Coating Growth Rate Research Articles

Oxidation resistance and thermal stability of (MoZrHfTaNb)-Si-B coatings deposited by HIPIMS method with different Ar pressure

The influence of argon pressure on the structure, mechanical characteristics, oxidation resistance, and thermal stability of (MoTaNbZrHf)-Si-B coatings deposited by HIPIMS method using a composite target based on high-entropy (MoZrHfTaNb)Si2 silicide and (MoZrHfTaNb)B2 boride was studied. Coatings deposited at Ar pressure of 0.1–0.2 and 1.3–2.2 Pa had a dense, defect-free structure. Increasing the Ar pressure to 37–42 Pa led to the formation of a coating with a columnar structure, while, according to X-ray diffraction and transmission electron microscopy, all coatings were amorphous. Increasing the Ar pressure from 0.1 to 0.2 to 37–42 Pa led to a magnifying the growth rate of coatings in 2.5 times. All coatings were characterized by a similar hardness of 14–15 GPa. The elastic modulus and elastic recovery decreased from 196 to 178 GPa and from 40 to 34 % when the argon pressure increased from 0.1 to 0.2 to 37–42 Pa, respectively. The coatings successfully resisted oxidation at temperatures of 1100 °C and 1300 °C. The protective properties of the coatings are due to the formation of a dense oxide film based on a-Si:B:O amorphous phase with crystallites of the m-HfO2, m-ZrO2, m-Nb2O3, o-Ta2O5, t-ZrSiO4 and t-HfSiO4 phases. Heating in a TEM column showed that the coating deposited at an Ar pressure of 0.1–0.2 Pa crystallizes immediately upon reaching a temperature of 700 °C with the release of predominantly the h-MoSi2 phase. Crystallization of the coating obtained at an Ar pressure of 37–42 Pa also occurs at 700 °C, but only during long-term exposure and is accompanied by the precipitation of the h-Ta5Si3 and t-Nb5Si3 phases. Thus, it has been shown that by increasing the gas flow rate, the productivity of sputtering in the HIPIMS mode can be increased without a significant loss in hardness, oxidation resistance and thermal stability of coatings.

Anodic polarization accelerated titanium carbide coating formation in molten salt

Salt-thermo-carburizing (STC) by simply soaking transition metals in molten CaCl2-CaC2 is an effective method to prepare carbide coatings on metallic substrates. Herein, more efficient anodic carburizing (AC) is demonstrated in the same molten salt via electrochemical oxidation of C22−, which greatly accelerating the growing rate of the carbide coating. Typically, TiC coating was successfully prepared on titanium anode coupled with a graphite cathode. The effect of current density, reaction temperature, and reaction time on the composition, morphology, and structure of the carbide coating was systematically investigated. The results demonstrate that anodic carburizing enables a dense, uniform TiC coating formation with a relatively high rate. The growing kinetics of TiC follows parabolic law for both of AC and STC process, but the rate constant of AC (17.61 μm h-0.5) is much higher than that of STC (5.17 μm h-0.5). It only takes ~0.7 h for the AC process to get a TiC coating with a thickness of 15 μm at 875 °C, but takes >8 h for the STC process. The applied anodic polarization improves the interfacial carbon potential gradient by promoting the C22− oxidation, thereby accelerating the growth rate of TiC coatings.

Relationship among Thermodynamic, Growth Kinetics, and Microstructure Characterization of the Simple and Silicon‐Modified Aluminide Coating on Ni‐based Superalloy

AbstractThis research investigates the effects of pack cementation parameters on the thermodynamics, growth kinetics, and microstructure of the simple and silicon‐modified aluminide coatings on the IN718 superalloy. The growth kinetic modelling of the aluminide coating, activated by NH4Cl, is established as . further optimizing the kinetics modelling that includes both CaCl2 activator or the mixture of CaCl2 and NH4Cl. The results showed that NH4Cl as an activator generated a higher equilibrium partial pressure of halides, which enhanced the deposition efficiency of active Al atoms and facilitated the significant precipitation of Cr‐rich carbides. Additionally, part of the CaCl2 substitute NH4Cl could maintain a high coating growth rate and reduce the hazards. Adding Si element preferentially combines with Cr formed the Cr9.1Si0.9 phase along grain boundaries, which blocked the inner‐diffusion channels of Al atoms and reduced the thickness of the silicon‐modified aluminide coating compared to simple aluminide coating. These researches revealed the relationship among the thermodynamics, growth kinetics, and microstructure of simple and silicon‐modified aluminide coatings. The thickness and microstructure of coatings can be effectively regulated by adjusting the powder composition, content, and process parameters to achieve precise control.

Numerical simulation and experimental study of dip angle spray film thickness under elliptical double Gaussian sum model

To address the problem of modeling the growth rate of coating film thickness when spraying at inclination angle, based on Gaussian sum model, it is proposed to use the elliptic double Gaussian sum model to establish the cumulative model of coating film thickness when spraying at static inclination angle of the spray gun. The differential geometry amplification theorem is used to establish the coating growth rate model with the spraying inclination angle as the variable; after that, the static inclination spraying experiments are carried out, and the coating thickness data of the sampling points are recorded through the spraying experiments, and the Levenberg-Maquart algorithm is used for the least-squares fitting of the model, which results in the static spraying film thickness distribution model. Finally, compared with the elliptic double β model, the fitting accuracy of the elliptic double Gaussian sum model is 6.3% higher than that of the elliptic double β model when spraying at inclination angle by comparing the R-square values, and the elliptic double Gaussian sum model is more capable of obtaining a better fitting accuracy, which further confirms the validity and practicability of the model.

Effect of low concentration electrolytes on the formation and corrosion resistance of PEO coatings on AM50 magnesium alloy

In this paper, the formation process, morphology, and electrochemical performance of PEO coatings on AM50 magnesium alloy prepared in low concentration phosphate, aluminate, and phosphate-aluminate electrolytes were systematically studied. The results show that the coatings prepared from the phosphate electrolytes have a higher thickness and better corrosion resistance properties compared to the other electrolytes. The coatings prepared from low concentration phosphate-aluminate mixed electrolytes have slightly thinner thickness, a similar coating structure and an order of magnitude lower value of electrochemical impedance compared with phosphate electrolyte coatings. The Coatings prepared from low concentration aluminate electrolytes have the lowest thickness and the worst corrosion resistance properties which gets close to corrosion behavior of the bare AM50 under the same test conditions. Considering application, coatings prepared from single low concentration phosphate electrolytes and low concentration phosphate-aluminate electrolytes have greater potential than single low concentration aluminate coatings. However, reducing the electrolyte concentrations of coating forming ions too much has negative influence on the coating growth rate.

Preparation of Alumina Thin Films by Reactive Modulated Pulsed Power Magnetron Sputtering with Millisecond Pulses

This paper aims to investigate the quality of thin alumina films deposited on glass samples using magnetron sputtering in the reactive modulated pulsed power mode (MPPMS) and evaluate the process productivity. The aluminum target was sputtered in Ar/O2 gas mixtures with different fractions of oxygen in the total gas flow, in the fixed pulsed voltage mode. The pulse-on duration was varied between 5 and 10 ms, while the pulse-off time was 100 or 200 ms. The dependences of mass deposition rate and discharge current on the oxygen flow were measured, and the specific deposition rate values were calculated. Prepared coatings had a thicknesses of 100–400 nm. Their quality was assessed by scratch testing and by measuring density, refractory index, and extinction coefficient for different power management strategies. The strong influence of pulse parameters on the coating properties was observed, resulting in a maximum density of 3.6 g/cm3 and a refractive index of 1.68 for deposition modes with higher duty cycle values. Therefore, adjusting the pulse-on and pulse-off periods in MPPMS can be used not only to optimize the deposition rate but also as a tool to tune the optical characteristics of the films. The performance of the studied deposition method was evaluated by comparing the specific growth rates of alumina coatings with the relevant data for other magnetron discharge modes. In MPPMS, a specific deposition rate of 200 nm/min/kW was obtained for highly transparent Al2O3, without using any dedicated feedback loop system for oxygen pressure stabilization, which makes MPPMS superior to short-pulse high-power impulse magnetron sputtering (HiPIMS) modes.

Methods of structural surface engineering in solving problems of multifactorial improvement of materials performance

Problem. Structural surface engineering encompasses a complex of scientific disciplines and technological methods of directed change of physical and chemical properties of materials surface layers by modification, deformation, application of films, coatings, protective layers, with the help of various combined methods. In the course of the study several different methods of structural engineering of the surface are considered for solving problems of multifactor increase of the level of exploitation characteristics of materials. The methods described in the article are characterized by different physics of the process on the way to obtaining the result, but are aimed at modifying the structure and properties of the surfaces to which they are applied. Goal. Consideration of different methods of influence on the surface of ferrous and non-ferrous alloy objects, analysis of their influence on the modification of the structural state and properties of the surface layers that were investigated, discussion of the peculiarities of each of the considered technologies. Method. The first direction includes technologies that include a friction component, namely thermofriction treatment (TFT) for thermofriction hardening (TFH), supplementary thermofriction hardening (STH) or thermofriction welding (TFW). The second direction is the technology involving the use of anodic-cathodic electrolysis mode in alkali-silicate electrolyte – micro-arc oxidation (MAO). The third direction is the technology of vacuum-arc PVD-method, which involves obtaining chromium coatings. The article describes the features and results of application of such technologies, as well as the expediency of using this or that method for materials of different classes, schemes of the corresponding installations are presented. Results. The result of additional hardening of U8A steel surface from the microhardness level of 7.2 GPa to 14.7 GPa by DTFZ method after its thermal hardening practically to the maximum possible level is shown. The microstructure of the cross section of the pre-hardened U8A steel sample after DTFZ is presented, where the degree and character of surface hardening can be reliably seen. It is emphasized that in previous studies a consistently effective hardening of steels of various classes was achieved, up to a level of 22 GPa in 65G steel. The structure and properties of coatings on low-alloy aluminum alloys AB and AD1 formed in alkali-silicate electrolyte in the anodic-cathodic mode of MDO in the process of application of the microarc oxidation method have been studied. It is shown that the method of MDO in alkali-silicate electrolyte allows to obtain coatings with thickness up to 300 μm, coating growth rate ~ 2 μm/min and coating hardness 10-20 GPa. The coatings have high adhesion to the substrate, have a layered structure, the properties of the coatings are determined by the properties of the base layer. The coatings have a crystalline structure and consist of the following phases: γ-Al2O3, α-Al2O3, mullite (3Al2O3⋅2SiO2), the ratio between the phases depends on the electrolysis conditions. It is established that phase formation begins with the γ-Al2O3 phase, which in the process of further growth of the coating turns into the α-Al2O3 phase or interacts with silicon oxide to form the mullite phase. The possibility of obtaining high-quality chromium nitride-based hard coating by vacuum-arc sputtering is shown.

Methods of Structural Engineering of Surface in Solving the Problems of Multifactorial Increase of the Level of Operational Characteristics of Materials

In the course of the study, several different methods of surface structural engineering are reviewed. The methods described in this paper are characterized by different process physics on the way to obtaining the result, but they are aimed at modifying the structure and properties of the surfaces to which they are applied. Among them, two different technological directions are considered. The first area involves technologies that include a friction component, namely thermofriction treatment (TFT) for thermofriction strengthening (TFS), additional thermofriction strengthening (ATFS) or thermofriction welding (TFW). The second direction is a technology that involves the use of an anode-cathode electrolysis mode in an alkaline-silicate electrolyte – micro-arc oxidation (MAO). The paper describes the features and results of the application of such technologies and the feasibility of using this or that method for materials of different classes, and presents schemes of the corresponding installations. The result of additional hardening of the surface of U8A steel from a microhardness level of 7.2 GPa to 14.7 GPa using the ATFS method after its thermal hardening to almost the maximum possible level is shown. The microstructure of the cross-section of a prehardened specimen of U8A steel after ATFS is presented, where the degree and nature of surface hardening are reliably visible. It is emphasized that in previous studies, consistently effective hardening of steels of various classes has been achieved, even up to the level of 22 GPa in 65G steel. Regarding the method of microarc oxidation, the structure and properties of coatings on low-alloy aluminum alloys AB and AD1 formed in an alkaline-silicate electrolyte in the anode-cathode MAO mode were investigated. It is shown that the method of MAO in alkaline-silicate electrolyte allows to obtain a coating thickness of up to 300 μm, a coating growth rate of ~ 2 μm/min, and a coating hardness of 10-20 GPa. The coatings have high adhesion to the substrate; they have a layered structure. The properties of the coatings are determined by the properties of the base layer. The coatings have a crystalline structure and consist of the following phases: γ-Al2O3, α-Al2O3, mullite (3Al2O3·2SіO2), the ratio between the phases depends on the electrolysis conditions. It has been established that phase formation begins with the γ-Al2O3 phase, which in the process of further coating growth turns into the α-Al2O3 phase or interacts with silicon oxide to form the mullite phase.

Structure and High-Temperature Oxidation Performance of Si-Co Diffusion Coatings Prepared on a TiAl-Nb Alloy

Si-Co diffusion coatings were prepared on a Y-modified TiAl-Nb alloy using the pack cementation process. The structures of the coatings prepared at different temperatures (1050, 1080, and 1120 °C) and pack Co contents (5, 10, and 20 wt.%) were comparatively studied. The coatings possessed the typical structure of a (Ti,X)Si2+Ti5Si4 (X represents Nb and Al elements) outer layer with a Co-rich superficial zone, a Ti5Si4+Ti5Si3 middle layer, and a TiAl2 inner layer. Increasing the co-deposition temperature in the range of 1050–1120 °C led to a larger coating thickness but a more-porous coating structure, while increasing the pack Co contents in the range of 5–20 wt.% caused a lower coating growth rate. The formation of the Si-Co diffusion coating followed an orderly process of depositing Si first and then Co. The Si-Co diffusion coating had much better anti-oxidation performance than both the TiAl-Nb substrate and pure silicide coating. After undergoing oxidation at 1000 °C for 100 h, the oxidation parabolic rate of the Si-Co diffusion coating was approximately 6.16 × 10−3 mg2/cm4h1, which was lower than those of the TiAl-Nb substrate by about two orders of magnitude and pure silicide coating by about one order of magnitude.

Effects of H3PO4 content on the properties of plasma electrolytic fluorination coatings on AZ31 Mg alloy in ethylene glycol electrolyte

Plasma electrolytic fluorination (PEF) was performed on AZ31 Mg alloy in the ethylene glycol (EG) electrolytes containing varying quantities of H3PO4. Effects of the H3PO4 addition on the microstructure, growth behaviour and corrosion resistance of the PEF coatings were analyzed. Results revealed that after the addition of H3PO4, the plasma discharges became weaker and the crystallinity of the PEF coating was detected to decrease with the H3PO4 content. As the H3PO4 content reached 20 g/L, the PEF coating was completely transformed into an amorphous state. Beside, adding H3PO4 into the EG electrolytes increased the growth rates of the PEF coatings, and changed the growth mechanism of the PEF coatings from inward growth to mixed growth dominated by outward growth. The influence of the H3PO4 addition on the corrosion resistance of PEF coating varied with the H3PO4 content in EG electrolytes. When the H3PO4 content was 10 g/L, the PEF coating had the best corrosion resistance.

Synthesis of Polycrystalline Diamond Films in Microwave Plasma at Ultrahigh Concentrations of Methane

Polycrystalline diamond (PCD) films are usually grown by chemical vapor deposition (CVD) in hydrogen–methane mixtures. The synthesis conditions determine the structure and quality of the grown material. Here, we report the complex effect of the microwave plasma CVD conditions on the morphology, growth rate and phase composition of the resulting PCD films. Specifically, we focus on the factors of (i) increased methane concentrations (νc) that are varied over a wide range of 4%–100% (i.e., pure methane gas) and (ii) substrate temperatures (Ts) varied between 700–1050 °C. Using scanning electron microscopy, X-ray diffraction and Raman spectroscopy, we show that diamond growth is possible even at ultrahigh methane concentrations, including νc = 100%, which requires relatively low synthesis temperatures of Ts < 800 °C. In general, lower substrate temperatures tend to facilitate the formation of higher-quality PCD films; however, this comes at the cost of lower growth rates. The growth rate of PCD coatings has a non-linear trend: for samples grown at Ts = 800 °C, the growth rate increases from 0.6 µm/h at νc = 4% to 3.4 µm/h at νc = 20% and then falls to 0.6 µm/h at νc = 100%. This research is a step toward control over the nature of the CVD-grown PCD material, which is essential for the precise and flexible production of diamond for various applications.

Calculation of coating growth rate using extended magnetron spray systems

The paper considers the theoretical distribution of the substance flow sprayed by an extended magnetron into cylindrical shells and radiation from a unit of the source length to a unit of the substrate length. A computational model is presented and an expression is obtained for determining the growth rate of the coating on the shell placed on the planetary carousel. The theoretical calculation of the growth rate of the coating and the results of its experimental verification are given on the example of applying a chromium-based coating to full-size cylindrical shells by magnetron sputtering. The methodology and results of determining the possible number of technological processes of coating before the wear of the target are presented.

HfB2 coating on C/C composites prepared by chemical vapor deposition: Thermodynamics and experimental investigation

A thermodynamic calculation on the HfB2 coating prepared by chemical vapor deposition (CVD) through HfCl4-BCl3-H2-Ar system was performed, together with the relevant verification experiments. The calculation results indicated that HfB2 coating could be obtained above 900 °C with the ratios of BCl3/HfCl4 and H2/HfCl4 higher than 1 and 12, respectively. The experimental results demonstrated that the deposition temperature, H2 and BCl3 flow rates had significant effects on the grain size, growth rate and phase composition of HfB2 coatings. A dense and uniform HfB2 coating was prepared at 1150 °C with a BCl3/HfCl4 ratio of 3 and a H2/HfCl4 ratio of 20, whose mass and linear ablation rates were 15.61 mg/s and 15.58 μm/s under oxyacetylene flame.

Method for determining of growth rate of coatings condensed from arc-vacuum discharge plasma

A program for calculating of the standard deviation and the confidence interval for the particle density distribution coefficients around an ion-plasma source depending on the number of measurements is developed.

Dense VSiCN coatings deposited by filament-assisted reactive magnetron sputtering with varying amorphous phase precursor flow rates

Phase-modulated VSiCN coatings were deposited with hot filament assistance by magnetron sputtering of a vanadium target in a gas mixture of argon, nitrogen, and hexamethyldisilazane (HMDS). HMDS flow conditions and total working pressure were varied to influence coating amorphous phase content (0 at.% ≤ Si ≤ 9 at.%). Scanning electron microscopy revealed that deposition with HMDS vapor disrupted columnar growth and increased coating growth rate by as much as 27% relative to a VN 0.8 reference. Coating surface morphologies were characterized by atomic force microscopy . A transition from a nodular appearance ( R q = 8.9 nm) for the VN 0.8 coating to a pitted appearance ( R q = 2.7 nm) for the coating containing 9 at.% Si was observed. X-ray diffraction analysis and transmission electron microscopy indicated that the VSiCN coatings contained a nanocrystalline B1-VC x N y phase and an amorphous phase, whose phase fraction increased with HMDS flow. The crystallographic out-of-plane preferred orientation of the VN 0.8 coating was (220) while all VSiCN coatings were (111) textured. Coating hardness and apparent elastic modulus were measured by nanoindentation . The VSiCN coating with 3 at.% Si exhibited the highest hardness of 31.4 GPa, which was 8.8 GPa greater than the VN 0.8 coating. Coating apparent elastic modulus decreased with increasing HMDS flow from 288 GPa to 188 GPa. All coatings exhibited excellent adhesion to stainless steel substrates as evaluated by the Rockwell indentation test . The disruption of columnar growth and incorporation of Si in VSiCN coatings is a possible method of improving the high temperature wear resistance of VN-based coatings. • Deposition of dense, non-columnar VSiCN coatings is demonstrated. • Hexamethyldisilazane (HMDS) vapor is used as an amorphous phase precursor. • Granular and pitted surface topographies are obtained with R q < 3 nm. • Coating preferred orientation is (220) for the VN 0.8 reference and (111) for VSiCN. • Hardness decreases from 31 GPa to 19 GPa with increasing amorphous phase content.

Effects of current output modes on the growth kinetics and corrosion resistance of micro-arc oxidation coatings on magnesium alloy

sMicro-arc oxidation (MAO) coatings were prepared on the AZ31 Mg alloy under the constant/gradient current control modes. The effects of current output modes on the growth rate, energy consumption, microstructure, and corrosion resistance of MAO coatings were studied. The results shows that the current step-down mode (G852) exhibited a lower unit energy consumption than the constant current mode (C5) and the current step-up mode (G258), even though the same average current density current was used during MAO process. Meanwhile, the G852 is conducive to a thick and dense coating, resulting in a better corrosion resistance. The method of energy saving preparation of corrosion resistant MAO coating by adjusting the current mode is of great significance for practical production.

Enhanced Growth Rate of Chemical Vapor Deposition Diamond Coating Motivated by Graphene Oxide

To improve the growth rate of chemical vapor deposition (CVD) diamond coating, increasing the chemical reaction rate is essential. A novel method of dispersing graphene oxide (GO) particles as adsorbent on the substrate prior to deposition was proposed, with which the diamond coating with large grain size and high thickness was deposited on the silicon nitride under the normal CVD environment. The as-deposited diamond coating was characterized by scanning electron microscopy (SEM), surface profilometer, atomic force microscope (AFM), Raman spectrum, and indentation. The surface morphologies showed that the GO particles were covered by a layer of diamond coating. The diamond coating without and with GO particles had growth rates of 1.10–1.38 and 1.50–2.94 μm h−1, respectively. No differences in the Raman spectra of the microcrystalline diamond (MCD) coatings without and with GO particles were found. Indentation tests suggested that GO particles could enhance the adhesive strength and the crack resistance of diamond coating, which may result from the large thickness and the strong adsorbed capacity of destructive energy. Hence, dispersing particles on the substrate can be regarded as a potential and alternative technique by accelerating the CVD chemical reaction to obtain desired diamond coating.

CVD TiAlN coatings with tunable nanolamella architectures

In this work, Ti1-xAlxN (TiAlN) coatings were synthesized by low pressure chemical vapour deposition (LPCVD), and the influence of a rotational precursor gas supply on the coating microstructure was studied. The microstructure of the TiAlN coatings were characterized using X-ray diffraction (XRD), scanning and transmission electron microscopy (SEM and TEM), and electron backscattered diffraction (EBSD). It is shown that a rotational precursor gas supply induces an oscillatory surface reaction, which causes a nanolamella architecture. When the gas beam directly hits the sample, the local gas flow velocity is high, which increases the deposition rate of Ti and a Ti(Al)N lamella is formed. When the gas beam rotates away, the local gas velocity is low, so the deposition rate of Ti decreases, and an Al(Ti)N lamella is formed. As this is repeated a periodic nanolamella architecture is formed. The nanolamellae grow epitaxially on three {001} facets of the 111 textured grains, which leads to a pyramidal surface morphology. Without gas supply rotation, a high Al content cubic phase was still obtained, but no nanolamella was formed. This indicates that Ti-rich lamellae are not necessary to stabilize an Al-rich cubic TiAlN phase. In addition, spinodal decomposition is not likely to be the driving force behind the nanolamella formation in LPCVD TiAlN, as this would also have happened in the sample without a rotational gas supply. Finally, the nanolamella periodicity is found to be tunable via controlling the rotation speed of the precursor supply relative to the coating growth rate.

INFLUENCE OF PLASMA-ELECTROLYTIC OXIDATION PROCESS TECHNOLOGICAL PARAMETERS OF ALUMINUM ON COATING GROWTH RATE

There has been carried out an analysis of methods of oxide covering formation productivity increasing during plasma electrolytic oxidation of aluminum in electrolyte. There has been developed a technology of blank manufacturing and part strengthening by plasma electrolytic oxidation in the electrolyte, as well as the workbench has been modernized. There has been studied the process of oxidoceramic coating synthesis for the D16T aluminum deformed alloy of during plasma electrolytic oxidation in the electrolyte for different process parameters. It is established that the growth rate of oxidoceramic coating can be significantly increased by electrolyte component concentration involved in aluminum oxidation and rational choice of process electrical parameters. Hydrogen peroxide addition leads to obtained oxoceramic coating thickness increasing due to O, O2, OH, OH– concentration increasing in the electrolyte. It is established that the optimal concentration of H2O2 ranges from 5 g/l to 7 g/l. A further increase of peroxide concentration leads to a decrease in peroxide effect on oxoceramic coating growth rate on the D16T aluminum deformed alloy due to pH changes of the electrolyte and the deterioration of the oxide coating.

Influence of Hydrogen on the Synthesis of Oxide-Ceramic Coatings on Aluminum Alloys in Electrolytic Plasmas

We determine the Gibbs energies for the reactions of interaction of aluminum oxides with neutral or ionized hydrogen in plasma channels in the course of synthesis of oxide-ceramic coatings. It is shown that ionized atomic hydrogen and molecular hydrogen reduce aluminum oxides and decrease the growth rate of oxide-ceramic coatings. We propose new methods for the acceleration of the process of formation of the coatings.