Coarse Grain Research Articles

Experimental and simulation study on mechanical properties of ZK60 magnesium alloy after accumulative roll bonding

Abstract The mechanical properties of two- and four-layered wrought ZK60 Mg alloy sheets after two passes of accumulative roll bonding (ARB) with different reduction were studied and the microstructure were analyzed. The four-layered ZK60 sheets after ARB with 50% reduction demonstrate better strength-ductility combinations with yield strength of 223 MPa, ultimate tensile strength of 327 MPa, and total elongation of 23.7%, compared with the initial ZK60 of 222 MPa, 291 MPa and 10.0%, respectively. The average grain size of four-layered ARB ZK60 sheet is reduced from 21.8 μm of the initial sample to 4.4 μm. Using a micromechanical finite element model, the strain hardening behavior of ZK60 sheet was successfully predicted. The predictions were in good agreement with the experimental results. The simulation results reveals that the high performance of ZK60 sheets may be contributed by the lamella structure formed by the fine and coarse grains, which can avoid the local stress concentration and inhibit initiation and propagation of the microcracks. These findings provide a theoretical basis for the structural optimization design of ZK60 Mg alloys.

Microstructure evolution of a novel low-silicon cast aluminum alloy modified with Mn and Cr during solution treatment

The evolution of eutectic Si, the precipitation behavior of dispersoids and microhardness change of the α-Al matrix in a Mn + Cr modified Al-Si-Mg-Cu alloy during solution treatment were investigated. The results revealed that the evolution of eutectic Si was divided into four paths during solution treatment: Dissolution, splitting, spheroidization and coarsening. Meanwhile, numerous α-Al(FeMnCr)Si dispersoids were precipitated in the eutectic region and the α-Al dendrite arms after solution treatment for 30 min. Due to differences in precipitation behavior, three different dispersoid precipitation zones were formed in the dendrite arms, including the dispersoid-free zone (DFZ) near the grain boundaries, coarse dispersoid zones (CDZ) located in the dendrite cores, and the remaining fine dispersoid zones (FDZ). The bimodal size distribution of the dispersoids within intradendritic regions were closely related to the micro-segregation of Mn and Cr. The precipitation of coarse grain boundary phases exhausted the Fe solute near the grain boundary, which was mainly responsible for the formation of the DFZ. Moreover, there was a partial coherent interface between the dispersoids and the α-Al matrix. The evolution mechanism of matrix microhardness can be well explained by dispersion strengthening effect

The influence of annealing process on the sagging resistance of AA3003 foil and laminated AA4343/AA3003/AA4343 composite foil materials

Upon 98% reduction cold-rolling, a single layer AA3003 foil material of 115 μm thick was intermediately annealed at 300–420 °C/1-8 h, and the preferred temperature and time of the intermediate annealing for the laminated AA4343/AA3003/AA4343 composite foil material were determined. All of these samples were cold rolled by 40% to 70 μm thick and finally annealed at a temperature in the range of 300–550 °C for 1–9 h. Their sagging resistance and microstructure were investigated using simulated brazing treatment, optical microscopy (OM), scanning electron microscopy (SEM) and transmission electron microscopy (TEM). For the single layer AA3003 foil, the sagging distance decreased first and then increased with increasing intermediate annealing temperature, and the lowest sagging distance corresponds to the coarsest grain in the recrystallized sample. After the final annealing for the single layer, the sagging distance decreased monotonously. For the laminated foil subjected to the final annealing, the sagging distance curves decreased first and then increased with increasing annealing temperature and time. The improvement of sagging resistance was attributed to the recovery of two types of materials during annealing process. The deterioration of the sagging resistance in the laminated foils was due to the corrosion in the brazing process, resulted from the Si diffusion from the cladding layer into the core layer. It is the coarse grains, few dislocations and minimal diffusion of Si that are crucial for improving the sagging resistance of the laminated foils.

Achieving fine tailoring of elastocaloric properties of laser powder bed-fused NiTi alloy via laser beam manipulation

Laser powder bed fusion (LPBF) technology enables the development of NiTi alloys with complex geometries and tunable phase-transformation temperatures (PTTs). This technology is increasingly acknowledged as promising in the field of elastocaloric (eC) refrigeration. However, the mechanisms governing the manner in which this technology tunes the eC performance remain ambiguous. This study evaluated the fine-tuning of the eC properties by regulating Ni evaporation through laser manipulation. Our results demonstrate that although adjusting Ni loss via laser heat input can effectively control the PTTs, inappropriate combinations of laser parameters may result in lower than anticipated cooling capacity (ΔTad) and coefficient of performance (COPmat) of produced samples. An excessive heat input results in Ni evaporation and in grain coarsening through the remelting and combination of fine grains owing to overlapping molten pools. Lower Ni enhances the phase-transformation enthalpy (ΔHtr). However, larger grains increase the energy dissipation and thereby, counteracting ΔTad improvements. Theoretical analysis and experiments revealed that finer grains increase the misorientation angles. This hinders the dislocation motion and thereby, enhances the mechanical properties. Meanwhile, coarser grains can more conveniently promote PT and thereby, increase ΔHtr. Thus, based on the naturally controllable grain size heterogeneity in LPBF-manufactured NiTi alloys, we propose optimizing the eC properties by controlling the morphology of the molten pool. Thermal-history simulations could balance this relationship. Ultimately, we developed two NiTi alloys for both high-temperature (70 °C) and room-temperature (25 °C) refrigeration. This study has provided effective insights for customizing high-performance eC components such as multistage caloric cascade regenerators, using additive manufacturing.

Microstructural and mechanical characterizations of weld metal of S960QL ultra high strength steel joints obtained with different multi-pass laying techniques using GMAW

Abstract 15 mm thick ultra-high strength steel plates with 960MPa yield strength were welded using different multi-pass laying techniques (i.e., stringer and weaving beads) with torch manipulation. Weld metals obtained were compared using different mechanical (i.e., micro tensile tests and Vickers hardness maps) and microstructural (i.e., optical microscope, scanning electron microscope, X-ray diffraction, electron backscatter diffraction) characterization techniques. Coarser grains and acicular ferrite were observed in weld metal obtained with weaving pass procedure. There were hardness differences in face and root passes of both weld metals. Yet, hardness values were 19% and 11% higher for face and root regions of the joint obtained by stringer pass procedure, respectively. Fractographs of micro tensile test specimens revealed dimples depicting ductile network structure for both joints.

Formation mechanism of edge crack during hot rolling process of high-grade non-oriented electrical steel

Edge crack formed during the hot rolling process significantly affected the quality of high-grade non-oriented electrical steel (NOES), posing substantial challenges to production. This study investigated the formation mechanism of serrated edge cracks in hot rolled strip, characterized by unusually coarse strip-like grains with typical thicknesses ranging from 0.5 to 0.8 mm and lengths ranging from 10 to 15 mm. These coarse strip-like grains evolved from abnormal columnar grains at the edges of reheating slab. During the continuous casting process, the bulge phenomenon occurred easily in high-grade NOES slabs, due to its lower yield strength at high temperatures. This bulge induced high internal stress at the slab edge, leading to abnormal growth of the columnar grains during the slab reheating process at high temperature. The orientation of coarse grains gradually changed to a rotated cube texture ({100}<011>) throughout the hot rolling process. These grains with rotated cube texture exhibited fewer slip systems and lower deformation storage energy, which is not conducive to the plastic deformation in thickness direction. Consequently, coarse grains at the slab edge deformed along TD direction and overflowed towards the lower surface of hot rolled strip, resulting in the original edge boundary enveloped by the overflowed metal to generate crack source. Finally, the serrated edge crack was formed from crack source under tensile stress during finish hot rolling.

Effect of filler wires on microstructure and mechanical properties of Inconel 718 welded joints by double pulse metal inert gas welding

ABSTRACT Inconel 718 possesses issues like microsegregation of Nb, Mo leads to the formation of Laves phase which degrades the mechanical properties of the welded joints. This study aims to investigate the mechanical properties and microstructural characteristics of Inconel 718 welded joints using the double pulse metal inert gas (DP-MIG) process by the combined effect of filler wires, such as ERNiFeCr-2, ERNiCrCoMo-1, and 9Cr-1Mo. All the weldments were found to have columnar dendrites with coarser grain morphology. Liquated grain boundaries, secondary phases, unmixed zones at the heat affected zone (HAZ) and segregation of Nb (21.3%) and Mo (10.4%) at the weld zone were identified for ERNiFeCr-2 and ERNiCrCoMo-1 fillers. From EBSD findings, the formation of peninsula and island at the HAZ and segregation of Fe (68%) in the weld zone of 9Cr-1Mo filler weldment was noticed. Even though the ultimate tensile strength (UTS) of all the weldments was found to be inferior to that of base metal (788.9MPa), the 9Cr-1Mo filler weldment shows better tensile strength of 403.5MPa with a joint efficiency of (51.14%). From the fractography results, the void formation due to secondary phases along with dimple networks ensures the ductility mode of fracture for all the weldments.

Surface mechanical rolling treatment-introduced gradient nanostructured Inconel 625 alloy with enhanced high-temperature wear resistance

Heterogeneous gradient nanostructures induced through surface treatment of nickel-based superalloys hold significant promise for enhancing wear resistance. In this study, a 700 µm ultra-thick gradient nanostructured (GNS) strengthening layer was fabricated on the surface of an Inconel 625 alloy plate via surface mechanical rolling treatment (SMRT). Subsequently, the tribological behaviors and wear resistance mechanisms of coarse-grained (CG) and GNS samples at temperatures ranging from 25 ℃ to 800 ℃ were comparatively investigated. The results indicated that the gradient nanostructures significantly enhanced the high-temperature wear resistance of the samples, which wear characterized by low coefficient of friction (COF), wear rate and thin friction layer. This enhancement was attributable to the stability and excellent hot hardness of the gradient nanostructures during friction.

Induction assisted autogenous plasma arc welding of HSLA steel

In this work, a high frequency induction heating (HFIH) assisted plasma arc welding (IPAW) technique is proposed to weld 6 mm thick S690QL high strength low alloy steel plates in square butt joint configuration and without using any filler material. A 3D finite element based coupled electromagnetic-thermal analysis is carried out to ascertain the weld's thermal characteristics. Microstructure evolution and mechanical performance are investigated using scanning electron microscopy, electron back scattered diffraction, transmission electron microscopy, tensile test, Charpy impact test and micro hardness test. The results demonstrate that 15 s initial static heating using a co-directional current coil with magnetic flux concentrator predominantly improves the weld penetration by 48 % and joint efficiency reaches 90 % to the base plate strength. Microstructural study shows that the addition of HFIH promotes low angle grain boundaries (LAGB) with bainite ferrite and granular bainite micro-constituents in the fusion zone, which causes localised yielding and failure in this zone during tensile test. Further investigation reveals that the HFIH encourages the formation of BI-type bainite ferrite laths of 1.3–2.2 μm width, combined with slender martensite-austenite (M-A) island at the bainite ferrite lath boundaries. The results also reveal that the induction heating promotes the formation of M23C6 precipitates and B2 structured Cu-enrich nano precipitates in the fusion zone (FZ). The microhardness distribution indicates that the FZ and coarse grain heat affected zone are significantly reduced due to the assistance of the HFIH. The impact test result shows a lower energy absorption by the IPAW weldments due to dominance of the LAGB with unfavourable strain distribution.

Competition between microstructural factors affecting growth of abnormally large grains in thin Cu foils

Grain boundary types and local boundary curvatures are generally considered to be important microstructural factors controlling grain boundary migration during grain growth. In this work, grain growth in thin copper foils is studied during annealing at a temperature of 1040 °C near the melting point by ex-situ experiments and Monte Carlo simulations. Few grains, stimulated by slight deformation at the sample edge, are observed to grow abnormally into the cube-oriented recrystallized microstructure with columnar grains spanning the foil thickness. The grain boundaries of these abnormally growing grains and the grain sizes in the adjacent polycrystalline recrystallized regions are analyzed. The experimental results suggest that spatial heterogeneities in the distribution of small recrystallized grains have a significant effect on the migrating boundaries. Potts model simulations confirm that grain boundary segments with small grains in front are more likely to migrate than segments facing coarser grains. The simulations also demonstrate the importance of grain morphology. Altogether, this work highlights the effects of a heterogeneous recrystallized microstructure on abnormal grain growth in thin foil samples.

An investigation of the microstructure and properties of rolled W-Al2O3 alloy

Pure tungsten and tungsten alloys have been widely used in metallurgy, energy, chemical industry, aerospace, national defense, electronics and other fields. However, there are inevitably some problems in the use of the process, such as high deformation resistance in the forming process prone to crack and fracture, coarse grain and low bending strength problems. Al2O3 particles were added to improve the comprehensive properties of tungsten alloys. In this paper, the W-0.2 wt%Al2O3 tungsten alloy sheets with different thicknesses of 3 mm, 2 mm, and 1 mm were prepared by induction sintering combined with hot rolling. For comparison, the pure tungsten sheet with a thickness of 3 mm was fabricated by the same preparation process. Comparative assessments were made on the microstructure, hardness, and three-point bending properties across types of three thicknesses of W-Al2O3 sheets and pure tungsten sheet with a thickness of 3 mm. The outcomes demonstrate that the microstructure and properties of the tungsten alloy vary considerably depending on the applied rolling degree, which exerts a profound impact on the grain size, morphology, and distribution within the tungsten alloy matrix. Furthermore, the tungsten alloy consistently exhibits significant enhancements over pure tungsten. Characterization of the rolled tungsten alloy revealed that the incorporation of alumina contributes to a reduction in shear band formation and an improvement in texture strength, thereby substantiating its positive impact on the overall mechanical properties of the alloy.

Effect of Extrusion Ratio on Mechanical Behavior and Microstructure Evolution of 7003 Aluminum Alloy at High-Speed Impact.

The extrusion ratio (ER) is one of the most important factors affecting the service performance of aluminum profiles. In this study, the influence of ER on the mechanical behavior and microstructure evolution of 7003 aluminum alloy at high-speed impact with strain rates ranging from 700 s-1 to 1100 s-1 was investigated. The studied alloy with an ER of 56 formed coarse grain rings during the heat treatment. The microstructure of the alloys with ERs of 20 and 9 is relatively uniform. The results indicate that under high-speed impact, the mechanical response behavior of the 7003-T6 alloy with different ERs is different. For the alloy with an ER of 56, strain hardening is the main mechanism of plastic deformation. In contrast, a flow stress reduction occurs at middle deformation stage for the ones with ERs of 20 and 9 due to concentrated deformation, which is more significant in the alloy with an ER of 20. Under high-speed impact, the alloy with an ER of 56 undergoes uneven plastic deformation due to the presence of coarse grain rings. The deformation is mainly borne by the region of coarse grains near the edge, and the closer to the center, the smaller the deformation. The deformation of the alloys with ERs of 20 and 9 is relatively uniform, but exhibits localized concentrated deformation in the area near the edge. The significant plastic deformation within deformation band causes a local temperature rise, resulting in a slight decrease in flow stress after the peak. These results can provide reliable data support for the application of 7003 aluminum alloy in the vehicle body crash energy absorption structure.

Gravel-inlaid mud clasts as indicators of transport processes of subaqueous sediment gravity-flows

Much sedimentological research aims to understand the depositional processes by establishing the relationship between the transport processes of subaqueous sediment gravity flows (SSGFs) and the characteristics of their deposits. A distinctive type of gravel-inlaid mud clasts, which has been largely overlooked, is embedded with occasional granules or pebbles, and exhibits various angular shapes that are present in cores of SSGF deposits worldwide. SSGF deposits from four cored wells in the Liushagang Formation of the Weixi'nan depression, China, have been analyzed to explore the characteristics, distribution, and potential formation mechanisms of gravel-inlaid mud clasts, thereby revealing the transport processes of SSGFs. In the research area, SSGF deposits are dominated by gravelly high-density turbidites, sandy high-density turbidites, low-density turbidites, and hybrid event beds. Gravel-inlaid mud clasts are common in massive sandstones and bipartite or tripartite beds, exhibiting various distribution patterns. The erosional contact at the base of these beds, where coarse grains are partially embedded within the muddy substrate, indicates that gravel-inlaid mud clasts originate through processes of erosion and delamination. Their distribution from the lower to the upper part of massive sandstones and bipartite or tripartite beds suggests a floating process from base to top. The formation and distribution of gravel-inlaid mud clasts demonstrate the downflow transformation from high-density turbidity currents to low-strength debris flows, driven by the erosion of the underlying muddy substrate, ultimately resulting in the formation of hybrid event beds. The lofting of gravel-inlaid mud clasts increases the cohesion of the upper part of the high-density turbidity current, facilitating its transformation into a low-strength debris flow. Furthermore, the occurrence of gravel-inlaid mud clasts within massive sandstones clearly demonstrates that they are products of high-density turbidity currents rather than sandy debris flows. The identification of gravel-inlaid mud clasts and their distribution within deep-water deposits can be regarded as a reliable indicator for reconstructing SSGF transport processes from high-density turbidity currents to low-strength debris flows, ultimately transitioning into low-density turbidity currents.

Grain refinement of Fe4N compound layer in nitrided steel

This study elucidated the microstructure of the Fe4N (γ’) compound layer in specimens subjected to the nitriding to the specimens with various finished surfaces. Gyrofinishing produces a specimen surface with an ultra-fine-grained (UFGed) structure and a rough surface, whereas the buff-finished specimen exhibited a coarse grain but smooth surface. The γ’ grains formed on the gyrofinished specimens after nitriding were considerably finer and more equiaxial compared with those on the buff-finished specimen. The γ’ nucleated from the grain boundary in the matrix, indicating that the grain boundaries act as a nucleation site. Therefore, the UFGed structure promotes the nucleation of γ’ during the nitriding, resulting in fine grains. Numerous pores were formed in the γ’ layer of the gyrofinished specimen owing to the rough surface. The UFGed structure and surface roughness before nitriding are key factors for controlling the microstructure in the γ’ compound layer.

Enhancing mechanical properties of medium Mn steel by warm rolling based on laminated elemental segregation

The hot-rolled microstructure of medium Mn steel has coarse grains and severe elemental segregation, resulting in low strength and plasticity. Constructing a multiphase structure, refining the microstructure, and regulating elemental segregation enhance the mechanical properties. In this study, liquid nitrogen treatment created a layered distribution of austenite and martensite. Warm rolling was then used to reduce layer thickness and refine grain structure. After liquid nitrogen and warm rolling treatments, the strength and plasticity of medium Mn steel increased to 1270 MPa and 23.3%, respectively, far exceeding the hot-rolled state (724 MPa, 12.8%). Warm rolling also triggers austenite reverted transformation (ART) and introduces high-density dislocations, further improving austenite stability. This strengthening effect is higher than that from intercritical annealing alone. Improved austenite stability delays the transformation induced plasticity (TRIP) effect, preventing brittle fracture and enhancing deformation coordination between layers, significantly increasing the plastic deformation capacity of medium Mn steel.

On the plastic deformation mechanism of Al0.6CoCrFeNi high entropy alloy: In-situ EBSD study and crystal plasticity modeling

In this study, in-situ tensile tests with electron back-scattered diffraction (EBSD) were conducted to reveal the microstructural effects on the plastic deformation behavior of dual-phase Al0.6CoCrFeNi high entropy alloys (HEAs). The in-situ EBSD results demonstrated a uniform distribution of dislocation density in the fine grain (FG) samples, whereas high dislocation density was predominantly localized near body-centered cubic (BCC) phases in the coarse grain (CG) samples. The difference in mechanical properties between face-centered cubic (FCC) and BCC phases caused stress concentration and cracking at the boundaries during tension. The FCC phase within FG samples exhibited excellent plasticity, effectively impeding the propagation and coalescence of microcracks emanating from the BCC phase into longer cracks. For CG samples, brittle cracks formed in BCC phases are easy to merge, thus evolving into long cracks. Crystal plasticity finite element analysis revealed that as the strain increases, stress distribution in FG samples tended to become more homogeneous, whereas for CG samples high stress concentration consistently occurred within BCC phases. The deformation characteristics of FG were attributed to the synergistic effect generated by the FCC phase with heterogeneous grain size and the BCC phase characterized by small grain size.

Effect of High Deformation without Preheating on Microstructure and Corrosion of Pure Mg

In this study, the relationship between the extrusion ratio and the corrosion resistance of pure Mg deformed using extrusion with an oscillating die (KoBo) without preheating of the initial billet was investigated. The materials investigated in this study were extruded at high deformation ratios, R1 5:1, R2 7:1, and R3 10:1, resulting in significant grain refinement from the very coarse grains formed in the initial billet to a few µm in the KoBo-extruded samples at room temperature, which is not typical for hexagonal structures. Our research clearly shows that KoBo extrusion improves the corrosion performance of pure Mg, but there is no straightforward dependence between the extrusion ratios and corrosion resistance improvement. Although it was expected that the smallest grain size should provide the highest corrosion resistance, the dislocation density accumulated in the grain interiors during deformation at the highest extrusion ratio, R3 10:1, supports dissolution reactions. This, in turn, provides the answers for the greater grain size observed after deformation at R2 7:1, where dynamic recovery prevailed over dynamic recrystallization. This situation led to the annihilation of dislocation, leading to better corrosion resistance of the respective alloy. Therefore, the alloy with the greatest grain size has the best corrosion resistance.

Source of plastic contamination of the rivers ending to the Gorgan Bay, southeast of the Caspian Sea, Iran

The widespread presence of microplastics (MPs) in freshwater systems as an emerging environmental pollutant has caused a global environmental problem. The present study investigates the distribution and abundance of source pathway and abundance of microplastics in surface sediment samples from rivers discharging into the Gorgan Bay, southeast of the Caspian Sea. A total of 57 surface sediment samples were taken from 19 stations to investigate the potential hot spots of pollution in the four rivers leading to the Gorgan Bay. The average level of microplastics was 333 ± 268 particles/kg. The highest amount is in the estuary of the Qarasu River (1080 ± 380 particles/kg) due to the accumulation of fishing, boating and tourism activities and the lowest amount in the forest area (80 ± 19 particles/kg) in the Klak River. The most common type of microplastic was fiber (68%). Microplastic pollution in the studied rivers is mostly black and gray (75.39%), and about 53% of them were sized less than 1000 μm. Spectroscopic analysis (Fourier Transform Infrared (FT-IR) of the MP showed that 37% were polyethylene, polyethylene (37%) and polypropylene (27%) were the dominating groups. The sediments’ size was significantly correlated (p&amp;gt;0.05) with the presence of microplastics. Sediments with a coarse grain (sand) demonstrated a great potential to store microplastics. The results of this study can be used for the management and protection policies of Gorgan Bay.

Spontaneous Dimerization and Distinct Packing Modes of Transmembrane Domains in Receptor Tyrosine Kinases.

The insulin receptor (IR) and the insulin-like growth factor-1 receptor (IGF1R) are homodimeric transmembrane glycoproteins that transduce signals across the membrane on binding of extracellular peptide ligands. The structures of IR/IGF1R fragments in apo and liganded states have revealed that the extracellular subunits of these receptors adopt Λ-shaped configurations to which are connected the intracellular tyrosine kinase (TK) domains. The binding of peptide ligands induces structural transitions in the extracellular subunits leading to potential dimerization of transmembrane domains (TMDs) and autophosphorylation in TKs. However, the activation mechanisms of IR/IGF1R, especially the role of TMDs in coordinating signal-inducing structural transitions, remain poorly understood, in part due to the lack of structures of full-length receptors in apo or liganded states. While atomistic simulations of IR/IGF1R TMDs showed that these domains can dimerize in single component membranes, spontaneous unbiased dimerization in a plasma membrane having physiologically representative lipid composition has not been observed. We address this limitation by employing coarse-grained (CG) molecular dynamics simulations to probe the dimerization propensity of IR/IGF1R TMDs. We observed that TMDs in both receptors spontaneously dimerized independent of their initial orientations in their dissociated states, signifying their natural propensity for dimerization. In the dimeric state, IR TMDs predominantly adopted X-shaped configurations with asymmetric helical packing and significant tilt relative to the membrane normal, while IGF1R TMDs adopted symmetric V-shaped or parallel configurations with either no tilt or a small tilt relative to the membrane normal. Our results suggest that IR/IGF1R TMDs spontaneously dimerize and adopt distinct dimerized configurations.

A Coarse-Grained SPICA Makeover for Solvated and Bare Sodium and Chloride Ions.

Aqueous ionic solutions are pivotal in various scientific domains due to their natural prevalence and vital roles in biological and chemical processes. Molecular dynamics has emerged as an effective methodology for studying the dynamic behavior of these systems. While all-atomistic models have made significant strides in accurately representing and simulating these ions, the challenge persists in achieving precise models for coarse-grained (CG) simulations. Our study introduces two optimized models for sodium and chloride ions within the nonpolarizable surface property fitting coarse-grained force field (SPICA-FF) framework. The two models represent solvated ions, such as the original FF model, and unsolvated or bare ions. The nonbonded Lennard-Jones interactions were reparameterized to faithfully reproduce bulk properties, including density and surface tension, in sodium chloride solutions at varying concentrations. Notably, these optimized models replicate experimental surface tensions at high ionic strengths, a property not well-captured by the ions of the original model in the SPICA-FF. The optimized unsolvated model also proved successful in reproducing experimental osmotic pressure. Additionally, the newly reparameterized ion models capture hydrophobic interactions within sodium chloride solutions and show qualitative agreement when modeling structural changes in phospholipid bilayers, aligning with experimental observations. For aqueous solutions, these optimized models promise a more precise representation of the ion behavior.