plasma jet were set at 10.5 kV and 10 L/min, respectively. The constituent particles of the air cold atmospheric pressure plasma jet were revealed by optical emission spectroscopy. At the end of the jet nozzle, the constituent particles were observed, such as hydroxyl radical ˙OH, N2 first negative system (N2 1 −), N2s positive system (N2 2 +), and atomic oxygen. The average size, average number of buds, fresh and dry weights simultaneously increased by cold air plasma treatment compared with the control ones. The highest positive effects of treated protocorms on average size, average number of buds, fresh and dry weight were significantly improved by 238.2, 475.9, 85.6, and 152.5%, respectively. The transmission electron microscope showed the cytoplasmic cell wall in orchid protocorm disturbed by air cold plasma. Thus, the effects of constituent particles of air plasma might attack in the cell wall of protocorm leading to cell loosening, which improved elongation and released bud dormancy. These results indicated that the propagation of orchid protocorms depended on the effects of air cold plasma treatment with different plasma time durations.

Modifying surface properties of polysulfone membrane with plasma from closed and opened plasma generators

Plasma jet has been widely used in the process of surface modification. However, the operation process often operates in an opened plasma jet system. This research investigated surface modification of flat-sheet polysulfone membrane by using three different types of atmospheric pressure cold plasma jet system that comprised of plasma jet in an opened system, in a closed system and in a closed with pump out plasma gas system. This research aims to improve surface wettability of membrane surfaces. The samples were irradiated with argon plasma in such three systems. The properties of the treated membranes were verified by measuring Water Contact Angle (WCA), Surface Energy (SE) and surface roughness. The results show that plasma jet in the closed with pump out plasma gas system provided the best results due to its lowest water contact angle, the highest surface energy and the highest surface roughness.

Decontamination of Aniline and Malathion on Material Surface by Array Cold Atmospheric Pressure Plasma Jet: Mechanism and Decontamination Pathways

Decontamination of Aniline and Malathion on Material Surface by Array Cold Atmospheric Pressure Plasma Jet: Mechanism and Decontamination Pathways

The spatial distribution of hydrogen and oxygen atoms in a cold atmospheric pressure plasma jet

Cold atmospheric pressure plasma jets (CAPJs) are an emerging technology for the localised treatment of heat sensitive surfaces. Adding humidity to the CAPJ’s feed gas yields an effective production of highly reactive intermediate species, such as hydrogen atoms, oxygen atoms, and hydroxyl radicals, among others, which are key species for biomedical applications. This study focusses on the effluent of the CAPJ kINPen, which was operated with argon feed gas and a humidity admixture of 3000 ppm, while a gas curtain was used to limit the diffusion of ambient air into the effluent. The axial and radial density distribution of O and H atoms is measured by means of picosecond two-photon absorption laser induced fluorescence spectroscopy (ps-TALIF). A maximum O atom density of (3.8 ± 0.7) × 1015 cm−3 and a maximum H atom density of (3.5 ± 0.7) × 1015 cm−3 are found at the nozzle of the plasma jet. The experimental results are compared to a two-dimensional reacting flow model that is coupled with a local zero-dimensional plasma chemical model. With this model, the main H and O atom production mechanisms are determined to be the dissociation of H2O and O2 in the plasma zone of the plasma jet. The latter indicates, that a significant amount of oxygen (1%) was present inside the device. The reaction of OH with O atoms represents the main consumption pathway for O atoms and is at the same time a significant production pathway for H atoms. The main consumption of H atoms is through a three-body reaction including O2 to form HO2, which consumes more H and O atoms to form OH. It is pointed out, that most of the species are produced in the plasma zone, and that O and H atoms, OH and HO2 radicals, and O2 and H2O molecules are strongly connected.