Coeval Mafic Magmatism Research Articles

Mercury isotope evidence for the importance of recycled fluids in collisional ore systems.

The sources of fluids and metals in porphyry systems of continental-collision settings are poorly constrained. Mercury isotopes display unique mass-independent fractionation (expressed as Δ199Hg) and may provide important constraints on metal and volatile sources given that Hg is a highly volatile metal. Here, we report Hg isotope data on ore-forming porphyries, barren magmatic rocks, and mantle-derived mafic magmas from southern Tibet. The fertile porphyries and coeval mafic magmas display mainly positive Δ199Hg values (up to +0.25 per mil), while Δ199Hg values in barren magmatic rocks and mafic magmas are largely negative (-0.54 to 0.00 per mil). The positive Δ199Hg values observed here are consistent with seawater and marine sediments, suggesting that the ultimate source of fluids involved in the genesis of post-subduction porphyry copper deposits was the mantle lithosphere metasomatized by previous oceanic plate subduction. Our Hg isotope data provide an alternative view to current metallogenetic models on collisional porphyry systems that focus on melting of the lower continental crust.

New geological insights on the Palaeoproterozoic Sembé-Ouesso Basin in northern Congo-Brazzaville – Implications for the Kibaran orogeny, Neoproterozoic rifting and Pan-African overprint

The Palaeoproterozoic Sembé-Ouesso Basin (SOB) is the northeasternmost of six foreland subbasins of the Eburnean orogen; it covers an area of about 64,000 km2 in the northern Republic of Congo, southeast Cameroun and the Central African Republic. The structural architecture and tectono-metamorphic history of the SOB have been studied in the Republic of Congo by airborne geophysical interpretation, geological mapping, and petrography, analysis of illite crystallinity and K-Ar geochronology.The oldest tectono-metamorphic event (D1/M1), which caused the main structuring of the SOB, coincides in age with the last (1.0–1.07 Ga) stage of Kibaran orogeny. Metamorphic conditions decrease from greenschist facies in the east to upper diagenesis in the west. D1 deformation started with west-vergent folding followed by N-S sinistral transpression in discrete shear zones. The tectonic style characterises the SOB as foreland in the external zone of an eastern concealed orogen that either represents the continuation of the Kibaran Belt or forms a separate, as yet unidentified unit.Subsequent Neoproterozoic extension is marked by two conjugate N-S/NNE-SSW and E-W/NW-SE fault systems and a local pull-apart structure (D2). Coeval mafic magmas were emplaced in the faults of both systems. At regional scale, the extension can be linked to Tonian rifting in the central part of the Congo Basin and within the West Congo Belt.The influence of the Neoproterozoic (600 Ma) Central African orogeny is mainly restricted to the north-western part of the SOB where the Dja nappe was thrust from the north over the Palaeoproterozoic rocks (D3/M2). Elsewhere, the Pan-African event had no thermal and only minor structural effects on the SOB.

Magmatic fluids responsible for lode gold mineralization in the giant Linglong deposit at Jiaodong, North China Craton: Constraints from Li[sbnd]O isotopes

The Jiaodong Peninsula, located in the eastern margin of the North China Craton, contains numerous world-class lode gold deposits that combined have a proven gold reserve of >5000 t. Despite a large amount of research, the source and evolution of hydrothermal fluids responsible for the gold mineralization in this region remains highly debated. The Linglong gold deposit is one of the largest deposits in the Jiaodong Peninsula. Gold lodes at Linglong are predominantly hosted within the Late Jurassic Linglong granite and structurally controlled by NE-trending faults. They are closely associated with large-scale hydrothermal alteration, which is paragenetically characterized by hydrothermal K-feldspar in pre-ore stage I, and sericite-quartz-pyrite in syn-ore stages II and III. The syn-ore alteration mineral assemblage is distributed within and around the gold lodes, whereas the K-feldspar alteration remains mainly distal to the gold lodes. From the unaltered to progressively intensifying K-feldspar-altered Linglong granites, there are decreasing trends for both whole-rock Li concentrations and δ7Li values, which are attributed to Rayleigh fractionation. The two values increase covariantly within the sericite-quartz-pyrite alteration zone towards the mineralization center, suggesting that further fluid-rock interaction and buffering of the ore fluid accounts for the observed Li elemental and isotopic variations. Fluid inclusion assemblages in quartz of stages I-III have homogenization temperatures of 349°-312 °C, 318°-272 °C, and 307°-246 °C, respectively. In-situ oxygen isotopic analysis on stage I quartz reveals δ18OQ values of 10.9–14.7 ‰, corresponding to δ18OW values of 4.3–9.2 ‰ for the equilibrated fluid. The δ18OW values of the equilibrated fluids of stages II and III are 5.6–8.9 ‰ and 5.2–8.8 ‰, respectively. The oxygen isotopic compositions indicate that magmatic fluid is prevailing for the K-feldspar and sericite-quartz-pyrite alterations. A binary mixing model using Li concentrations and δ7Li values further implies that the hydrothermal fluid was mainly sourced from coeval mafic magmas derived from the metasomatized lithospheric mantle. Our study highlights that lithium and in-situ oxygen isotopes can be used effectively to fingerprint the source of hydrothermal fluids and fluid-rock interactions.

First identification of Early Cretaceous mafic dikes in the Baingoin area, central Tibet: Implications for crust-mantle interactions and magmatic flare-up

Mafic dikes are generally emplaced in extensional tectonic settings and provide key information regarding deep mantle processes and sources. The Bangong-Nujiang suture zone was formed by the collision of the Qiangtang and Lhasa terranes and experienced intense magmatism during the Early Cretaceous. However, the deep mantle processes and mechanisms involved in this magmatic flare-up (ca. 115 Ma) in the collisional belt remain controversial because of the lack of evidence for coeval mafic magmatism. Here, we present detailed petrological, geochronological, geochemical, and Sr-Nd-Hf-O isotope data for the newly discovered hypersthene-bearing mafic dikes in the Baingoin area in the middle-eastern parts of the Bangong-Nujiang suture zone, central Tibet. Secondary ion mass spectroscopy (SIMS) zircon U-Pb dating showed that the mafic dikes were emplaced during 120−115 Ma. These mafic rocks are characterized by variable MgO contents (2.7−5.2 wt%) and Mg# values (38.5−52.8), slight enrichment in light rare earth elements (REEs; [La/Yb]N = 7.5−8.1), relatively flat heavy REE patterns ([Gd/Yb]N = 1.75−1.84), and negative Eu, Ta, Nb, and Ti anomalies. The dikes also have relatively low initial 87Sr/86Sr ratios (0.7060−0.7062) and negative εNd(t) (−2.2 to −1.6) and positive εHf(t) (+2.5 to +3.6) values, and variable zircon εHf(t) (−2.2 to +7.2) and slightly elevated zircon δ18O (5.6‰−7.0‰) values. These geochemical characteristics indicate that the mafic dikes were derived from an enriched lithospheric mantle source. However, compared with coeval magmatic rocks, the mafic dikes have relatively high εNd(t) and εHf(t) values, indicating that they contain a depleted mantle component. The mafic dikes contain clinopyroxene and orthopyroxene (i.e., hypersthene), indicative of derivation from a high-temperature magma source. Clinopyroxene-melt thermobarometry yielded a temperature range of 1167−1213 °C, further supporting the involvement of a high-temperature asthenospheric component. Therefore, we suggest that the parental magmas of the Nakoulai mafic dikes were probably generated by the interaction between the asthenospheric mantle and overlying metasomatized lithospheric mantle. Combined with data from nearby Cretaceous magmatic rocks and sedimentary rocks, we suggest that the mafic dikes were generated in a postcollisional setting caused by upwelling of asthenospheric mantle owing to slab breakoff beneath the Bangong-Nujiang suture zone. Slab breakoff played a key role in the crust-mantle interactions and the onset of the magmatic flare-up in the middle-eastern parts of the Bangong-Nujiang suture zone.

The newly recognized ca. 1.23–1.21 Ga dolerite sills and flood basalts from Fanhe Basin in the northeastern North China Craton: Petrogenesis and tectonic implications

The Ectasion Period (1400–1200 Ma) represents a transition stage from Columbia (Nuna) to Rodinia supercontinents. LIPs and mafic magmatic events during this period can provide important constraints on deep processes and paleogeographic reconstructions during this transition. In this paper, we firstly reported some ca. 1.23–1.21 Ga flood basalts coeval with mafic sills from the Fanhe Basin in the northeastern North China Craton (NCC). New zircon/baddeleyite U-Pb/Pb-Pb dating on dolerite sills emplaced into the Fanhe Group yields emplacement ages from 1231 ± 9 Ma to 1206 ± 20 Ma. Whole-rock 40Ar/39Ar dating of two basalts from the Erdaogou Formation yields approximate total gas ages of ca. 1250 Ma and ca. 1210 Ma. These new geochronological results revealed that the Erdaogou basalts are coeval with some dolerite sills emplaced into the Kuangzhuangzi, Guanmenshan and Tongjiajie Formations and the dolerite sills emplaced into the Hutouling and Erdaogou Formations. These newly recognized ca. 1.23–1.21 Ga mafic rocks can be linked to the broader Licheng LIP of the previous studies. The ca. 1.23–1.21 Ga mafic rocks in the Fanhe basin can be divided into alkaline and sub-alkaline series and these two series exhibit distinct trace element and Nd isotopic compositions. The alkaline rocks show strongly fractionated chondrite-normalized REE patterns with high LaN/YbN values of 12.69–15.05. The sub-alkaline samples display less fractionated REE patterns with lower LaN/YbN values of 2.74–10.13. The alkaline rocks have OIB-like trace element patterns and slightly negative to positive εNd(t) values from −0.7 to 0.7. An OIB-like, asthenospheric mantle source is suggested as the source of the alkaline rocks. In contrast, the sub-alkaline rocks exhibit low negative εNd(t) values from −10.9 to −4.6 and are interpreted to be derived from a subduction-modified subcontinental lithospheric mantle. By comparisons with the coeval mafic magmatism in other parts of the NCC and other cratons, we suggest that the ca. 1.23–1.21 Ga mafic magmatism or LIP in the NCC was either related to the mantle plume that resulted in the Marnda Moorn LIP in Western Australia or related to a back-arc extension prior to the formation of a Grenvillian orogen located in another continent connected to the southeastern margin of the NCC during assembly of the Rodinia supercontinent.

Geochemical Constraints on Petrogenesis and Tectonics of the Middle Devonian Granitic and Coeval Mafic Magmatism from the Tannuola Terrane (Northern Central Asian Orogenic Belt)

The Tannuola terrane, located in the northern Central Asian Orogenic Belt, comprises magmatic rocks, attributed to island-arc and collisional settings during the Early Cambrian to the Late Ordovician. However, zircon U-Pb age, geochemical, and Sr-Nd isotopic constraints demonstrate that there was a short episode of peralkaline A-type granite magmatism in the northeast border area of the Tannuola terrane. The obtained zircon U-Pb age of 387.7 ± 3.3 Ma indicates emplacement of the peralkaline A-type granitic rocks in the Middle Devonian (Eifelian–Givetian period boundary). Petrologically, these rocks are mainly composed of riebeckite granites and aplites, which are approximately synchronous with augite-rich dolerites. The granitic rocks are ferroan and calc-alkalic to alkali-calcic in composition. They are characterized by a high content of SiO2, total alkali, Zr, and total REE. Significant depletion of Ba, Sr, P, Ti, and Eu indicates fractionation of plagioclase and/or K-feldspar. The values of εNd(t) in riebeckite granites range from +5.61 to +6.55, and the calculated two-stage model age ranges between 610 and 520 Ma. Coeval dolerites on the chondrite-normalized REE pattern, (Th/Yb)pm–(Nb/Yb)pm, and Th/Yb–Nb/Yb diagrams show compositional affinity between E-MORB and OIB. They are rich in incompatible elements with high HFSE/LREE ratios (Nb/La > 1), indicating that the primary magma originated from the lithospheric mantle metasomatized by asthenosphere-derived melt. Based on these geochemical characteristics, it can be reasonably inferred that the peralkaline A-type granitic rocks, and the coeval mafic rocks, are anorogenic and were emplaced in an extensional tectonic environment despite slightly higher Y/Nb values, which might be caused by a crustal contamination effect. The geochemistry of mafic rocks suggests that the magma originated from the enriched mantle sources. The results of a zircon-saturation thermometer show high initial magma temperatures between 923 and 1184 °C, with an average of 1030 °C, indicating this rock association might be related to a mantle plume beneath the northern Central Asian Orogenic Belt.

Chronological and Geochemical Study of the Cenozoic Potassic Felsic Igneous Rocks in Western Yunnan, SE Tibet: Implications for their Tectonic Mechanisms

AbstractWhether there is a relationship between widespread Cenozoic igneous rocks and the activated Ailao Shan–Red River shear zone (ASRR) in western Yunnan, SE Tibet, remains highly controversial. New geochronological, and geochemical data derived from Cenozoic igneous rocks both within and far from the ASRR offers answers. Although these coeval felsic rocks (36.9–33.5 Ma) are enriched in large‐ion lithophile elements relative to high field strength elements, they also display some special geochemical features, such as high Y and Yb values of syenitic porphyries, which contrast with the high Sr and low Y contents of monzoporphyries and granitic porphyries. The syenitic porphyries exhibit geochemical characteristics similar to those of coeval mafic magmas, e.g., high K2O, Y, and Yb contents, indicating that the former were probably generated by fractional crystallization of the latter. However, the high Sr/Y (56.1–109) monzoporphyries and granitic porphyries, combined with their low MgO, and Cr (or Ni) contents, suggest that they were mainly derived from partial melting of a thickened mafic lower crust. Given that these Cenozoic magmatic events exhibiting planar distributions occurred outside of the activation of the ASRR (31–20 Ma), then they were not controlled by the latter. Instead, they were tied to convective removal of a thickened lower lithospheric mantle in western Yunnan during the Paleogene.

Rare metal enrichment of the Tianbao trachytic complex, North Daba Mountains (South Qinling): Insights from textures and geochemistry of trachytes and Nb-REE minerals

South Qinling hosts abundant alkaline igneous rocks characterized by rare metal mineralization, which, however, is not well understood, particularly for those extrusive alkaline magmatic systems. This study focuses on the Tianbao trachyte Nb(-REE) deposit located in the North Daba Mountains (South Qinling) and investigates textures and geochemistry of ore-bearing trachytes and Nb-REE minerals to reveal relative contributions of magmatic and hydrothermal processes to rare metal enrichment. Low K2O/Na2O ratios (0.26–1.64), depletions of Ba, Sr, and enrichments of Nb, Ta, Zr, Hf in the Tianbao trachytic complex resemble geochemical signatures of rifting-related alkaline igneous rocks, highlighting an intraplate rifting origin. Positive εNd(t) values (3.1 – 3.6) and constrained La/Yb (21.2 – 35.8) and Nb/Zr (3.7 – 4.8) ratios indicate that they might have originated from mixing of the asthenospheric mantle and metasomatized lithospheric mantle and formed due to protracted magmatic differentiation of coeval mafic magmas. Niobium and REEs in the Tianbao trachytic complex primarily originated from an enriched mantle source, and then upgraded to initial enrichment due to intense differentiation of the trachytic magmas. Niobium and REEs in the trachytic magmas were firstly incorporated into magmatic mineral phases (e.g., biotite, niobian titanite, niobian ilmenite and apatite) under relatively reduced (below the Ni-NiO oxygen fugacity buffer) conditions. With the differentiation of trachytic magmas, niobium, REEs and anion ligands (F-, CO32– and PO43-) got saturated in the late-stage alkaline melts and then entered the exsolved fluids. Ca-rich components should have been leached from the magmatic minerals during the hydrothermal stage and reacted with these ligands to develop Ca-rich hydrothermal mineral phases, including fluorite and calcite veins, allanite and apatite overgrowth under relatively oxidized (between the Ni-NiO and hematite-magnetite oxygen fugacity buffer) conditions. The remaining Nb and REEs finally precipitated as the economic minerals (e.g., allanite-(Ce), loparite-(Ce) and niobian Y-rich zircon) along fractures. Mass balance calculations indicate that these hydrothermal economic mineral phases account for the majority of Nb-REE reserve in the trachytic complex, and thus, the hydrothermal process might have played the key role in leading to Nb and REE concentrating to ore grade.

Periodicity of Karoo rift zone magmatism inferred from zircon ages of silicic rocks: Implications for the origin and environmental impact of the large igneous province

New U-Pb ages for zircons constrain the duration of silicic magmatism and timing of coeval mafic magmatism across the main rift zone of the Karoo large igneous province in Mozambique. Our 190 ± 2 Ma, 188.4 ± 0.9 Ma, 181.7 ± 1.0 Ma, 180 ± 3 Ma, 178 ± 2 Ma and 172 ± 2 Ma ages support periodicity of Karoo magmatism previously inferred from 40Ar/39Ar age data. The ∼ 190–188 Ma ages confirm early onset of magmatism and the ∼ 182–178 Ma ages correlate the bimodal volcanic successions of the Lower Zambezi and the Movene Formation with widespread silicic magmatism across the rift zone. The ∼ 172 Ma age corresponds to waning magmatic activity. The age range and Hf isotopic compositions of zircons indicate up to ∼9 Ma lifespan for the Jurassic silicic magma chambers and suggest that the ∼2700–400 Ma xenocrysts represent crustal sources of the host rocks. The available chronological data indicate that the ∼183 Ma main phase magmatism was largely confined within the main Karoo and Kalahari basins and that the preceding and subsequent phases were mainly associated with the Karoo rift zone. Judging from geochemical literature, different kinds of magmas were erupted during the successive magmatic phases. We calculate from published geochemical data that the mafic main phase magmas were relatively poor in CO2 and SO2 and the lava stacking patterns point to low eruption rates, which suggests that degassing of sedimentary wall-rocks of intrusions probably triggered the coeval Pliensbachian-Toarcian extinction. In contrast, the mafic late phase magmas were rich in CO2 and SO2 and at least some of the lavas indicate high eruption rates. We propose that efficient degassing from widespread mafic magmatism and explosive eruption of over 30,000 km3 of silicic magmas in the Karoo rift zone linked the ∼182–178 Ma late phase magmatism with contemporaneous global biosphere crises.

Cretaceous crustal melting records of tectonic transition from subduction to slab rollback of the Paleo-Pacific Plate in SE China

The Mesozoic geology of SE China has been widely considered to relate to subduction of the Paleo-Pacific Plate beneath the Eurasia, accompanied with extensive felsic magmatism. However, the relationship between the origin of the voluminous crust-derived magmatism and the Paleo-Pacific slab subduction remains unclear. Here we present petrology, zircon U-Pb-Hf isotope data, and whole-rock geochemical and isotopic compositions of two episodes of Cretaceous silicic volcanic rocks (~114–113 Ma for Group 1 and ~ 100–93 Ma for Group 2) from southeastern Zhejiang Province in SE China, to provide new constraints on the geodynamic transition of the Paleo-Pacific slab subduction. Both volcanic groups show similarly unradiogenic whole-rock εNd(t) and zircon εHf(t) values (εNd(t) = −8.6 to −6.4 and εHf(t) = −8.5 to −0.7 for Group 1, and εNd(t) = −7.1 to −6.1 and εHf(t) = −7.8 to −2.2 for Group 2). The limited emplacement of coeval mafic magmas and absence of mafic microgranular enclave and intermediate lavas suggest an insignificant role of mantle-derived melt either as a parental magma for differentiation or a mafic component during magma mixing. Instead, the low MgO and high concentrations of SiO2 and incompatible elements and the evolved Nd and Hf isotopic compositions indicate derivation of these two groups of silicic magmas from similar hybrid crustal sources containing the metasedimentary rocks of Cathaysia basement and the newly accreted arc crust. Group 1 rocks contain a higher proportion of hydrous minerals (e.g., biotite) and Sr/Y and La/YbCN ratios but lower zircon saturation temperature than Group 2. Such variations in mineral and geochemical compositions could be mainly attributed to the change of melting conditions from a relatively deeper, colder and water-fluxed crust to a shallower, hotter and less hydrous state. By combining our new results and previous studies of the late Mesozoic volcanic rocks in SE China, we propose that a geodynamic transition from subduction to slab rollback of the Paleo-Pacific Plate was responsible for such P-T-H2O variations of the crustal source.

Cambrian mafic and granitic intrusions in the Mazar-Tianshuihai terrane, West Kunlun Orogenic Belt: Constraints on the subduction orientation of the Proto-Tethys Ocean

The West Kunlun Orogenic Belt (WKOB) carries key information about the evolution of the Proto-Tethys Ocean. In order to have a better understanding of the early Paleozoic tectonic evolution of the WKOB and to unravel the process of the Tarim assemblage to Gondwana, we report field observations, petrography, ages, chemical and Sr-Nd-Hf isotopic compositions of the newly identified Cambrian mafic and granitic intrusions in the Mazar Terrane-Tianshuihai terrane (MZT-TSHT) at the interior of the WKOB. Our zircon U–Pb dating reveals that the mafic and granitic rocks in Tianshuihai Terrane (TSHT) emplaced at ca. 530 Ma, and that the mafic rocks in the Mazar Terrane (MZT) emplaced at ca. 500–490 Ma. Whole-rock major and trace element geochemistry defines a tholeiitic signature for these mafic rocks. Isotopically, the TSHT mafic rocks have depleted Nd isotope compositions with initial εNd(t) isotopes ranging from 2.74 to 3.60, whereas the MZT mafic rocks exhibit enriched whole-rock Nd isotope compositions with εNd(t) values ranging from −12.90 to −9.71. The distinct chemical and isotopic signatures argue that the Cambrian mafic rocks in the TSHT were derived from a depleted mantle source in an initial subduction setting, whereas the mafic rocks from MZT were derived from an enriched sub-continental lithospheric mantle source in an arc setting. The Cambrian granites in the TSHT show typical fractionated I-type granite elemental signatures, in line with their Nd-Sr-Hf isotope compositions. These Cambrian granites were most likely generated by partial melting of Mesoproterozoic (0.9–1.3 Ga) crustal sources due to underplating of the coeval mafic magma. Our results in combination with previous studies suggest that the Cambrian mafic and granitic rocks in the MZT-TSHT were generated by the southward subduction of the Proto-Tethys Ocean initiated at ca. 530 Ma. The long-term southward subduction led to the formation of the massive early Paleozoic accretionary wedge in WKOB. The Proto-Tethys Ocean finally closed at ca. 440 Ma as demonstrated by the amphibolite facies metamorphism of the accretionary complex and the middle to late Devonian molasses unconformably overlying the accretionary complex. This process caused the blocks in East Asia, including the Tarim, Qaidam and North Qilian, Yangtze and Indochina, to dock at the northern fringe of the Eastern Gondwana.

Break-up related 2170–2120 Ma mafic dykes across the North Atlantic craton: Final dismembering of a North Atlantic-Dharwar craton connection?

Progress with supercontinental reconstructions relies on accurate age determinations for continental geological units such as mafic dyke swarms. Here we present zircon and baddeleyite U-Pb ID-TIMS isotope data of six mafic dykes from the Archean North Atlantic craton in present-day southern West and South-East Greenland. Two dykes in southern West Greenland yield crystallization ages of 2021 ± 4 Ma, for the NE-trending Hamborgersund dyke, and 2125 ± 9 Ma, for the E-trending Angissunguaq dyke. Additional age determinations of mafic dykes from South-East Greenland are 2166 ± 8 Ma and 2158 ± 8 Ma for two E–W trending dykes, herein named the Skjoldungen dykes, and 2137 ± 11 and 2124 ± 11 for two ENE and NE trending dykes, respectively. The name Ruinnæsset dykes is proposed for this slightly younger, ca. 2137–2124 Ma, generation of dykes in SE Greenland, and Nuuk dykes for coeval ca. 2125 Ma dykes in SW Greenland. The Skjoldungen and the Ruinnæsset dykes have primordial mantle geochemical signatures, with only minor LILE-enrichments. These signatures differ from other, more ‘lithospheric’, Proterozoic dykes within the region, and may reflect highly attenuated lithospheric extension during their emplacement. Coeval mafic magmatism in North Atlantic and Dharwar cratons suggests that these two fragments coexisted within a common Paleoproterozoic supercraton. A lack of younger age-matches further argue for ca. 2170–2140 Ma rifting and subsequent break-up of this Dharwar-North Atlantic connection, prior to the 2137–2124 Ma emplacement of the Ruinnæsset dykes. Other global age correlations are discussed and a likely paleogeographic reconstruction of North Atlantic craton together with the Dharwar and Superior cratons within a Paleoproterozoic supercraton is presented.

Petrogenesis of Cenozoic high–Sr/Y shoshonites and associated mafic microgranular enclaves in an intracontinental setting: Implications for porphyry Cu-Au mineralization in western Yunnan, China

Cenozoic high–Sr/Y shoshonites in western Yunnan, China, are spatially and temporally associated with porphyry deposits and mafic volcanic rocks that formed at a post–collisional setting. However, the petrogenesis of these rocks and the origins of the associated mineralization remain unclear. Here we present new geochemical data for the high–Sr/Y shoshonites and associated mafic microgranular enclaves (MMEs) in the Jinshajiang–Ailaoshan mineralization belt, which formed as a result of India–Asia collision during the Cenozoic. Both fertile and barren shoshonitic porphyries were emplaced during the Eocene–Oligocene (32–37 Ma) and are characterized by enrichment in large–ion lithophile elements (LILE), depletion in high field strength elements (HFSE), high K2O (4–6 wt%), Sr contents (674–1370 ppm), and low Y contents (7–18 ppm). The barren Zhanhe, Yongsheng, Songgui, and Jianchuan, and fertile Machangqing (Cu–Au–Mo mineralization) porphyry intrusions have variable zircon εHf(t) values of −6 to +9 and old TDM2 ages of 1433 to 900 Ma. However, the barren Shigu porphyry intrusion yields relatively positive zircon εHf(t) values (−4 to +8) and younger TDM2 ages (903–631 Ma). These features indicate that the Shigu intrusion was derived from late Permian juvenile lower crust, and the other high Sr/Y shoshonites were derived mainly from Neoproterozoic juvenile lower crust. Fertile and barren porphyries have variable whole–rock εNd(t) values (−5 to −0.7) and (87Sr/86Sr) i ratios (0.70595–0.70788) that are within the range of coeval mafic magmas in western Yunnan. The MMEs comprise mafic enclaves and andesitic enclaves that formed during the Eocene (34–35 Ma) and have spheroidal shapes, igneous textures and contain acicular apatites. This indicates that the MMEs are globules of coeval mafic magma that was injected into and mixed with the host shoshonitic magma. The enclaves show low TiO2 contents (0.7–0.8 wt%), high MgO (6–9 wt%), Cr (184–450 ppm) and Ni contents (98–157 ppm), positive LILE anomalies, marked negative HFSE anomalies, a narrow range of εNd(t) values (−1.2 to −0.6), and (87Sr/86Sr) i values of 0.70556–0.70635. The andesitic enclaves show adakitic geochemical affinities and have similar zircon εHf(t) values (−2.7 to +2.5) to the host porphyries, whereas, the mafic enclaves have relatively negative zircon εHf(t) values (−8.7 to +1.5), similar to enriched mantle. These evidences suggest the high−Sr/Y shoshonites were produced by partial melting of juvenile lower crust mixed with ultrapotassic or potassic mafic magmas as represented by the andesitic enclaves. The mafic enclave melts were derived from enriched mantle metasomatized by slab–derived fluids, which elevated the Mg#, Cr, Ni contents of the host porphyries at Machangqing, Zhanhe and Yongsheng.Zircon saturation temperatures (TZr) of the high–Sr/Y shoshonitic rocks range from 735 to 777 °C and indicate the shoshonites were derived mainly from water–fluxed melting of lower crust. The Manchangqing fertile intrusion had a high oxidation state (zircon Ce4+/Ce3+ = 38–180, average = 91) and was derived by mixing between juvenile lower–crustal melts and voluminous coeval lamprophyres. In contrast, the barren Jianchuan, Songgui, Shigu, Yongsheng and Zhanhe high–Sr/Y shoshonites formed by partial melting of juvenile lower crust and some mixing with mafic lavas, and are characterized by low oxygen fugacity (zircon Ce4+/Ce3+ = 0.5–77, average = 20). As such, we suggest the mafic magmas triggered water–fluxed, moderate–degree partial melting of the lower crust and caused amphibole breakdown during melting. This process could not provide enough water for the formation of porphyry Cu-Au deposits in western Yunnan, and therefore formed low–fO2, relatively low–H2O, and barren high–Sr/Y magmas. However, ultrapotassic magmas (e.g., lamprophyres) with high H2O are able to trigger intense water–fluxed, partial melting of metal–fertilized lower crust, which generated high–fO2, relatively high–H2O, fertile, high–Sr/Y shoshonitic magmas in this intracontinental setting.

Petrogenesis and Geodynamic Implications of Late Jurassic Diorite Porphyry in the Neoproterozoic Ophiolitic Mélange of NE Jiangxi (South China)

Mesozoic magmatism is widespread in the eastern South China Block and has a close genetic relationship with intensive polymetallic mineralization. However, proper tectonic driver remains elusive to reconcile the broad intracontinental magmatic province. This study presents integrated zircon U–Pb dating, Hf isotopes and whole‐rock geochemistry of the Xiwan dioritic porphyry in the NE Jiangxi ophiolitic mélange. Zircon U–Pb dating by SIMS and LA‐ICP‐MS methods yielded an emplacement age of ∼160 Ma for the Xiwan diorite, confirming its inclusion into the Mesozoic magmatic province in SE China, instead of a component of the Neoproterozoic ophiolitic mélange genetically. The dioritic rocks have low SiO2 (58.08wt%–59.15wt%), and high Na2O (5.00wt%–5.21wt%) and MgO (4.60wt%–5.24wt%) contents with low TFeO/MgO ratios (1.02–1.09). They show an adakitic geochemical affinity but exhibit relatively low Sr/Y ratios (24.8–31.1) and high Y contents (14.6–18.3 ppm) compared to the Dexing adakitic porphyries. In addition, the Xiwan diorites have moderately evolved zircon Hf isotopic compositions (εHf(t)=−6.1‐ −0.1; TDM2=1597–1219 Ma). These elemental and isotopic signatures suggest that the Xiwan diorite formed through partial melting of a remnant arc lower crust (i.e., early Neoproterozoic mafic arc‐related rocks) in response to the underplating of coeval mafic magmas. In conjunction with the temporal‐spatial distribution and complex geochemical characteristics of the Mesozoic magmatism, our case study attests to the feasibility of a flat‐slab subduction model in developing the broad intracontinental magmatic province in SE China. The flat‐slab delamination tends to trigger an asthenospheric upwelling and thus results in extensive partial melting of the overlying lithospheric mantle and lower crustal materials in an extensional setting during the Mesozoic.

Phanerozoic granitoids in the central and eastern parts of Central Asia and their tectonic significance

The widespread occurrence of voluminous granitoids is a typical characteristic of the Central Asian Orogenic Belt (CAOB) in the central and eastern parts of Central Asia. The granitoids occupy a total area more than 8 million km2, with three major area peaks at Cambro-Ordovician, Carboniferous-Permian, and Jurassic. Six zircon age peaks at ca. 500, 430–370, 330–300, 290–260, 210–170 and 145–110Ma.The early Paleozoic granitoids (540–440Ma, with age peak at ca. 500Ma) mainly occur in the northwestern CAOB, and are of calc-alkaline I-type. They probably formed in a subduction setting (500–480Ma) within the Paleo-Asian Ocean (PAO) and subsequent microcontinental-collision (ca. 460Ma). The middle Paleozoic granitoids (430–370Ma) predominately occur in the NW and southern CAOB, and are characterized by a high-K calc-alkaline affinity, suggesting an accretionary and/or a collisional setting. The late Paleozoic (350–260Ma) granitoids are widespread in the CAOB and formed in variable tectonic settings within an intra-continental regime or active continental margins in the PAO and in the evolving Mongol-Okhotsk Ocean (MOO). Carboniferous granitoids (350–300Ma) in the northern and northwestern CAOB exhibit A-type, alkaline features and formed in a post-accretionary settings, whereas granitoids in the southern CAOB show I-type, calc-alkaline features and were generated in an arc setting. Permian granitoids (290–270Ma) are predominantly of I-A, A-type with alkaline signatures, associated with coeval mafic magmatism and suggesting a post-collisional or intraplate setting, contemporaneous with a Large Igneous Province (LIP) in the Tarim Craton. Some 270–250Ma calc-alkaline granitoids also occur in the southernmost CAOB. Combined with 250–245Ma high Sr/Y granitoids, these rocks reflect final closure of the PAO during 270–250Ma.Early Mesozoic (mainly Triassic) granitoids occur mainly in the eastern CAOB or eastern Central Asia. The early-phase granitoids (250–230Ma) are of I- and S-types, whereas the mid- and late-phase granitoids (ca. 230–190Ma) are of A-type and transitional I-A type or highly fractionated I-type. All these granitoids occur in variable settings (intraplate, post-orogenic, and continental arc) related to three tectonics regimes, namely the Paleo-Asian Ocean (PAO), the Mongol-Okhotsk Ocean (MOO), and the Paleo-Pacific Ocean (PPO). Late Mesozoic granitoids mainly occur in eastern Central Asia and were emplaced during 6 major magmatic events at 190–180, 180–165, 165–145, 145–135, 135–100 and 100–60Ma. The 190–165Ma granitoids are of I-type, calc-alkaline/high-K calc-alkaline, and evolved along active margins related to the Mongol-Okhotsk and Paleo-Pacific ocean domains. The 145–120Ma granitoids are highly fractionated I-, transitional I-A or, A-types, with high-K calc-alkaline/shoshonitic signatures. The magmatic evolution from the Late Jurassic to Early Cretaceous coincided with a tectonic transition from contractional, thickened crust to extensional thinning. The 120–65Ma granitoid magmatism displays a southeastward younging trend, suggesting a roll-back of the Paleo-Pacific oceanic plate.The granitoids in the CAOB of eastern Central Asia show variable whole-rock Nd and Hf-in-zircon isotopic compositions, and most have juvenile signatures. In some regions (e.g., Altai-Junggar and Great Xing’an), the volume of juvenile and slightly juvenile crust (<1.0Ga) is much higher than that of other orogens (such as the Qinling in Central China. The proportion of juvenile vs. old crust may be a marker to identify a typical accretionary orogen from a collisional orogen.

Systematic mineralogical diversity in A-type granitic intrusions: Control of magmatic source and geological processes

The origin and causes of mineralogical diversity of A-type granites are debated. The series of A-type granite plutons, with distinct mineralogical differences, emplaced along an Upper Paleozoic crustal-scale shear zone in the Cobequid Highlands, Nova Scotia, provide an opportunity to examine the origin of different A-type plutons in a similar tectonic setting. Based on the ferromagnesian minerals present, the plutons are classified into sodic granites with sodic amphibole, calcic granites with calcic amphibole, and biotite granites. Sodic and calcic granites occur exclusively in complex intrusions with subequal amounts of gabbro in the eastern shear zone, whereas plutons in the western shear zone, with lesser gabbro, are solely biotite granites. Trace elements and radiogenic isotopes show that the three granite types have different sources. Intensive parameters including temperature, pressure, and water-in-melt contents were estimated from mineralogical and geochemical data. Modeling of these geochemical data suggests that the biotite and calcic granites were derived by 20%–40% partial melting of intracrustal feldspathic rocks, whereas the sodic granites are extreme fractionates (90%) of coeval mafic magma. We propose that supply of Upper Paleozoic mafic magma, probably related to regional extension and decompression melting beneath the Magdalen Basin, created a deep crustal hot zone in the eastern Cobequid Highlands, and extreme fractionation of underplated mafic sills produced the sodic granites. Heat transfer from crystallizing mafic magma induced partial melting of the surrounding crust, creating batches of biotite and calcic granitic melts in different depths. Fractionated and crustally derived melts segregated along crustal-scale faults, constructing the complex plutons in the east. Melting of the crust was further facilitated by the release of water from the crustal rocks upon heating. In the eastern shear zone, water was released predominantly by magmatic rocks and in lesser amounts compared to the west, where Neoproterozoic sedimentary and volcaniclastic rocks are more abundant. The volatile-rich granitic melts in the western part of the shear zone were crystallized rapidly, stabilizing only biotite. This study demonstrates that the mineralogical variations in A-type granites arise from rather similar magma compositions, but they are important petrogenetic indicators of varying sources, specific magmatic processes, and emplacement conditions.

Geochronological data from TTG-type rock associations of the Arroio dos Ratos Complex and implications for crustal evolution of southernmost Brazil in Paleoproterozoic times

U–Pb isotope analyses by LA-MC-ICPMS (Laser Ablation – Multi Collector – Inductively Coupled Plasma Mass Spectrometry) in zircon crystals from metatonalites, tonalites and granodiorite gneiss from the Arroio dos Ratos Complex (ARC) early magmatism in southernmost Brazil are presented. The ARC is located in the eastern portion of the Sul-rio-grandense Shield, occurring as septa and roof pendants on granitoids emplaced along the Southern Brazilian Shear Belt (SBSB). The SBSB corresponds to a translithospheric structure composed of several anastomosed shear zones of dominantly transcurrent kinematics whose syntectonic magmatism, of Neoproterozoic age, is characteristic of post-collisional environments. The studied rocks comprise TTG-type associations with coeval mafic magmatism, deformed and metamorphosed within a ductile shear zone. Zircon crystals obtained from six samples are interpreted as igneous given that the crystals are subhedral to euhedral, bipyramidal, with concentric zonation, have ratios Th/U between 0.13 and 0.81 and have restricted evidence of overgrowth. The oldest Association 1 (A1) has structures compatible with recrystallization under conditions of high temperature and an igneous age of 2148 ± 33 Ma, obtained in a metatonalite. The rocks of Association 2 (A2) have similar compositions, although with a more significant coeval mafic fraction. They are intrusive into A1 and also show high-temperature recrystallization features. However, they are less deformed and partly preserve their primary, igneous fabric. The igneous ages obtained from two A2 tonalites are 2150 ± 28 Ma and 2136 ± 27 Ma. Association 3 (A3) is represented by tonalitic to granodioritic gneisses whose structure, composition and metamorphic features are similar to those of A1 rocks, except for the absence of coeval mafic magmas in the former. Local features resulting from partial melting are present in A3 rocks. Three samples from A3 were dated. A tonalitic gneiss gives igneous age of 2099 ± 10 Ma and two granodioritic gneisses give igneous ages of 2081 ± 7 Ma and 2077 ± 13 Ma. Restricted to A1, inheritance is represented by one subhedral, zoned, gently rounded zircon crystal interpreted as igneous, of 2732 ± 40 Ma (207Pb/206Pb age), with discordance of 9% and 232Th/238U ratio of 1.17. A single Neoproteozoic metamorphic date value was obtained from the rim of a zircon crystal of Paleoproterozoic core. The age of 635 ± 6 Ma (207Pb/206Pb age), with Th/U ratio < 0.1 and 1% discordance, is interpreted as compatible with adjacent SBSB magmatism. The three associations are interpreted to represent the record of successive magmatic pulses that mark the evolution of a Paleoproterozoic continental magmatic arc. In the study area, these magmatic arc associations represent relict areas partly reworked and relatively well-preserved from Neoproterozoic tectono-magmatic post-collisional events during the construction of the Southern Brazilian Shear Belt.

Proterozoic granulite formation driven by mafic magmatism: An example from the Fraser Range Metamorphics, Western Australia

Elevated heat flow and mafic magmatism during lithospheric extension have often been invoked as a mechanism to drive high-temperature low-pressure metamorphism that produces granulite facies mineral assemblages. Typically, however, evidence of the contemporaneous heat source, such as coeval mafic magmatism, is absent. In this study, we present pressure–temperature (P–T) pseudosection analysis combined with U–Pb isotopic data from zircon and monazite that constrain both the conditions and timing of granulite facies metamorphism in the Fraser Range Metamorphics of the Albany-Fraser Orogen in southern Western Australia. These results also elucidate the extremely rapid timing of, sequentially, deposition of sedimentary protoliths, mafic magmatism, partial melting, and metamorphism within the Fraser Zone during the Mesoproterozoic. The youngest detrital zircons, together with the magmatic ages of intrusive rocks, constrain the depositional age of the protoliths to the Fraser Range Metamorphics to between 1334 and 1293Ma. Peak metamorphic conditions at c. 1290Ma were c. 850°C at pressures of 7–9kbar. Peak metamorphism was followed by a period of isobaric cooling at pressures of c. 9kbar. U–Pb zircon ages from leucosomes and metamorphic overgrowths in the metapelitic rocks indicate crystallization of partial melts at 1290Ma, essentially coincident with the emplacement of mafic rocks at 1292Ma. In situ analyses of both matrix hosted monazite and monazite inclusions in garnet yield ages between 1285 and 1268Ma, with no significant age difference between monazite in the two textural positions. Cooling of the Fraser Zone below the Rb-Sr biotite closure temperature (∼400°C) occurred at 1260Ma. Cooling and strengthening of the Fraser Zone rendered it less susceptible to subsequent tectonic events that affected rocks to the north and south of this resistant lozenge. Only rare geochronological evidence of later events can be resolved in recrystallised monazite rims dated at 1234±17Ma.

Petrogenesis of syntectonic granites emplaced at the transition from thrusting to transcurrent tectonics in post-collisional setting: Whole-rock and Sr–Nd–Pb isotope geochemistry in the Neoproterozoic Quatro Ilhas and Mariscal Granites, Southern Brazil

The Neoproterozoic post-collisional period in southern Brazil (650–580Ma) is characterized by substantial volumes of magma emplaced along the active shear zones that compose the Southern Brazilian Shear Belt. The early-phase syntectonic magmatism (630–610Ma) is represented by the porphyritic, high-K, metaluminous to peraluminous Quatro Ilhas Granitoids and the younger heterogranular, slightly peraluminous Mariscal Granite. Quatro Ilhas Granitoids include three main petrographic varieties (muscovite–biotite granodiorite — mbg; biotite monzogranite — bmz; and leucogranite — lcg) that, although sharing some significant geochemical characteristics, are not strictly comagmatic, as shown by chemical and Sr–Nd–Pb isotope data. The most primitive muscovite–biotite granodiorite was produced by contamination of more mafic melts (possibly with some mantle component) with peraluminous crustal melts; the biotite monzogranite, although more felsic, has higher Ca, MgO, TiO2 and Ba, and lower K2O, FeOt, Sr and Rb contents, possibly reflecting some mixing with coeval mafic magmas of tholeiitic affinity; the leucogranite may be derived from pure crustal melts. The Mariscal Granite is formed by two main granite types which occur intimately associated in the same pluton, one with higher K (5–6.5wt.% K2O) high Rb and lower CaO, Na2O, Ba and Zr as compared to the other (3–5wt.% of K2O). The two Mariscal Granite varieties have compositional correspondence with fine-grained granites (fgg) that occur as tabular bodies which intruded the Quatro Ilhas Granoitoids before they were fully crystallized, and are inferred to correspond to the Mariscal Granite feeders, an interpretation that is reinforced by similar U–Pb zircon crystallization ages. The initial evolution of the post-collisional magmatism, marked by the emplacement of the Quatro Ilhas Granitoids varieties, activated sources that produced mantle and crustal magmas whose emplacement was controlled both by flat-lying and transcurrent structures. The transition from thrust to transcurrent-related tectonics coincides with the increase in the proportion of crustal-derived melts. The transcurrent tectonics seems to have played an essential role in the generation of mantle-derived magmas and may have facilitated their interaction with crustal melts which seem to be to a large extent the products of reworking of orthogneiss protoliths.

Dating coeval mafic magmatism and ultrahigh temperature metamorphism in the Anápolis–Itauçu Complex, Central Brazil

Dating granulites has always been of great interest because they represent one of the most extreme settings of an orogen. Owing to the resilience of zircon, even in such severe environments, the link between P–T conditions and geological time is possible. However, a challenge to geochronologists is to define whether the growth of new zircon is related to pre- or post-P–T peak conditions and which processes might affect the (re)crystallization. In this context, the Anápolis–Itauçu Complex, a high-grade complex in central Brazil with ultrahigh temperature (UHT) granulites, may provide valuable information within this topic.The Anápolis–Itauçu Complex (AIC) includes ortho- and paragranulites, locally presenting UHT mineral assemblages, with igneous zircon ages varying between 760 and 650Ma and metamorphic overgrowths dated at around 650–640Ma. Also common in the Anápolis–Itauçu Complex are layered mafic–ultramafic complexes metamorphosed under high-grade conditions.This article presents the first geological and geochronological constraints of three of these layered complexes within the AIC, the Damolândia, Taquaral and Goianira–Trindade complexes. U–Pb (LA-MC-ICPMS, SHRIMP and ID-TIMS) zircon analyses reveal a spread of concordant ages spanning within an age interval of ~80Ma with an “upper” intercept age of ~670Ma. Under cathodoluminescence imaging, these crystals show partially preserved primary sector zoning, as well as internal textures typical of alteration during high-grade metamorphism, such as inward-moving boundaries. Zircon grains reveal homogeneous initial 176Hf/177Hf values in distinct crystal-scale domains in all samples. Moreover, Hf isotopic ratios show correlation neither with U–Pb ages nor with Th/U ratios, suggesting that zircon grains crystallized during a single growth event. It is suggested, therefore, that the observed spread of concordant U–Pb ages may be related to a memory effect due to coupled dissolution–reprecipitation process during high grade metamorphism.Therefore, understanding the emplacement and metamorphism of this voluminous mafic magmatism is crucial as it may represent an additional heat source for the development of the ultrahigh temperature paragenesis recorded in the paragranulites.